Zep 41585 User Manual

SAFETY DATA SHEET

ZEP BIG ORANGE 55GL

Version 3.0

Revision Date 01/22/2018

Print Date 11/07/2018

Material name

:

ZEP BIG ORANGE 55GL
Material number

:

000000000000041585

Company

:

Zep Inc.

Address

:

350 Joe Frank Harris Parkway, SE
Emerson, GA 30137
Telephone

:

404-352-1680

Emergency telephone numbers

For SDS Information

:

Compliance Services 1-877-428-9937

For a Medical Emergency

:

877-541-2016 Toll Free - All Calls Recorded

For a Transportation
Emergency

:

CHEMTREC: 800-424-9300 - All Calls Recorded.
In the District of Columbia 202-483-7616

Recommended use

:

Degreaser
Appearance

liquid

Colour

clear, orange

Odour

strong

Flammable liquids

:

Category 3

Skin irritation

:

Category 2

Eye irritation

:

Category 2A

Skin sensitisation

:

Category 1

Aspiration hazard

:

Category 1

Hazard pictograms

:

Signal word

:

Danger

Hazard statements

:

H226 Flammable liquid and vapour.
H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.

SECTION 1. PRODUCT AND COMPANY IDENTIFICATION

Manufacturer or supplier's details

Recommended use of the chemical and restrictions on use

SECTION 2. HAZARDS IDENTIFICATION

Emergency Overview

GHS Classification

GHS label elements

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SAFETY DATA SHEET

ZEP BIG ORANGE 55GL

Version 3.0

Revision Date 01/22/2018

Print Date 11/07/2018

Precautionary statements

:

Prevention:
P210 Keep away from heat/sparks/open flames/hot surfaces.
No smoking.
P233 Keep container tightly closed.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ ventilating/ lighting
equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
P264 Wash skin thoroughly after handling.
P272 Contaminated work clothing should not be allowed out of
the workplace.
P280 Wear protective gloves/ eye protection/ face protection.

Response:

P301 + P310 IF SWALLOWED: Immediately call a POISON
CENTER/doctor.
P303 + P361 + P353 IF ON SKIN (or hair): Take off
immediately all contaminated clothing. Rinse skin with
water/shower.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water
for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing.
P331 Do NOT induce vomiting.
P333 + P313 If skin irritation or rash occurs: Get medical
advice/ attention.
P337 + P313 If eye irritation persists: Get medical advice/
attention.
P362 Take off contaminated clothing and wash before reuse.
P370 + P378 In case of fire: Use dry sand, dry chemical or
alcohol-resistant foam to extinguish.
Storage:
P403 + P235 Store in a well-ventilated place. Keep cool.
Disposal:
P501 Dispose of contents/container in accordance with local
regulation.
Substance / Mixture

:

Mixture

Chemical name

CAS-No.

Concentration [%]

d-limonene

5989-27-5

>= 70 - < 90

4-Nonylphenol branched, ethoxylated

127087-87-0

>= 5 - < 10

p-mentha-1,4-diene

99-85-4

>= 1 - < 5

linalool

78-70-6

>= 1 - < 5

7-methyl-3-methyleneocta-1,6-diene

123-35-3

>= 1 - < 5

General advice

:

Move out of dangerous area.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Hazardous components

The exact percentages of disclosed substances are withheld as trade secrets.

SECTION 4. FIRST AID MEASURES

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SAFETY DATA SHEET

ZEP BIG ORANGE 55GL

Version 3.0

Revision Date 01/22/2018

Print Date 11/07/2018

Show this safety data sheet to the doctor in attendance.
Do not leave the victim unattended.

If inhaled

:

If unconscious, place in recovery position and seek medical
advice.
If symptoms persist, call a physician.

In case of skin contact

:

In case of contact, immediately flush skin with soap and plenty
of water.
If skin irritation persists, call a physician.

In case of eye contact

:

Flush eyes with water at least 15 minutes. Get medical
attention if eye irritation develops or persists.
Remove contact lenses.
Protect unharmed eye.
Keep eye wide open while rinsing.

If swallowed

:

Clean mouth with water and drink afterwards plenty of water.
Keep respiratory tract clear.
Do not give milk or alcoholic beverages.
Never give anything by mouth to an unconscious person.
If symptoms persist, call a physician.
DO NOT induce vomiting unless directed to do so by a
physician or poison control center.

Most important symptoms
and effects, both acute and
delayed

:

Effects are immediate and delayed.
Symptoms may include irritation, redness, pain, and rash.
Causes skin irritation.
Causes serious eye irritation.
Review section 2 of SDS to see all potential hazards.

Notes to physician

:

Treat symptomatically. Symptoms may be delayed.

Suitable extinguishing media

:

Alcohol-resistant foam
Carbon dioxide (CO2)
Dry chemical

Unsuitable extinguishing
media

:

High volume water jet

Specific hazards during
firefighting

:

Do not allow run-off from fire fighting to enter drains or water
courses.

Hazardous combustion
products

:

Carbon dioxide (CO2)
Carbon monoxide
Smoke

Specific extinguishing
methods

:

Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.

Further information

:

Collect contaminated fire extinguishing water separately. This
must not be discharged into drains.
Fire residues and contaminated fire extinguishing water must

SECTION 5. FIREFIGHTING MEASURES

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SAFETY DATA SHEET

ZEP BIG ORANGE 55GL

Version 3.0

Revision Date 01/22/2018

Print Date 11/07/2018

be disposed of in accordance with local regulations.
For safety reasons in case of fire, cans should be stored
separately in closed containments.
Use a water spray to cool fully closed containers.

Special protective equipment
for firefighters

:

Wear self-contained breathing apparatus for firefighting if
necessary.

Personal precautions,
protective equipment and
emergency procedures

:

Use personal protective equipment.
Remove all sources of ignition.
Evacuate personnel to safe areas.
Beware of vapours accumulating to form explosive
concentrations. Vapours can accumulate in low areas.

Environmental precautions

:

Prevent product from entering drains.
Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains inform
respective authorities.

Methods and materials for
containment and cleaning up

:

Contain spillage, and then collect with non-combustible
absorbent material, (e.g. sand, earth, diatomaceous earth,
vermiculite) and place in container for disposal according to
local / national regulations (see section 13).

Advice on safe handling

:

Avoid exposure - obtain special instructions before use.
Avoid contact with skin and eyes.
For personal protection see section 8.
Smoking, eating and drinking should be prohibited in the
application area.
Take precautionary measures against static discharges.
Provide sufficient air exchange and/or exhaust in work rooms.
Open drum carefully as content may be under pressure.
Dispose of rinse water in accordance with local and national
regulations.
Persons susceptible to skin sensitisation problems or asthma,
allergies, chronic or recurrent respiratory disease should not
be employed in any process in which this mixture is being
used.

Conditions for safe storage

:

No smoking.
Keep container tightly closed in a dry and well-ventilated
place.
Containers which are opened must be carefully resealed and
kept upright to prevent leakage.
Observe label precautions.
Electrical installations / working materials must comply with
the technological safety standards.

Materials to avoid

:

Keep away from oxidizing agents and strongly acid or alkaline
materials.

SECTION 6. ACCIDENTAL RELEASE MEASURES

SECTION 7. HANDLING AND STORAGE

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SAFETY DATA SHEET

ZEP BIG ORANGE 55GL

Version 3.0

Revision Date 01/22/2018

Print Date 11/07/2018

Components

CAS-No.

Value type
(Form of
exposure)

Control
parameters /
Permissible
concentration

Basis

d-limonene

5989-27-5

TWA

30 ppm

US WEEL

Engineering measures

:

effective ventilation in all processing areas

Respiratory protection

:

In case of insufficient ventilation, wear suitable respiratory
equipment.
Material

:

Protective gloves

Remarks

:

The suitability for a specific workplace should be discussed
with the producers of the protective gloves.

Eye protection

:

Tightly fitting safety goggles
Wear face-shield and protective suit for abnormal processing
problems.

Skin and body protection

:

Impervious clothing
Choose body protection according to the amount and
concentration of the dangerous substance at the work place.

Hygiene measures

:

When using do not eat or drink.
When using do not smoke.
Wash hands before breaks and at the end of workday.

Appearance

:

liquid

Colour

:

clear, orange

Odour

:

strong

Odour Threshold

:

No data available

pH : Not applicable

Melting point/freezing point

:

No data available

Boiling point

:

170 °C

Flash point

:

53.9 °C
Method: closed cup

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Components with workplace control parameters

Personal protective equipment

Hand protection

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

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SAFETY DATA SHEET

ZEP BIG ORANGE 55GL

Version 3.0

Revision Date 01/22/2018

Print Date 11/07/2018

Evaporation rate

:

< 1

Upper explosion limit

:

No data available

Lower explosion limit

:

No data available

Vapour pressure

:

2.533 hPa

Relative vapour density

:

No data available

Density

:

0.864 g/cm3

Water solubility

:

emulsifiable

Solubility in other solvents

:

Not applicable

Partition coefficient: n­octanol/water

:

No data available

Auto-ignition temperature

:

not determined

Thermal decomposition

:

No data available

Viscosity, kinematic

:

3.8 mm2/s (20 °C)
Reactivity

:

Stable

Chemical stability

:

Stable under normal conditions.

Possibility of hazardous
reactions

:

Vapours may form explosive mixture with air.
No decomposition if stored and applied as directed.

Conditions to avoid

:

Extremes of temperature and direct sunlight.
Heat, flames and sparks.

Incompatible materials

:

Acids
Oxidizing agents

Hazardous decomposition
products

:

Carbon monoxide, carbon dioxide and unburned
hydrocarbons (smoke).
Nitrogen oxides (NOx)

Aggravated Medical
Condition

:

None known.

Solubility(ies)

Viscosity

SECTION 10. STABILITY AND REACTIVITY

SECTION 11. TOXICOLOGICAL INFORMATION

Potential Health Effects

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SAFETY DATA SHEET

ZEP BIG ORANGE 55GL

Version 3.0

Revision Date 01/22/2018

Print Date 11/07/2018

Symptoms of Overexposure

:

Effects are immediate and delayed.
Symptoms may include irritation, redness, pain, and rash.

IARC

No component of this product present at levels greater than or
equal to 0.1% is identified as probable, possible or confirmed
human carcinogen by IARC.

ACGIH

No component of this product present at levels greater than or
equal to 0.1% is identified as a carcinogen or potential
carcinogen by ACGIH.

OSHA

No component of this product present at levels greater than or
equal to 0.1% is on OSHA’s list of regulated carcinogens.

NTP

No component of this product present at levels greater than or
equal to 0.1% is identified as a known or anticipated carcinogen
by NTP.

Acute oral toxicity

:

Acute toxicity estimate : > 5,000 mg/kg
Method: Calculation method

Acute dermal toxicity

:

Acute toxicity estimate : > 5,000 mg/kg
Method: Calculation method

Acute oral toxicity

:

LD50 Oral Rat: 4,400 mg/kg

Acute dermal toxicity

:

LD50 Dermal Rabbit: > 5,000 mg/kg

Acute oral toxicity

:

LD50 Oral Rat: 16,000 mg/kg

Acute dermal toxicity

:

LD50 Rabbit: 2,573 mg/kg

Acute oral toxicity

:

LD50 Oral Rat: > 5,000 mg/kg

Acute dermal toxicity

:

LD50 Dermal Rabbit: > 5,000 mg/kg

Remarks: Irritating to skin.

Carcinogenicity:

Acute toxicity

Product:

Components:
d-limonene:

4-Nonylphenol branched, ethoxylated:

7-methyl-3-methyleneocta-1,6-diene:

Skin corrosion/irritation

Product:

Serious eye damage/eye irritation

Product:

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SAFETY DATA SHEET

ZEP BIG ORANGE 55GL

Version 3.0

Revision Date 01/22/2018

Print Date 11/07/2018

Remarks: Severe eye irritation

Remarks: Causes sensitisation.

Remarks: Solvents may degrease the skin.

Partition coefficient: n­octanol/water

:

Remarks: No data available

Respiratory or skin sensitisation

Product:

Germ cell mutagenicity

No data available

Carcinogenicity

No data available

Reproductive toxicity

No data available

STOT - single exposure

No data available

STOT - repeated exposure

No data available

Aspiration toxicity

No data available

Further information

Product:

SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity

No data available

Persistence and degradability

No data available

Bioaccumulative potential

Product:

Mobility in soil

No data available

Other adverse effects

No data available

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SAFETY DATA SHEET

ZEP BIG ORANGE 55GL

Version 3.0

Revision Date 01/22/2018

Print Date 11/07/2018

Regulation

40 CFR Protection of Environment; Part 82 Protection of
Stratospheric Ozone - CAA Section 602 Class I
Substances

Remarks

This product neither contains, nor was manufactured
with a Class I or Class II ODS as defined by the U.S.
Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A
+ B).

Additional ecological
information

:

No data available

Waste from residues

:

The product should not be allowed to enter drains, water
courses or the soil.
Do not contaminate ponds, waterways or ditches with
chemical or used container.
Dispose of in accordance with local regulations.

Contaminated packaging

:

Empty remaining contents.
Dispose of as unused product.
Do not re-use empty containers.
Do not burn, or use a cutting torch on, the empty drum.

Transportation Regulation: 49 CFR (USA):
NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS MATERIAL

Transportation Regulation: IMDG (Vessel):
UN1993, FLAMMABLE LIQUID, N.O.S., (D-LIMONENE), 3, III, MP: (D-LIMONENE)

Transportation Regulation: IATA (Cargo Air):
UN1993, Flammable liquid, n.o.s., (D-LIMONENE), 3, III, MP: (D-LIMONENE)

Transportation Regulation: IATA (Passenger Air):
UN1993, Flammable liquid, n.o.s., (D-LIMONENE), 3, III, MP: (D-LIMONENE)

Transportation Regulation: TDG (Canada):
NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS MATERIAL

Product:

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods

SECTION 14. TRANSPORT INFORMATION

The product as delivered to the customer conforms to packaging requirements for shipment by road
under US Department of Transportation (DOT) regulations. Additional transportation classifications
noted above are for reference only, and not a certification or warranty of the suitability of the packaging
for shipment under these alternative transport regulations.

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SAFETY DATA SHEET

ZEP BIG ORANGE 55GL

Version 3.0

Revision Date 01/22/2018

Print Date 11/07/2018

TSCA list

:

No substances are subject to a Significant New Use Rule.

No substances are subject to TSCA 12(b) export notification
requirements.

SARA 311/312 Hazards

:

Flammable (gases, aerosols, liquids, or solids)
Skin corrosion or irritation
Serious eye damage or eye irritation
Respiratory or skin sensitisation
Aspiration hazard

SARA 302

:

No chemicals in this material are subject to the reporting
requirements of SARA Title III, Section 302.

SARA 313

:

This material does not contain any chemical components with
known CAS numbers that exceed the threshold (De Minimis)
reporting levels established by SARA Title III, Section 313.

WARNING: This product can expose you to chemicals
including 7-methyl-3-methyleneocta-1,6-diene, which is/are
known to the State of California to cause cancer. For more
information go to www.P65Warnings.ca.gov.

DSL

This product contains one or more components that are listed on the
Canadian NDSL. All other components are on the Canadian DSL.

TSCA

On TSCA Inventory

SECTION 15. REGULATORY INFORMATION

EPCRA - Emergency Planning and Community Right-to-Know Act
CERCLA Reportable Quantity

This material does not contain any components with a CERCLA RQ.

SARA 304 Extremely Hazardous Substances Reportable Quantity

This material does not contain any components with a section 304 EHS RQ.

California Prop. 65

The components of this product are reported in the following inventories:

For information on the country notification status for other regions please contact the

manufacturer’s regulatory group.

Inventory Acronym and Validity Area Legend:

TSCA (USA), DSL (Canada), NDSL (Canada)

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SAFETY DATA SHEET

ZEP BIG ORANGE 55GL

Version 3.0

Revision Date 01/22/2018

Print Date 11/07/2018

NFPA:

HMIS III:

Hazard pictograms

:

Signal word

:

Danger:

Hazard statements

:

Flammable liquid and vapour. May be fatal if swallowed and enters airways. Causes
skin irritation. May cause an allergic skin reaction. Causes serious eye irritation.

Precautionary statements

:

Prevention: Keep away from heat/sparks/open flames/hot surfaces. No smoking. Keep
container tightly closed. Ground/bond container and receiving equipment. Use
explosion-proof electrical/ ventilating/ lighting equipment. Use only non-sparking tools.
Take precautionary measures against static discharge. Avoid breathing dust/ fume/ gas/
mist/ vapours/ spray. Wash skin thoroughly after handling. Contaminated work clothing
should not be allowed out of the workplace. Wear protective gloves/ eye protection/
face protection.
Response: IF SWALLOWED: Immediately call a POISON CENTER/doctor. IF ON
SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with
water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing. Do NOT induce vomiting. If
skin irritation or rash occurs: Get medical advice/ attention. If eye irritation persists: Get
medical advice/ attention. Take off contaminated clothing and wash before reuse. In
case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish.

Storage: Store in a well-ventilated place. Keep cool.
Disposal: Dispose of contents/container in accordance with local regulation.

Version:

3.0

Revision Date:

01/22/2018

Print Date:

11/07/2018

Flammability

Health

Instability

2

2

0

Special hazard.

FLAMMABILITY

PHYSICAL HAZARD

HEALTH

2

0

2

0 = not significant, 1 =Slight,
2 = Moderate, 3 = High
4 = Extreme, * = Chronic

SECTION 16. OTHER INFORMATION

Further information

OSHA - GHS Label Information:

We believe the statements, technical information and recommendations contained herein are
reliable, but they are given without warranty or guarantee of any kind. The information in this
document applies to this specific material as supplied. It may not be valid for this material if it
is used in combination with any other materials. Users should make their own investigations
to determine the suitability and applicability of the information for their particular purposes.

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SAFETY DATA SHEET

ZEP BIG ORANGE 55GL

Version 3.0

Revision Date 01/22/2018

Print Date 11/07/2018

This SDS has been prepared by the Compliance Services organization supporting this
manufacturer, supplier or distributor.

Zep Inc. markets products under well recognized and established brand names such as Zep®,
Zep Commercial®,Zep Professional®, Enforcer®, National Chemical™, Selig™, Misty®, Next
Dimension™, Petro®, i-Chem®, TimeMist®, TimeWick™, MicrobeMax®, Country Vet®,
Konk®, Original Bike Spirits®, Blue Coral®, Black Magic®, Rain-X®, Niagara National™, FC
Forward Chemicals®,Rexodan®, Mykal™, and a number of private labeled brands.

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