Ink for Ball point pen refills USA
Safety Data Sheet
１．Identification of the mixture and of the company
Product name ： Ink for Ball point pen refills as follows:
K-0.7(Black, Blue, Red) ： BR-6A-K-BK,BL,R
SK-0.7(Black, Blue, Red) ： BR-6A-SK-BK,BL,R
SH-0.5(Black, Blue, Red) ： BR-8A-SH-BK,BL,R
H-0.7(Black, Blue, Red) ： BR-6A-H-BK,BL,R
LH-1.0(Black, Blue, Red) ： RLH10-BK,BL,R
LH-1.2(Black, Blue, Red) ： RLH12-BK,BL,R
LH-1.6(Black, Blue, Red) ： RLH16-BK,BL,R
F-0.7(Black, Blue, Red) ： BR-1B-F-BK,BL,R
F-1.0(Black, Blue, Red) ： BRM-1B-F-BK,BL,R
4C-0.4（Black) ： R4C4-BK
4C-0.5（Black) ： R4CS-BK
4C-0.7(Black, Blue, Red) ： BR-8A-4C-BK,BL,R
4C-1.0(Black, Blue, Red) ： R4C10-BK,BL,R
ST-0.7(Black, Blue, Red) ： BR-3B-ST-BK,BL,R
Ink for Lite Rite DE(Ball-point Pen Side：Black ink)
Company ： ZEBRA CO., LTD.
2-9 Higashi-gokencho Shinjuku-ku Tokyo JAPAN
TEL: +81-3-3268-1193
FAX: +81-3-3268-1197
Emergency telephone ： +81-3-3268-1193
This phone number is available only during office hours: 9 a.m. to half past 5 p.m.
（Japan time)
Product use ： Infill Ink for writing implement
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Date of issue：2012-10-26
Revision Date：2014-11-18
２．Hazards identification
GHS classification
Physical hazards
Flammable liquids Not classified
Pyrophoric liquids Not classified
Self-heating mixtures Not classified
Corrosive to metals Not classified
Health hazards
Acute toxicity-Oral Category ４
Acute toxicity-Dermal Not classified
Acute toxicity-Inhalation：vapour Not classified
Acute toxicity-Inhalation：mist Not classified
Skin corrosion / irritation Category ２
Serious eye damage / eye irritation Category １
Respiratory or skin sensitization Classification not possible／Not classified
Germ cell mutagenicity Not classified
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Carcinogenicity Not classified
Reproductive toxicity Not classified
Specific target organ toxicity (Singel exposure) Classification not possible
Specific target organ toxicity(Repeated exposure) Not classified
Aspiration hazard Classification not possible
GHS label elements
Pictograms or Symbol
Exclamation mark Corrosion
Signal Word
Danger
Hazard statement
・Harmful if swallowed
・Causes skin irritation
・Causes serious eye damage
Precautionary Statements
Prevention
・Read label and Material Safety Data Sheet before use.
・Do not eat, drink or smoke when using this product
・Wear protective gloves/eye protection.
・Wash hand throughly after handling
・Avoid release to the environment
Response
・IF SWALLOWED:Rinse mouth. Call a doctor/physician if you feel unwell
・IF ON SKIN: Wash with soap and water
・If skin irritation occurs: Get medical advice/attention
・IF IN EYES:Immediately call a doctor/physician.Rinse continuously with water for several minutes.
Remove contact lenses if present and easy to do . Continue rinsing
・Take off contaminated clothing and wash before reuse
Storage
・Store in a well ventilated place. Keep cool and container tightly closed.
Disposal
・Dispose of contents/container to in accordance with local government regulation.
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３．Composition/information on ingredients
Mixture
Component and Amount
Reference Number in Gazetted List in Japan
Component Amount CAS No. （Japanese Chemical Substances Control Act）
Dyes 20-30% Nondisclosure Nondisclosure(registered)
Resins 15-25% Nondisclosure Nondisclosure(registered)
Ethylenglycol
monophenyleth
Benzyl alchol 10-20% 100-51-6 (3)-1011
Additives 1-5% Nondisclosure Nondisclosure(registered)
30-45% 122-99-6 (9)-1277
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４．First-aid measures
After inhalation:
Call a doctor/physician if you feel unwell.
Remove victim to fresh air and keep at rest in a position comfortable for breathing.
After skin contact:
Wash with soap and water
If skin irritation occurs: Get medical advice/attention
Take off contaminated clothing and wash before reuse
Call a doctor/physician if you feel unwell.
After eye contact:
Immediately call a doctor/physician.Rinse continuously with water for several minutes.
Remove contact lenses if present and easy to do . Continue rinsing
After ingestion:
・Rinse mouth. Call a doctor/physician if you feel unwell
Protection of the person who takes first aid
Nothing in particular.
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５．Fire-fighting measures
Suitable Extinguishing media
Carbon dioxide, dry chemical powder, water fog, foam
Prohibition extinguishing media for safety reason
Water spray (straight)
Specific hazards
May produce toxic fumes if burning.
Specific fire fighting procedures
If safe to do so, move undamaged containers from the fire area.
If can't move the container , cool containers and surrounding with spray water.
Cool containers with large quantities of water until well after extinguished the fire.
Special protective equipment for fire-fighters
Fire-fighting should be performed from the windward side.
Respiratory protection, and other suitable protective equipment
６．Accidental release measures
Personal precautions
The pollution area should be established as off limits without concerned persons.
Protective equipment and emergency measure
Do not touch the leakage or its damaged container without suitable protection.
Do not walk through the leakage.
Keep sufficient ventilation if the area is indoor.
Remove ignition sources.
Environmental precautions
Keep away from drains, and prevent from releasing to the environment.
Methods for cleaning up
Use non-flammable absorbent materials, and put them in airtight container.
Dispose of absorbent in accordance with law.
Prevention of secondary disaster
Remove nearby ignition source and hot surface.
Equipped with suitable extinguishing media. (Preparation for in case of ignition)
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７．Handling and storage
Handling
Technical measures
Do suitable equipment measures and use suitable protection that refer to
"８．Exposure control/ personal protection".
Local exhaust ventilation and general ventilation
Use local exhaust ventilation and general ventilation that refer to
"８．Exposure control/ personal protection".
Caution
When handling do not use high temperature articles, spark and fire.
Handle container with care, do not make it turn over, drop, give impact and drag.
Do not breathe, contact and swallow.
Maintain air concentrations below exposure limit using exhaust ventilation.
Do not eat, drink or smoke when using this product.
Wash hand throughly after handling.
Use only outdoors or in awell-ventilated area.
Avoid release to the environment.
Avoid contact
Refer to section 10 about stability and reactivity.
Storage
Incompatible materials
Refer to section 10 about stability and reactivity.
Storage condition
Store away from heat/sparks/open flames – No smoking
Store in a well ventilated place. Keep cool and container tightly closed.
Store locked up.
The Containers
Use the container that our company filled up when ship products
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８．Exposure control/ personal protection
Exposure limit values
Permissible concentration Administrative levels
Chemical name
Ethylenglycol monophenylether
Benzyl alchol Not established Not established Not established
Equipment measures
Put up local exhaust ventilation.Use explosion-proof electrical/ventilating/lighting.
Take precautionary measures against static discharge.
Put up emergency eyewash and shower in case of storage or handling about this product.
Protection
Respiratory protection
Use suitable respiratory protection.
Hand
Eye protection
rotection
Use suitable protective gloves.
Use suitable eye protection.
The Japan Society for
Occupational Health
Not established Not established Not established
ACGIH TLV-TWA
Ministry of Health, Labour and
Welfare(JAPAN)
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Skin/body protection
Use suitable face protection.
Hygiene measures
Do not eat ,drink or smoke when using this product.
Wash thoroughly after handling.
９.Physical and chemical properties
Appearance Coloring liquid
Odour Peculiar odour
ｐＨ No data available
Melting point / Coagulating point No data available
Boiling point Black ink ： 100℃
Blue ink ： 100℃
Red ink ： 100℃
Flash point Black ink ： 118℃
Blue ink ： 121℃
Red ink ： 123℃
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Explosive limit UEL No data available
Explosive limit LEL No data available
Vapour pressure No data available
Vapour density No data available
Specific gravity No data available
Water solubility No data available
Partition coefficient n-octanol/water
Ignition point No data available
Decomposition point No data available
No data available
１０．Stability and reactivity
Chemical stability This product is stable in normal condition.
Materials to Avoid Strong oxidizing agent
Conditions to avoid High temperature
Incompatible materials Strong oxidizing agent
Hazardous decomposition products
Nothing in particular.
１１．Toxicological information
Acute toxicity-Oral Category ４
Acute toxicity-Dermal Not classified
Acute toxicity-Inhalation：vapour Not classified
Acute toxicity-Inhalation：mist Not classified
Skin corrosion / irritation Category ２
Serious eye damage / eye irritation Category １
Respiratory or skin sensitization Classification not possible／Not classified
Germ cell mutagenicity Not classified
Carcinogenicity Not classified
Reproductive toxicity Not classified
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Specific target organ toxicity(Singel exposure) Classification not possible
Specific target organ toxicity(Repeated exposure) Not classified
Aspiration hazard Classification not possible
１２．Ecological information
Hazardous to the aquatic environment(acute) Not classified
Hazardous to the aquatic environment(chronic) Not classified
Degradability No data is available
Bioaccumulative potential No data is available
Mobility in soil No data is available
１３．Disposal considerations
Waste residues
Disposal must be made according to official regulations.
Avoid release to the environment.
Contaminated container and packaging
Do not flush into the sewer.
Remove all contents when you dispose of empty containers.
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１４．Transport information
The contents are as follows when transport only ink
International regulation
IMDG（maritime transport）
UN No. Not applicable
Class Packing Group Marine Pollutant -
ICAO/IATA（air transport）
UN No. Not applicable
Class Packing Group -
Special precautions
Prevent from falling, sｔumbling and doing damage when the container loading..
Avoid acute vibration and friction for container.
If there are some indications of hazard in transporting like acute leak in transporting,
take emergency measures and report the accident at once to disaster management agency.
Avoid transport with foods or feeds.
Above regulations are applied to transport of writing instruments filled with the ink.
１５．Regulatory information(Japan)
Follow all regulation in your country.
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１６．Other information
In this sheet, the contents of ingredients and the value of physical and chemical properties
are not guaranteed performance.
The information contained in this sheet is based on the data available at now.
But this shall not constitute a guarantee for any specific or classification.
Please be alert to handling this product because chemicals shall have unknown hazards.
This sheet may be revised when we get new information.
The information is assumed in the case of large-scale handling on business operations.
They cannot be always applicable to general use of writing instruments.
Reference
Globally Harmonized System of Classification and Labelling of Chemicals (GHS) second revised edition 2007
Recommendation of Occupational Exposure Limits(2009-2010) by The Japan Society for Occupational Health
2009 TLVs and BEIs by ACGIH
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