Zep 85624 User Manual

SAFETY DATA SHEET

ZEP MORADO SUPER CLEANER 4-1GL

Version 4.1

Revision Date 06/26/2018

Print Date 11/07/2018

Material name

:

ZEP MORADO SUPER CLEANER 4-1GL
Material number

:

000000000000085624

Company

:

Zep Inc.

Address

:

350 Joe Frank Harris Parkway, SE
Emerson, GA 30137
Telephone

:

404-352-1680

Emergency telephone numbers

For SDS Information

:

Compliance Services 1-877-428-9937

For a Medical Emergency

:

877-541-2016 Toll Free - All Calls Recorded

For a Transportation
Emergency

:

CHEMTREC: 800-424-9300 - All Calls Recorded.
In the District of Columbia 202-483-7616

Recommended use

:

Cleaner
Appearance

liquid

Colour

purple

Odour

ether-like

Skin corrosion

:

Category 1

Serious eye damage

:

Category 1

Hazard pictograms

:

Signal word

:

Danger

Hazard statements

:

H314 Causes severe skin burns and eye damage.

Precautionary statements

:

Prevention:
P264 Wash skin thoroughly after handling.
P280 Wear protective gloves/ protective clothing/ eye
protection/ face protection.

Response:

P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT
induce vomiting.

SECTION 1. PRODUCT AND COMPANY IDENTIFICATION

Manufacturer or supplier's details

Recommended use of the chemical and restrictions on use

SECTION 2. HAZARDS IDENTIFICATION

Emergency Overview

GHS Classification

GHS label elements

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SAFETY DATA SHEET

ZEP MORADO SUPER CLEANER 4-1GL

Version 4.1

Revision Date 06/26/2018

Print Date 11/07/2018

P303 + P361 + P353 IF ON SKIN (or hair): Take off
immediately all contaminated clothing. Rinse skin with
water/shower.
P304 + P340 + P310 IF INHALED: Remove person to fresh air
and keep comfortable for breathing. Immediately call a
POISON CENTER/doctor.
P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with
water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. Immediately call a POISON
CENTER/doctor.
P363 Wash contaminated clothing before reuse.
Disposal:
P501 Dispose of contents/container in accordance with local
regulation.
Substance / Mixture

:

Mixture

Chemical name

CAS-No.

Concentration [%]

Alcohols, C9-11, ethoxylated

68439-46-3

>= 1 - < 5

2-butoxyethanol

111-76-2

>= 1 - < 5

sodium hydroxide

1310-73-2

>= 1 - < 5

Fatty acids, tall-oil, sodium salts

61790-45-2

>= 1 - < 5

General advice

:

Move out of dangerous area.
Show this safety data sheet to the doctor in attendance.
Do not leave the victim unattended.
Get medical attention immediately.

If inhaled

:

If unconscious, place in recovery position and seek medical
advice.
If symptoms persist, call a physician.

In case of skin contact

:

Immediate medical treatment is necessary as untreated
wounds from corrosion of the skin heal slowly and with
difficulty.
Wash off immediately with plenty of water for at least 15
minutes.
If skin irritation persists, call a physician.
Remove contaminated clothing and shoes.
Wash contaminated clothing before reuse.

In case of eye contact

:

Small amounts splashed into eyes can cause irreversible
tissue damage and blindness.
Rinse immediately with plenty of water, also under the eyelids,
for at least 15 minutes.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Hazardous components

The exact percentages of disclosed substances are withheld as trade secrets.

SECTION 4. FIRST AID MEASURES

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SAFETY DATA SHEET

ZEP MORADO SUPER CLEANER 4-1GL

Version 4.1

Revision Date 06/26/2018

Print Date 11/07/2018

Continue rinsing eyes during transport to hospital.
Remove contact lenses.
Protect unharmed eye.
Keep eye wide open while rinsing.
If eye irritation persists, consult a specialist.

If swallowed

:

Keep respiratory tract clear.
Never give anything by mouth to an unconscious person.
DO NOT induce vomiting unless directed to do so by a
physician or poison control center.
Take victim immediately to hospital.
Do not give milk or alcoholic beverages.

Most important symptoms
and effects, both acute and
delayed

:

Effects are immediate and delayed.
Symptoms may include blistering, irritation, burns, and pain.
Effects are dependent on exposure (dose, concentration,
contact time).
Causes severe skin burns and eye damage.
Review section 2 of SDS to see all potential hazards.

Notes to physician

:

Treat symptomatically. Symptoms may be delayed.

Suitable extinguishing media

:

Dry chemical
Water spray jet
Alcohol-resistant foam
Carbon dioxide (CO2)

Unsuitable extinguishing
media

:

High volume water jet

Specific hazards during
firefighting

:

Do not allow run-off from fire fighting to enter drains or water
courses.

Hazardous combustion
products

:

Carbon dioxide (CO2)
Carbon monoxide
Smoke

Specific extinguishing
methods

:

Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.

Further information

:

Collect contaminated fire extinguishing water separately. This
must not be discharged into drains.
Fire residues and contaminated fire extinguishing water must
be disposed of in accordance with local regulations.
Standard procedure for chemical fires.

Special protective equipment
for firefighters

:

Wear self-contained breathing apparatus for firefighting if
necessary.
Personal precautions,

:

Use personal protective equipment.

SECTION 5. FIREFIGHTING MEASURES

SECTION 6. ACCIDENTAL RELEASE MEASURES

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SAFETY DATA SHEET

ZEP MORADO SUPER CLEANER 4-1GL

Version 4.1

Revision Date 06/26/2018

Print Date 11/07/2018

protective equipment and
emergency procedures

Environmental precautions

:

Prevent product from entering drains.
Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains inform
respective authorities.

Methods and materials for
containment and cleaning up

:

Soak up with inert absorbent material (e.g. sand, silica gel,
acid binder, universal binder, sawdust).
Keep in suitable, closed containers for disposal.

Advice on safe handling

:

Avoid exposure - obtain special instructions before use.
Avoid contact with skin and eyes.
For personal protection see section 8.
Smoking, eating and drinking should be prohibited in the
application area.
Do not breathe vapours or spray mist.
Take precautionary measures against static discharges.
Provide sufficient air exchange and/or exhaust in work rooms.
Dispose of rinse water in accordance with local and national
regulations.

Conditions for safe storage

:

Keep container tightly closed in a dry and well-ventilated
place.
Observe label precautions.
Electrical installations / working materials must comply with
the technological safety standards.

Materials to avoid

:

Store and keep away from, oxidizing agents and acids.

Components

CAS-No.

Value type
(Form of
exposure)

Control
parameters /
Permissible
concentration

Basis

2-butoxyethanol

111-76-2

TWA

20 ppm

ACGIH

TWA

5 ppm
24 mg/m3

NIOSH REL

TWA

50 ppm
240 mg/m3

OSHA Z-1

TWA

25 ppm
120 mg/m3

OSHA P0

PEL

20 ppm
97 mg/m3

CAL PEL
sodium hydroxide

1310-73-2

C

2 mg/m3

ACGIH

C

2 mg/m3

NIOSH REL

TWA

2 mg/m3

OSHA Z-1

C

2 mg/m3

OSHA P0

SECTION 7. HANDLING AND STORAGE

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Components with workplace control parameters

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SAFETY DATA SHEET

ZEP MORADO SUPER CLEANER 4-1GL

Version 4.1

Revision Date 06/26/2018

Print Date 11/07/2018

C

2 mg/m3

CAL PEL

Component

CAS-No.

Control

parameters

Biological
specimen

Sampling

time

Permissible

concentration

Basis

2-BUTOXYETHANOL

111-76-2

Butoxyacetic
acid (BAA)

Urine

End of

shift (As

soon as

possible

after

exposure

ceases)

200.mg/g
Creatinine

ACGIH BEI

Engineering measures

:

effective ventilation in all processing areas

Respiratory protection

:

Use respiratory protection unless adequate local exhaust
ventilation is provided or exposure assessment demonstrates
that exposures are within recommended exposure guidelines.
Material

:

Protective gloves

Remarks

:

The suitability for a specific workplace should be discussed
with the producers of the protective gloves.

Eye protection

:

Access to clean water to rinse eyes must be available, options
include: eye wash stations or showers, or eye wash bottles
with pure water.
Tightly fitting safety goggles
Wear face-shield and protective suit for abnormal processing
problems.

Skin and body protection

:

Impervious clothing
Choose body protection according to the amount and
concentration of the dangerous substance at the work place.

Hygiene measures

:

When using do not eat or drink.
When using do not smoke.
Wash hands before breaks and at the end of workday.

Appearance

:

liquid

Colour

:

purple

Odour

:

ether-like

Odour Threshold

:

No data available

pH : 13.5

Melting point/freezing point

:

No data available

Biological occupational exposure limits

Personal protective equipment

Hand protection

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

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SAFETY DATA SHEET

ZEP MORADO SUPER CLEANER 4-1GL

Version 4.1

Revision Date 06/26/2018

Print Date 11/07/2018

Boiling point

:

98.9 °C

Flash point

:

does not flash

Evaporation rate

:

1

Upper explosion limit

:

No data available

Lower explosion limit

:

No data available

Vapour pressure

:

not determined

Relative vapour density

:

No data available

Density

:

1.029 g/cm3

Water solubility

:

soluble

Solubility in other solvents

:

not determined

Partition coefficient: n­octanol/water

:

No data available

Auto-ignition temperature

:

not determined

Thermal decomposition

:

No data available

Viscosity, kinematic

:

6.6 mm2/s (20 °C)
Reactivity

:

Stable

Chemical stability

:

Stable under normal conditions.

Possibility of hazardous
reactions

:

No decomposition if stored and applied as directed.

Conditions to avoid

:

Heat, flames and sparks.

Incompatible materials

:

Acids
Oxidizing agents
This product contains sodium hydroxide or potassium
hydroxide that may corrode some soft metals and may react
with tin, zinc, aluminum to form hydrogen gas.

Hazardous decomposition
products

:

Carbon monoxide, carbon dioxide and unburned
hydrocarbons (smoke).

Solubility(ies)

Viscosity

SECTION 10. STABILITY AND REACTIVITY

SECTION 11. TOXICOLOGICAL INFORMATION

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SAFETY DATA SHEET

ZEP MORADO SUPER CLEANER 4-1GL

Version 4.1

Revision Date 06/26/2018

Print Date 11/07/2018

Aggravated Medical
Condition

:

None known.

Symptoms of Overexposure

:

Effects are immediate and delayed.
Symptoms may include blistering, irritation, burns, and pain.
Effects are dependent on exposure (dose, concentration,
contact time).

IARC

No component of this product present at levels greater than or
equal to 0.1% is identified as probable, possible or confirmed
human carcinogen by IARC.

ACGIH

Confirmed animal carcinogen with unknown relevance to
humans

2-butoxyethanol

111-76-2

OSHA

No component of this product present at levels greater than or
equal to 0.1% is on OSHA’s list of regulated carcinogens.

NTP

No component of this product present at levels greater than or
equal to 0.1% is identified as a known or anticipated carcinogen
by NTP.

Acute oral toxicity

:

Acute toxicity estimate : > 5,000 mg/kg
Method: Calculation method

Acute inhalation toxicity

:

Acute toxicity estimate : > 200 mg/l
Exposure time: 4 h
Test atmosphere: vapour
Method: Calculation method

Acute dermal toxicity

:

Acute toxicity estimate : > 5,000 mg/kg
Method: Calculation method

Acute oral toxicity

:

LD50 Oral Rat: 1,400 mg/kg

Acute oral toxicity

:

LD50 Oral Rat: 880 mg/kg

Acute dermal toxicity

:

LD50 Dermal Rabbit: 1,060 mg/kg

Acute dermal toxicity

:

Acute toxicity estimate Rabbit: 1,350 mg/kg

Potential Health Effects

Carcinogenicity:

Acute toxicity

Product:

Components:
Alcohols, C9-11, ethoxylated:

2-butoxyethanol:

sodium hydroxide:

Skin corrosion/irritation

Product:

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SAFETY DATA SHEET

ZEP MORADO SUPER CLEANER 4-1GL

Version 4.1

Revision Date 06/26/2018

Print Date 11/07/2018

Remarks: Extremely corrosive and destructive to tissue.

Remarks: May cause irreversible eye damage.

Remarks: No data available

Partition coefficient: n­octanol/water

:

Remarks: No data available

Serious eye damage/eye irritation

Product:

Respiratory or skin sensitisation

No data available

Germ cell mutagenicity

No data available

Carcinogenicity

No data available

Reproductive toxicity

No data available

STOT - single exposure

No data available

STOT - repeated exposure

No data available

Aspiration toxicity

No data available

Further information

Product:

SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity

No data available

Persistence and degradability

No data available

Bioaccumulative potential

Product:

Mobility in soil

No data available

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SAFETY DATA SHEET

ZEP MORADO SUPER CLEANER 4-1GL

Version 4.1

Revision Date 06/26/2018

Print Date 11/07/2018

Regulation

40 CFR Protection of Environment; Part 82 Protection of
Stratospheric Ozone - CAA Section 602 Class I
Substances

Remarks

This product neither contains, nor was manufactured
with a Class I or Class II ODS as defined by the U.S.
Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A
+ B).

Additional ecological
information

:

Not applicable

Waste from residues

:

Do not dispose of waste into sewer.
Do not contaminate ponds, waterways or ditches with
chemical or used container.
Dispose of in accordance with local regulations.

Contaminated packaging

:

Empty remaining contents.
Dispose of as unused product.
Do not re-use empty containers.

Transportation Regulation: 49 CFR (USA):
UN3266, Corrosive liquid, basic, inorganic, n.o.s., (SODIUM HYDROXIDE), 8, II

Transportation Regulation: IMDG (Vessel):
UN3266, CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S., (SODIUM HYDROXIDE), 8, II

Transportation Regulation: IATA (Cargo Air):
UN3266, Corrosive liquid, basic, inorganic, n.o.s., (SODIUM HYDROXIDE), 8, II

Transportation Regulation: IATA (Passenger Air):
UN3266, Corrosive liquid, basic, inorganic, n.o.s., (SODIUM HYDROXIDE), 8, II

Transportation Regulation: TDG (Canada):
UN3266, CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S., (SODIUM HYDROXIDE), 8, II

Other adverse effects

No data available

Product:

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods

SECTION 14. TRANSPORT INFORMATION

The product as delivered to the customer conforms to packaging requirements for shipment by road
under US Department of Transportation (DOT) regulations. Additional transportation classifications
noted above are for reference only, and not a certification or warranty of the suitability of the packaging
for shipment under these alternative transport regulations.

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SAFETY DATA SHEET

ZEP MORADO SUPER CLEANER 4-1GL

Version 4.1

Revision Date 06/26/2018

Print Date 11/07/2018

TSCA list

:

No substances are subject to a Significant New Use Rule.

No substances are subject to TSCA 12(b) export notification
requirements.

Components

CAS-No.

Component RQ

(lbs)

Calculated product RQ

(lbs)

sodium hydroxide

1310-73-2

1000

*

SARA 311/312 Hazards

:

Skin corrosion or irritation
Serious eye damage or eye irritation

SARA 302

:

No chemicals in this material are subject to the reporting
requirements of SARA Title III, Section 302.

SARA 313

:

The following components are subject to reporting levels
established by SARA Title III, Section 313:

2-butoxyethanol

111-76-2

3.4 %

This product does not contain any chemicals known to State of

California to cause cancer, birth defects, or any other
reproductive harm.

DSL

All components of this product are on the Canadian DSL

TSCA

On TSCA Inventory

SECTION 15. REGULATORY INFORMATION

EPCRA - Emergency Planning and Community Right-to-Know Act

CERCLA Reportable Quantity

*: Calculated RQ exceeds reasonably attainable upper limit.

SARA 304 Extremely Hazardous Substances Reportable Quantity

This material does not contain any components with a section 304 EHS RQ.

California Prop. 65

The components of this product are reported in the following inventories:

For information on the country notification status for other regions please contact the

manufacturer’s regulatory group.

Inventory Acronym and Validity Area Legend:

TSCA (USA), DSL (Canada), NDSL (Canada)

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SAFETY DATA SHEET

ZEP MORADO SUPER CLEANER 4-1GL

Version 4.1

Revision Date 06/26/2018

Print Date 11/07/2018

NFPA:

HMIS III:

Hazard pictograms

:

Signal word

:

Danger:

Hazard statements

:

Causes severe skin burns and eye damage.

Precautionary statements

:

Prevention: Wash skin thoroughly after handling. Wear protective gloves/ protective
clothing/ eye protection/ face protection.
Response: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or
hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. IF
INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately
call a POISON CENTER/doctor. IF IN EYES: Rinse cautiously with water for several
minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Immediately call a POISON CENTER/doctor. Wash contaminated clothing before
reuse.

Disposal: Dispose of contents/container in accordance with local regulation.

Version:

4.1

Revision Date:

06/26/2018

Print Date:

11/07/2018

Flammability

Health

Instability

3

1

0

Special hazard.

FLAMMABILITY

PHYSICAL HAZARD

HEALTH

1

0

3

0 = not significant, 1 =Slight,
2 = Moderate, 3 = High
4 = Extreme, * = Chronic

SECTION 16. OTHER INFORMATION

Further information

OSHA - GHS Label Information:

We believe the statements, technical information and recommendations contained herein are
reliable, but they are given without warranty or guarantee of any kind. The information in this
document applies to this specific material as supplied. It may not be valid for this material if it
is used in combination with any other materials. Users should make their own investigations
to determine the suitability and applicability of the information for their particular purposes.
This SDS has been prepared by the Compliance Services organization supporting this
manufacturer, supplier or distributor.

Zep Inc. markets products under well recognized and established brand names such as Zep®,
Zep Commercial®,Zep Professional®, Enforcer®, National Chemical™, Selig™, Misty®, Next
Dimension™, Petro®, i-Chem®, TimeMist®, TimeWick™, MicrobeMax®, Country Vet®,

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SAFETY DATA SHEET

ZEP MORADO SUPER CLEANER 4-1GL

Version 4.1

Revision Date 06/26/2018

Print Date 11/07/2018

Konk®, Original Bike Spirits®, Blue Coral®, Black Magic®, Rain-X®, Niagara National™, FC
Forward Chemicals®,Rexodan®, Mykal™, and a number of private labeled brands.

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