Zep 357501 User Manual

SAFETY DATA SHEET

A07648 ZEP 75 INDUST DGRSR 357501

Version 4.0

Revision Date 04/04/2019

Print Date 04/26/2019

Material name

:

A07648 ZEP 75 INDUST DGRSR 357501
Material number

:

000000000000357501

Company

:

Zep Inc.

Address

:

350 Joe Frank Harris Parkway, SE
Emerson, GA 30137
Telephone

:

404-352-1680

Emergency telephone numbers

For SDS Information

:

Compliance Services 1-877-428-9937

For a Medical Emergency

:

877-541-2016 Toll Free - All Calls Recorded

For a Transportation
Emergency

:

CHEMTREC: 800-424-9300 - All Calls Recorded.
In the District of Columbia 202-483-7616

Recommended use

:

Degreaser
Appearance

Aerosol containing a compressed gas

Colour

colourless

Odour

characteristic

Flammable aerosols

:

Category 1

Gases under pressure

:

Compressed gas

Skin irritation

:

Category 2

Eye irritation

:

Category 2A

Skin sensitisation

:

Category 1

Hazard pictograms

:

Signal word

:

Danger

SECTION 1. PRODUCT AND COMPANY IDENTIFICATION

Manufacturer or supplier's details

Recommended use of the chemical and restrictions on use

Note: This product is labeled as a consumer product in accordance with the United States
Consumer Product Safety Commission regulations. The warnings presented below in this Safety
Data Sheet (SDS) comply with the 2012 OSHA Hazard Communication Standard (GHS - Globally
Harmonized System of Classification and Labeling). The requirements for the labeling and
warnings of consumer products may differ from those required for GHS based hazard
communication.

SECTION 2. HAZARDS IDENTIFICATION

Emergency Overview

GHS Classification

GHS label elements

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SAFETY DATA SHEET

A07648 ZEP 75 INDUST DGRSR 357501

Version 4.0

Revision Date 04/04/2019

Print Date 04/26/2019

Hazard statements

:

H222 Extremely flammable aerosol.
H280 Contains gas under pressure; may explode if heated.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.

Precautionary statements

:

Prevention:
P210 Keep away from heat, hot surfaces, sparks, open flames
and other ignition sources. No smoking.
P211 Do not spray on an open flame or other ignition source.
P251 Pressurized container: Do not pierce or burn, even after
use.
P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
P264 Wash skin thoroughly after handling.
P272 Contaminated work clothing should not be allowed out of
the workplace.
P280 Wear protective gloves/ eye protection/ face protection.

Response:

P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water
for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing.
P333 + P313 If skin irritation or rash occurs: Get medical
advice/ attention.
P337 + P313 If eye irritation persists: Get medical advice/
attention.
P362 Take off contaminated clothing and wash before reuse.
Storage:
P410 + P412 Protect from sunlight. Do not expose to
temperatures exceeding 50 °C/ 122 °F.
Disposal:
P501 Dispose of contents/container in accordance with local
regulation.
Substance / Mixture

:

Mixture

Chemical name

CAS-No.

Concentration [%]

Distillates (petroleum), hydrotreated light

64742-47-8

>= 50 - < 70

Citrus, ext.

94266-47-4

>= 5 - < 10

Solvent naphtha (petroleum), heavy aliph.

64742-96-7

>= 5 - < 10

Alcohols, C12-16, ethoxylated

68551-12-2

>= 5 - < 10

carbon dioxide

124-38-9

>= 1 - < 3

General advice

:

Move out of dangerous area.
Show this safety data sheet to the doctor in attendance.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Hazardous components

The exact percentages of disclosed substances are withheld as trade secrets.

SECTION 4. FIRST AID MEASURES

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SAFETY DATA SHEET

A07648 ZEP 75 INDUST DGRSR 357501

Version 4.0

Revision Date 04/04/2019

Print Date 04/26/2019

Do not leave the victim unattended.

If inhaled

:

If unconscious, place in recovery position and seek medical
advice.
Consult a physician after significant exposure.
Remove to fresh air.

In case of skin contact

:

If skin irritation persists, call a physician.
Wash off immediately with plenty of water for at least 15
minutes.
Remove contaminated clothing and shoes.
Wash contaminated clothing before re-use.

In case of eye contact

:

Remove contact lenses.
Protect unharmed eye.
If eye irritation persists, consult a specialist.
Keep eye wide open while rinsing.
Rinse immediately with plenty of water for at least 15 minutes.

If swallowed

:

Keep respiratory tract clear.
Never give anything by mouth to an unconscious person.
If symptoms persist, call a physician.
DO NOT induce vomiting unless directed to do so by a
physician or poison control center.
Take victim immediately to hospital.

Most important symptoms
and effects, both acute and
delayed

:

Effects are immediate and delayed.
Symptoms may include irritation, redness, pain, and rash.
Causes skin irritation.
Review section 2 of SDS to see all potential hazards.
May cause an allergic skin reaction.
Causes serious eye irritation.

Notes to physician

:

Treat symptomatically. Symptoms may be delayed.

Suitable extinguishing media

:

Dry chemical
Foam
Carbon dioxide (CO2)
Water spray jet

Unsuitable extinguishing
media

:

High volume water jet

Specific hazards during
firefighting

:

Do not allow run-off from fire fighting to enter drains or water
courses.

Hazardous combustion
products

:

Carbon dioxide (CO2)
Carbon monoxide
Smoke

Specific extinguishing
methods

:

Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.

SECTION 5. FIREFIGHTING MEASURES

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SAFETY DATA SHEET

A07648 ZEP 75 INDUST DGRSR 357501

Version 4.0

Revision Date 04/04/2019

Print Date 04/26/2019

Further information

:

Collect contaminated fire extinguishing water separately. This
must not be discharged into drains.
Fire residues and contaminated fire extinguishing water must
be disposed of in accordance with local regulations.
For safety reasons in case of fire, cans should be stored
separately in closed containments.
Use a water spray to cool fully closed containers.

Special protective equipment
for firefighters

:

Wear self-contained breathing apparatus for firefighting if
necessary.

Personal precautions,
protective equipment and
emergency procedures

:

Use personal protective equipment.
Ensure adequate ventilation.
Remove all sources of ignition.
Evacuate personnel to safe areas.
Beware of vapours accumulating to form explosive
concentrations. Vapours can accumulate in low areas.

Environmental precautions

:

Prevent product from entering drains.
Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains inform
respective authorities.

Methods and materials for
containment and cleaning up

:

Soak up with inert absorbent material (e.g. sand, silica gel,
acid binder, universal binder, sawdust).
Sweep up or vacuum up spillage and collect in suitable
container for disposal.

Advice on safe handling

:

For personal protection see section 8.
Smoking, eating and drinking should be prohibited in the
application area.
Avoid exposure - obtain special instructions before use.
Avoid contact with skin and eyes.
Take precautionary measures against static discharges.
Provide sufficient air exchange and/or exhaust in work rooms.
Do not breathe vapours or spray mist.
Dispose of rinse water in accordance with local and national
regulations.
Always replace cap after use.
Persons susceptible to skin sensitisation problems or asthma,
allergies, chronic or recurrent respiratory disease should not
be employed in any process in which this mixture is being
used.

Conditions for safe storage

:

BEWARE: Aerosol is pressurized. Keep away from direct sun
exposure and temperatures over 50 °C. Do not open by force
or throw into fire even after use. Do not spray on flames or
red-hot objects.
No smoking.
Keep in a dry, cool and well-ventilated place.

SECTION 6. ACCIDENTAL RELEASE MEASURES

SECTION 7. HANDLING AND STORAGE

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SAFETY DATA SHEET

A07648 ZEP 75 INDUST DGRSR 357501

Version 4.0

Revision Date 04/04/2019

Print Date 04/26/2019

Observe label precautions.
Electrical installations / working materials must comply with
the technological safety standards.

Materials to avoid

:

Oxidizing agents
Do not store near acids.

Components

CAS-No.

Value type
(Form of
exposure)

Control
parameters /
Permissible
concentration

Basis
Distillates (petroleum),

hydrotreated light

64742-47-8

TWA

500 ppm
2,000 mg/m3

OSHA Z-1

TWA

400 ppm
1,600 mg/m3

OSHA P0
TWA (Mist)

5 mg/m3

OSHA Z-1

TWA (Mist)

5 mg/m3

OSHA P0

TWA (Mist)

5 mg/m3

NIOSH REL

ST (Mist)

10 mg/m3

NIOSH REL

PEL
(particulate)

5 mg/m3

CAL PEL
carbon dioxide

124-38-9

TWA

5,000 ppm

ACGIH

STEL

30,000 ppm

ACGIH

TWA

5,000 ppm
9,000 mg/m3

NIOSH REL

ST

30,000 ppm
54,000 mg/m3

NIOSH REL

TWA

5,000 ppm
9,000 mg/m3

OSHA Z-1

TWA

10,000 ppm
18,000 mg/m3

OSHA P0

STEL

30,000 ppm
54,000 mg/m3

OSHA P0

PEL

5,000 ppm
9,000 mg/m3

CAL PEL

STEL

30,000 ppm
54,000 mg/m3

CAL PEL

Engineering measures

:

effective ventilation in all processing areas

Respiratory protection

:

Use respiratory protection unless adequate local exhaust
ventilation is provided or exposure assessment demonstrates
that exposures are within recommended exposure guidelines.
Material

:

Protective gloves

Remarks

:

The suitability for a specific workplace should be discussed
with the producers of the protective gloves.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Components with workplace control parameters

Personal protective equipment

Hand protection

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SAFETY DATA SHEET

A07648 ZEP 75 INDUST DGRSR 357501

Version 4.0

Revision Date 04/04/2019

Print Date 04/26/2019

Eye protection

:

Safety glasses
Access to clean water to rinse eyes must be available, options
include: eye wash stations or showers, or eye wash bottles
with pure water.

Skin and body protection

:

Impervious clothing
Choose body protection according to the amount and
concentration of the dangerous substance at the work place.

Hygiene measures

:

When using do not smoke.
When using do not eat or drink.
Wash hands before breaks and at the end of workday.

Appearance

:

Aerosol containing a compressed gas

Colour

:

colourless

Odour

:

characteristic

Odour Threshold

:

No data available

pH : Not applicable

Melting point/freezing point

:

Not applicable

Boiling point

:

Not applicable

Flash point

:

Not applicable

Evaporation rate

:

No data available

Flammability (solid, gas)

:

Extremely flammable aerosol.

Upper explosion limit

:

No data available

Lower explosion limit

:

No data available

Vapour pressure

:

No data available

Relative vapour density

:

No data available

No data available

No data available

Density

:

No data available

Water solubility

:

slightly soluble

Solubility in other solvents

:

not determined

Partition coefficient: n­octanol/water

:

No data available

Auto-ignition temperature

:

not determined

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Solubility(ies)

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SAFETY DATA SHEET

A07648 ZEP 75 INDUST DGRSR 357501

Version 4.0

Revision Date 04/04/2019

Print Date 04/26/2019

Thermal decomposition

:

No data available

Viscosity, kinematic

:

No data available

Reactivity

:

Stable

Chemical stability

:

Stable under normal conditions.

Possibility of hazardous
reactions

:

Vapours may form explosive mixture with air.
No decomposition if stored and applied as directed.

Conditions to avoid

:

Heat, flames and sparks.
Extremes of temperature and direct sunlight.

Incompatible materials

:

Oxidizing agents
Acids

Hazardous decomposition
products

:

Carbon oxides

Aggravated Medical
Condition

:

None known.

Symptoms of Overexposure

:

Effects are immediate and delayed.
Symptoms may include irritation, redness, pain, and rash.

IARC

No component of this product present at levels greater than or
equal to 0.1% is identified as probable, possible or confirmed
human carcinogen by IARC.

ACGIH

No component of this product present at levels greater than or
equal to 0.1% is identified as a carcinogen or potential
carcinogen by ACGIH.

OSHA

No component of this product present at levels greater than or
equal to 0.1% is on OSHA’s list of regulated carcinogens.

NTP

No component of this product present at levels greater than or
equal to 0.1% is identified as a known or anticipated carcinogen
by NTP.

Viscosity

SECTION 10. STABILITY AND REACTIVITY

SECTION 11. TOXICOLOGICAL INFORMATION

Potential Health Effects

Carcinogenicity:

Acute toxicity

Product:

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SAFETY DATA SHEET

A07648 ZEP 75 INDUST DGRSR 357501

Version 4.0

Revision Date 04/04/2019

Print Date 04/26/2019

Acute dermal toxicity

:

Acute toxicity estimate : 3,752 mg/kg
Method: Calculation method

Acute oral toxicity

:

LD50 Rat: > 5,000 mg/kg

Acute inhalation toxicity

:

LC50 Rat: > 4.6 mg/l
Exposure time: 6 h

Acute dermal toxicity

:

LD50 Rat: > 2,000 mg/kg

Remarks: Irritating to skin.

Remarks: Irritating to eyes.

Remarks: Causes sensitisation.

Remarks: No data available

Components:
Distillates (petroleum), hydrotreated light:

Skin corrosion/irritation

Product:

Serious eye damage/eye irritation

Product:

Respiratory or skin sensitisation

Product:

Germ cell mutagenicity

No data available

Carcinogenicity

No data available

Reproductive toxicity

No data available

STOT - single exposure

No data available

STOT - repeated exposure

No data available

Aspiration toxicity

No data available

Further information

Product:

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SAFETY DATA SHEET

A07648 ZEP 75 INDUST DGRSR 357501

Version 4.0

Revision Date 04/04/2019

Print Date 04/26/2019

Toxicity to fish

:

LC50 (Fish): 0.1 - 1.0 mg/l
Remarks: Information taken from reference works and
the literature.

Toxicity to daphnia and
other aquatic invertebrates

:

EC50 (Daphnia magna (Water flea)): 0.1 - 1.0 mg/l
Remarks: Information taken from reference works and
the literature.

Biodegradability

:

Remarks: Readily biodegradable
Information taken from reference works and the
literature.

Partition coefficient: n­octanol/water

:

Remarks: No data available

Bioaccumulation

:

Bioconcentration factor (BCF): < 2,000
Remarks: Information taken from reference works and
the literature.

Regulation

40 CFR Protection of Environment; Part 82 Protection of
Stratospheric Ozone - CAA Section 602 Class I
Substances

Remarks

This product neither contains, nor was manufactured
with a Class I or Class II ODS as defined by the U.S.
Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A
+ B).

Additional ecological
information

:

An environmental hazard cannot be excluded in the
event of unprofessional handling or disposal., Toxic to

SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity

Components:
Citrus, ext. :

Persistence and degradability

Components:
Citrus, ext. :

Bioaccumulative potential

Product:

Components:
Citrus, ext. :

Mobility in soil

No data available

Other adverse effects

Product:

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SAFETY DATA SHEET

A07648 ZEP 75 INDUST DGRSR 357501

Version 4.0

Revision Date 04/04/2019

Print Date 04/26/2019

aquatic life.

Results of PBT and vPvB
assessment

:

This substance is not considered to be persistent,
bioaccumulating and toxic (PBT)., Remarks: Information
taken from reference works and the literature.

Waste from residues

:

The product should not be allowed to enter drains, water
courses or the soil.
Do not contaminate ponds, waterways or ditches with
chemical or used container.
Dispose of in accordance with local regulations.

Contaminated packaging

:

Empty remaining contents.
Dispose of as unused product.
Do not re-use empty containers.
Do not burn, or use a cutting torch on, the empty drum.

Transportation Regulation: 49 CFR (USA):
ORM-D, CONSUMER COMMODITY

Transportation Regulation: IMDG (Vessel):
UN1950, AEROSOLS, FLAMMABLE, 2.1, - Limited quantity

Transportation Regulation: IATA (Cargo Air):
UN1950, Aerosols, flammable, 2.1, - Limited quantity

Transportation Regulation: IATA (Passenger Air):
UN1950, Aerosols, flammable, 2.1, - Limited quantity

Transportation Regulation: TDG (Canada):
UN1950, AEROSOLS, FLAMMABLE, 2.1, (LQ), - Limited quantity

Components:
Citrus, ext. :

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods

SECTION 14. TRANSPORT INFORMATION

The product as delivered to the customer conforms to packaging requirements for shipment by road
under US Department of Transportation (DOT) regulations. Additional transportation classifications
noted above are for reference only, and not a certification or warranty of the suitability of the packaging
for shipment under these alternative transport regulations.

SECTION 15. REGULATORY INFORMATION

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SAFETY DATA SHEET

A07648 ZEP 75 INDUST DGRSR 357501

Version 4.0

Revision Date 04/04/2019

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TSCA list

:

No substances are subject to a Significant New Use Rule.

No substances are subject to TSCA 12(b) export notification
requirements.

SARA 311/312 Hazards

:

Flammable (gases, aerosols, liquids, or solids)
Gases under pressure
Skin corrosion or irritation
Respiratory or skin sensitisation
Serious eye damage or eye irritation

SARA 302

:

No chemicals in this material are subject to the reporting
requirements of SARA Title III, Section 302.

SARA 313

:

This material does not contain any chemical components with
known CAS numbers that exceed the threshold (De Minimis)
reporting levels established by SARA Title III, Section 313.

This product does not contain any chemicals known to State of

California to cause cancer, birth defects, or any other
reproductive harm.

DSL

All components of this product are on the Canadian DSL

TSCA

On TSCA Inventory

EPCRA - Emergency Planning and Community Right-to-Know Act
CERCLA Reportable Quantity

This material does not contain any components with a CERCLA RQ.

SARA 304 Extremely Hazardous Substances Reportable Quantity

This material does not contain any components with a section 304 EHS RQ.

California Prop. 65

The components of this product are reported in the following inventories:

For information on the country notification status for other regions please contact the

manufacturer’s regulatory group.

Inventory Acronym and Validity Area Legend:

TSCA (USA), DSL (Canada), NDSL (Canada)

SECTION 16. OTHER INFORMATION

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SAFETY DATA SHEET

A07648 ZEP 75 INDUST DGRSR 357501

Version 4.0

Revision Date 04/04/2019

Print Date 04/26/2019

NFPA:

HMIS III:

Hazard pictograms

:

Signal word

:

Danger:

Hazard statements

:

Extremely flammable aerosol. Contains gas under pressure; may explode if heated.
Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation.

Precautionary statements

:
Prevention: Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking. Do not spray on an open flame or other ignition source.
Pressurized container: Do not pierce or burn, even after use. Avoid breathing dust/
fume/ gas/ mist/ vapours/ spray. Wash skin thoroughly after handling. Contaminated
work clothing should not be allowed out of the workplace. Wear protective gloves/ eye
protection/ face protection.
Response: IF ON SKIN: Wash with plenty of soap and water. IF IN EYES: Rinse
cautiously with water for several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing. If skin irritation or rash occurs: Get medical advice/ attention. If
eye irritation persists: Get medical advice/ attention. Take off contaminated clothing and
wash before reuse.
Storage: Protect from sunlight. Do not expose to temperatures exceeding 50 °C/ 122
°F.
Disposal: Dispose of contents/container in accordance with local regulation.

Version:

4.0

Revision Date:

04/04/2019

Print Date:

04/26/2019

Flammability

Health

Instability

2

4

0

Special hazard.

FLAMMABILITY

PHYSICAL HAZARD

HEALTH

4

3

2

0 = not significant, 1 =Slight,

2 = Moderate, 3 = High

4 = Extreme, * = Chronic

Further information

OSHA - GHS Label Information:

We believe the statements, technical information and recommendations contained herein are
reliable, but they are given without warranty or guarantee of any kind. The information in this
document applies to this specific material as supplied. It may not be valid for this material if it
is used in combination with any other materials. Users should make their own investigations
to determine the suitability and applicability of the information for their particular purposes.
This SDS has been prepared by the Compliance Services organization supporting this
manufacturer, supplier or distributor.

Zep Inc. markets products under well recognized and established brand names such as Zep®,

Zep Commercial®,Zep Professional®, Enforcer®, National Chemical™, Selig™, Misty®, Next
Dimension™, Petro®, i-Chem®, TimeMist®, TimeWick™, MicrobeMax®, Country Vet®,

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SAFETY DATA SHEET

A07648 ZEP 75 INDUST DGRSR 357501

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Revision Date 04/04/2019

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Konk®, Original Bike Spirits®, Blue Coral®, Black Magic®, Rain-X®, Niagara National™, FC
Forward Chemicals®,Rexodan®, Mykal™, and a number of private labeled brands.

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