1. Identification
SAFETY DATA SHEET
Product number
Product identifier ATTA
Company information
Company phone
Emergency telephone US
Emergency telephone outside
US
Version #
Recommended use
Recommended restrictions
1000025140 (19-1216)
K-G Spray-Pak Inc. (Packaging, SDS assembly)
P.O. Box 89
8001 Keefe St
Vaughan, Ontario L4K 1Y8 Canada
www.kgpackaging.com
General Assistance 1-905-669-9855
1-866-836-8855
1-952-852-4046
01
Cleaner
None known.
2. Hazard(s) identification
Physical hazards
Health hazards
Environmental hazards
OSHA defined hazards
hazard
long-term hazard
Not classified.
X HEAVY DUTY SPRAY DEGREASER 450G
Category 1Flammable aerosols
Category 2Serious eye damage/eye irritation
Category 2Hazardous to the aquatic environment, acute
Category 2Hazardous to the aquatic environment,
Label elements
Signal word
Hazard statement
Precautionary statement
Prevention
Response
Storage
Disposal
Hazard(s) not otherwise
classified (HNOC)
Supplemental information
Danger
Extremely flammable aerosol. Causes serious eye irritation. Toxic to aquatic life. Toxic to aquatic
life with long lasting effects.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open
flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Avoid
release to the environment. Wear eye/face protection.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Collect
spillage.
Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F.
Not available.
None known.
15% of the mixture consists of component(s) of unknown acute hazards to the aquatic
environment. 15% of the mixture consists of component(s) of unknown long-term hazards to the
aquatic environment.
3. Composition/information on ingredients
Mixtures
Product name: ATTAX HEAVY-DUTY SPRAY DEGREASER 450G
Product #: 1000025140 (19-1216) Version #: 01 Issue date: 10-16-2014
SD
S US
1 / 10
CAS number %Chemical name Common name and synonyms
water to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose
74-98-6Propane
106-97-8Butane
64742-47-8Distillates (Petroleum),
Hydrotreated Light
5989-27-5d-Limonene
141-43-5Monoethanolamine
Other components below reportable levels 60 - 80
*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.
4. First-aid measures
Inhalation
Skin contact
Eye contact
Ingestion
Most important
symptoms/effects, acute and
delayed
Indication of immediate
medical attention and special
treatment needed
General information
Move to fresh air. Call a physician if symptoms develop or persist.
Rinse skin with water/shower. Get medical attention if irritation develops and persists.
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists.
In the unlikely event of swallowing contact a physician or poison control center. Rinse mouth.
Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred
vision.
Provide general supportive measures and treat symptomatically. Keep victim under observation.
Symptoms may be delayed.
Ensure that medical personnel are aware of the material(s) involved, and take precautions to
protect themselves.
10 - 20
2.5 - 10
2.5 - 10
2.5 - 10
2.5 - 10
5. Fire-fighting measures
Suitable extinguishing media
Unsuitable extinguishing
media
Specific hazards arising from
the chemical
Special protective equipment
and precautions for firefighters
Fire-fighting
equipment/instructions
Specific methods
General fire hazards
Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).
Do not use water jet as an extinguisher, as this will spread the fire.
Contents under pressure. Pressurized container may explode when exposed to heat or flame.
Firefighters must use standard protective equipment including flame retardant coat, helmet with
face shield, gloves, rubber boots, and in enclosed spaces, SCBA.
Move containers from fire area if you can do so without risk. Containers should be cooled with
holder or monitor nozzles, if possible. If not, withdraw and let fire burn out.
Use standard firefighting procedures and consider the hazards of other involved materials. Move
containers from fire area if you can do so without risk. In the event of fire and/or explosion do not
breathe fumes.
Extremely flammable aerosol.
6. Accidental release measures
Personal precautions,
protective equipment and
emergency procedures
Methods and materials for
containment and cleaning up
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of
low areas. Wear appropriate protective equipment and clothing during clean-up. Do not touch
damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate
closed spaces before entering them. Local authorities should be advised if significant spillages
cannot be contained. For personal protection, see section 8 of the SDS.
Refer to attached safety data sheets and/or instructions for use. Eliminate all ignition sources (no
smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.)
away from spilled material. Stop leak if you can do so without risk. Move the cylinder to a safe and
open area if the leak is irreparable. Cover with plastic sheet to prevent spreading. Absorb in
vermiculite, dry sand or earth and place into containers. Prevent entry into waterways, sewer,
basements or confined areas. Following product recovery, flush area with water.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination. For waste disposal, see section 13 of the SDS.
Environmental precautions
Avoid release to the environment. Inform appropriate managerial or supervisory personnel of all
environmental releases. Prevent further leakage or spillage if safe to do so. Avoid discharge into
drains, water courses or onto the ground.
Product name: ATTAX HEAVY DUTY SPRAY DEGREASER 450G
Product #: 1000025140 (19-1216) Version #: 01 Issue date: 10-16-2014
S US
SD
2 / 10
7. Handling and storage
while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
US. ACGIH Threshold Limit Values
US. NIOSH: Pocket Guide to Chemical Hazards
Precautions for safe handling
Conditions for safe storage,
including any incompatibilities
Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing
or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke
expose containers to heat, flame, sparks, or other sources of ignition. All equipment used when
handling the product must be grounded. Do not re-use empty containers. Do not get in eyes, on
skin, or on clothing. Use only in well-ventilated areas. Wear appropriate personal protective
equipment. Avoid release to the environment. Observe good industrial hygiene practices.
Level 1 Aerosol.
Pressurized container. Protect from sunlight and do not expose to temperatures exceeding
50°C/122 °F. Do not puncture, incinerate or crush. Do not handle or store near an open flame,
heat or other sources of ignition. This material can accumulate static charge which may cause
spark and become an ignition source. Refrigeration recommended. Store away from incompatible
materials (see Section 10 of the SDS).
8. Exposure controls/personal protection
Occupational exposure limits
PEL 6 mg/m3Monoethanolamine (CAS
141-43-5)
PEL 1800 mg/m3Propane (CAS 74-98-6)
ValueComponents Type
3 ppm
1000 ppm
STEL 1000 ppmButane (CAS 106-97-8)
STEL 6 ppmMonoethanolamine (CAS
141-43-5)
TWA 3 ppm
TWA 1900 mg/m3Butane (CAS 106-97-8)
STEL 15 mg/m3Monoethanolamine (CAS
141-43-5)
TWA 8 mg/m3
TWA 1800 mg/m3Propane (CAS 74-98-6)
Biological limit values
Appropriate engineering
controls
No biological exposure limits noted for the ingredient(s).
Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates
should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,
or other engineering controls to maintain airborne levels below recommended exposure limits. If
exposure limits have not been established, maintain airborne levels to an acceptable level. Provide
eyewash station.
Individual protection measures, such as personal protective equipment
Eye/face protection
Hand protection
Wear safety glasses with side shields (or goggles).
Wear appropriate chemical resistant gloves.
Skin protection
Other
Respiratory protection
Thermal hazards
General hygiene
considerations
Wear suitable protective clothing.
In case of insufficient ventilation, wear suitable respiratory equipment.
Wear appropriate thermal protective clothing, when necessary.
When using do not smoke. Always observe good personal hygiene measures, such as washing
after handling the material and before eating, drinking, and/or smoking. Routinely wash work
clothing and protective equipment to remove contaminants.
ValueComponents Type
ValueComponents Type
800 ppm
6 ppm
3 ppm
1000 ppm
Product name: ATTAX HEAVY DUTY SPRAY DEGREASER 450G
Product #: 1000025140 (19-1216) Version #: 01 Issue date: 10-16-2014
S US
SD
3 / 10
9. Physical and chemical properties
Ingestion
Inhalation
Eye contact
Appearance
Physical state
Form
Color
Odor
Odor threshold
pH
Melting point/freezing point
Initial boiling point and boiling
range
Flash point
Evaporation rate
Flammability (solid, gas)
Upper/lower flammability or explosive limits
Flammability limit - lower
(%)
Flammability limit - upper
(%)
Explosive limit - lower (%)
Explosive limit - upper (%)
Vapor pressure
Vapor density
Relative density
Solubility(ies)
Solubility (water)
Partition coefficient
(n-octanol/water)
Auto-ignition temperature
Decomposition temperature
Viscosity
Other information
Specific gravity
Liquid.
Aerosol.
Not available.
Not available.
Not available.
10.3 Supplier estimated
Not available.
347.9 °F (175.5 °C) estimated
156.0 °F (72.0 °C) Propellant estimated
Not available.
Not available.
1.9 % estimated
9.5 % estimated
Not available.
Not available.
Not available.
Not available.
Not available.
Not available.
Not available.
Not available.
Not available.
Not available.
0.85 estimated
10. Stability and reactivity
Reactivity
Chemical stability
Possibility of hazardous
reactions
Conditions to avoid
Incompatible materials
Hazardous decomposition
products
11. Toxicological information
Information on likely routes of exposure
Product name: ATTAX HEAVY DUTY SPRAY DEGREASER 450G
Product #: 1000025140 (19-1216) Version #: 01 Issue date: 10-16-2014
Skin contact
The product is stable and non-reactive under normal conditions of use, storage and transport.
Material is stable under normal conditions.
No dangerous reaction known under conditions of normal use.
Avoid temperatures exceeding the flash point. Contact with incompatible materials.
Strong oxidizing agents.
No hazardous decomposition products are known.
Expected to be a low ingestion hazard.
No adverse effects due to inhalation are expected.
Prolonged or repeated exposure may cause liver and kidney damage. These effects have not
been observed in humans.
Causes serious eye irritation.
US
SDS
4 / 10
Symptoms related to the
Acute toxicity
physical, chemical and
Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred
vision.
toxicological characteristics
Information on toxicological effects
WORK X DEGREASER 450G (CAS Mixture)
Acute
Dermal
LD50 Rabbit
Rat 2823.5293 mg/kg estimated
Inhalation
LC100 Cat
LC50 Mouse 8246.667 mg/l, 120 Minutes estimated
Rat 86820 ppm, 4 Hours estimated
Oral
LD50 Rat
Butane (CAS 106-97-8)
Acute
Inhalation
LC50 Mouse
Rat 1355 mg/l
Distillates (Petroleum), Hydrotreated Light (CAS 64742-47-8)
Acute
Dermal
LD50 Rabbit
Inhalation
LC50 Rat
Oral
LD50 Rat
Monoethanolamine (CAS 141-43-5)
Acute
Dermal
LD50 Rabbit
Inhalation
LC50 Rat
Oral
LD50 Rat
Test ResultsProduct Species
9338.9629 mg/kg, 24 Hours estimated
72.3529 ml/kg, 24 Hours estimated
600 % estimated
346.6667 %, 120 Minutes estimated
106.6667 mm/l, 2 Hours estimated
4386.6665 mg/l/4h estimated
48.9314 mg/l, 4 Hours estimated
38.2353 mg/l, 6 Hours estimated
20031.5273 mg/kg estimated
4783.5293 ml/kg estimated
Test ResultsComponents Species
1237 mg/l, 120 Minutes
52 %, 120 Minutes
> 2000 mg/kg
> 2000 mg/kg, 24 Hours
> 7.5 mg/l, 6 Hours
> 4.6 mg/l, 4 Hours
> 5000 mg/kg
2504 mg/kg, 24 Hours
2.46 - 2.83 ml/kg, 24 Hours
> 1.3 mg/l, 6 Hours
1089 mg/kg
Product name: ATTAX HEAVY DUTY SPRAY DEGREASER 450G
Product #: 1000025140 (19-1216) Version #: 01 Issue date: 10-16-2014
SDS US
5 / 10
Propane (CAS 74-98-6)
Respiratory sensitization
Carcinogenicity
Aspiration hazard
Acute
Inhalation
LC50 Mouse
Rat 1355 mg/l
* Estimates for product may be based on additional component data not shown.
Skin corrosion/irritation
Serious eye damage/eye
Prolonged skin contact may cause temporary irritation.
Causes serious eye irritation.
irritation
Respiratory or skin sensitization
Not available.
Skin sensitization
Germ cell mutagenicity
This product is not expected to cause skin sensitization.
No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
IARC Monographs. Overall Evaluation of Carcinogenicity
d-Limonene (CAS 5989-27-5) 3 Not classifiable as to carcinogenicity to humans.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
Reproductive toxicity
Specific target organ toxicity -
This product is not expected to cause reproductive or developmental effects.
Not classified.
single exposure
Specific target organ toxicity -
Not classified.
repeated exposure
Not available.
Chronic effects
May be harmful if absorbed through skin.
Test ResultsComponents Species
1.07 ml/kg
1237 mg/l, 120 Minutes
52 %, 120 Minutes
658 mg/l/4h
Prolonged or repeated exposure may cause liver and kidney damage. These effects have not
been observed in humans.
12. Ecological information
Ecotoxicity
Product Test ResultsSpecies
WORK X DEGREASER 450G (CAS Mixture)
Aquatic
Components Test ResultsSpecies
Distillates (Petroleum), Hydrotreated Light (CAS 64742-47-8)
Aquatic
d-Limonene (CAS 5989-27-5)
Aquatic
Toxic to aquatic life with long lasting effects.
IC50Algae 441.1765 mg/L, 72 Hours estimatedAlgae
EC50Crustacea 31.7647 ppm, 48 Hours estimatedDaphnia
LC50Fish 25.0588 mg/l, 96 Hours estimatedFish
LC50Fish 2.9 mg/l, 96 hoursRainbow trout,donaldson trout
(Oncorhynchus mykiss)
EC50Crustacea 69.6 mg/l, 48 hoursWater flea (Daphnia pulex)
LC50Fish 0.619 - 0.796 mg/l, 96 hoursFathead minnow (Pimephales promelas)
Product name: ATTAX HEAVY DUTY SPRAY DEGREASER 450G
Product #: 1000025140 (19-1216) Version #: 01 Issue date: 10-16-2014
SDS US
6 / 10
Components Test ResultsSpecies
Partition coefficient n-octanol / water (log Kow)
Monoethanolamine (CAS 141-43-5)
Aquatic
IC50Algae 15 mg/L, 72 HoursAlgae
EC50Crustacea 65 mg/L, 48 HoursDaphnia
LC50Fish 114 - 196 mg/l, 96 hoursRainbow trout,donaldson trout
(Oncorhynchus mykiss)
* Estimates for product may be based on additional component data not shown.
Persistence and degradability
Bioaccumulative potential
No data is available on the degradability of this product.
No data available.
Butane 2.89
d-Limonene 4.232
Monoethanolamine -1.31
Propane 2.36
Mobility in soil
Other adverse effects
No data available.
No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.
13. Disposal considerations
Disposal instructions
Local disposal regulations
Hazardous waste code
Waste from residues / unused
products
Contaminated packaging
Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Contents
under pressure. Do not puncture, incinerate or crush. Do not allow this material to drain into
sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used
container. Dispose of contents/container in accordance with local/regional/national/international
regulations.
Dispose in accordance with all applicable regulations.
The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Dispose of in accordance with local regulations. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Empty containers should be taken to an approved waste handling site for recycling or disposal.
Since emptied containers may retain product residue, follow label warnings even after container is
emptied. Do not re-use empty containers.
14. Transport information
DOT
UN number
UN proper shipping name
Transport hazard class(es)
Class
Subsidiary risk
Label(s)
Packing group
Special precautions for user
Special provisions
Packaging exceptions
Packaging non bulk
Packaging bulk
This product meets the exception requirements of section 173.306 as a limited quantity and may be shipped as a limited quantity.
Until 12/31/2020, the "Consumer Commodity - ORM-D" marking may still be used in place of the new limited quantity diamond
mark for packages of UN 1950 Aerosols. Limited quantities require the limited quantity diamond mark on cartons after 12/31/20
and may be used now in place of the "Consumer Commodity ORM-D" marking and both may be displayed concurrently.
IATA
UN number
UN proper shipping name
Transport hazard class(es)
Class
Subsidiary risk
Product name: ATTAX HEAVY DUTY SPRAY DEGREASER 450G
Product #: 1000025140 (19-1216) Version #: 01 Issue date: 10-16-2014
UN1950
Aerosols, flammable, (each not exceeding 1 L capacity)
2.1
-
2.1
Not applicable.
Read safety instructions, SDS and emergency procedures before handling.
N82
306
None
None
UN1950
Aerosols, flammable
2.1
-
S US
SD
7 / 10
Label(s)
Packing group
Environmental hazards
ERG Code
Special precautions for user
Other information
Passenger and cargo
aircraft
Cargo aircraft only
Packaging Exceptions
IMDG
UN number
UN proper shipping name
Transport hazard class(es)
Class
Subsidiary risk
Label(s)
Packing group
Environmental hazards
Marine pollutant
EmS
Special precautions for user
Packaging Exceptions
Transport in bulk according to
Annex II of MARPOL 73/78 and
the IBC Code
DOT
2.1
Not applicable.
Yes
10L
Read safety instructions, SDS and emergency procedures before handling.
Allowed.
Allowed.
LTD QTY
UN1950
AEROSOLS
2.1
-
2.1
Not applicable.
Yes
F-D, S-U
Read safety instructions, SDS and emergency procedures before handling.
LTD QTY
Not applicable.
IATA; IMDG
Marine pollutant
Product name: ATTAX HEAVY DUTY SPRAY DEGREASER 450G
Product #: 1000025140 (19-1216) Version #: 01 Issue date: 10-16-2014
S US
SD
8 / 10
15. Regulatory information
US federal regulations
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4)
Not listed.
SARA 304 Emergency release notification
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous
chemical
SARA 313 (TRI reporting)
Not regulated.
This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
All components are on the U.S. EPA TSCA Inventory List.
Immediate Hazard - Yes
Delayed Hazard - No
Fire Hazard - Yes
Pressure Hazard - No
Reactivity Hazard - No
No
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Butane (CAS 106-97-8)
Propane (CAS 74-98-6)
Safe Drinking Water Act
Not regulated.
(SDWA)
US state regulations
US. Massachusetts RTK - Substance List
Butane (CAS 106-97-8)
Monoethanolamine (CAS 141-43-5)
Propane (CAS 74-98-6)
US. New Jersey Worker and Community Right-to-Know Act
Butane (CAS 106-97-8)
Monoethanolamine (CAS 141-43-5)
Propane (CAS 74-98-6)
US. Pennsylvania Worker and Community Right-to-Know Law
Butane (CAS 106-97-8)
Monoethanolamine (CAS 141-43-5)
Propane (CAS 74-98-6)
US. Rhode Island RTK
Butane (CAS 106-97-8)
Propane (CAS 74-98-6)
US. California Proposition 65
California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain
any chemicals currently listed as carcinogens or reproductive toxins.
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
YesAustralia Australian Inventory of Chemical Substances (AICS)
YesCanada Domestic Substances List (DSL)
NoCanada Non-Domestic Substances List (NDSL)
Product name: ATTAX HEAVY DUTY SPRAY DEGREASER 450G
Product #: 1000025140 (19-1216) Version #: 01 Issue date: 10-16-2014
S US
SD
9 / 10
Country(s) or region Inventory name On inventory (yes/no)*
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
Substances (EINECS)
(PICCS)
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
country(s).
16. Other information, including date of preparation or last revision
Issue date
Version #
Disclaimer
10-16-2014
01
KGSP cannot anticipate all conditions under which this information and its product, or the products
of other manufacturers in combination with its product, may be used. It is the user’s responsibility
to ensure safe conditions for handling, storage and disposal of the product, and to assume liability
for loss, injury, damage or expense due to improper use. The information in the sheet was written
based on the best knowledge and experience currently available.
YesChina Inventory of Existing Chemical Substances in China (IECSC)
YesEurope European Inventory of Existing Commercial Chemical
NoEurope European List of Notified Chemical Substances (ELINCS)
YesJapan Inventory of Existing and New Chemical Substances (ENCS)
YesKorea Existing Chemicals List (ECL)
YesNew Zealand New Zealand Inventory
YesPhilippines Philippine Inventory of Chemicals and Chemical Substances
YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory
Product name: ATTAX HEAVY DUTY SPRAY DEGREASER 450G
Product #: 1000025140 (19-1216) Version #: 01 Issue date: 10-16-2014
S US
SD
10 / 10
Loading...