SAFETY DATA SHEET ATTAX HEAVY-DUTY DEGREASER
<< N/E = Not established N/AP = Not Applicable N/AV = Not Available C.O.C = Cleveland Open Cup>>
Product Name:
Product Codes:
Material
Intended Use:
Chemical
Family:
CAS number:
Manufacturer's
Name:
Address:
City & Province:
ATTAX HEAVY-DUTY DEGREASER
19-0105, 19-0045, 19-0001
Heavy Duty Degreasing Syrup
Proprietary complex mixture/ preparation
N/AP
WORX Environmental Products Inc.
Unit 10, 2305 - 52nd Ave SE
Calgary, AB T2C 4X7
Emergency Telephone:
403-273-7600 or 1-800-424-9679
E-mail of the competent
Person responsible for
the Safety Data Sheet: worxrd@worx.ca
2.1
Classification of the mixture
Flammable liquid (Category 4),
Aspiration hazard (Category 1)
Eye irritation (Category 2B)
2.2
Label elements
2.2.1 Label elements
Hazard pictogram(s): Aspiration
Hazard Signal word(s): Danger
Hazard statement(s):
Combustible liquid
May be fatal if swallowed and enters airways.
Causes eye irritation
Precautionary Statement(s):
Prevention:
Store in well-ventilated place.
Keep cool.
Keep away from flames and hot surfaces - No smoking.
Wear protective gloves/ eye protection.
In case of fire: Use water or dry foam for extinction
Wash skin and eyes thoroughly after handling
Dispose of contents/container in accordance with local regulations.
Response:
IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
If eye irritation persists, get medical attention.
IF SWALLOWED: Immediately consult a physician. DO NOT induce
vomiting.
Other Hazards: no hazard known.
SECTION I: MATERIAL IDENTIFICATION AND USE
SECTION II: HAZARDS IDENTIFICATION
SAFETY DATA SHEET ATTAX HEAVY-DUTY DEGREASER
Ingredient(s)
% W/W
CAS No.
d-Limonene
5-10
5989-27-5
Glycol*
7-13
1569-01-3
*Glycol listed is a non-hazardous, non-toxic and is NOT Ethylene Glycol Monobutyl Ether.
The specific chemical identity is being withheld as a trade secret.
4.1. Description of first aid measures
Eyes: Check for and remove any contact lenses. Do not rub eyes.
Immediately flush with warm running water, holding the eyelids apart,
for 1 5 minutes. Call a physician if irritation develops.
Skin: Remove contaminated clothing and shoes. Wash affected skin with soap
and water. See physician if irritation develops.
Ingestion: No toxic effect is expected, but as a precautio n drink a glass of water or
milk to dilute. Consult a physician if nausea develops.
Inhalation: Immediately remove the affected victim to fresh air. If symptoms persist, obtain
medical attention.
4.2
Most important symptoms and effects, both acute and delayed:
May cause lungs damage if swallowed and enters airways.
May cause eye irritation.
4.3
Indication of the immediate medical attention and special treatment needed: Treat
symptomatically.
5.1
Extinguishing media
Suitable Extinguishing Media: Extinguish preferably with
water or dry foam Unsuitable Extinguishing Media: Not
applicable.
5.2
Special hazards arising from the substance or mixture: Product is combustible and a slip
hazard.
5.3
Protective equipment: Not applicable.
5.4
Flammability classification (OSHA 29 CFR 1910.106) (Hazcom 2012): Combustible liquid
(Category 4)
5.5
Additional Information: Will not sustain flame <162°F if the ignition is removed;
therefore, under normal operating conditions the UEL and LEL are not applicable.
6.1
Personal precautions, protective equipment and emergency procedures
For non- emergency personnel: Small spill: Use appropriate tools to wipe up the
product. Rinse contaminated area with water. Large spill: Stop the leak if possible.
Ventilate the area involved. Block release of the chemical from sewer or storm
SECTION IV: FIRST AID MEASURES
SECTION lII: COMPOSITION/INFORMATION ON INGREDIENTS
SECTION V: FIRE FIGHTING MEASURES
SECTION VI: ACCIDENTAL RELEASE MEASURES
SAFETY DATA SHEET ATTAX HEAVY-DUTY DEGREASER
drains. Contain and clean-up the spill. Observe all personal protection equipment
recommendations. Ensure personal protection during removal of spillages.
Eliminate all ignition sources if safe to do so. Local authority should be advised if
significant spill cannot be contained.
For emergency responders: Use personnel protection recommended in Section 8
6.2
Environmental precautions: Prevent further leakage or spillage if safe to do so.
Avoid discharge into drains, water courses or onto the ground
6.3
Methods and material for containment and cleaning up
Do not release large quantities into the surface water or into drains.
Wear suitable gloves and eye/face protection.
Remove or make safe all sources of ignition. Rinse remaining liquid with water
6.4
Reference to other sections See Also Section 7, 8, 13.
6.5
Additional Information: For waste Disposal: Follow local regulations for discharge of waste
effluent.
7.1
Precautions for safe handling Use only in well-ventilated areas if significant misting will occur.
If irritation develops in nose or throat leave the area and ventilate area prior to re-entry. Keep
away from oxidizing, reducing agents. Keep away from fire, sparks and heated surfaces - no
smoking.
7.2
Conditions for safe storage, including any incompatibilities Store in a cool, dry, well-
ventilated place. Do not use or store near heat or open flame. Do not store and transport with
oxidizers etc. Keep container closed when not in use. Storage Temperature < 50 ºC.
7.3
Incompatible materials: Oxidizing agents, Strong Acids
7.4
Additional Information: When product is used in confined space, the use of proper ventilation
is required.
8.1
Control parameters
8.1.1
Occupational Exposure Limits:
US. Workplace Environmental Exposure Level (WEEL) Guides
D-limonene (CAS 5989-27-5) TWA 165.5 mg/m3
8.1.2
Biological limit value: Biological limit values are not available for this product.
8.2
Engineering Controls: provide good ventilations. Ensure that eyewash stations and
safety showers are proximal to the work-station location.
8.3
Personal protection equipment (PPE)
Protective Handwear: Nitrile gloves recommended preventing drying of hands.
Protective Eyewear: Safety glasses with side shields or goggles
Other protective clothing: Not required.
Respiratory Apparatus: None required, however if applicable results in
significant misting of product respiratory
protection is recommended. If needed, use a
MSHA/NIOSH approved half mask air purifying
respirator with carbon filters.
SECTION VIII: EXPOSURE CONTROL / PERSONAL PROTCTION
SECTION VII: SAFE HANDLING AND STORAGE
SAFETY DATA SHEET ATTAX HEAVY-DUTY DEGREASER
Local/mechanical exhaust: Not required.
8.3.1
Environmental Exposure Controls: Adequate ventilation must be used.
Guarantee sufficient ventilation during and after use, in order to
prevent vapor accumulation.
Physical State:
Appearance:
Specific Gravity:
Vapor Density :( Air=1)
Liquid
Gold*
0.870
N/Av
Odor:
Odor Threshold:
Vapor Pressure:
Evaporation rate:
Peac
h N/E
N/Av
N/E
Boiling Point: (0C.)
N/Av
Freezing Point: (0C.)
-40
Solubility in Water:
Soluble
pH factor:
10-11
Flash Point:
72ºC (162°F)
C.O.C
% Volatile:
N/Av
Explosive limits
N/Av
Oxidizer
N/E
Water solubility
N/Av
Viscosity
N/E
Partition coefficient
N/Av
Auto ignition
temperature
N/E
Decomposition Temperature
N/Av
Explosive properties
N/E
*Within the first 48 hours of being blended, the product is light gold in colour and is visibly clear.
Over a period of 2 weeks the colour with slightly darken into and amber colour, with no impact to
the product,
10.1
Reactivity: Strong oxidizing agents, strong reducing acids.
10.2
Chemical stability: Stable under normal conditions.
10.3
Possibility of hazardous reactions: Can react if in contact with – strong oxidizing agents.
10.4
Conditions to avoid: Avoid contact with heat and ignition sources.
10.5
Incompatible materials: Strong oxidizing agents, strong reducing acids
10.6
Hazardous Decomposition Product(s): Carbon monoxide, Carbon dioxide.
10.7
Hazardous polymerization: Will not occur.
Information on toxicological effects:
11.1.1
Information on likely routes of exposure. Signs and Symptoms of short term exposure:
Inhalation: May slightly irritate respiratory system, if used in poorly ventilated area
Ingestion: No toxic effects are expected, but consult a physician if nausea develops.
Skin Contact: Prolonged contact may cause slight irritation, dryness.
Eye Contact: May cause eye irritation. Monogoggles recommended if significant
misting of product will occur.
11.1.2
Mixtures
Acute Oral Toxicity Estimate: Terpenes Hydrocarbon: LD50 (oral, rabbit) 5,000 mg/kg
Glycol: LD50 (oral rat) 2,000-4,000 mg/kg
Acute Dermal Toxicity Estimate: Terpenes Hydrocarbon: LD50 (dermal, rabbit) 5,000
mg/kg
SECTION IX: PHYSICAL DATA
SECTION X: STABILITY AND REACTIVITY DATA
SECTION XI: TOXICOLOGICAL INFORMATION
SAFETY DATA SHEET ATTAX HEAVY-DUTY DEGREASER
Glycol: LD50 (dermal, rat) 2,000-4,000 mg/kg
Acute Inhalation Toxicity Estimate: N/Av
Irritation Causes eye irritation.
Corrosivity: Not to be expected.
Carcinogenicity Data: The ingredients of this product are not classed as
carcinogenic by ACGIH, IARC, OSHA
Reproductive Data: None.
Mutagenicity Data: None.
Skin sensitization: Is not a skin sensitizer
11.2 Chronic effects (humans): N/Ap
11.3 Numerical Measure of Toxicity: N/Av
12.1
Toxicity
96 hour LC
50
(Tilapia Nilotica)
= 22.6 mg/l
96 hour LC
50
(Rainbow trout)
=
20
mg/l
48 hour EC
50
(Daphnia magna)
= 27ppm
72 hour EC
50
(Raphidocelis subcapitata)
=
40
mg/l
12.2
Persistence and degradability: Readily biodegradable
12.3
Bioaccumulative potential Not Available
12.4
Mobility in soil Not Available
12.5
Results of PBT and vPvB assessment Not Available.
12.6
Other adverse effects: None
13.1
Waste treatment methods: Follow treatment/disposal applicable local, provincial,
and federal regulations. This material is readily biodegradable in aerobic and
anaerobic conditions. It is not expected to bioaccumulate.
13.2
Contaminated Packaging: N/Av
13.3
Additional Information Avoid release to the environment.
14.1
ADR Classification Not Regulated
14.2
US 49 CFR/DOT (Department of Transportation) Not Regulated
14.3
TDG (Canada Transport of Dangerous Goods) Not Regulated
14.4
ICAO/IATA Not Regulated
14.5
IMO/IMDG Not Regulated
14.6
Marine Pollutant Not Regulated
SECTION XII: ECOLOGICAL INFORMATION
SECTION XIII: DISPOSAL CONSIDERATIONS
SECTION XIV: TRANSPORTATION INFORMATION
SAFETY DATA SHEET ATTAX HEAVY-DUTY DEGREASER
15.1. US Federal Information:
OSHA: This material is classified as a “hazardous chemical” under OSHA regulations (29 CFR
1910.1200). Hazardous classification:
Combustible liquid (Category4)
Aspiration hazard (Category 1)
Eye irritation (Category 2B)
USA TSCA (Toxic Substance Control Act): All chemicals listed
SARA TITLE III: Sec.302. 40 CFR 355: No extremely hazardous substances are present in this
material.
SARA TITLE III: Sec.313. 40 CFR 372 This product does not contain any toxic
chemicals subject to the reporting requirements of SARA (III) Section 313 of the
Emergency Planning and Community Right-to-Know Act.
SARA TITLE III: Sec.311 and 312. 40 CFR 370 MSDS Requirements. Hazardous
Classes: Fire Hazard; Acute Health Hazard. Under SARA Section 311 and 312, the EPA
has established threshold quantities for the reporting of hazardous chemicals. The current
thresholds are 500 pounds for the threshold planning quantity (TPQ), whichever is low,
for extremely hazardous substances and 10,000 pounds for all the other hazardous
chemicals.
US State Right to Know Law
Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986:
This product is not known to contain any chemicals currently listed as carcinogens or
reproductive toxins under California Proposition 65 at levels under which would be subject
to the proposition.
International information
Canadian Environmental Protection Act (CEPA) All ingredients listed appear on
the Domestic Substances List (DSL)
15.2
Safety, health and environmental regulations/legislation specific for the substance or
mixture
European Union (EINECS/ELINCS): All chemicals listed
Canada WHMIS Classification: Class B 3, Combustible Liquid, Class D 2B (Mild
Eye irritation)
15.3
Chemical Safety Assessment: COMBUSTIBLE LIQUID, ASPIRATION HAZARD, IRRITANT
TO EYES
Information for this Safety Data Sheet was prepared from sources considered reliable. While
every effort has been made to ensure full disclosure of product hazards, data is not available
SECTION XV: REGULATORY INFORMATION
SECTION XVI: ADDITIONAL INFORMATION
SAFETY DATA SHEET ATTAX HEAVY-DUTY DEGREASER
in some cases and is so stated where applicable. The manufacturer assumes no liability or
responsibility, and no warranty is expressed or implied, in cases where products are
mishandled, misused or instructions are not strictly observed. Each recipient of this SDS is
encouraged to study it carefully to fully understand this product
SECTION XVII:
PREPARATION INFORMATION
Prepared by:
WORX Environmental Products
Telephone:
1-800-424-9679
Date:
June 20, 2018
Replaces:
April 19, 2017
Loading...