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Report No.:HDRMSDS200102-11 Manganese Dioxide Primary Lithium Battery 1/6
1. Product and Company identification
Type
Lithium (gr.)
Type
Lithium (gr.)
FR14505,AA
0.99
FR10445,AAA
0.51
2. Hazards identification
The important hazards
and adverse effects of
the chemical product
No information available
Chemical product
-specific hazards
No information available
Outline of an anticipated
emergency
Chemical contents are sealed in metal can. Therefore, risk of
exposure never occurs unless battery is mechanically or
electrically abused. Risk of explosion by fire is anticipated if
batteries are disposed of in fire or heated above 100 degree
Celsius. Stacking or jumbling of batteries may cause external short
circuits, heat generation, in some case, allowing fire or explosion.
3. Composition/ information on Ingredients
Material
CAS No.
Contents
Iron Disulfide
1309-36-0
20 ～ 40 wt%
Lithium or Lithium Alloy
7439-93-2
2 ～ 7 wt%
Acetylene black
1333-86-4
1 ～ 4 wt%
Issued date: Jan 2, 2020
PRODUCT SAFETY DATA SHEET
Product Category: Lithium Iron Disulfide Battery, Nonrechargeable
Nominal Voltage: 1.5 V
Product name:
Supplier’s Name: Huiderui Lithium Battery Technology Co., LTD.
Supplier’s Address: No.67, Hechang West 3rd Road, Zhongkai Hi-Tech Development
Telephone (0086)-752-2652968
Emergency Contact: (0086)-752-2652968
Note: The battery is neither substance nor mixture but product and having no risk to life and
health under normal use or transportation because ingredients of battery is not leaked out
by virtue of hermetical sealing with metal case. This sheet notifies possible risk of our
battery under abnormal use but mainly aim to provide information about ingredients,
notification of handling and transportation regulations as a useful reference.
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Report No.:HDRMSDS200102-11 Manganese Dioxide Primary Lithium Battery 2/6
Graphite
7782-42-5
2 ～ 7 wt%
polyethylene
9002-88-4
1 ～ 4 wt%
Electrolyte[Mixture of organic solvent]
－
8 ～ 16 wt%
Iron
65997-19-5
20 ～ 40 wt%
4. First-aid measures
Inhalation
If ingredient leaked out from inside of a battery and if inhaled it, move to a
place where fresh air is provided. Refer for medical attention.
Skin contact
If ingredient leaked out from inside of a battery and stuck on skin, wash the
contact areas off immediately with plenty of water and soap. If appropriate
procedures are not taken, this may cause sores on the skin. Refer for medical
attention.
Eyes contact
If ingredient leaked out from inside of a battery and came into eyes, flush the
eyes with plenty of water for at least 15 minutes immediately without rubbing.
Take a medical treatment. If appropriate procedures are not taken, this may
cause an eye irritation.
Swallowing
In case of swallowing of battery, immediately refer for medical attention.
5. Fire-fighting measures
Note: Electrolyte is mixture of organic solvent and does not include substances available for
classification of GHS.
Note: Carbon black is listed as a possible carcinogen by International Agency for Research on
Cancer (IARC).
Fire extinguishing agent:
Dry chemical, alcohol-resistant foam, powder, atomized water; carbon dioxide and dry sand are
effective.
Extinguishing method:
Escape batteries to safe place prevent from ignition by spreading fire. Because packaging
material of battery is paper, use water extinguisher, CO2extinguisher or powder extinguisher as
normal extinguisher.
Since vapor, generated from burning batteries may make eyes, nose and throat irritate, be sure
to extinguish the fire on the windward side. Wear the respiratory protection equipment in some
cases.
Emergency Responders should wear self-contained breathing apparatus. Burning lithium-iron
disulfide batteries produce toxic and corrosive lithium hydroxide fumes and sulfur dioxide gas.
6. Accidental release measures
To cleanup leaking batteries:
Ventilation Requirements: Room ventilation may be required in areas where there are open
or leaking batteries.
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7. Handling and storage
8. Exposure controls and personal protection
Respiratory Protection: Avoid exposure to electrolyte fumes from open or leaking batteries.
Eye Protection: Wear safety glasses with side shields if handling an open or leaking battery.
Gloves: Use neoprene or natural rubber gloves if handling an open or leaking battery. Battery
materials should be disposed of in a leak-proof container.
Storage: Store in a cool, well ventilated area. Elevated temperatures can result in shortened
battery life. In locations that handle large quantities of lithium batteries, such as warehouses,
lithium batteries should be isolated from unnecessary combustibles.
Mechanical Containment: If potting or sealing the battery in an airtight or watertight
container is required, consult your Energizer Battery Manufacturing, Inc. representative for
precautionary suggestions. Do not obstruct safety release vents on batteries. Encapsulation of
batteries will not allow cell venting and can cause high pressure rupture.
Handling: Accidental short circuit for a few seconds will not seriously affect the battery.
Prolonged short circuit will cause the battery to lose energy, generate significant heat and can
cause the safety release vent to open. Sources of short circuits include jumbled batteries in bulk
containers, metal jewelry, metal covered tables or metal belts used for assembly of batteries into
devices. Damaging a lithium battery may result in an internal short circuit.
The contents of an open battery, including a vented battery, when exposed to water, may result
in a fire and/or explosion. Crushed or damaged batteries may result in a fire.
If soldering or welding to the battery is required, consult Huiderui representative for proper
precautions to prevent seal damage or short circuit.
Charging: This battery is manufactured in a charged state. It is not designed for recharging.
Recharging can cause battery leakage or, in some cases, high pressure rupture. Inadvertent
charging can occur if a battery is installed backwards.
Labeling: If the Huiderui label or package warnings are not visible, it is important to provide a
package and/or device label stating:
WARNING: Battery can explode or leak and cause burns if installed backwards, disassembled,
charged, or exposed to water, fire or high temperature.
Where accidental ingestion of small batteries is possible, the label should include:
WARNING: (1) Keep away from small children. If swallowed, promptly see doctor; (2) Battery
can explode or leak and cause burns if installed backwards, disassembled, charged, or exposed
to water, fire or high temperature.
There is no need of personal protective equipment on regular handling and storage. In the event,
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9. Physical and chemical properties
Appearance (physical state, color, etc.):
Solid object
Upper Explosive Limits:
Not applicable for an Article
Lower Explosive Limits
Not applicable for an Article
Odor
No odor
Vapor Pressure (mm Hg @ 25°C)
Not applicable for an Article
Odor Threshold
No odor
Vapor Density (Air = 1)
Not applicable for an Article
pH
Not applicable for an Article
Density (g/cm3)
1.7 -2.0
Melting point/Freezing Point
Not applicable for an Article
Solubility in Water (% by weight)
Not applicable for an Article
Boiling Point @ 760 mm Hg (°C)
Not applicable for an Article
Flash Point
Not applicable for an Article
Evaporation Rate (Butyl Acetate = 1)
Not applicable for an Article
Flammability
Not applicable for an Article
Partition Coefficient
Not applicable for an Article
Auto-ignition Temperature
Not applicable for an Article
Decomposition Temperature
Not applicable for an Article
Viscosity
Not applicable for an Article
10. Stability and reactivity
11. Toxicological information
12. Ecological information
Respiratory protection
: Mask (with a filter preferably)
Hand protection
: Synthetic rubber gloves
Eye protection
: Goggles or glasses
however, a large amount of electrolyte should be released by mechanical or electrical abuse, use
the protections as shown below
Lithium iron disulfide batteries contain no sulfides or cyanides and they do not meet any other
reactivity criteria including “reacts violently with water” and therefore do not meet any of the
criteria established in 40 CFR 261.2 for reactivity.
Under normal conditions of use, lithium iron disulfide batteries are non-toxic.
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13. Disposal considerations
14. Transportation Information
UN No.
Proper Shipping Name/Description
3090
Lithium metal batteries
3091
Lithium metal batteries contained in equipment
3091
Lithium metal batteries packed with equipment
Transportations
Related organization / Issue documents
Air transport (by
airplane)
ICAO（International Civil Aviation Organization）/ TI（Technical
Instruction） IATA （ International Air Transport Association ） /
Persistence and degradability
No information available
Mobility in soil
No information available
Dispose of batteries in accordance with applicable federal, state and local regulations.
For safety precaution, battery should be insulated in proper manner; covering both terminals by
tape, wrapping of battery in insulative bag or packing battery in original package is
recommended in order to prevent ignition or explosion due to short-circuit
Lithium metal cells and batteries are classified as Class 9 Dangerous Goods in the United
Nations Recommendation, and given UN numbers as shown in the below table. In case of
transport of lithium metal cells and batteries, compliance with all the relevant UN regulations in
addition to the requirements of United Nations Recommendation is required.
Our battery (listed on section 1) and its shipping package complies with the requirement of UN
Manual of Test and Criteria, Part III, subsection 38.3 as well as the requirements described
below, so it is permitted to transport.
＜Air Transport＞
Our battery is applicable to IATA Dangerous Goods Regulations (IATA-DGR) Packing Instruction
968 section IB because it corresponds to either case that the cell – lithium content is more than
0.3g and less than 1g or the battery – lithium content is more than 0.3g and less than 2g. Our
battery and its shipping package is permitted to transport as Class 9 Dangerous Goods but
without using packing group II package when it complies with all requirements of the transport
conditions for Section IB.
＜Sea Transport＞
Our battery is applicable to the International Maritime Dangerous Goods Code (IMDG-Code)
Special provision 188 because it corresponds to either case that the cell – lithium content is less
than 1g or the battery – lithium content is less than 2g, so it is permitted to transport as
Exempted Dangerous Goods when it complies with all requirements of the transport conditions.
Related regulations: Following regulations shall be cited and considered.
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DGR （ Dangerous Goods Regulations）*1
Maritime transport (by
ship)
IMO（International Maritime Organization）/ IMDG Code
（International Maritime Dangerous Goods Code）*2
Land transport
(Intra-European)
RID（International Carriage of Dangerous Goods by Rail）、ADR
（International Carriage of Dangerous Goods by Road）
USA / UN
USDOT（US Department of Transportation）/ DOT 49 CFR（US law）
UN: Recommendations on the transport of dangerous goods:
Manual of Tests and Criteria 5th revised edition Amendment 1
[ST/SG/AC.10/11/Rev.5/Amend.1]: PartⅢ,Subsection 38.3
15. Regulatory information
Environment-related law of batteries: EU nations have applicable law in accordance with
Directive 2006/66/EC and other some countries, China, Korea, Brazil, some provinces of USA
and Canada or so have similar law.
16. Other information
Reference
● IATA Dangerous Goods Regulations, latest edition
*Notes on this sheet
*Dangerous Goods Regulations – 61th Edition Effective 2020: International Air Transport
Association (IATA)
*IMDG Code – 2016 Edition: International Maritime Organization (IMO)
This sheet refers to normal use of the product. Huiderui Lithium Battery Technology Co., LTD.
makes no warranty expressed or implied
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