White Lightning WL3333320 User Manual

WHITE LIGHTNING® STOP GAP!™ Triple Expanding Insulating Foam
Not available. Spray
(216) 566-2917
SAFETY DATA SHEET
Other means of identification
Product type
Emergency telephone number of the company
Section 1. Identification
:
:::
Manufacturer
:
White Lightning Products 101 W. Prospect Avenue Cleveland, OH 44115
Relevant identified uses of the substance or mixture and uses advised against
Not applicable.
WL3333300
WL3333300
Product code
:
Product Information Telephone Number
:
(800) 241-5295
Regulatory Information Telephone Number
:
(216) 566-2902
Transportation Emergency Telephone Number
:
(800) 424-9300
National contact
:
White Lightning Products 180 Brunel Road Mississauga, Ontario L4Z 1T5 Canada
CAS #
:
Not applicable.
Section 2. Hazards identification
FLAMMABLE AEROSOLS - Category 1 GASES UNDER PRESSURE - Compressed gas ACUTE TOXICITY (inhalation) - Category 4 SKIN CORROSION/IRRITATION - Category 2 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A RESPIRATORY SENSITIZATION - Category 1 SKIN SENSITIZATION - Category 1 CARCINOGENICITY - Category 2 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) ­Category 3 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2
Classification of the substance or mixture
:
Hazard pictograms
:
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 10%
Date of issue/Date of revision
:
7/26/2016
Date of previous issue
:
No previous validation
Version
:11/13
Section 2. Hazards identification
Signal word
:
Danger
Precautionary statements
Prevention
:
Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves. Wear eye or face protection. Wear protective clothing. Wear respiratory protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Do not spray on an open flame or other ignition source. Use only outdoors or in a well-ventilated area. Do not breathe vapor. Wash hands thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace. Pressurized container: Do not pierce or burn, even after use.
Response
:
Get medical attention if you feel unwell. IF exposed or concerned: Get medical attention. IF INHALED: If breathing is difficult, remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. If experiencing respiratory symptoms: Call a POISON CENTER or physician. IF ON SKIN: Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation or rash occurs: Get medical attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention.
Storage
:
Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F. Store in a well-ventilated place.
Disposal
Dispose of contents and container in accordance with all local, regional, national and international regulations.
General
:
Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand.
Hazards not otherwise classified
:
None known.
Extremely flammable aerosol. Contains gas under pressure; may explode if heated. Harmful if inhaled. Causes serious eye irritation. Causes skin irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. Suspected of causing cancer. May cause respiratory irritation. May cause drowsiness or dizziness. May cause damage to organs through prolonged or repeated exposure.
:
Hazard statements
Please refer to the SDS for additional information. Keep out of reach of children. Keep upright in a cool, dry place. Do not discard empty can in trash compactor.
Supplemental label elements
DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which can cause permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. VAPOR AND SPRAY MIST HARMFUL. Gives off harmful vapor of solvents and isocyanates. DO NOT USE IF YOU HAVE CHRONIC (LONG-TERM) LUNG OR BREATHING PROBLEMS, OR IF YOU HAVE EVER HAD A REACTION TO ISOCYANATES. USE ONLY WITH ADEQUATE VENTILATION. WHERE OVERSPRAY IS PRESENT, A POSITIVE PRESSURE AIR SUPPLIED RESPIRATOR (NIOSH approved) SHOULD BE WORN TO PREVENT EXPOSURE. IF UNAVAILABLE, AN APPROPRIATE PROPERLY FITTED APPROVED NIOSH VAPOR/PARTICULATE RESPIRATOR MAY BE EFFECTIVE. Follow directions for respirator use. Wear the respirator for the whole time of spraying and until all vapors and mists are gone. If you have any breathing problems during use, LEAVE THE AREA and get fresh air. If problems remain or happen later, IMMEDIATELY call a doctor - If not available get emergency medical treatment. Have this label with you. Reacts with water in closed container to produce pressure which may cause container to burst.
:
Date of issue/Date of revision
:
7/26/2016
Date of previous issue
:
No previous validation
Version
:12/13
Section 3. Composition/information on ingredients
Diphenylmethane Diisocyanate Polymer
37.5
9016-87-9
4, 4'-Diphenylmethane Diisocyanate
13.5
101-68-8
Propane
10
74-98-6
2-Methylpropane
10
75-28-5
Ingredient name
CAS number
% by weight
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health and hence require reporting in this section.
Other means of identification
:
Not available.
Substance/mixture
CAS number/other identifiers
:
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Get medical attention. If necessary, call a poison center or physician.
Get medical attention.
Wash with plenty of soap and water. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Get medical attention. In the event of any complaints or symptoms, avoid further exposure.
If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. In the event of any complaints or symptoms, avoid further exposure.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion
:
:
:
:
Description of necessary first aid measures
Most important symptoms/effects, acute and delayed
Inhalation
:
Harmful if inhaled. Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. May cause respiratory irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled.
Can cause central nervous system (CNS) depression.
:
Ingestion
Skin contact
:
Causes skin irritation. May cause an allergic skin reaction.
Causes serious eye irritation.
:
Eye contact
Over-exposure signs/symptoms
Inhalation
Adverse symptoms may include the following: respiratory tract irritation coughing wheezing and breathing difficulties asthma nausea or vomiting headache drowsiness/fatigue dizziness/vertigo
:
Eye contact
:
Adverse symptoms may include the following: pain or irritation watering redness
Potential acute health effects
Date of issue/Date of revision
:
7/26/2016
Date of previous issue
:
No previous validation
Version
:13/13
Section 4. First aid measures
Protection of first-aiders
:
No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.
Notes to physician
:
In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments
:
No specific treatment.
Skin contact
Ingestion
unconsciousness
No specific data.
Adverse symptoms may include the following: irritation redness
:
:
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.
Hazardous thermal decomposition products
Specific hazards arising from the chemical
Decomposition products may include the following materials: carbon dioxide carbon monoxide nitrogen oxides
Extremely flammable aerosol. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Gas may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back, causing fire or explosion. Bursting aerosol containers may be propelled from a fire at high speed. Runoff to sewer may create fire or explosion hazard.
Special protective equipment for fire-fighters
Use an extinguishing agent suitable for the surrounding fire.
Extinguishing media
: :
:
None known.
Suitable extinguishing media
:
Unsuitable extinguishing media
:
Special protective actions for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
:
:
In the case of aerosols being ruptured, care should be taken due to the rapid escape of the pressurized contents and propellant. If a large number of containers are ruptured, treat as a bulk material spillage according to the instructions in the clean-up section. Shut off all ignition sources. No flares, smoking or flames in hazard area.
No specific hazard.
For non-emergency personnel
For emergency responders
:
If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non­emergency personnel".
Date of issue/Date of revision
:
7/26/2016
Date of previous issue
:
No previous validation
Version
:14/13
Section 6. Accidental release measures
Use spark-proof tools and explosion-proof equipment. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.
Large spill
:
Use spark-proof tools and explosion-proof equipment.
Small spill
:
Methods and materials for containment and cleaning up
Section 7. Handling and storage
Advice on general occupational hygiene
Conditions for safe storage, including any incompatibilities
Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.
Store in accordance with local regulations. Protect from sunlight. Store locked up. Eliminate all ignition sources.
:
:
Protective measures
Persons with a history of skin sensitization problems or asthma, allergies or chronic or recurrent respiratory disease should not be employed in any process in which this product is used. Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do not pierce or burn, even after use. Avoid exposure ­obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools.
:
Precautions for safe handling
Diphenylmethane Diisocyanate Polymer
None.
4, 4'-Diphenylmethane Diisocyanate
ACGIH TLV (United States, 3/2015).
TWA: 0.005 ppm 8 hours.
NIOSH REL (United States, 10/2013).
TWA: 0.05 mg/m³ 10 hours. TWA: 0.005 ppm 10 hours. CEIL: 0.2 mg/m³ 10 minutes. CEIL: 0.02 ppm 10 minutes.
OSHA PEL (United States, 2/2013).
CEIL: 0.02 ppm CEIL: 0.2 mg/m³
Propane
NIOSH REL (United States, 10/2013).
TWA: 1000 ppm 10 hours. TWA: 1800 mg/m³ 10 hours.
OSHA PEL (United States, 2/2013).
TWA: 1000 ppm 8 hours. TWA: 1800 mg/m³ 8 hours.
2-Methylpropane
NIOSH REL (United States, 10/2013).
TWA: 800 ppm 10 hours. TWA: 1900 mg/m³ 10 hours.
ACGIH TLV (United States, 3/2015).
STEL: 1000 ppm 15 minutes.
Section 8. Exposure controls/personal protection
Ingredient name
Exposure limits
Control parameters
Occupational exposure limits (OSHA United States)
Occupational exposure limits (Canada)
Date of issue/Date of revision
:
7/26/2016
Date of previous issue
:
No previous validation
Version
:15/13
Section 8. Exposure controls/personal protection
Hand protection
Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles.
Eye/face protection
:
:
Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
Appropriate engineering controls
:
Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.
Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
Hygiene measures
:
Individual protection measures
Skin protection
Diphenylmethane Diisocyanate Polymer
CA Alberta Provincial (Canada, 4/2009).
8 hrs OEL: 0.07 mg/m³ 8 hours. 8 hrs OEL: 0.005 ppm 8 hours.
CA British Columbia Provincial (Canada, 5/2015).
TWA: 0.005 ppm 8 hours. C: 0.01 ppm
CA Ontario Provincial (Canada, 7/2015).
C: 0.02 ppm TWA: 0.005 ppm 8 hours.
4, 4'-Diphenylmethane Diisocyanate
CA Alberta Provincial (Canada, 4/2009).
8 hrs OEL: 0.005 ppm 8 hours. 8 hrs OEL: 0.05 mg/m³ 8 hours.
CA British Columbia Provincial (Canada, 5/2015). Absorbed through skin. Skin sensitizer.
TWA: 0.005 ppm 8 hours. C: 0.01 ppm
CA Quebec Provincial (Canada, 1/2014). Skin sensitizer.
TWAEV: 0.005 ppm 8 hours. TWAEV: 0.051 mg/m³ 8 hours.
CA Ontario Provincial (Canada, 7/2015).
TWA: 0.005 ppm 8 hours.
CA Saskatchewan Provincial (Canada, 7/2013).
STEL: 0.015 ppm 15 minutes. TWA: 0.005 ppm 8 hours.
Ingredient name
Exposure limits
Environmental exposure controls
:
Date of issue/Date of revision
:
7/26/2016
Date of previous issue
:
No previous validation
Version
:16/13
Section 8. Exposure controls/personal protection
Respiratory protection
:
Body protection
Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti­static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves.
:
Other skin protection
:
Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
Section 9. Physical and chemical properties
Physical state
Melting point
Vapor pressure
Relative density
Vapor density
Solubility
Liquid.
Not available.
0.93
1.55 [Air = 1]
13.5 kPa (101 mm Hg) [at 20°C]
Not available.
Not available.
Odor
pH
Not available.
Color
Evaporation rate
Not available.
Auto-ignition temperature
Flash point
Not available.
Closed cup: -29°C (-20.2°F) [Pensky-Martens Closed Cup]
Not available. Not available.
Viscosity
Kinematic (room temperature): <0.205 cm2/s (<20.5 cSt)
Not available.
Odor threshold
Partition coefficient: n­octanol/water
:::
:::::
:::
::::Appearance
Boiling point
:
Not available.
Flammability (solid, gas)
:
Not available.
Lower and upper explosive (flammable) limits
:
Lower: 1.8% Upper: 27%
Decomposition temperature
:
Not available.
Type of aerosol
:
Spray
Heat of combustion
:
26.56 kJ/g
Aerosol product
Molecular weight
:
Not applicable.
Section 10. Stability and reactivity
Conditions to avoid
Avoid all possible sources of ignition (spark or flame).
The product is stable.
Chemical stability
No specific data.
:
:
Incompatible materials
:
Possibility of hazardous reactions
:
Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity
:
No specific test data related to reactivity available for this product or its ingredients.
Date of issue/Date of revision
:
7/26/2016
Date of previous issue
:
No previous validation
Version
:17/13
Section 10. Stability and reactivity
Hazardous decomposition products
Under normal conditions of storage and use, hazardous decomposition products should not be produced.
:
Section 11. Toxicological information
Acute toxicity
Diphenylmethane Diisocyanate Polymer
LC50 Inhalation Vapor
Rat
490 mg/m³
4 hours
LD50 Dermal
Rabbit
>9400 mg/kg
-
LD50 Oral
Rat
49 g/kg
-
4, 4'-Diphenylmethane Diisocyanate
LD50 Oral
Rat
9200 mg/kg
-
2-Methylpropane
LC50 Inhalation Vapor
Rat
658000 mg/m³
4 hours
Product/ingredient name
Result
Species
Dose
Exposure
Carcinogenicity
Not available.
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Irritation/Corrosion
Diphenylmethane Diisocyanate Polymer
Eyes - Mild irritant
Rabbit
-
100 milligrams
-
4, 4'-Diphenylmethane Diisocyanate
Eyes - Moderate irritant
Rabbit
-
100 milligrams
-
Product/ingredient name
Result
Score
Exposure
Observation
Sensitization
Not available.
Species
Specific target organ toxicity (single exposure)
Diphenylmethane Diisocyanate Polymer
Category 3
Not applicable.
Respiratory tract irritation
4, 4'-Diphenylmethane Diisocyanate
Category 3
Not applicable.
Respiratory tract irritation
Propane
Category 3
Not applicable.
Respiratory tract irritation and Narcotic effects
2-Methylpropane
Category 3
Not applicable.
Respiratory tract irritation and
Name
Category
Route of exposure
Target organs Information on toxicological effects
Classification
Diphenylmethane Diisocyanate Polymer
-3-
4, 4'-Diphenylmethane Diisocyanate
-3-
Product/ingredient name
NTP
IARC
OSHA
Date of issue/Date of revision
:
7/26/2016
Date of previous issue
:
No previous validation
Version
:18/13
Section 11. Toxicological information
Specific target organ toxicity (repeated exposure)
Narcotic effects
Name
Category
Diphenylmethane Diisocyanate Polymer
Category 2
Not determined
Not determined
4, 4'-Diphenylmethane Diisocyanate
Category 2
Not determined
Not determined
Propane
Category 2
Not determined
Not determined
2-Methylpropane
Category 2
Not determined
Not determined
Aspiration hazard
Name
Result
Propane
ASPIRATION HAZARD - Category 1
2-Methylpropane
ASPIRATION HAZARD - Category 1
Route of exposure
Target organs
Information on the likely routes of exposure
Inhalation
:
Harmful if inhaled. Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. May cause respiratory irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled.
Can cause central nervous system (CNS) depression.
:
Ingestion
Skin contact
:
Causes skin irritation. May cause an allergic skin reaction.
Causes serious eye irritation.
:
Eye contact
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation
Adverse symptoms may include the following: respiratory tract irritation coughing wheezing and breathing difficulties asthma nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness
No specific data.
Adverse symptoms may include the following: irritation redness
:::
Eye contact
:
Adverse symptoms may include the following: pain or irritation watering redness
Delayed and immediate effects and also chronic effects from short and long term exposure
:
Not available.
Potential acute health effects
Potential immediate effects
:
Not available.
Short term exposure
Potential delayed effects
:
Not available.
Potential immediate effects
:
Not available.
Long term exposure
Date of issue/Date of revision
:
7/26/2016
Date of previous issue
:
No previous validation
Version
:19/13
Not available.
May cause damage to organs through prolonged or repeated exposure. Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels.
General
:
Suspected of causing cancer. Risk of cancer depends on duration and level of exposure.
Carcinogenicity
:
No known significant effects or critical hazards.
Mutagenicity
:
No known significant effects or critical hazards.
Teratogenicity
:
Developmental effects
:
No known significant effects or critical hazards.
Fertility effects
:
No known significant effects or critical hazards.
Potential chronic health effects
Numerical measures of toxicity
Inhalation (gases)
12000 ppm
Inhalation (vapors)
29.33 mg/l
Inhalation (dusts and mists)
2.941 mg/l
Route
ATE value
Acute toxicity estimates
Potential delayed effects
:
Not available.
Section 12. Ecological information
LogP
ow
BCF
Potential
Bioaccumulative potential
Other adverse effects
:
No known significant effects or critical hazards.
Product/ingredient name
4, 4'-Diphenylmethane Diisocyanate
-
200
low
Toxicity
Not available.
Persistence and degradability
Soil/water partition coefficient (KOC)
:
Not available.
Mobility in soil
Not available.
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues.
:
Disposal methods
Date of issue/Date of revision
:
7/26/2016
Date of previous issue
:
No previous validation
Version
:110/13
Section 14. Transport information
AEROSOLS
2.1
-
AEROSOLS
2.1
-
UN1950
UN1950
-
Emergency schedules (EmS)
F-D, S-U
DOT
Classification
IMDG
UN number
UN proper shipping name
Transport hazard class(es)
Packing group
Additional information
Environmental hazards
Special precautions for user
Transport in bulk according to Annex II of MARPOL and the IBC Code
No.
No. Not available.
:
Proper shipping name
:
Ship type
:
Not available.
Pollution category
:
Not available.
Not available.
:
TDG
Classification
UN1950
AEROSOLS
2.1
-
No.
Product classified as per the following sections of the Transportation of Dangerous Goods Regulations: 2. 13-2.17 (Class 2).
Mexico
Classification
UN1950
AEROSOLS
2.1
-
No.
-
Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (sea, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. People loading and unloading dangerous goods must be trained on all of the risks deriving from the substances and on all actions in case of emergency situations.
IATA
UN1950
AEROSOLS, flammable
2.1
-
No.
-
126
ERG No.
126
126
ERG No.
ERG No.
Section 15. Regulatory information
SARA 313
SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet.
Date of issue/Date of revision
:
7/26/2016
Date of previous issue
:
No previous validation
Version
:111/13
Not applicable.
California Prop. 65
Section 16. Other information
7/26/2016
History
Date of printing
Date of issue/Date of revision
Version
Notice to reader
Date of previous issue
:
:::
Key to abbreviations
:
ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations
7/26/2016
No previous validation
1
Hazardous Material Information System (U.S.A.)
3
3
1
*
Health
Flammability
Physical hazards
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868.
The customer is responsible for determining the PPE code for this material.
Procedure used to derive the classification
Classification
Justification
FLAMMABLE AEROSOLS - Category 1
On basis of test data
GASES UNDER PRESSURE - Compressed gas
Calculation method
ACUTE TOXICITY (inhalation) - Category 4
Calculation method
SKIN CORROSION/IRRITATION - Category 2
Calculation method
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A
Calculation method
RESPIRATORY SENSITIZATION - Category 1
Calculation method
SKIN SENSITIZATION - Category 1
Calculation method
CARCINOGENICITY - Category 2
Calculation method
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3
Calculation method
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3
Calculation method
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2
Calculation method
Date of issue/Date of revision
:
7/26/2016
Date of previous issue
:
No previous validation
Version
:112/13
Section 16. Other information
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. This information is provided in good faith and believed to be accurate as of the effective date herein. However, no warranty, express or implied, is given. The information presented here applies only to the product as shipped. The addition of any material can change the composition, hazards and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed by Sherwin-Williams, including but not limited to the incorporation of non Sherwin-Williams products or the use or addition of products in proportions not specified by Sherwin-Williams. Regulatory requirements are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the product for any purpose other than the purpose shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from any other source.
Date of issue/Date of revision
:
7/26/2016
Date of previous issue
:
No previous validation
Version
:113/13
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