Zep 28201 User Manual

Page 1
SAFETY DATA SHEET
A07244 ZEP POWERHOUSE 028201 20n18
Version 3.0
Print Date 04/26/2019
Material name
:
A07244 ZEP POWERHOUSE 028201 20n18 Material number
:
000000000000028201
Company
:
Zep Inc.
Address
:
350 Joe Frank Harris Parkway, SE Emerson, GA 30137 Telephone
:
404-352-1680
Emergency telephone numbers
For SDS Information
:
Compliance Services 1-877-428-9937
For a Medical Emergency
:
877-541-2016 Toll Free - All Calls Recorded
For a Transportation Emergency
:
CHEMTREC: 800-424-9300 - All Calls Recorded. In the District of Columbia 202-483-7616
Recommended use
:
Degreaser Appearance
Aerosol containing a liquefied gas
Colour
colourless
Odour
characteristic
Gases under pressure
:
Liquefied gas
Skin irritation
:
Category 2
Eye irritation
:
Category 2A
Hazard pictograms
:
Signal word
:
Warning
Hazard statements
:
H280 Contains gas under pressure; may explode if heated. H315 Causes skin irritation. H319 Causes serious eye irritation.
Precautionary statements
:
Prevention: P264 Wash skin thoroughly after handling. P280 Wear protective gloves/ eye protection/ face protection.
Response:
SECTION 1. PRODUCT AND COMPANY IDENTIFICATION
Manufacturer or supplier's details
Recommended use of the chemical and restrictions on use
SECTION 2. HAZARDS IDENTIFICATION
Emergency Overview
GHS Classification
GHS label elements
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SAFETY DATA SHEET
A07244 ZEP POWERHOUSE 028201 20n18
Version 3.0
Print Date 04/26/2019
P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P332 + P313 If skin irritation occurs: Get medical advice/ attention. P337 + P313 If eye irritation persists: Get medical advice/ attention. P362 Take off contaminated clothing and wash before reuse. Storage: P410 + P403 Protect from sunlight. Store in a well-ventilated place. P412 Do not expose to temperatures exceeding 50 °C/ 122 °F. Substance / Mixture
:
Mixture
Chemical name
CAS-No.
Concentration [%]
ethanol
64-17-5
>= 10 - < 20
butane
106-97-8
>= 1 - < 5
2-butoxyethanol
111-76-2
>= 1 - < 5
2-aminoethanol
141-43-5
>= 1 - < 3
propan-2-ol
67-63-0
>= 1 - < 5
propane
74-98-6
>= 1 - < 5
General advice
:
Move out of dangerous area. Show this safety data sheet to the doctor in attendance. Do not leave the victim unattended.
If inhaled
:
If unconscious, place in recovery position and seek medical advice. If symptoms persist, call a physician.
In case of skin contact
:
If skin irritation persists, call a physician. Wash off immediately with plenty of water for at least 15 minutes. If on clothes, remove clothes.
In case of eye contact
:
Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing. If eye irritation persists, consult a specialist. If in eyes, rinse with water for 15 minutes.
If swallowed
:
Keep respiratory tract clear. Never give anything by mouth to an unconscious person. DO NOT induce vomiting unless directed to do so by a
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous components
The exact percentages of disclosed substances are withheld as trade secrets.
SECTION 4. FIRST AID MEASURES
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SAFETY DATA SHEET
A07244 ZEP POWERHOUSE 028201 20n18
Version 3.0
Print Date 04/26/2019
physician or poison control center. If symptoms persist, call a physician.
Most important symptoms and effects, both acute and delayed
:
Effects are immediate and delayed. Symptoms may include irritation, redness, pain, and rash. Causes skin irritation. Causes serious eye irritation. Review section 2 of SDS to see all potential hazards.
Notes to physician
:
Treat symptomatically. Symptoms may be delayed.
Suitable extinguishing media
:
Water spray jet Alcohol-resistant foam Carbon dioxide (CO2) Dry chemical
Unsuitable extinguishing media
:
High volume water jet
Specific hazards during firefighting
:
Do not allow run-off from fire fighting to enter drains or water courses.
Hazardous combustion products
:
Carbon dioxide (CO2) Carbon monoxide Smoke Nitrogen oxides (NOx)
Specific extinguishing methods
:
Standard procedure for chemical fires.
Further information
:
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Special protective equipment for firefighters
:
Wear self-contained breathing apparatus for firefighting if necessary.
Personal precautions, protective equipment and emergency procedures
:
Use personal protective equipment. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. Evacuate personnel to safe areas. Ensure adequate ventilation. Remove all sources of ignition.
Environmental precautions
:
Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. Prevent product from entering drains.
Methods and materials for containment and cleaning up
:
Wipe up with absorbent material (e.g. cloth, fleece).
SECTION 5. FIREFIGHTING MEASURES
SECTION 6. ACCIDENTAL RELEASE MEASURES
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SAFETY DATA SHEET
A07244 ZEP POWERHOUSE 028201 20n18
Version 3.0
Print Date 04/26/2019
Advice on safe handling
:
Avoid contact with skin and eyes. For personal protection see section 8. Smoking, eating and drinking should be prohibited in the application area. Always replace cap after use. Dispose of rinse water in accordance with local and national regulations. Do not breathe vapours or spray mist. Avoid exposure - obtain special instructions before use. Take precautionary measures against static discharges. Provide sufficient air exchange and/or exhaust in work rooms.
Conditions for safe storage
:
BEWARE: Aerosol is pressurized. Keep away from direct sun exposure and temperatures over 50 °C. Do not open by force or throw into fire even after use. Do not spray on flames or red-hot objects. No smoking. Observe label precautions. Electrical installations / working materials must comply with the technological safety standards. Keep in a dry, cool and well-ventilated place.
Materials to avoid
:
Do not store near acids. Strong oxidizing agents
Components
CAS-No.
Value type (Form of exposure)
Control parameters / Permissible concentration
Basis
ethanol
64-17-5
TWA
1,000 ppm
ACGIH
TWA
1,000 ppm 1,900 mg/m3
NIOSH REL
TWA
1,000 ppm 1,900 mg/m3
OSHA Z-1
TWA
1,000 ppm 1,900 mg/m3
OSHA P0 STEL
1,000 ppm
ACGIH
PEL
1,000 ppm 1,900 mg/m3
CAL PEL
butane
106-97-8
TWA
800 ppm 1,900 mg/m3
NIOSH REL
TWA
800 ppm 1,900 mg/m3
OSHA P0
PEL
800 ppm 1,900 mg/m3
CAL PEL 2-butoxyethanol
111-76-2
TWA
20 ppm
ACGIH
TWA
5 ppm 24 mg/m3
NIOSH REL
SECTION 7. HANDLING AND STORAGE
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters
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SAFETY DATA SHEET
A07244 ZEP POWERHOUSE 028201 20n18
Version 3.0
Print Date 04/26/2019
TWA
50 ppm 240 mg/m3
OSHA Z-1
TWA
25 ppm 120 mg/m3
OSHA P0
PEL
20 ppm 97 mg/m3
CAL PEL 2-aminoethanol
141-43-5
TWA
3 ppm
ACGIH
STEL
6 ppm
ACGIH
TWA
3 ppm 8 mg/m3
NIOSH REL
ST
6 ppm 15 mg/m3
NIOSH REL
TWA
3 ppm 6 mg/m3
OSHA Z-1
STEL
6 ppm 15 mg/m3
OSHA P0
TWA
3 ppm 8 mg/m3
OSHA P0
PEL
3 ppm 8 mg/m3
CAL PEL
STEL
6 ppm 15 mg/m3
CAL PEL propan-2-ol
67-63-0
TWA
200 ppm
ACGIH
STEL
400 ppm
ACGIH
TWA
400 ppm 980 mg/m3
NIOSH REL
ST
500 ppm 1,225 mg/m3
NIOSH REL
TWA
400 ppm 980 mg/m3
OSHA Z-1
TWA
400 ppm 980 mg/m3
OSHA P0
STEL
500 ppm 1,225 mg/m3
OSHA P0
PEL
400 ppm 980 mg/m3
CAL PEL
STEL
500 ppm 1,225 mg/m3
CAL PEL propane
74-98-6
TWA
1,000 ppm
ACGIH
TWA
1,000 ppm 1,800 mg/m3
NIOSH REL
TWA
1,000 ppm 1,800 mg/m3
OSHA Z-1
TWA
1,000 ppm 1,800 mg/m3
OSHA P0
PEL
1,000 ppm 1,800 mg/m3
CAL PEL
Component
CAS-No.
Control
parameters
Biological specimen
Sampling
time
Permissible
concentration
Basis
2-BUTOXYETHANOL
111-76-2
Butoxyacetic acid (BAA)
Urine
End of
shift (As
soon as
possible
after
200.mg/g Creatinine
ACGIH BEI
Biological occupational exposure limits
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SAFETY DATA SHEET
A07244 ZEP POWERHOUSE 028201 20n18
Version 3.0
Print Date 04/26/2019
exposure
ceases)
PROPAN-2-OL
67-63-0
Acetone
Urine
End of shift at end of
workwee
k
40 mg/l
ACGIH BEI
Engineering measures
:
effective ventilation in all processing areas
Respiratory protection
:
Use respiratory protection unless adequate local exhaust ventilation is provided or exposure assessment demonstrates that exposures are within recommended exposure guidelines. Material
:
Protective gloves
Remarks
:
The suitability for a specific workplace should be discussed with the producers of the protective gloves.
Eye protection
:
Tightly fitting safety goggles Ensure that eyewash stations and safety showers are close to the workstation location.
Skin and body protection
:
Impervious clothing Choose body protection according to the amount and concentration of the dangerous substance at the work place.
Hygiene measures
:
When using do not eat or drink. When using do not smoke. Wash hands before breaks and at the end of workday.
Appearance
:
Aerosol containing a liquefied gas
Colour
:
colourless
Odour
:
characteristic
Odour Threshold
:
No data available
pH : 10.5 - 11.5
Melting point/freezing point
:
No data available
Boiling point
:
Not applicable
Flash point
:
Not applicable
Evaporation rate
:
< 1 n-Butyl Acetate = 1.0
Flammability (solid, gas)
:
The product is not flammable.
Personal protective equipment
Hand protection
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
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SAFETY DATA SHEET
A07244 ZEP POWERHOUSE 028201 20n18
Version 3.0
Print Date 04/26/2019
Upper explosion limit
:
Not applicable
Lower explosion limit
:
Not applicable
Vapour pressure
:
No data available
Relative vapour density
:
No data available
Density
:
0.97 g/cm3
Water solubility
:
soluble
Solubility in other solvents
:
not determined
Partition coefficient: n­octanol/water
:
No data available
Auto-ignition temperature
:
not determined
Thermal decomposition
:
No data available
Viscosity, kinematic
:
No data available
Heat of combustion
:
< 20 kJ/g
Reactivity
:
Stable
Chemical stability
:
Stable under normal conditions.
Possibility of hazardous reactions
:
Vapours may form explosive mixture with air. No decomposition if stored and applied as directed.
Conditions to avoid
:
Heat, flames and sparks. Extremes of temperature and direct sunlight.
Incompatible materials
:
Acids Strong oxidizing agents
Hazardous decomposition products
:
Carbon monoxide, carbon dioxide and unburned hydrocarbons (smoke). Nitrogen oxides (NOx)
Aggravated Medical Condition
:
None known. Symptoms of Overexposure
:
Effects are immediate and delayed.
Solubility(ies)
Viscosity
SECTION 10. STABILITY AND REACTIVITY
SECTION 11. TOXICOLOGICAL INFORMATION
Potential Health Effects
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SAFETY DATA SHEET
A07244 ZEP POWERHOUSE 028201 20n18
Version 3.0
Print Date 04/26/2019
Symptoms may include irritation, redness, pain, and rash.
IARC
No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.
ACGIH
Confirmed animal carcinogen with unknown relevance to humans
ethanol
64-17-5
2-butoxyethanol
111-76-2
OSHA
No component of this product present at levels greater than or equal to 0.1% is on OSHA’s list of regulated carcinogens.
NTP
No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP.
Acute oral toxicity
:
Acute toxicity estimate : > 5,000 mg/kg Method: Calculation method
Acute inhalation toxicity
:
Acute toxicity estimate : 22.33 mg/l Exposure time: 4 h Test atmosphere: dust/mist Method: Calculation method
Acute dermal toxicity
:
Acute toxicity estimate : > 5,000 mg/kg Method: Calculation method
Acute oral toxicity
:
LD50 Oral Rat: 7,060 mg/kg
Acute inhalation toxicity
:
LC50 Rat: 124.7 mg/l Exposure time: 4 h Test atmosphere: vapour
Acute oral toxicity
:
LD50 Oral Rat: 880 mg/kg
Acute dermal toxicity
:
LD50 Dermal Rabbit: 1,060 mg/kg
Acute oral toxicity
:
LD50 Oral Mouse: 700 mg/kg
LD50 Oral Rat: 1,515 mg/kg
Acute inhalation toxicity
:
LC50 Mouse: > 1.21 mg/l
Carcinogenicity:
Acute toxicity
Product:
Components: ethanol:
2-butoxyethanol:
2-aminoethanol:
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SAFETY DATA SHEET
A07244 ZEP POWERHOUSE 028201 20n18
Version 3.0
Print Date 04/26/2019
Acute oral toxicity
:
LD50 Oral Rat: 4,396 mg/kg Method: Calculation method
Remarks: Irritating to skin.
Remarks: Severe eye irritation
Remarks: No data available
propan-2-ol:
Skin corrosion/irritation
Product:
Serious eye damage/eye irritation
Product:
Respiratory or skin sensitisation
No data available
Germ cell mutagenicity
No data available
Carcinogenicity
No data available
Reproductive toxicity
No data available
STOT - single exposure
No data available
STOT - repeated exposure
No data available
Aspiration toxicity
No data available
Further information
Product:
SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity
No data available
Persistence and degradability
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SAFETY DATA SHEET
A07244 ZEP POWERHOUSE 028201 20n18
Version 3.0
Print Date 04/26/2019
Partition coefficient: n­octanol/water
:
Remarks: No data available
Partition coefficient: n­octanol/water
:
Remarks: No data available
Partition coefficient: n­octanol/water
:
Pow: 2.89
Regulation
40 CFR Protection of Environment; Part 82 Protection of Stratospheric Ozone - CAA Section 602 Class I Substances
Remarks
This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B).
Additional ecological information
:
No data available
Waste from residues
:
Do not dispose of waste into sewer. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of in accordance with local regulations.
Contaminated packaging
:
Empty remaining contents. Dispose of as unused product. Do not re-use empty containers. Do not burn, or use a cutting torch on, the empty drum.
Transportation Regulation: 49 CFR (USA): ORM-D, CONSUMER COMMODITY
No data available
Bioaccumulative potential
Product:
Components: ethanol :
butane :
Mobility in soil
No data available
Other adverse effects
No data available
Product:
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods
SECTION 14. TRANSPORT INFORMATION
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SAFETY DATA SHEET
A07244 ZEP POWERHOUSE 028201 20n18
Version 3.0
Print Date 04/26/2019
Transportation Regulation: IMDG (Vessel): UN1950, AEROSOLS, NON-FLAMMABLE, 2.2, - Limited quantity
Transportation Regulation: IATA (Cargo Air): UN1950, AEROSOLS, NON-FLAMMABLE, 2.2, - Limited quantity
Transportation Regulation: IATA (Passenger Air): UN1950, AEROSOLS, NON-FLAMMABLE, 2.2, - Limited quantity
Transportation Regulation: TDG (Canada): UN1950, AEROSOLS, NON-FLAMMABLE, 2.2, - Limited quantity
TSCA list
:
No substances are subject to a Significant New Use Rule.
No substances are subject to TSCA 12(b) export notification requirements.
Components
CAS-No.
Component RQ
(lbs)
Calculated product RQ
(lbs)
2,2'-iminodiethanol
111-42-2
100
*
SARA 311/312 Hazards
:
Gases under pressure Skin corrosion or irritation Serious eye damage or eye irritation
SARA 302
:
No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313
:
The following components are subject to reporting levels established by SARA Title III, Section 313:
2-butoxyethanol
111-76-2
3.9604 %
The product as delivered to the customer conforms to packaging requirements for shipment by road under US Department of Transportation (DOT) regulations. Additional transportation classifications noted above are for reference only, and not a certification or warranty of the suitability of the packaging for shipment under these alternative transport regulations.
SECTION 15. REGULATORY INFORMATION
EPCRA - Emergency Planning and Community Right-to-Know Act
CERCLA Reportable Quantity
*: Calculated RQ exceeds reasonably attainable upper limit.
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.
California Prop. 65
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SAFETY DATA SHEET
A07244 ZEP POWERHOUSE 028201 20n18
Version 3.0
Print Date 04/26/2019
WARNING: This product can expose you to chemicals including 2,2'-iminodiethanol, which is/are known to the State of California to cause cancer. For more information go to www.P65Warnings.ca.gov.
DSL
All components of this product are on the Canadian DSL
TSCA
On TSCA Inventory
NFPA:
HMIS III:
Hazard pictograms
:
Signal word
:
Warning:
Hazard statements
:
Contains gas under pressure; may explode if heated. Causes skin irritation. Causes serious eye irritation.
Precautionary statements
: Prevention: Wash skin thoroughly after handling. Wear protective gloves/ eye protection/ face protection. Response: IF ON SKIN: Wash with plenty of soap and water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If skin irritation occurs: Get medical advice/ attention. If eye irritation persists: Get medical advice/ attention. Take off contaminated clothing and wash before reuse.
Flammability
Health
Instability
2
1
0
Special hazard.
FLAMMABILITY
PHYSICAL HAZARD
HEALTH
1
3
2
0 = not significant, 1 =Slight,
2 = Moderate, 3 = High
4 = Extreme, * = Chronic
The components of this product are reported in the following inventories:
For information on the country notification status for other regions please contact the
manufacturer’s regulatory group.
Inventory Acronym and Validity Area Legend:
TSCA (USA), DSL (Canada), NDSL (Canada)
SECTION 16. OTHER INFORMATION
Further information
OSHA - GHS Label Information:
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SAFETY DATA SHEET
A07244 ZEP POWERHOUSE 028201 20n18
Version 3.0
Print Date 04/26/2019
Storage: Protect from sunlight. Store in a well-ventilated place. Do not expose to temperatures exceeding 50 °C/ 122 °F.
Version:
3.0
Revision Date:
02/19/2018
Print Date:
04/26/2019
We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind. The information in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. Users should make their own investigations to determine the suitability and applicability of the information for their particular purposes. This SDS has been prepared by the Compliance Services organization supporting this manufacturer, supplier or distributor.
Zep Inc. markets products under well recognized and established brand names such as Zep®, Zep Commercial®,Zep Professional®, Enforcer®, National Chemical™, Selig™, Misty®, Next Dimension™, Petro®, i-Chem®, TimeMist®, TimeWick™, MicrobeMax®, Country Vet®, Konk®, Original Bike Spirits®, Blue Coral®, Black Magic®, Rain-X®, Niagara National™, FC Forward Chemicals®,Rexodan®, Mykal™, and a number of private labeled brands.
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