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SAFETY DATA SHEET
ZEP ORIGINAL ORANGE 4-1GL_CNDS
Version 1.0
Revision Date 11/08/2019
Print Date 06/11/2020
Material name
:
ZEP ORIGINAL ORANGE 4-1GL_CNDS
Material number
:
000000000000302824
Company
:
Zep Inc.
Address
:
350 Joe Frank Harris Parkway, SE
Emerson, GA 30137
Telephone
:
404-352-1680
Emergency telephone numbers
For SDS Information
:
Compliance Services 1-877-428-9937
For a Medical Emergency
:
877-541-2016 Toll Free - All Calls Recorded
For a Transportation
Emergency
:
CHEMTREC: 800-424-9300 - All Calls Recorded.
In the District of Columbia 202-483-7616
Recommended use
:
Hand Care
Appearance
liquid
Colour
orange
Odour
pleasant
Substance / Mixture
:
Mixture
Chemical name
CAS-No.
Concentration [%]
Distillates (petroleum), hydrotreated light
64742-47-8
>= 5 - < 10
Alcohols, C12-16, ethoxylated
68551-12-2
>= 1 - < 5
quartz (SiO2)
14808-60-7
>= 0.1 - < 1
palygorskite
12174-11-7
>= 0.1 - < 1
SECTION 1. PRODUCT AND COMPANY IDENTIFICATION
Manufacturer or supplier's details
Recommended use of the chemical and restrictions on use
SECTION 2. HAZARDS IDENTIFICATION
Emergency Overview
GHS Classification
Not a hazardous substance or mixture.
GHS label elements
Not a hazardous substance or mixture.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous components
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SAFETY DATA SHEET
ZEP ORIGINAL ORANGE 4-1GL_CNDS
Version 1.0
Revision Date 11/08/2019
Print Date 06/11/2020
General advice
:
Move out of dangerous area.
Do not leave the victim unattended.
Get medical attention.
Show this safety data sheet to the doctor in attendance.
Do not leave the victim unattended.
If inhaled
:
If unconscious, place in recovery position and seek medical
advice.
If symptoms persist, call a physician.
In case of skin contact
:
This product is formulated for use on skin but should always
be immediately washed off with plenty of water. Discontinue
use if irritation and redness develop. If conditions persist for
more than 72 hours, consult a physician.
In case of eye contact
:
Rinse with plenty of water.
Remove contact lenses.
Protect unharmed eye.
Keep eye wide open while rinsing.
If eye irritation persists, consult a specialist.
If swallowed
:
Keep respiratory tract clear.
Never give anything by mouth to an unconscious person.
If symptoms persist, call a physician.
DO NOT induce vomiting unless directed to do so by a
physician or poison control center.
Most important symptoms
and effects, both acute and
delayed
:
Effects may be delayed, symptoms may include minor eye or
skin irritation.
Overexposure may cause mild eye or skin irritation.
Notes to physician
:
Treat symptomatically. Symptoms may be delayed.
Suitable extinguishing media
:
Alcohol-resistant foam
Carbon dioxide (CO2)
Dry chemical
Unsuitable extinguishing
media
:
High volume water jet
Specific hazards during
firefighting
:
Do not allow run-off from fire fighting to enter drains or water
courses.
Hazardous combustion
products
:
Carbon dioxide (CO2)
Carbon monoxide
Smoke
Specific extinguishing
:
Standard procedure for chemical fires.
The exact percentages of disclosed substances are withheld as trade secrets.
SECTION 4. FIRST AID MEASURES
SECTION 5. FIREFIGHTING MEASURES
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SAFETY DATA SHEET
ZEP ORIGINAL ORANGE 4-1GL_CNDS
Version 1.0
Revision Date 11/08/2019
Print Date 06/11/2020
methods
Further information
:
Collect contaminated fire extinguishing water separately. This
must not be discharged into drains.
Fire residues and contaminated fire extinguishing water must
be disposed of in accordance with local regulations.
For safety reasons in case of fire, cans should be stored
separately in closed containments.
Use a water spray to cool fully closed containers.
Special protective equipment
for firefighters
:
Wear self-contained breathing apparatus for firefighting if
necessary.
Personal precautions,
protective equipment and
emergency procedures
:
Use personal protective equipment.
Remove all sources of ignition.
Evacuate personnel to safe areas.
Environmental precautions
:
Prevent product from entering drains.
Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains, inform
respective authorities.
Methods and materials for
containment and cleaning up
:
Soak up condensate with inert absorbent material and collect
in ventilated waste container for disposal.
Contain spillage, and then collect with non-combustible
absorbent material, (e.g. sand, earth, diatomaceous earth,
vermiculite) and place in container for disposal according to
local / national regulations (see section 13).
Advice on safe handling
:
Do not breathe vapours or spray mist.
Avoid exposure - obtain special instructions before use.
Avoid contact with skin and eyes.
For personal protection see section 8.
Smoking, eating and drinking should be prohibited in the
application area.
Take precautionary measures against static discharges.
Provide sufficient air exchange and/or exhaust in work rooms.
Open drum carefully as content may be under pressure.
Dispose of rinse water in accordance with local and national
regulations.
Persons susceptible to skin sensitisation problems or asthma,
allergies, chronic or recurrent respiratory disease should not
be employed in any process in which this mixture is being
used.
Conditions for safe storage
:
No smoking.
Keep container tightly closed in a dry and well-ventilated
place.
Containers which are opened must be carefully resealed and
kept upright to prevent leakage.
Observe label precautions.
SECTION 6. ACCIDENTAL RELEASE MEASURES
SECTION 7. HANDLING AND STORAGE
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SAFETY DATA SHEET
ZEP ORIGINAL ORANGE 4-1GL_CNDS
Version 1.0
Revision Date 11/08/2019
Print Date 06/11/2020
Electrical installations / working materials must comply with
the technological safety standards.
Materials to avoid
:
Oxidizing agents
Do not store near acids.
Components
CAS-No.
Value type
(Form of
exposure)
Control
parameters /
Permissible
concentration
Basis
Distillates (petroleum),
hydrotreated light
64742-47-8
TWA
500 ppm
2,000 mg/m3
OSHA Z-1
TWA
400 ppm
1,600 mg/m3
OSHA P0
TWA (Mist)
5 mg/m3
OSHA Z-1
TWA (Mist)
5 mg/m3
OSHA P0
TWA (Mist)
5 mg/m3
NIOSH REL
ST (Mist)
10 mg/m3
NIOSH REL
PEL
(particulate)
5 mg/m3
CAL PEL
quartz (SiO2)
14808-60-7
TWA (total
dust)
30 mg/m3 /
%SiO2+2
OSHA Z-3
TWA
(Respirable
dust)
0.05 mg/m3
NIOSH REL
TWA
(Respirable
dust)
0.05 mg/m3
OSHA Z-1
PEL
(Respirable
dust)
0.05 mg/m3
CAL PEL
Engineering measures
:
effective ventilation in all processing areas
Respiratory protection
:
No personal respiratory protective equipment normally
required.
Remarks
:
The use of skin protection is not normally required; however,
good industrial hygiene practice suggests the use of gloves or
other appropriate skin protection whenever working with
chemicals, and especially if prolonged or frequent contact is
possible or likely.
Eye protection
:
Eye protection is not required while washing with this product.
In the workplace, the use of safety glasses is recommended to
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters
Personal protective equipment
Hand protection
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SAFETY DATA SHEET
ZEP ORIGINAL ORANGE 4-1GL_CNDS
Version 1.0
Revision Date 11/08/2019
Print Date 06/11/2020
avoid eye exposure during the handling of containers or
during spill clean-up.
Skin and body protection
:
No special protection is required.
Hygiene measures
:
When using do not eat or drink.
When using do not smoke.
Wash hands before breaks and at the end of workday.
Appearance
:
liquid
Colour
:
orange
Odour
:
pleasant
Odour Threshold
:
No data available
pH : 7.5 - 8.5
Melting point/freezing point
:
No data available
Boiling point
:
No data available
Flash point
:
> 93.3 °C
Vapour pressure
:
No data available
Relative vapour density
:
No data available
Density
:
1.04 g/cm3
Water solubility
:
emulsifiable
Solubility in other solvents
:
soluble
Partition coefficient: noctanol/water
:
No data available
Viscosity, kinematic
:
No data available
Reactivity
:
No decomposition if stored and applied as directed.
Chemical stability
:
No decomposition if stored and applied as directed.
Possibility of hazardous
reactions
:
Stable under recommended storage conditions.
No hazards to be specially mentioned.
Conditions to avoid
:
No data available
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Solubility(ies)
Viscosity
SECTION 10. STABILITY AND REACTIVITY
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SAFETY DATA SHEET
ZEP ORIGINAL ORANGE 4-1GL_CNDS
Version 1.0
Revision Date 11/08/2019
Print Date 06/11/2020
Hazardous decomposition
products
:
No decomposition if stored and applied as directed.
Aggravated Medical
Condition
:
None known.
Symptoms of Overexposure
:
Effects may be delayed, symptoms may include minor eye or
skin irritation.
IARC
Group 1: Carcinogenic to humans
quartz (SiO2)
14808-60-7
ACGIH
No component of this product present at levels greater than or
equal to 0.1% is identified as a carcinogen or potential
carcinogen by ACGIH.
OSHA
No component of this product present at levels greater than or
equal to 0.1% is on OSHA’s list of regulated carcinogens.
NTP
No component of this product present at levels greater than or
equal to 0.1% is identified as a known or anticipated carcinogen
by NTP.
Acute dermal toxicity
:
Acute toxicity estimate : > 5,000 mg/kg
Method: Calculation method
Acute oral toxicity
:
LD50 Rat: > 5,000 mg/kg
Acute inhalation toxicity
:
LC50 Rat: > 4.6 mg/l
Exposure time: 6 h
Acute dermal toxicity
:
LD50 Rat: > 2,000 mg/kg
Result: No skin irritation
SECTION 11. TOXICOLOGICAL INFORMATION
Potential Health Effects
Carcinogenicity:
Acute toxicity
Product:
Components:
Distillates (petroleum), hydrotreated light:
Skin corrosion/irritation
Product:
Serious eye damage/eye irritation
Product:
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SAFETY DATA SHEET
ZEP ORIGINAL ORANGE 4-1GL_CNDS
Version 1.0
Revision Date 11/08/2019
Print Date 06/11/2020
Remarks: Contact with eyes may cause irritation.
Carcinogenicity Assessment
:
Not classifiable as a human carcinogen., Not classified
due to product form (liquid) and classification route of
entry (inhaled powder).
Remarks: No data available
Remarks: No data available
Partition coefficient: noctanol/water
:
Remarks: No data available
Respiratory or skin sensitisation
No data available
Germ cell mutagenicity
No data available
Carcinogenicity
Product:
Reproductive toxicity
No data available
STOT - single exposure
No data available
STOT - repeated exposure
No data available
Aspiration toxicity
No data available
Further information
Product:
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
No data available
Persistence and degradability
No data available
Bioaccumulative potential
Product:
Mobility in soil
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SAFETY DATA SHEET
ZEP ORIGINAL ORANGE 4-1GL_CNDS
Version 1.0
Revision Date 11/08/2019
Print Date 06/11/2020
Regulation
40 CFR Protection of Environment; Part 82 Protection of
Stratospheric Ozone - CAA Section 602 Class I
Substances
Remarks
This product neither contains, nor was manufactured
with a Class I or Class II ODS as defined by the U.S.
Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A
+ B).
Additional ecological
information
:
No data available
An environmental hazard cannot be excluded in the
event of unprofessional handling or disposal., Harmful to
aquatic life.
Waste from residues
:
The product should not be allowed to enter drains, water
courses or the soil.
Do not contaminate ponds, waterways or ditches with
chemical or used container.
Dispose of in accordance with local regulations.
Contaminated packaging
:
Empty remaining contents.
Dispose of as unused product.
Do not re-use empty containers.
Transportation Regulation: 49 CFR (USA):
NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS MATERIAL
Transportation Regulation: IMDG (Vessel):
NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS MATERIAL
Transportation Regulation: IATA (Cargo Air):
NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS MATERIAL
Transportation Regulation: IATA (Passenger Air):
NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS MATERIAL
No data available
Other adverse effects
No data available
Product:
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods
SECTION 14. TRANSPORT INFORMATION
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SAFETY DATA SHEET
ZEP ORIGINAL ORANGE 4-1GL_CNDS
Version 1.0
Revision Date 11/08/2019
Print Date 06/11/2020
Transportation Regulation: TDG (Canada):
NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS MATERIAL
TSCA list
:
No substances are subject to a Significant New Use Rule.
No substances are subject to TSCA 12(b) export notification
requirements.
Components
CAS-No.
Component RQ
(lbs)
Calculated product RQ
(lbs)
copper dinitrate
3251-23-8
100
*
SARA 311/312 Hazards
:
No SARA Hazards
SARA 302
:
No chemicals in this material are subject to the reporting
requirements of SARA Title III, Section 302.
SARA 313
:
This material does not contain any chemical components with
known CAS numbers that exceed the threshold (De Minimis)
reporting levels established by SARA Title III, Section 313.
This product does not contain any chemicals known to State of
California to cause cancer, birth defects, or any other
reproductive harm.
DSL
This product contains one or more components that are listed on the
The product as delivered to the customer conforms to packaging requirements for shipment by road
under US Department of Transportation (DOT) regulations. Additional transportation classifications
noted above are for reference only, and not a certification or warranty of the suitability of the packaging
for shipment under these alternative transport regulations.
SECTION 15. REGULATORY INFORMATION
EPCRA - Emergency Planning and Community Right-to-Know Act
CERCLA Reportable Quantity
*: Calculated RQ exceeds reasonably attainable upper limit.
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.
California Prop. 65
The components of this product are reported in the following inventories:
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SAFETY DATA SHEET
ZEP ORIGINAL ORANGE 4-1GL_CNDS
Version 1.0
Revision Date 11/08/2019
Print Date 06/11/2020
Canadian NDSL. All other components are on the Canadian DSL.
TSCA
On TSCA Inventory
NFPA:
HMIS III:
Version:
1.0
Revision Date:
11/08/2019
Print Date:
06/11/2020
Flammability
Health
Instability
1
1
0
Special hazard.
FLAMMABILITY
PHYSICAL HAZARD
HEALTH
1
0
0
0 = not significant, 1 =Slight,
2 = Moderate, 3 = High
4 = Extreme, * = Chronic
For information on the country notification status for other regions please contact the
manufacturer’s regulatory group.
Inventory Acronym and Validity Area Legend:
TSCA (USA), DSL (Canada), NDSL (Canada)
SECTION 16. OTHER INFORMATION
Further information
OSHA - GHS Label Information:
Not a hazardous substance or mixture.
We believe the statements, technical information and recommendations contained herein are
reliable, but they are given without warranty or guarantee of any kind. The information in this
document applies to this specific material as supplied. It may not be valid for this material if it
is used in combination with any other materials. Users should make their own investigations
to determine the suitability and applicability of the information for their particular purposes.
This SDS has been prepared by the Compliance Services organization supporting this
manufacturer, supplier or distributor.
Zep Inc. markets products under well recognized and established brand names such as Zep®,
Zep Commercial®,Zep Professional®, Enforcer®, National Chemical™, Selig™, Misty®, Next
Dimension™, Petro®, i-Chem®, TimeMist®, TimeWick™, MicrobeMax®, Country Vet®,
Konk®, Original Bike Spirits®, Blue Coral®, Black Magic®, Rain-X®, Niagara National™, FC
Forward Chemicals®,Rexodan®, Mykal™, and a number of private labeled brands.
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SAFETY DATA SHEET
ZEP ORIGINAL ORANGE 4-1GL_CNDS
Version 1.0
Revision Date 11/08/2019
Print Date 06/11/2020
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