Page 1
Shenzhen BCTC Testing Co., Ltd.
BCTC Building & 1-2F, East of B Building, Pengzhou Industrial, Fuyuan 1st Road, Qiaotou
Community, Fuyong Street, Bao’an District, Shenzhen, China.
Tel : +86-400-788-9558
Fax: +86-755-33229357
Material Safety Data Sheet (MSDS)
Model/type reference ........................ :
18650 2600mAh
Trademark
...........................................
:
Nominal Voltage……….…………….:
3.7V
Typical Capacity……........………….:
2600mAh 9.62Wh
Weight…….......……................…….:
47g
Shape and Physical Dimension
(mm)……………………………...…..:
Cylindrical
D: 18.5mm
H: 68.7mm
Version number………………..…….:
V1.0
Preparation Date……………...….….:
Nov. 22, 2017~Nov. 29, 2017
Revision date………………….……..:
Jan. 05, 2018
Laboratory ...........................................:
Shenzhen BCTC Testing Co., Ltd.
Address ............................................... :
BCTC Building & 1-2F, East of B Building, Pengzhou Industrial,
Fuyuan 1st Road, Qiaotou Community, Fuyong Street, Bao’an
District, Shenzhen, China.
Tested by (name + signature)
.......
:
Simon Gong
Compiled by (name+ signature)..:
Levi Li
Approved by (name+ signature)..:
Andy Yan
Report No.: BCTC-FY171107737S
Page 1 of 11
For
SHENZHEN XTAR ELECTRONICS CO.,LTD
5th Floor, No.77 Xinhe Rd, Shangmugu, Pinghu Area, Longgang District,
Shenzhen, Guangdong, China
and for their product
Rechargeable Li-ion Battery
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Shenzhen BCTC Testing Co., Ltd. Report No.: BCTC-FY171107737S
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product Identifier
Product name: Rechargeable Li-ion Battery
Model: 18650 2600mAh
Other means of identification
Synonyms:none
Recommended use of the chemical and restrictions on use
Recommended Use:Used in portable electronic equipments;
Uses advidsed against:
a) Do not dismantle, open or shred secondary cells or batteries.
b) Do not expose cells or batteries to heat or fire. Avoid storage in direct sunlight.
c) Do not short-circuit a cell or a battery. Do not store cells or batteries haphazardly in a box or drawer
where they may short-circuit each other or be short-circuited by other metal objects.
d) Do not remove a cell or battery from its original packaging until required for use.
e) Do not subject cells or batteries to mechanical shock.
f) In the event of a cell leaking, do not allow the liquid to come in contact with the skin or eyes. If
contact has been made, wash the affected area with copious amounts of water and seek medical
advice.
g) Do not use any charger other than that specifically provided for use with the equipment.
h) Observe the plus (+) and minus (–) marks on the cell, battery and equipment and ensure correct
use.
i) Do not use any cell or battery which is not designed for use with the equipment.
j) Do not mix cells of different manufacture, capacity, size or type within a device.
k) Battery usage by children should be supervised.
l) Seek medical advice immediately if a cell or a battery has been swallowed.
m) Always purchase the battery recommended by the device manufacturer for the equipment.
n) Keep cells and batteries clean and dry.
o) Wipe the cell or battery terminals with a clean dry cloth if they become dirty.
p) Secondary cells and batteries need to be charged before use. Always use the correct charger and
refer to the manufacturer’s instructions or equipment manual for proper charging instructions.
q) Do not leave a battery on prolonged charge when not in use.
r) After extended periods of storage, it may be necessary to charge and discharge the cells or batteries
several times to obtain maximum performance.
s) Retain the original product literature for future reference.
t) Use only the cell or battery in the application for which it was intended.
u) When possible, remove the battery from the equipment when not in use.
v) Dispose of properly.
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Shenzhen BCTC Testing Co., Ltd. Report No.: BCTC-FY171107737S
2. HAZARDS IDENTIFICATION
Details of the supplier of the safety data sheet:
Supplier Name: SHENZHEN XTAR ELECTRONICS CO.,LTD
Address: 5th Floor, No.77 Xinhe Rd, Shangmugu, Pinghu Area, Longgang District,
Shenzhen, Guangdong, China
Telephone number of the supplier: N/A
Emergency Telephone No.(24h): N/A
Fax: N/A
Postcode:N/A
E-mail address: N/A
Classification
No harm at the normal use. If contact the Electrolyte liquid in the Li-ion Battery, reference as follows:
Classification of the substance or mixture
Classification according to GHS
Acute Toxicity, Oral(Hazard category 4)
Acute Toxicity, Dermal(Hazard category 3)
Skin, irritate(Cagegory 1B)
Eye Irritate (Hazard category 1)
GHS Label elements, including precautionary statements:
GHS02 GHS05 GHS06
Signal word: Warning
Hazard statement(s):
H242:Heating may cause a fire;
H311: Toxic in contact with skin;
H314:Causes severe skin burns and eye damage;
H302:Harmful if swallowed;
precautionary statements:
Prevention:
P264 Wash thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Response:
P312:Call a Poison center or doctor/physician if you feel unwell.
P302+P350-IF ON SKIN: Gently wash with plenty of soap and water
P301+P330+P331-IF SWALLOWED: rise mouth. Do NOT induce vomiting
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
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Shenzhen BCTC Testing Co., Ltd. Report No.: BCTC-FY171107737S
3. COMPOSITION/INFORMATION ON INGREDIENTS
Common Chemical Name
Concentration (%)
CAS Number
Lithium Cobalt Dioxide (LiCoO2)
34.36
12190-79-3
Graphite (C)
26.3
7782-42-5
Poly Vnylidene Fluoride (PVDF)
13.24
24937-79-9
Acetylene Black
2.32
1333-86-4
Electrolyte
10.25
623-53-0/21324-40-3
4. FIRST-AID MEASURES
Storage:
None
Disposal
P501: Dispose of contents/container in accordance with local/national regulations
Hazards not otherwise classified (HNOC)
Not Applicable
Other information
No information available.
Chemical characterixation: Mixtures
Description:
Product: Consisting of the following components.
Note: CAS number is Chemical Abstract Service Registry Number.
N/A=Not apply.
First aid measures
Eye Contact Rinse thoroughly with plenty of water, also under the eyelids. If symptoms persist, call a
physician.
Skin Contact Remove contaminated clothing and shoes. Wash skin with soap and water. In the case
of skin irritation or allergic reactions see a physician.
Inhalation Move to fresh air. If symptoms persist, call a physician.
Ingestion Do NOT induce vomiting. Drink plenty of water. If symptoms persist, call a physician.
Most important symptoms and effects, both acute and delayed
Swallowing Do not induce vomiting. Get medical attention.
Most Important Symptoms/Effects No information available.
Indication of any immediate medical attention and special treatment needed
Notes to Physician Treat symptomatically
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Shenzhen BCTC Testing Co., Ltd. Report No.: BCTC-FY171107737S
5. FIRE-FIGHTING MEASURES
Suitable Extinguishing Media
CO2, dry chemical powder, water spray.
Unsuitable Extinguishing Media:No information available.
Specific Hazards Arising from the Chemical
Formation of toxic gases is possible during heating or in case of fire.
In case of fire, the following can be released:
Carbon monoxide(CO)
Carbon dioxide
Other irritating and toxic gases.
Hazardous Combustion Products
Carbon oxides.
Explosion Data
Sensitivity to Mechanical Impact No
Sensitivity to Static Discharge No
Protective Equipment and Precautions for Firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or
equivalent) and full protective gear. For example: Wear self-contained respiratory protective device.
Wear suitable protective clothing and eye/face protection.
Special hazards arising from the substance or mixture:
Battery may burst and release hazardus decomposition products when exposed to a fire situation.
Lithium ion batteries contain flammable electrolyte that may vent, ignite and produce sparks when
subjected to high temperature(>150℃), When damaged or abused(e.g. mechanical damage or
electrical overcharging); may burn rapidly with flare-burning effect; may ignite other batteries in clothes
proximity.
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Shenzhen BCTC Testing Co., Ltd. Report No.: BCTC-FY171107737S
6. ACCIDENTAL RELEASE MEASURES
7. HANDLING AND STORAGE
Precautions for safe handling
Handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with
skin, eyes and clothing. Wear personal protective equipment.
Wash thoroughly after handling. Use this material with adequate ventilation.
The product is not explosive.
Conditions for safe storage, including any incompatibilities
If the Lithium-ion Battery is subject to storage for such a long term as more than 3 months, it is
recommended to recharge the Lithium-ion Polymer Battery periodically.
3 months: -10℃~+40℃, 45 to 85%RH
And recommended at 0℃~+35℃ for long period storage.
The capacity recovery rate in the delivery state (50% capacity of fully charged) after storage is
assumed to be 80% or more.
The voltage for a long time storage shall be 3.8V~4.8V range.
Do not storage Lithium-ion Battery haphazardly in a box or drawer where they may short-circuit each
other or be short-circuited by other metal objects.
Keep out of reach of children.
Do not expose Lithium-ion Polymer Battery to heat or fire. Avoid storage in direct sunlight.
Do not store together with oxidizing and acidic materials.
Keep ignition sources away- Do not smoke.
Store in cool, dry and well-ventilated place.
Incompatible Products None known.
Personal precautions, protective equipment and emergency procedures
Personal Precautions Avoid contact with eyes.
Refer to section 8 for personal protective equipment. Ensure adequate ventilation. Remove all sources
of ignition.
Evacuate personnel to safe areas.
Environmental precautions
Environmental Precautions Refer to protective measures listed in Sections 7 and 8.
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
Methods and material for containment and cleaning up
Methods for Containment Prevent further leakage or spillage if safe to do so.
Methods for Cleaning up Use personal protective equipment. Dam up. Cover liquid spill with sand,
earth or other Non combustible absorbent material. Pick up and transfer to properly labeled containers.
Clean contaminated surface thoroughly.
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Shenzhen BCTC Testing Co., Ltd. Report No.: BCTC-FY171107737S
8. EXPOSURE CONTROLS AND PERSONAL PROTECTION
Ingredients with limit values that require monitoring at the workplace:
12190-79-3 Lithium Cobalt Oxide
TLV (USA)
0.02mg/m
3
MAK (Germany)
0.1mg/m
3
Control parameters
Other Exposure Guidelines Vacated limits revoked by the Court of Appeals decision in AFL-CIO
v. OSHA, 965 F.2d 962(11th Cir., 1992).
Appropriate engineering controls
Engineering Measures Showers
Eyewash stations
Ventilation systems
Use adequate general or local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits. Ensure adequate ventilation.
Individual protection measures, such as personal protective equipment
Eye/Face Protection:
Tightly sealed goggles
Body protection:
Protective work clothing.
Skin protection:
Protective gloves
Material of gloves:
The selection of the suitable gloves does not only depend on the material, but also on further marks of
quality and varies from manufacturer to manufacturer. As the product is a preparation of several
substances, the resistance of the glove material can not be calculated in advance and has therefore to
be checked prior to the application.
Penetration time of glove material:
The exact break trough time has to be found out by the manufacturer of the protective gloves and has
to be observed.
Respiratory Protection No protective equipment is needed under normal use conditions. If
exposure limits are exceeded or irritation is experienced, ventilation and evacuation may be required.
Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.
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Shenzhen BCTC Testing Co., Ltd. Report No.: BCTC-FY171107737S
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical
State
Form: Cylindrical
Color: Multi-Colored
Odour: Odourless
Odor Threshold: No information available
Change in condition:
pH, with indication of the concentration
Not determined.
Melting point/freezing point
Not determined.
Initial boiling point and Boiling range:
Not determined.
Flash Point
Not determined.
Evaporation rate
Not determined.
Flammability (solid, gas)
Not determined.
Upper/lower flammability or explosive limits
Not determined.
Vapor Pressure:
Not determined.
Vapor Density:
Not determined.
relative density:
Not determined.
Solubility in Water:
Not determined.
Solubility in other solvents
Not determined.
n-octanol/water partition coefficient
Not determined.
Auto-ignition temperature
Product is not self-igniting.
Decomposition temperature
Not determined.
Odout threshold
Not determined.
Evaporation rate
Not determined.
Viscosity
Not determined.
Other Information
No further relevant information available.
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Shenzhen BCTC Testing Co., Ltd. Report No.: BCTC-FY171107737S
10. STABILITY AND REACTIVITY
11. TOXICOLOGICAL INFORMATION
LD/LC50 values relevant for classification:
Not available.
12.Ecological Information
Acquatic toxicity:
No further relevant information available.
Reactivity: Stable under recommended storage and handling conditions (see section 7, Handling and
storage).
Chemical stability: Stable under normal conditions of use, storage and transport.
Thermal decomposition/conditions to be avoided: No decomposition if used according to
specifications.
Possibility of Hazardous Reactions: None under normal processing.
Hazardous Polymerization: Hazardous polymerization does not occur.
Conditions to avoid: Strong heating, fire, Incompatible materials.
Incompatible materials: Strong oxidizing agents. Strong acids.Base metals.
Hazardous Decomposition Products: Carbon oxides, Other irritating and toxic gases.
Acute toxiciy: No data available.
Skin corrosion/irritation: No irritant effect.
Serious eye damage/irritation: Cause serious eye irritation.
Respiratory or skin sensitization: No sensitizing effects known.
Specific target organ system toxicity: No information available.
CMR effects(carcinogenity, mutagenicity and toxicity for reproduction): No information available.
Toxicity:
Persistence and degradability: No further relevant information available.
Bioaccumulative potential: No further relevant information available.
Mobility in soil: No further relevant information available.
Results of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.
Other adverse effects: No information available.
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Shenzhen BCTC Testing Co., Ltd. Report No.: BCTC-FY171107737S
13. DISPOSAL CONSIDERATIONS
14.TRANSPORT INFORMATION
Waste treatment methods
Recommendation: Must not be disposed together with household garbage.
Do not allow product to reach sewage system
Uncleaned packaging:
Recommendation: Disposal must be made according to official regulations.
The Rechargeable Li-ion Battery had been tested according to the requirements of the UN
manual of tests and Criteria, Part III, subsection 38.3;
The Rechargeable Li-ion Battery with a Watt-hour rating not exceeding 100Wh or the cell with a
Watt-hour rating in not exceeding of 20Wh, The Rechargeable Li-ion Battery according to Section
II/Section IB of PACKING INSTRUCTION 965, or Section II of PACKING INSTRUCTION 966～967 of
the Dangerous Goods regulations 59th Edition may be transported.
The packaging shall be adequate to avoid mechanical damage during transport, handling and stacking.
The materials and pack design shall be chosen so as to prevent the development of unintentional
electrical conduction, corrosion of the terminals and ingress of moisture.
Meets requirements of International Maritime Dangerous Goods(IMDG)-2014 Special Provision
188 to be transported as non-dangerous goods;
Meets the requirements of 49CFR173.185 to be transported as non-dangerous goods for road,
rail, air, and vessel.
Meets the requirements of TDG special provision 34 to be transported as non-dangerous goods.
The package must be handled with care and that a flammability hazard exists if the package is
damaged;
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Shenzhen BCTC Testing Co., Ltd. Report No.: BCTC-FY171107737S
15.REGULATORY INFORMATION
CAS No.
EU
(EINECS
)
US
(TSCA)
Japan
(ENCS)
Canada
(DSL/
NDSL)
Austrlia
(AICS)
Korea
(ECL)
China
(IECSC)
12190-79-
3
Listed
Not listed
Not listed
NDSL
Not listed
Not listed
Not listed
24937-79-
9
Listed
Listed
Listed
DSL
Listed
Listed
Listed
7782-42-5
Not listed
Listed
Not listed
DSL
Listed
Listed
Listed
1333-86-4
Listed
Listed
Listed
DSL
Listed
Listed
Listed
623-53-0/2
1324-40-3
Listed
Listed
Listed
DSL
Listed
Listed
Listed
16.OTHER INFORMATION
Safety, health and environmental regulations/legislation specific for the substance or mixture
EU Regulation:
Authorisations: No information available.
Restrictions on use: No information available.
Regulatory information
Chemical safety assessment A Chemical Safety Assessment has not been carried out.
This information is based on our present knowledge. However, this shall not constitute a guarantee
for any specific product features and shall not establish a legally valid contractual relationship.
Relevant phrases:
R20/22: Harmful by inhalation and if swallowed.
R36: Irritating to eyes.
H302: Harmful if swallowed.
H332: Harmful if inhaled.
******************End of MSDS******************
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