Page 1
SAFETY DATA SHEET
A07317 ZEP 65 CITRUS FOAM 003701 20N18
Version 3.2
Revision Date 02/14/2018
Print Date 04/25/2019
Material name
:
A07317 ZEP 65 CITRUS FOAM 003701 20N18
Material number
:
000000000000003701
Company
:
Zep Inc.
Address
:
350 Joe Frank Harris Parkway, SE
Emerson, GA 30137
Telephone
:
404-352-1680
Emergency telephone numbers
For SDS Information
:
Compliance Services 1-877-428-9937
For a Medical Emergency
:
877-541-2016 Toll Free - All Calls Recorded
For a Transportation
Emergency
:
CHEMTREC: 800-424-9300 - All Calls Recorded.
In the District of Columbia 202-483-7616
Recommended use
:
Cleaner
Appearance
Aerosol containing a liquefied gas
Colour
clear, light yellow
Odour
characteristic
Gases under pressure
:
Liquefied gas
Skin irritation
:
Category 2
Serious eye damage
:
Category 1
Skin sensitisation
:
Category 1
Hazard pictograms
:
Signal word
:
Danger
Hazard statements
:
H280 Contains gas under pressure; may explode if heated.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
Precautionary statements
:
Prevention:
P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
SECTION 1. PRODUCT AND COMPANY IDENTIFICATION
Manufacturer or supplier's details
Recommended use of the chemical and restrictions on use
SECTION 2. HAZARDS IDENTIFICATION
Emergency Overview
GHS Classification
GHS label elements
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SAFETY DATA SHEET
A07317 ZEP 65 CITRUS FOAM 003701 20N18
Version 3.2
Revision Date 02/14/2018
Print Date 04/25/2019
P264 Wash skin thoroughly after handling.
P272 Contaminated work clothing should not be allowed out of
the workplace.
P280 Wear protective gloves/ eye protection/ face protection.
Response:
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with
water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. Immediately call a POISON
CENTER/doctor.
P333 + P313 If skin irritation or rash occurs: Get medical
advice/ attention.
P362 Take off contaminated clothing and wash before reuse.
Storage:
P410 + P403 Protect from sunlight. Store in a well-ventilated
place.
P412 Do not expose to temperatures exceeding 50 °C/ 122 °F.
Disposal:
P501 Dispose of contents/container in accordance with local
regulation.
Substance / Mixture
:
Mixture
Chemical name
CAS-No.
Concentration [%]
butane
106-97-8
>= 1 - < 5
2-(2-butoxyethoxy)ethanol
112-34-5
>= 1 - < 5
Alcohols, C9-11, ethoxylated
68439-46-3
>= 1 - < 3
d-limonene
5989-27-5
>= 1 - < 5
Benzenesulfonic acid, C10-16-alkyl derivs.
68584-22-5
>= 1 - < 3
propane
74-98-6
>= 1 - < 5
General advice
:
Do not leave the victim unattended.
Get medical attention immediately.
Show this safety data sheet to the doctor in attendance.
Move out of dangerous area.
If inhaled
:
If unconscious, place in recovery position and seek medical
advice.
If symptoms persist, call a physician.
In case of skin contact
:
If skin irritation persists, call a physician.
Wash off immediately with plenty of water for at least 15
minutes.
Wash contaminated clothing before reuse.
Remove contaminated clothing and shoes.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous components
The exact percentages of disclosed substances are withheld as trade secrets.
SECTION 4. FIRST AID MEASURES
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SAFETY DATA SHEET
A07317 ZEP 65 CITRUS FOAM 003701 20N18
Version 3.2
Revision Date 02/14/2018
Print Date 04/25/2019
In case of eye contact
:
Remove contact lenses.
Protect unharmed eye.
Keep eye wide open while rinsing.
If eye irritation persists, consult a specialist.
Rinse immediately with plenty of water, also under the eyelids,
for at least 15 minutes.
If swallowed
:
Keep respiratory tract clear.
Never give anything by mouth to an unconscious person.
If symptoms persist, call a physician.
DO NOT induce vomiting unless directed to do so by a
physician or poison control center.
Most important symptoms
and effects, both acute and
delayed
:
Effects are immediate and delayed.
Symptoms may include blistering, irritation, burns, and pain.
Effects are dependent on exposure (dose, concentration,
contact time).
Causes serious eye damage.
Causes skin irritation.
Review section 2 of SDS to see all potential hazards.
Notes to physician
:
Treat symptomatically. Symptoms may be delayed.
Suitable extinguishing media
:
Alcohol-resistant foam
Carbon dioxide (CO2)
Dry chemical
Water spray jet
Unsuitable extinguishing
media
:
High volume water jet
Specific hazards during
firefighting
:
Do not allow run-off from fire fighting to enter drains or water
courses.
Hazardous combustion
products
:
Carbon dioxide (CO2)
Carbon monoxide
Smoke
Sulphur oxides
Specific extinguishing
methods
:
Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.
Further information
:
Standard procedure for chemical fires.
Special protective equipment
for firefighters
:
Wear self-contained breathing apparatus for firefighting if
necessary.
Personal precautions,
protective equipment and
emergency procedures
:
Use personal protective equipment.
Ensure adequate ventilation.
Remove all sources of ignition.
SECTION 5. FIREFIGHTING MEASURES
SECTION 6. ACCIDENTAL RELEASE MEASURES
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SAFETY DATA SHEET
A07317 ZEP 65 CITRUS FOAM 003701 20N18
Version 3.2
Revision Date 02/14/2018
Print Date 04/25/2019
Beware of vapours accumulating to form explosive
concentrations. Vapours can accumulate in low areas.
Evacuate personnel to safe areas.
Environmental precautions
:
Prevent further leakage or spillage if safe to do so.
Prevent product from entering drains.
If the product contaminates rivers and lakes or drains inform
respective authorities.
Methods and materials for
containment and cleaning up
:
Soak up with inert absorbent material (e.g. sand, silica gel,
acid binder, universal binder, sawdust).
Sweep up or vacuum up spillage and collect in suitable
container for disposal.
Advice on safe handling
:
For personal protection see section 8.
Smoking, eating and drinking should be prohibited in the
application area.
Always replace cap after use.
Do not breathe vapours or spray mist.
Avoid contact with skin and eyes.
Take precautionary measures against static discharges.
Avoid exposure - obtain special instructions before use.
Dispose of rinse water in accordance with local and national
regulations.
Conditions for safe storage
:
BEWARE: Aerosol is pressurized. Keep away from direct sun
exposure and temperatures over 50 °C. Do not open by force
or throw into fire even after use. Do not spray on flames or
red-hot objects.
No smoking.
Observe label precautions.
Keep in a dry, cool and well-ventilated place.
Electrical installations / working materials must comply with
the technological safety standards.
Materials to avoid
:
Oxidizing agents
Components
CAS-No.
Value type
(Form of
exposure)
Control
parameters /
Permissible
concentration
Basis
butane
106-97-8
TWA
800 ppm
1,900 mg/m3
NIOSH REL
TWA
800 ppm
1,900 mg/m3
OSHA P0
PEL
800 ppm
1,900 mg/m3
CAL PEL
SECTION 7. HANDLING AND STORAGE
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters
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SAFETY DATA SHEET
A07317 ZEP 65 CITRUS FOAM 003701 20N18
Version 3.2
Revision Date 02/14/2018
Print Date 04/25/2019
2-(2-butoxyethoxy)ethanol
112-34-5
TWA
(Inhalable
fraction and
vapor)
10 ppm
ACGIH
d-limonene
5989-27-5
TWA
30 ppm
US WEEL
propane
74-98-6
TWA
1,000 ppm
ACGIH
TWA
1,000 ppm
1,800 mg/m3
NIOSH REL
TWA
1,000 ppm
1,800 mg/m3
OSHA Z-1
TWA
1,000 ppm
1,800 mg/m3
OSHA P0
PEL
1,000 ppm
1,800 mg/m3
CAL PEL
Engineering measures
:
effective ventilation in all processing areas
Respiratory protection
:
Use respiratory protection unless adequate local exhaust
ventilation is provided or exposure assessment demonstrates
that exposures are within recommended exposure guidelines.
Material
:
Protective gloves
Remarks
:
The suitability for a specific workplace should be discussed
with the producers of the protective gloves.
Eye protection
:
Tightly fitting safety goggles
Access to clean water to rinse eyes must be available, options
include: eye wash stations or showers, or eye wash bottles
with pure water.
Skin and body protection
:
Impervious clothing
Choose body protection according to the amount and
concentration of the dangerous substance at the work place.
Hygiene measures
:
Wash hands before breaks and at the end of workday.
When using do not eat, drink or smoke.
Appearance
:
Aerosol containing a liquefied gas
Colour
:
clear, light yellow
Odour
:
characteristic
Odour Threshold
:
No data available
pH : No data available
Melting point/freezing point
:
No data available
Personal protective equipment
Hand protection
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
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SAFETY DATA SHEET
A07317 ZEP 65 CITRUS FOAM 003701 20N18
Version 3.2
Revision Date 02/14/2018
Print Date 04/25/2019
Boiling point
:
not determined
Flash point
:
Not applicable
Evaporation rate
:
not determined
Flammability (solid, gas)
:
The product is not flammable.
Upper explosion limit
:
No data available
Lower explosion limit
:
No data available
Vapour pressure
:
not determined
Relative vapour density
:
No data available
Density
:
1.004 g/cm3
Water solubility
:
not determined
Partition coefficient: noctanol/water
:
No data available
Auto-ignition temperature
:
not determined
Thermal decomposition
:
No data available
Viscosity, kinematic
:
No data available
Heat of combustion
:
< 20 kJ/g
Reactivity
:
Stable
Chemical stability
:
Stable under normal conditions.
Possibility of hazardous
reactions
:
Vapours may form explosive mixture with air.
No decomposition if stored and applied as directed.
Conditions to avoid
:
Heat, flames and sparks.
Extremes of temperature and direct sunlight.
Incompatible materials
:
Oxidizing agents
Hazardous decomposition
products
:
Carbon oxides
Aggravated Medical
:
None known.
Solubility(ies)
Viscosity
SECTION 10. STABILITY AND REACTIVITY
SECTION 11. TOXICOLOGICAL INFORMATION
Potential Health Effects
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SAFETY DATA SHEET
A07317 ZEP 65 CITRUS FOAM 003701 20N18
Version 3.2
Revision Date 02/14/2018
Print Date 04/25/2019
Condition
Symptoms of Overexposure
:
Effects are immediate and delayed.
Symptoms may include blistering, irritation, burns, and pain.
Effects are dependent on exposure (dose, concentration,
contact time).
IARC
No component of this product present at levels greater than or
equal to 0.1% is identified as probable, possible or confirmed
human carcinogen by IARC.
ACGIH
No component of this product present at levels greater than or
equal to 0.1% is identified as a carcinogen or potential
carcinogen by ACGIH.
OSHA
No component of this product present at levels greater than or
equal to 0.1% is on OSHA’s list of regulated carcinogens.
NTP
No component of this product present at levels greater than or
equal to 0.1% is identified as a known or anticipated carcinogen
by NTP.
Acute oral toxicity
:
Acute toxicity estimate : > 5,000 mg/kg
Method: Calculation method
Acute oral toxicity
:
LD50 Oral Rat: 1,400 mg/kg
Acute oral toxicity
:
LD50 Oral Rat: 4,400 mg/kg
Acute dermal toxicity
:
LD50 Dermal Rabbit: > 5,000 mg/kg
Remarks: Irritating to skin.
Remarks: Severe eye irritation
Remarks: Causes sensitisation.
Carcinogenicity:
Acute toxicity
Product:
Components:
Alcohols, C9-11, ethoxylated:
d-limonene:
Skin corrosion/irritation
Product:
Serious eye damage/eye irritation
Product:
Respiratory or skin sensitisation
Product:
Germ cell mutagenicity
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SAFETY DATA SHEET
A07317 ZEP 65 CITRUS FOAM 003701 20N18
Version 3.2
Revision Date 02/14/2018
Print Date 04/25/2019
Remarks: No data available
Partition coefficient: noctanol/water
:
Remarks: No data available
Partition coefficient: noctanol/water
:
Pow: 2.89
Partition coefficient: noctanol/water
:
Pow: 1
Regulation
40 CFR Protection of Environment; Part 82 Protection of
No data available
Carcinogenicity
No data available
Reproductive toxicity
No data available
STOT - single exposure
No data available
STOT - repeated exposure
No data available
Aspiration toxicity
No data available
Further information
Product:
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
No data available
Persistence and degradability
No data available
Bioaccumulative potential
Product:
Components:
butane :
2-(2-butoxyethoxy)ethanol :
Mobility in soil
No data available
Other adverse effects
No data available
Product:
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SAFETY DATA SHEET
A07317 ZEP 65 CITRUS FOAM 003701 20N18
Version 3.2
Revision Date 02/14/2018
Print Date 04/25/2019
Stratospheric Ozone - CAA Section 602 Class I
Substances
Remarks
This product neither contains, nor was manufactured
with a Class I or Class II ODS as defined by the U.S.
Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A
+ B).
Additional ecological
information
:
No data available
Waste from residues
:
The product should not be allowed to enter drains, water
courses or the soil.
Do not contaminate ponds, waterways or ditches with
chemical or used container.
Dispose of in accordance with local regulations.
Contaminated packaging
:
Empty remaining contents.
Dispose of as unused product.
Do not re-use empty containers.
Do not burn, or use a cutting torch on, the empty drum.
Transportation Regulation: 49 CFR (USA):
ORM-D, CONSUMER COMMODITY
Transportation Regulation: IMDG (Vessel):
UN1950, AEROSOLS, NON-FLAMMABLE, 2.2, - Limited quantity
Transportation Regulation: IATA (Cargo Air):
UN1950, AEROSOLS, NON-FLAMMABLE, 2.2, - Limited quantity
Transportation Regulation: IATA (Passenger Air):
UN1950, AEROSOLS, NON-FLAMMABLE, 2.2, - Limited quantity
Transportation Regulation: TDG (Canada):
UN1950, AEROSOLS, NON-FLAMMABLE, 2.2, - Limited quantity
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods
SECTION 14. TRANSPORT INFORMATION
The product as delivered to the customer conforms to packaging requirements for shipment by road
under US Department of Transportation (DOT) regulations. Additional transportation classifications
noted above are for reference only, and not a certification or warranty of the suitability of the packaging
for shipment under these alternative transport regulations.
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SAFETY DATA SHEET
A07317 ZEP 65 CITRUS FOAM 003701 20N18
Version 3.2
Revision Date 02/14/2018
Print Date 04/25/2019
TSCA list
:
No substances are subject to a Significant New Use Rule.
No substances are subject to TSCA 12(b) export notification
requirements.
Components
CAS-No.
Component RQ
(lbs)
Calculated product RQ
(lbs)
sodium hydroxide
1310-73-2
1000
*
SARA 311/312 Hazards
:
Gases under pressure
Skin corrosion or irritation
Serious eye damage or eye irritation
Respiratory or skin sensitisation
SARA 302
:
No chemicals in this material are subject to the reporting
requirements of SARA Title III, Section 302.
SARA 313
:
The following components are subject to reporting levels
established by SARA Title III, Section 313:
2-(2-butoxyethoxy)ethanol
112-34-5
3.2751 %
2-butoxyethanol
111-76-2
0.0498 %
This product does not contain any chemicals known to State of
California to cause cancer, birth defects, or any other
reproductive harm.
DSL
This product contains one or more components that are listed on the
Canadian NDSL. All other components are on the Canadian DSL.
TSCA
On TSCA Inventory
SECTION 15. REGULATORY INFORMATION
EPCRA - Emergency Planning and Community Right-to-Know Act
CERCLA Reportable Quantity
*: Calculated RQ exceeds reasonably attainable upper limit.
California Prop. 65
The components of this product are reported in the following inventories:
For information on the country notification status for other regions please contact the
manufacturer’s regulatory group.
Inventory Acronym and Validity Area Legend:
TSCA (USA), DSL (Canada), NDSL (Canada)
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SAFETY DATA SHEET
A07317 ZEP 65 CITRUS FOAM 003701 20N18
Version 3.2
Revision Date 02/14/2018
Print Date 04/25/2019
NFPA:
HMIS III:
Hazard pictograms
:
Signal word
:
Danger:
Hazard statements
:
Contains gas under pressure; may explode if heated. Causes skin irritation. May cause
an allergic skin reaction. Causes serious eye damage.
Precautionary statements
:
Prevention: Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. Wash skin
thoroughly after handling. Contaminated work clothing should not be allowed out of the
workplace. Wear protective gloves/ eye protection/ face protection.
Response: IF ON SKIN: Wash with plenty of soap and water. IF IN EYES: Rinse
cautiously with water for several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing. Immediately call a POISON CENTER/doctor. If skin irritation or
rash occurs: Get medical advice/ attention. Take off contaminated clothing and wash
before reuse.
Storage: Protect from sunlight. Store in a well-ventilated place. Do not expose to
temperatures exceeding 50 °C/ 122 °F.
Disposal: Dispose of contents/container in accordance with local regulation.
Version:
3.2
Revision Date:
02/14/2018
Print Date:
04/25/2019
Flammability
Health
Instability
3
0
0
Special hazard.
FLAMMABILITY
PHYSICAL HAZARD
HEALTH
0
2
3
0 = not significant, 1 =Slight,
2 = Moderate, 3 = High
4 = Extreme, * = Chronic
SECTION 16. OTHER INFORMATION
Further information
OSHA - GHS Label Information:
We believe the statements, technical information and recommendations contained herein are
reliable, but they are given without warranty or guarantee of any kind. The information in this
document applies to this specific material as supplied. It may not be valid for this material if it
is used in combination with any other materials. Users should make their own investigations
to determine the suitability and applicability of the information for their particular purposes.
This SDS has been prepared by the Compliance Services organization supporting this
manufacturer, supplier or distributor.
Zep Inc. markets products under well recognized and established brand names such as Zep®,
Zep Commercial®,Zep Professional®, Enforcer®, National Chemical™, Selig™, Misty®, Next
11 / 12
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SAFETY DATA SHEET
A07317 ZEP 65 CITRUS FOAM 003701 20N18
Version 3.2
Revision Date 02/14/2018
Print Date 04/25/2019
Dimension™, Petro®, i-Chem®, TimeMist®, TimeWick™, MicrobeMax®, Country Vet®,
Konk®, Original Bike Spirits®, Blue Coral®, Black Magic®, Rain-X®, Niagara National™, FC
Forward Chemicals®,Rexodan®, Mykal™, and a number of private labeled brands.
12 / 12
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