Page 1
SAFETY DATA SHEET
A07316 ZEP BIG ORANGE-E 018501 20N15
Version 2.0
Revision Date 09/29/2017
Print Date 04/26/2019
Material name
:
A07316 ZEP BIG ORANGE-E 018501 20N15
Material number
:
000000000000018501
Company
:
Zep Inc.
Address
:
350 Joe Frank Harris Parkway, SE
Emerson, GA 30137
Telephone
:
404-352-1680
Emergency telephone numbers
For SDS Information
:
Compliance Services 1-877-428-9937
For a Medical Emergency
:
877-541-2016 Toll Free - All Calls Recorded
For a Transportation
Emergency
:
CHEMTREC: 800-424-9300 - All Calls Recorded.
In the District of Columbia 202-483-7616
Recommended use
:
Degreaser
Appearance
Aerosol containing a liquefied gas
Colour
clear, orange
Odour
citrus
Flammable aerosols
:
Category 1
Gases under pressure
:
Liquefied gas
Skin irritation
:
Category 2
Serious eye damage
:
Category 1
Skin sensitisation
:
Category 1
Hazard pictograms
:
Signal word
:
Danger
Hazard statements
:
H222 Extremely flammable aerosol.
H280 Contains gas under pressure; may explode if heated.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
SECTION 1. PRODUCT AND COMPANY IDENTIFICATION
Manufacturer or supplier's details
Recommended use of the chemical and restrictions on use
SECTION 2. HAZARDS IDENTIFICATION
Emergency Overview
GHS Classification
GHS label elements
1 / 12
Page 2
SAFETY DATA SHEET
A07316 ZEP BIG ORANGE-E 018501 20N15
Version 2.0
Revision Date 09/29/2017
Print Date 04/26/2019
Precautionary statements
:
Prevention:
P210 Keep away from heat/sparks/open flames/hot surfaces.
No smoking.
P211 Do not spray on an open flame or other ignition source.
P251 Pressurized container: Do not pierce or burn, even after
use.
P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
P264 Wash skin thoroughly after handling.
P272 Contaminated work clothing should not be allowed out of
the workplace.
P280 Wear protective gloves/ eye protection/ face protection.
Response:
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with
water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. Immediately call a POISON
CENTER/doctor.
P333 + P313 If skin irritation or rash occurs: Get medical
advice/ attention.
P362 Take off contaminated clothing and wash before reuse.
Storage:
P410 + P412 Protect from sunlight. Do not expose to
temperatures exceeding 50 °C/ 122 °F.
Disposal:
P501 Dispose of contents/ container to an approved waste
disposal plant.
Substance / Mixture
:
Mixture
Chemical name
CAS-No.
Concentration [%]
d-limonene
5989-27-5
>= 20 - < 30
propane
74-98-6
>= 5 - < 10
butane
106-97-8
>= 5 - < 10
Alcohols, C9-11, ethoxylated
68439-46-3
>= 3 - < 5
Alcohols, C12-16, ethoxylated
68551-12-2
>= 1 - < 5
p-mentha-1,4-diene
99-85-4
>= 1 - < 5
linalool
78-70-6
>= 1 - < 5
General advice
:
Move out of dangerous area.
Consult a physician.
Show this safety data sheet to the doctor in attendance.
Do not leave the victim unattended.
If inhaled
:
If unconscious, place in recovery position and seek medical
advice.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous components
The exact percentages of disclosed substances are withheld as trade secrets.
SECTION 4. FIRST AID MEASURES
2 / 12
Page 3
SAFETY DATA SHEET
A07316 ZEP BIG ORANGE-E 018501 20N15
Version 2.0
Revision Date 09/29/2017
Print Date 04/26/2019
If unconscious, place in recovery position and seek medical
advice.
If symptoms persist, call a physician.
In case of skin contact
:
Wash off immediately with plenty of water for at least 15
minutes.
Wash contaminated clothing before re-use.
Remove contaminated clothing and shoes.
If skin irritation persists, call a physician.
In case of eye contact
:
Small amounts splashed into eyes can cause irreversible
tissue damage and blindness.
Continue rinsing eyes during transport to hospital.
Remove contact lenses.
Protect unharmed eye.
Keep eye wide open while rinsing.
If eye irritation persists, consult a specialist.
Rinse immediately with plenty of water, also under the eyelids,
for at least 15 minutes.
If swallowed
:
Keep respiratory tract clear.
Never give anything by mouth to an unconscious person.
DO NOT induce vomiting unless directed to do so by a
physician or poison control center.
If symptoms persist, call a physician.
Most important symptoms
and effects, both acute and
delayed
:
Effects are dependent on exposure (dose, concentration,
contact time).
Effects are immediate and delayed.
Symptoms may include irritation, redness, pain, and rash.
Causes skin irritation.
Causes serious eye damage.
Review section 2 of SDS to see all potential hazards.
Notes to physician
:
Treat symptomatically. Symptoms may be delayed.
Suitable extinguishing media
:
Alcohol-resistant foam
Carbon dioxide (CO2)
Dry chemical
Unsuitable extinguishing
media
:
High volume water jet
Specific hazards during
firefighting
:
Do not allow run-off from fire fighting to enter drains or water
courses.
Hazardous combustion
products
:
Carbon dioxide (CO2)
Carbon monoxide
Smoke
Specific extinguishing
methods
:
Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.
SECTION 5. FIREFIGHTING MEASURES
3 / 12
Page 4
SAFETY DATA SHEET
A07316 ZEP BIG ORANGE-E 018501 20N15
Version 2.0
Revision Date 09/29/2017
Print Date 04/26/2019
Further information
:
Collect contaminated fire extinguishing water separately. This
must not be discharged into drains.
Fire residues and contaminated fire extinguishing water must
be disposed of in accordance with local regulations.
For safety reasons in case of fire, cans should be stored
separately in closed containments.
Use a water spray to cool fully closed containers.
Special protective equipment
for firefighters
:
Wear self-contained breathing apparatus for firefighting if
necessary.
Personal precautions,
protective equipment and
emergency procedures
:
Use personal protective equipment.
Ensure adequate ventilation.
Remove all sources of ignition.
Evacuate personnel to safe areas.
Beware of vapours accumulating to form explosive
concentrations. Vapours can accumulate in low areas.
Environmental precautions
:
Prevent product from entering drains.
Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains inform
respective authorities.
Methods and materials for
containment and cleaning up
:
Soak up with inert absorbent material (e.g. sand, silica gel,
acid binder, universal binder, sawdust).
Sweep up or vacuum up spillage and collect in suitable
container for disposal.
Advice on safe handling
:
Do not breathe vapours/dust.
Avoid exposure - obtain special instructions before use.
Avoid contact with skin and eyes.
For personal protection see section 8.
Smoking, eating and drinking should be prohibited in the
application area.
Take precautionary measures against static discharges.
Provide sufficient air exchange and/or exhaust in work rooms.
Dispose of rinse water in accordance with local and national
regulations.
Persons susceptible to skin sensitisation problems or asthma,
allergies, chronic or recurrent respiratory disease should not
be employed in any process in which this mixture is being
used.
Conditions for safe storage
:
BEWARE: Aerosol is pressurized. Keep away from direct sun
exposure and temperatures over 50 °C. Do not open by force
or throw into fire even after use. Do not spray on flames or
red-hot objects.
No smoking.
Observe label precautions.
Electrical installations / working materials must comply with
SECTION 6. ACCIDENTAL RELEASE MEASURES
SECTION 7. HANDLING AND STORAGE
4 / 12
Page 5
SAFETY DATA SHEET
A07316 ZEP BIG ORANGE-E 018501 20N15
Version 2.0
Revision Date 09/29/2017
Print Date 04/26/2019
the technological safety standards.
Materials to avoid
:
Oxidizing agents
Components
CAS-No.
Value type
(Form of
exposure)
Control
parameters /
Permissible
concentration
Basis
d-limonene
5989-27-5
TWA
30 ppm
US WEEL
propane
74-98-6
TWA
1,000 ppm
ACGIH
TWA
1,000 ppm
1,800 mg/m3
NIOSH REL
TWA
1,000 ppm
1,800 mg/m3
OSHA Z-1
TWA
1,000 ppm
1,800 mg/m3
OSHA P0
PEL
1,000 ppm
1,800 mg/m3
CAL PEL
butane
106-97-8
TWA
800 ppm
1,900 mg/m3
NIOSH REL
TWA
800 ppm
1,900 mg/m3
OSHA P0
PEL
800 ppm
1,900 mg/m3
CAL PEL
Engineering measures
:
effective ventilation in all processing areas
Respiratory protection
:
Use respiratory protection unless adequate local exhaust
ventilation is provided or exposure assessment demonstrates
that exposures are within recommended exposure guidelines.
Material
:
Protective gloves
Remarks
:
The suitability for a specific workplace should be discussed
with the producers of the protective gloves.
Eye protection
:
Tightly fitting safety goggles
Wear face-shield and protective suit for abnormal processing
problems.
Access to clean water to rinse eyes must be available, options
include: eye wash stations or showers, or eye wash bottles
with pure water.
Skin and body protection
:
Impervious clothing
Choose body protection according to the amount and
concentration of the dangerous substance at the work place.
Hygiene measures
:
When using do not eat or drink.
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters
Personal protective equipment
Hand protection
5 / 12
Page 6
SAFETY DATA SHEET
A07316 ZEP BIG ORANGE-E 018501 20N15
Version 2.0
Revision Date 09/29/2017
Print Date 04/26/2019
When using do not smoke.
Wash hands before breaks and at the end of workday.
Appearance
:
Aerosol containing a liquefied gas
Colour
:
clear, orange
Odour
:
citrus
Odour Threshold
:
No data available
pH : Not applicable
Melting point/freezing point
:
Not applicable
Boiling point
:
No data available
Flash point
:
No data available
Evaporation rate
:
No data available
Flammability (solid, gas)
:
Extremely flammable aerosol.
Upper explosion limit
:
No data available
Lower explosion limit
:
No data available
Vapour pressure
:
No data available
Relative vapour density
:
No data available
Density
:
0.808 g/cm3
Water solubility
:
emulsifiable
Partition coefficient: noctanol/water
:
No data available
Auto-ignition temperature
:
not determined
Thermal decomposition
:
No data available
Viscosity, kinematic
:
No data available
Reactivity
:
Stable
Chemical stability
:
Stable under normal conditions.
Possibility of hazardous
reactions
:
Vapours may form explosive mixture with air.
No decomposition if stored and applied as directed.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Solubility(ies)
Viscosity
SECTION 10. STABILITY AND REACTIVITY
6 / 12
Page 7
SAFETY DATA SHEET
A07316 ZEP BIG ORANGE-E 018501 20N15
Version 2.0
Revision Date 09/29/2017
Print Date 04/26/2019
Conditions to avoid
:
Heat, flames and sparks.
Incompatible materials
:
Acids
Oxidizing agents
Hazardous decomposition
products
:
Carbon dioxide (CO2)
Carbon monoxide
Organic Substances
Aggravated Medical
Condition
:
None known.
Symptoms of Overexposure
:
Effects are dependent on exposure (dose, concentration,
contact time).
Effects are immediate and delayed.
Symptoms may include irritation, redness, pain, and rash.
IARC
No component of this product present at levels greater than or
equal to 0.1% is identified as probable, possible or confirmed
human carcinogen by IARC.
OSHA
No component of this product present at levels greater than or
equal to 0.1% is on OSHA’s list of regulated carcinogens.
NTP
No component of this product present at levels greater than or
equal to 0.1% is identified as a known or anticipated carcinogen
by NTP.
Acute oral toxicity
:
Acute toxicity estimate : > 5,000 mg/kg
Method: Calculation method
Acute oral toxicity
:
LD50 Oral Rat: 4,400 mg/kg
Acute dermal toxicity
:
LD50 Dermal Rabbit: > 5,000 mg/kg
Acute oral toxicity
:
LD50 Oral Rat: 1,400 mg/kg
SECTION 11. TOXICOLOGICAL INFORMATION
Potential Health Effects
Carcinogenicity:
Acute toxicity
Product:
Components:
d-limonene:
Alcohols, C9-11, ethoxylated:
Skin corrosion/irritation
Product:
7 / 12
Page 8
SAFETY DATA SHEET
A07316 ZEP BIG ORANGE-E 018501 20N15
Version 2.0
Revision Date 09/29/2017
Print Date 04/26/2019
Remarks: Irritating to skin.
Remarks: May cause irreversible eye damage.
Remarks: Causes sensitisation.
Remarks: No data available
Partition coefficient: noctanol/water
:
Remarks: No data available
Serious eye damage/eye irritation
Product:
Respiratory or skin sensitisation
Product:
Germ cell mutagenicity
No data available
Carcinogenicity
No data available
Reproductive toxicity
No data available
STOT - single exposure
No data available
STOT - repeated exposure
No data available
Aspiration toxicity
No data available
Further information
Product:
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
No data available
Persistence and degradability
No data available
Bioaccumulative potential
Product:
Components:
8 / 12
Page 9
SAFETY DATA SHEET
A07316 ZEP BIG ORANGE-E 018501 20N15
Version 2.0
Revision Date 09/29/2017
Print Date 04/26/2019
Partition coefficient: noctanol/water
:
Pow: 2.89
Regulation
40 CFR Protection of Environment; Part 82 Protection of
Stratospheric Ozone - CAA Section 602 Class I
Substances
Remarks
This product neither contains, nor was manufactured
with a Class I or Class II ODS as defined by the U.S.
Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A
+ B).
Additional ecological
information
:
No data available
Waste from residues
:
The product should not be allowed to enter drains, water
courses or the soil.
Do not contaminate ponds, waterways or ditches with
chemical or used container.
Dispose of in accordance with local regulations.
Contaminated packaging
:
Empty remaining contents.
Dispose of as unused product.
Do not re-use empty containers.
Do not burn, or use a cutting torch on, the empty drum.
Transportation Regulation: 49 CFR (USA):
ORM-D, CONSUMER COMMODITY
Transportation Regulation: IMDG (Vessel):
UN1950, AEROSOLS, FLAMMABLE, 2.1, - Limited quantity
Transportation Regulation: IATA (Cargo Air):
UN1950, Aerosols, flammable, 2.1, - Limited quantity
Transportation Regulation: IATA (Passenger Air):
UN1950, Aerosols, flammable, 2.1, - Limited quantity
butane :
Mobility in soil
No data available
Other adverse effects
No data available
Product:
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods
SECTION 14. TRANSPORT INFORMATION
9 / 12
Page 10
SAFETY DATA SHEET
A07316 ZEP BIG ORANGE-E 018501 20N15
Version 2.0
Revision Date 09/29/2017
Print Date 04/26/2019
Transportation Regulation: TDG (Canada):
UN1950, AEROSOLS, FLAMMABLE, 2.1, (LQ), - Limited quantity
TSCA list
:
No substances are subject to a Significant New Use Rule.
No substances are subject to TSCA 12(b) export notification
requirements.
SARA 311/312 Hazards
:
Flammable (gases, aerosols, liquids, or solids)
Gases under pressure
Skin corrosion or irritation
Serious eye damage or eye irritation
Respiratory or skin sensitisation
SARA 302
:
No chemicals in this material are subject to the reporting
requirements of SARA Title III, Section 302.
SARA 313
:
This material does not contain any chemical components with
known CAS numbers that exceed the threshold (De Minimis)
reporting levels established by SARA Title III, Section 313.
WARNING: This product can expose you to chemicals
including 7-methyl-3-methyleneocta-1,6-diene, which is/are
known to the State of California to cause cancer. For more
information go to www.P65Warnings.ca.gov.
DSL
All components of this product are on the Canadian DSL
TSCA
On TSCA Inventory
The product as delivered to the customer conforms to packaging requirements for shipment by road
under US Department of Transportation (DOT) regulations. Additional transportation classifications
noted above are for reference only, and not a certification or warranty of the suitability of the packaging
for shipment under these alternative transport regulations.
SECTION 15. REGULATORY INFORMATION
EPCRA - Emergency Planning and Community Right-to-Know Act
CERCLA Reportable Quantity
This material does not contain any components with a CERCLA RQ.
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.
California Prop. 65
The components of this product are reported in the following inventories:
10 / 12
Page 11
SAFETY DATA SHEET
A07316 ZEP BIG ORANGE-E 018501 20N15
Version 2.0
Revision Date 09/29/2017
Print Date 04/26/2019
NFPA:
HMIS III:
Hazard pictograms
:
Signal word
:
Danger:
Hazard statements
:
Extremely flammable aerosol. Contains gas under pressure; may explode if heated.
Causes skin irritation. May cause an allergic skin reaction. Causes serious eye
damage.
Precautionary statements
:
Prevention: Keep away from heat/sparks/open flames/hot surfaces. No smoking. Do
not spray on an open flame or other ignition source. Pressurized container: Do not
pierce or burn, even after use. Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
Wash skin thoroughly after handling. Contaminated work clothing should not be allowed
out of the workplace. Wear protective gloves/ eye protection/ face protection.
Response: IF ON SKIN: Wash with plenty of soap and water. IF IN EYES: Rinse
cautiously with water for several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing. Immediately call a POISON CENTER/doctor. If skin irritation or
rash occurs: Get medical advice/ attention. Take off contaminated clothing and wash
before reuse.
Storage: Protect from sunlight. Do not expose to temperatures exceeding 50 °C/ 122
°F.
Disposal: Dispose of contents/ container to an approved waste disposal plant.
Version:
2.0
Revision Date:
09/29/2017
Print Date:
04/26/2019
Flammability
Health
Instability
3
4
0
Special hazard.
FLAMMABILITY
PHYSICAL HAZARD
HEALTH
4
2
3
0 = not significant, 1 =Slight,
2 = Moderate, 3 = High
4 = Extreme, * = Chronic
For information on the country notification status for other regions please contact the
manufacturer’s regulatory group.
Inventory Acronym and Validity Area Legend:
TSCA (USA), DSL (Canada), NDSL (Canada)
SECTION 16. OTHER INFORMATION
Further information
OSHA - GHS Label Information:
11 / 12
Page 12
SAFETY DATA SHEET
A07316 ZEP BIG ORANGE-E 018501 20N15
Version 2.0
Revision Date 09/29/2017
Print Date 04/26/2019
We believe the statements, technical information and recommendations contained herein are
reliable, but they are given without warranty or guarantee of any kind. The information in this
document applies to this specific material as supplied. It may not be valid for this material if it
is used in combination with any other materials. Users should make their own investigations
to determine the suitability and applicability of the information for their particular purposes.
This SDS has been prepared by the Compliance Services organization supporting this
manufacturer, supplier or distributor.
Zep Inc. markets products under well recognized and established brand names such as Zep®,
Zep Commercial®,Zep Professional®, Enforcer®, National Chemical™, Selig™, Misty®, Next
Dimension™, Petro®, i-Chem®, TimeMist®, TimeWick™, MicrobeMax®, Country Vet®,
Konk®, Original Bike Spirits®, Blue Coral®, Black Magic®, Rain-X®, Niagara National™, FC
Forward Chemicals®,Rexodan®, Mykal™, and a number of private labeled brands.
12 / 12
Loading...