Zep 4501 User Manual

SAFETY DATA SHEET
A00395 ZEP DRILL CHILL 004501 20N16
Version 3.0
Print Date 04/26/2019
Material name
:
A00395 ZEP DRILL CHILL 004501 20N16 Material number
:
000000000000004501
Company
:
Zep Inc.
Address
:
350 Joe Frank Harris Parkway, SE Emerson, GA 30137 Telephone
:
404-352-1680
Emergency telephone numbers
For SDS Information
:
Compliance Services 1-877-428-9937
For a Medical Emergency
:
877-541-2016 Toll Free - All Calls Recorded
For a Transportation Emergency
:
CHEMTREC: 800-424-9300 - All Calls Recorded. In the District of Columbia 202-483-7616
Recommended use
:
Lubricant Appearance
Aerosol containing a liquefied gas
Colour
brown, opaque
Odour
characteristic
Flammable aerosols
:
Category 1
Gases under pressure
:
Liquefied gas
Skin irritation
:
Category 2
Eye irritation
:
Category 2A
Aspiration hazard
:
Category 1
Hazard pictograms
:
Signal word
:
Danger
Hazard statements
:
H222 Extremely flammable aerosol. H280 Contains gas under pressure; may explode if heated. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H319 Causes serious eye irritation.
SECTION 1. PRODUCT AND COMPANY IDENTIFICATION
Manufacturer or supplier's details
Recommended use of the chemical and restrictions on use
SECTION 2. HAZARDS IDENTIFICATION
Emergency Overview
GHS Classification
GHS label elements
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SAFETY DATA SHEET
A00395 ZEP DRILL CHILL 004501 20N16
Version 3.0
Print Date 04/26/2019
Precautionary statements
:
Prevention: P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P211 Do not spray on an open flame or other ignition source. P251 Pressurized container: Do not pierce or burn, even after use. P264 Wash skin thoroughly after handling. P280 Wear protective gloves/ eye protection/ face protection.
Response:
P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor. P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P331 Do NOT induce vomiting. P332 + P313 If skin irritation occurs: Get medical advice/ attention. P337 + P313 If eye irritation persists: Get medical advice/ attention. P362 Take off contaminated clothing and wash before reuse. Storage: P410 + P412 Protect from sunlight. Do not expose to temperatures exceeding 50 °C/ 122 °F. Disposal: P501 Dispose of contents/container in accordance with local regulation. Substance / Mixture
:
Mixture
Chemical name
CAS-No.
Concentration [%]
Distillates (petroleum), hydrotreated heavy naphthenic
64742-52-5
>= 30 - < 50 Distillates (petroleum), hydrotreated middle
64742-46-7
>= 30 - < 50
propane
74-98-6
>= 5 - < 10
butane
106-97-8
>= 1 - < 5
General advice
:
Move out of dangerous area. Show this safety data sheet to the doctor in attendance. Do not leave the victim unattended.
If inhaled
:
If unconscious, place in recovery position and seek medical advice. If symptoms persist, call a physician.
In case of skin contact
:
If skin irritation persists, call a physician. Wash off immediately with plenty of water for at least 15
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous components
The exact percentages of disclosed substances are withheld as trade secrets.
SECTION 4. FIRST AID MEASURES
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SAFETY DATA SHEET
A00395 ZEP DRILL CHILL 004501 20N16
Version 3.0
Print Date 04/26/2019
minutes. If on clothes, remove clothes.
In case of eye contact
:
Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing. If eye irritation persists, consult a specialist. Rinse immediately with plenty of water for at least 15 minutes.
If swallowed
:
Keep respiratory tract clear. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician. DO NOT induce vomiting unless directed to do so by a physician or poison control center.
Most important symptoms and effects, both acute and delayed
:
Effects are immediate and delayed. Symptoms may include irritation, redness, pain, and rash. Aspiration may cause pulmonary oedema and pneumonitis. Effects are dependent on exposure (dose, concentration, contact time). Causes skin irritation. Causes serious eye irritation. Review section 2 of SDS to see all potential hazards.
Notes to physician
:
Treat symptomatically. Symptoms may be delayed.
Suitable extinguishing media
:
Alcohol-resistant foam Carbon dioxide (CO2) Dry chemical Water spray jet
Unsuitable extinguishing media
:
High volume water jet
Specific hazards during firefighting
:
Do not allow run-off from fire fighting to enter drains or water courses.
Hazardous combustion products
:
Carbon dioxide (CO2) Carbon monoxide Smoke
Specific extinguishing methods
:
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Further information
:
For safety reasons in case of fire, cans should be stored separately in closed containments. Use a water spray to cool fully closed containers.
Special protective equipment for firefighters
:
Wear self-contained breathing apparatus for firefighting if necessary.
SECTION 5. FIREFIGHTING MEASURES
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SAFETY DATA SHEET
A00395 ZEP DRILL CHILL 004501 20N16
Version 3.0
Print Date 04/26/2019
Personal precautions, protective equipment and emergency procedures
:
Use personal protective equipment. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas.
Environmental precautions
:
Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities.
Methods and materials for containment and cleaning up
:
Sweep up or vacuum up spillage and collect in suitable container for disposal. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust).
Advice on safe handling
:
Avoid contact with skin and eyes. For personal protection see section 8. Smoking, eating and drinking should be prohibited in the application area. Take precautionary measures against static discharges. Provide sufficient air exchange and/or exhaust in work rooms. Always replace cap after use. Dispose of rinse water in accordance with local and national regulations. Do not breathe vapours or spray mist.
Conditions for safe storage
:
BEWARE: Aerosol is pressurized. Keep away from direct sun exposure and temperatures over 50 °C. Do not open by force or throw into fire even after use. Do not spray on flames or red-hot objects. No smoking. Observe label precautions. Keep in a dry, cool and well-ventilated place. Electrical installations / working materials must comply with the technological safety standards.
Materials to avoid
:
Strong oxidizing agents
Components
CAS-No.
Value type (Form of exposure)
Control parameters / Permissible concentration
Basis
Distillates (petroleum),
64742-52-5
TWA (Mist)
5 mg/m3
OSHA Z-1
SECTION 6. ACCIDENTAL RELEASE MEASURES
SECTION 7. HANDLING AND STORAGE
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters
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SAFETY DATA SHEET
A00395 ZEP DRILL CHILL 004501 20N16
Version 3.0
Print Date 04/26/2019
hydrotreated heavy naphthenic
TWA (Inhalable fraction)
5 mg/m3
ACGIH propane
74-98-6
TWA
1,000 ppm
ACGIH
TWA
1,000 ppm 1,800 mg/m3
NIOSH REL
TWA
1,000 ppm 1,800 mg/m3
OSHA Z-1
TWA
1,000 ppm 1,800 mg/m3
OSHA P0
PEL
1,000 ppm 1,800 mg/m3
CAL PEL
butane
106-97-8
TWA
800 ppm 1,900 mg/m3
NIOSH REL
TWA
800 ppm 1,900 mg/m3
OSHA P0
PEL
800 ppm 1,900 mg/m3
CAL PEL
Engineering measures
:
effective ventilation in all processing areas
Respiratory protection
:
Use respiratory protection unless adequate local exhaust ventilation is provided or exposure assessment demonstrates that exposures are within recommended exposure guidelines. Material
:
Protective gloves
Remarks
:
The suitability for a specific workplace should be discussed with the producers of the protective gloves.
Eye protection
:
Safety glasses Ensure that eyewash stations and safety showers are close to the workstation location.
Skin and body protection
:
Impervious clothing Choose body protection according to the amount and concentration of the dangerous substance at the work place.
Hygiene measures
:
When using do not eat or drink. When using do not smoke. Wash hands before breaks and at the end of workday.
Appearance
:
Aerosol containing a liquefied gas
Colour
:
brown, opaque
Odour
:
characteristic
Personal protective equipment
Hand protection
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
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SAFETY DATA SHEET
A00395 ZEP DRILL CHILL 004501 20N16
Version 3.0
Print Date 04/26/2019
Odour Threshold
:
No data available
pH : Not applicable
Melting point/freezing point
:
No data available
Boiling point
:
No data available
Flash point
:
Not applicable
Evaporation rate
:
No data available
Flammability (solid, gas)
:
Extremely flammable aerosol.
Upper explosion limit
:
No data available
Lower explosion limit
:
No data available
Vapour pressure
:
No data available
Density
:
0.910 g/cm3
Water solubility
:
insoluble
Solubility in other solvents
:
not determined
Partition coefficient: n­octanol/water
:
No data available
Auto-ignition temperature
:
not determined
Thermal decomposition
:
No data available
Viscosity, kinematic
:
No data available
Heat of combustion
:
42.46 kJ/g Reactivity
:
Stable
Chemical stability
:
Stable under normal conditions.
Possibility of hazardous reactions
:
Vapours may form explosive mixture with air. No decomposition if stored and applied as directed.
Conditions to avoid
:
Heat, flames and sparks. Extremes of temperature and direct sunlight.
Incompatible materials
:
Strong oxidizing agents
Hazardous decomposition products
:
Carbon oxides Sulphur oxides
Solubility(ies)
Viscosity
SECTION 10. STABILITY AND REACTIVITY
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SAFETY DATA SHEET
A00395 ZEP DRILL CHILL 004501 20N16
Version 3.0
Print Date 04/26/2019
Aggravated Medical Condition
:
None known.
Symptoms of Overexposure
:
Effects are immediate and delayed. Symptoms may include irritation, redness, pain, and rash. Aspiration may cause pulmonary oedema and pneumonitis. Effects are dependent on exposure (dose, concentration, contact time).
IARC
No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.
ACGIH
No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH.
OSHA
No component of this product present at levels greater than or equal to 0.1% is on OSHA’s list of regulated carcinogens.
NTP
No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP.
Acute oral toxicity
:
LD50 Rat: > 5,000 mg/kg
Acute inhalation toxicity
:
LC50 Rat: > 5 mg/l Exposure time: 4 h
Acute dermal toxicity
:
LD50 Rabbit: > 5,000 mg/kg
Remarks: May cause skin irritation and/or dermatitis.
Remarks: Severe eye irritation
SECTION 11. TOXICOLOGICAL INFORMATION
Potential Health Effects
Carcinogenicity:
Acute toxicity
Components: Distillates (petroleum), hydrotreated heavy naphthenic:
Skin corrosion/irritation
Product:
Serious eye damage/eye irritation
Product:
Respiratory or skin sensitisation
No data available
Germ cell mutagenicity
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SAFETY DATA SHEET
A00395 ZEP DRILL CHILL 004501 20N16
Version 3.0
Print Date 04/26/2019
May be fatal if swallowed and enters airways.
Remarks: No data available
Partition coefficient: n­octanol/water
:
Remarks: No data available
Partition coefficient: n­octanol/water
:
Pow: 2.89
Regulation
40 CFR Protection of Environment; Part 82 Protection of
No data available
Carcinogenicity
No data available
Reproductive toxicity
No data available
STOT - single exposure
No data available
STOT - repeated exposure
No data available
Aspiration toxicity
Product:
Further information
Product:
SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity
No data available
Persistence and degradability
No data available
Bioaccumulative potential
Product:
Components: butane :
Mobility in soil
No data available
Other adverse effects
No data available
Product:
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SAFETY DATA SHEET
A00395 ZEP DRILL CHILL 004501 20N16
Version 3.0
Print Date 04/26/2019
Stratospheric Ozone - CAA Section 602 Class I Substances
Remarks
This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B).
Additional ecological information
:
No data available
Waste from residues
:
Do not dispose of waste into sewer. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of in accordance with local regulations.
Contaminated packaging
:
Empty remaining contents. Dispose of as unused product. Do not re-use empty containers. Do not burn, or use a cutting torch on, the empty drum.
Transportation Regulation: 49 CFR (USA): ORM-D, CONSUMER COMMODITY
Transportation Regulation: IMDG (Vessel): UN1950, AEROSOLS, FLAMMABLE, 2.1, - Limited quantity
Transportation Regulation: IATA (Cargo Air): UN1950, Aerosols, flammable, 2.1, - Limited quantity
Transportation Regulation: IATA (Passenger Air): UN1950, Aerosols, flammable, 2.1, - Limited quantity
Transportation Regulation: TDG (Canada): UN1950, AEROSOLS, FLAMMABLE, 2.1, - Limited quantity
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods
SECTION 14. TRANSPORT INFORMATION
The product as delivered to the customer conforms to packaging requirements for shipment by road under US Department of Transportation (DOT) regulations. Additional transportation classifications noted above are for reference only, and not a certification or warranty of the suitability of the packaging for shipment under these alternative transport regulations.
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SAFETY DATA SHEET
A00395 ZEP DRILL CHILL 004501 20N16
Version 3.0
Print Date 04/26/2019
TSCA list
:
No substances are subject to a Significant New Use Rule.
No substances are subject to TSCA 12(b) export notification requirements.
SARA 311/312 Hazards
:
Flammable (gases, aerosols, liquids, or solids) Gases under pressure Skin corrosion or irritation Serious eye damage or eye irritation Aspiration hazard
SARA 302
:
No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313
:
This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
This product does not contain any chemicals known to State of
California to cause cancer, birth defects, or any other reproductive harm.
DSL
All components of this product are on the Canadian DSL
TSCA
On TSCA Inventory
SECTION 15. REGULATORY INFORMATION
EPCRA - Emergency Planning and Community Right-to-Know Act CERCLA Reportable Quantity
This material does not contain any components with a CERCLA RQ.
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.
California Prop. 65
The components of this product are reported in the following inventories:
For information on the country notification status for other regions please contact the
manufacturer’s regulatory group.
Inventory Acronym and Validity Area Legend:
TSCA (USA), DSL (Canada), NDSL (Canada)
SECTION 16. OTHER INFORMATION
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SAFETY DATA SHEET
A00395 ZEP DRILL CHILL 004501 20N16
Version 3.0
Print Date 04/26/2019
NFPA:
HMIS III:
Hazard pictograms
:
Signal word
:
Danger:
Hazard statements
:
Extremely flammable aerosol. Contains gas under pressure; may explode if heated. May be fatal if swallowed and enters airways. Causes skin irritation. Causes serious eye irritation.
Precautionary statements
:
Prevention: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Wash skin thoroughly after handling. Wear protective gloves/ eye protection/ face protection. Response: IF SWALLOWED: Immediately call a POISON CENTER/doctor. IF ON SKIN: Wash with plenty of soap and water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Do NOT induce vomiting. If skin irritation occurs: Get medical advice/ attention. If eye irritation persists: Get medical advice/ attention. Take off contaminated clothing and wash before reuse. Storage: Protect from sunlight. Do not expose to temperatures exceeding 50 °C/ 122 °F. Disposal: Dispose of contents/container in accordance with local regulation.
Version:
3.0
Revision Date:
02/20/2018
Print Date:
04/26/2019
Flammability
Health
Instability
3
4
0
Special hazard.
FLAMMABILITY
PHYSICAL HAZARD
HEALTH
4
3
3
0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic
Further information
OSHA - GHS Label Information:
We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind. The information in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. Users should make their own investigations to determine the suitability and applicability of the information for their particular purposes. This SDS has been prepared by the Compliance Services organization supporting this manufacturer, supplier or distributor.
Zep Inc. markets products under well recognized and established brand names such as Zep®,
Zep Commercial®,Zep Professional®, Enforcer®, National Chemical™, Selig™, Misty®, Next Dimension™, Petro®, i-Chem®, TimeMist®, TimeWick™, MicrobeMax®, Country Vet®,
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SAFETY DATA SHEET
A00395 ZEP DRILL CHILL 004501 20N16
Version 3.0
Print Date 04/26/2019
Konk®, Original Bike Spirits®, Blue Coral®, Black Magic®, Rain-X®, Niagara National™, FC Forward Chemicals®,Rexodan®, Mykal™, and a number of private labeled brands.
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