White Lightning B150003, WL099112W User Manual

WHITE LIGHTNING® Silicone Rubber All Purpose Sealant (RTV Formula) Clear
Not available. Liquid.
(216) 566-2917
SAFETY DATA SHEET
Section 1. Identification
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White Lightning Products 101 W. Prospect Avenue Cleveland, OH 44115
Relevant identified uses of the substance or mixture and uses advised against
Not applicable.
WL09010
WL09010
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(800) 241-5295
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(216) 566-2902
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(800) 424-9300
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White Lightning Products 180 Brunel Road Mississauga, Ontario L4Z 1T5 Canada
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Not applicable.
Section 2. Hazards identification
SKIN CORROSION/IRRITATION - Category 1B SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1 TOXIC TO REPRODUCTION (Fertility) - Category 2 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2
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Signal word
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Danger
Hazard pictograms
:
Precautionary statements
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 5%
General
:
Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand.
Causes severe skin burns and eye damage. Suspected of damaging fertility. May cause damage to organs through prolonged or repeated exposure.
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Hazard statements
Date of issue/Date of revision
:
7/26/2016
Date of previous issue
:
No previous validation
Version
:11/12
Section 2. Hazards identification
Prevention
:
Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves. Wear eye or face protection. Wear protective clothing. Do not breathe vapor. Wash hands thoroughly after handling.
Response
:
Get medical attention if you feel unwell. IF exposed or concerned: Get medical attention. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER or physician. IF SWALLOWED: Immediately call a POISON CENTER or physician. Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. Wash contaminated clothing before reuse. Immediately call a POISON CENTER or physician. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or physician.
Storage
:
Store locked up.
Disposal
Dispose of contents and container in accordance with all local, regional, national and international regulations.
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None known.
Please refer to the SDS for additional information. Keep out of reach of children. Do not transfer contents to other containers for storage.
Supplemental label elements
None known.
:
Section 3. Composition/information on ingredients
Middle Petroleum Distillates
5
64742-46-7
Ethyl Triacetoxysilane
3.6
17689-77-9
Methyl Triacetoxysilane
3.5
4253-34-3
Acetic Acid
2.9
64-19-7
Octamethylcyclotetrasiloxane
0.5
556-67-2
Ingredient name
CAS number
% by weight
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health and hence require reporting in this section.
:
Not available.
CAS number/other identifiers
:
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Get medical attention immediately. Call a poison center or physician. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Chemical burns must be treated promptly by a physician.
Get medical attention immediately. Call a poison center or physician. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Section 4. First aid measures
Eye contact
Inhalation
:
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Description of necessary first aid measures
Date of issue/Date of revision
:
7/26/2016
Date of previous issue
:
No previous validation
Version
:12/12
Section 4. First aid measures
Get medical attention immediately. Call a poison center or physician. Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Chemical burns must be treated promptly by a physician. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Get medical attention immediately. Call a poison center or physician. Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Chemical burns must be treated promptly by a physician. Wash clothing before reuse. Clean shoes thoroughly before reuse.
Skin contact
Ingestion
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Protection of first-aiders
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No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.
Notes to physician
:
Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.
Specific treatments
:
No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation
:
No known significant effects or critical hazards.
No known significant effects or critical hazards.
:
Ingestion
Skin contact
:
Causes severe burns.
Causes serious eye damage.
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Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion Inhalation
Adverse symptoms may include the following: reduced fetal weight increase in fetal deaths skeletal malformations
Adverse symptoms may include the following: stomach pains reduced fetal weight increase in fetal deaths skeletal malformations
Adverse symptoms may include the following: pain or irritation redness blistering may occur reduced fetal weight increase in fetal deaths skeletal malformations
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Eye contact
:
Adverse symptoms may include the following: pain watering redness
Potential acute health effects
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Date of issue/Date of revision
:
7/26/2016
Date of previous issue
:
No previous validation
Version
:13/12
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training.
Hazardous thermal decomposition products
Decomposition products may include the following materials: carbon dioxide carbon monoxide metal oxide/oxides
In a fire or if heated, a pressure increase will occur and the container may burst.
Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Use an extinguishing agent suitable for the surrounding fire.
Extinguishing media
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None known.
Suitable extinguishing media
:
Unsuitable extinguishing media
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Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.
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No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Do not breathe vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).
Large spill
:
Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.
Small spill
:
Methods and materials for containment and cleaning up
For non-emergency personnel
For emergency responders
:
If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non­emergency personnel".
Date of issue/Date of revision
:
7/26/2016
Date of previous issue
:
No previous validation
Version
:14/12
Section 7. Handling and storage
Advice on general occupational hygiene
Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.
Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination.
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Protective measures
Put on appropriate personal protective equipment (see Section 8). Avoid exposure ­obtain special instructions before use. Avoid exposure during pregnancy. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. If during normal use the material presents a respiratory hazard, use only with adequate ventilation or wear appropriate respirator. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container.
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Precautions for safe handling
Middle Petroleum Distillates
NIOSH REL (United States, 10/2013).
TWA: 5 mg/m³ 10 hours. Form: Mist STEL: 10 mg/m³ 15 minutes. Form: Mist
Ethyl Triacetoxysilane
None.
Methyl Triacetoxysilane
None.
Acetic Acid
ACGIH TLV (United States, 3/2015).
TWA: 10 ppm 8 hours. TWA: 25 mg/m³ 8 hours. STEL: 15 ppm 15 minutes. STEL: 37 mg/m³ 15 minutes.
NIOSH REL (United States, 10/2013).
TWA: 10 ppm 10 hours. TWA: 25 mg/m³ 10 hours. STEL: 15 ppm 15 minutes. STEL: 37 mg/m³ 15 minutes.
OSHA PEL (United States, 2/2013).
TWA: 10 ppm 8 hours. TWA: 25 mg/m³ 8 hours.
Octamethylcyclotetrasiloxane
None.
Section 8. Exposure controls/personal protection
Ingredient name
Exposure limits
:
If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits.
Control parameters
Occupational exposure limits (OSHA United States)
None.
Ingredient name
Exposure limits
Occupational exposure limits (Canada)
Date of issue/Date of revision
:
7/26/2016
Date of previous issue
:
No previous validation
Version
:15/12
Section 8. Exposure controls/personal protection
Hand protection
Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use.
Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles and/ or face shield. If inhalation hazards exist, a full-face respirator may be required instead.
Eye/face protection Respiratory protection
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Body protection
Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
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Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
Hygiene measures
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Individual protection measures
Skin protection
Other skin protection
:
Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
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Section 9. Physical and chemical properties
Physical state
Liquid.
Not available.
1.06
2.07 [Air = 1]
0.13 kPa (1 mm Hg) [at 20°C]
Not available.
Not available.
Not available.
Color
0.97 (butyl acetate = 1)
Closed cup: >93.3°C (>199.9°F) [Pensky-Martens Closed Cup]
Not available.
Not available.
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Appearance
:
117°C (242.6°F)
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Not available.
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Lower: 5.4% Upper: 19.3%
Date of issue/Date of revision
:
7/26/2016
Date of previous issue
:
No previous validation
Version
:16/12
Section 9. Physical and chemical properties
Not available.
Not available.
Kinematic (room temperature): >0.07 cm2/s (>7 cSt)
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:
:
Not available.
Heat of combustion
:
5.125 kJ/g
Aerosol product
:
Not applicable.
Section 10. Stability and reactivity
No specific data.
Under normal conditions of storage and use, hazardous decomposition products should not be produced.
The product is stable.
No specific data.
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Incompatible materials
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Under normal conditions of storage and use, hazardous reactions will not occur.
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No specific test data related to reactivity available for this product or its ingredients.
Section 11. Toxicological information
Acute toxicity
Methyl Triacetoxysilane
LD50 Oral
Rat
2060 mg/kg
-
Acetic Acid
LC50 Inhalation Vapor
Rat
11000 mg/m³
4 hours
LD50 Dermal
Rabbit
1060 mg/kg
-
LD50 Oral
Rat
3310 mg/kg
-
Octamethylcyclotetrasiloxane
LC50 Inhalation Vapor
Rat
36 g/m³
4 hours
LD50 Dermal
Rat
1770 mg/kg
-
LD50 Oral
Rat
1540 mg/kg
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Product/ingredient name
Result
Species
Dose
Exposure
Irritation/Corrosion
Acetic Acid
Eyes - Mild irritant
Rabbit
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0.5 minutes 5 milligrams
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Skin - Mild irritant
Human
-
24 hours 50 milligrams
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Skin - Mild irritant
Rabbit
-
24 hours 50 milligrams
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Skin - Severe irritant
Rabbit
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525 milligrams
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Octamethylcyclotetrasiloxane
Eyes - Mild irritant
Rabbit
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24 hours 500 milligrams
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Skin - Mild irritant
Rabbit
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24 hours 500 milligrams
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Product/ingredient name
Result
Score
Exposure
Observation
Sensitization
Species
Information on toxicological effects
Date of issue/Date of revision
:
7/26/2016
Date of previous issue
:
No previous validation
Version
:17/12
Section 11. Toxicological information
Carcinogenicity
Not available.
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Not available.
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
Middle Petroleum Distillates
Category 3
Not applicable.
Respiratory tract irritation and Narcotic effects
Name
Category
Name
Category
Middle Petroleum Distillates
Category 2
Not determined
Not determined
Aspiration hazard
Name
Result
Middle Petroleum Distillates
ASPIRATION HAZARD - Category 1
Route of exposure
Target organs
Route of exposure
Target organs
Inhalation
:
No known significant effects or critical hazards.
No known significant effects or critical hazards.
:
Ingestion
Skin contact
:
Causes severe burns.
Causes serious eye damage.
:
Eye contact
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Inhalation
Adverse symptoms may include the following: reduced fetal weight increase in fetal deaths skeletal malformations
Adverse symptoms may include the following: pain or irritation redness blistering may occur reduced fetal weight increase in fetal deaths skeletal malformations
:
:
Eye contact
:
Adverse symptoms may include the following: pain watering redness
:
Not available.
Potential acute health effects
Date of issue/Date of revision
:
7/26/2016
Date of previous issue
:
No previous validation
Version
:18/12
Not available.
May cause damage to organs through prolonged or repeated exposure.
General
:
No known significant effects or critical hazards.
Carcinogenicity
:
No known significant effects or critical hazards.
Mutagenicity
:
No known significant effects or critical hazards.
Teratogenicity
:
Developmental effects
:
No known significant effects or critical hazards.
Fertility effects
:
Suspected of damaging fertility.
Ingestion
Adverse symptoms may include the following: stomach pains reduced fetal weight increase in fetal deaths skeletal malformations
:
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Numerical measures of toxicity
Oral
6633 mg/kg
Dermal
36551.7 mg/kg
Inhalation (vapors)
379.3 mg/l
Route
ATE value
Acute toxicity estimates
Potential immediate effects
:
Not available.
Short term exposure
Potential delayed effects
:
Not available.
Potential immediate effects
:
Not available.
Long term exposure
Potential delayed effects
:
Not available.
Section 12. Ecological information
Bioaccumulative potential
Toxicity
Acetic Acid
Acute EC50 73400 µg/l Fresh water
Algae - Navicula seminulum
96 hours
Acute EC50 65000 µg/l Fresh water
Daphnia - Daphnia magna ­Neonate
48 hours
Acute LC50 50.1 ul/L Marine water
Crustaceans - Artemia sp.
48 hours
Acute LC50 75000 µg/l Fresh water
Fish - Lepomis macrochirus
96 hours
Octamethylcyclotetrasiloxane
Chronic NOEC 1.7 to 15 µg/l Fresh water
Daphnia - Daphnia magna
21 days
Chronic NOEC 4.4 µg/l Fresh water
Fish - Oncorhynchus mykiss ­Egg
93 days
Species
Result
Exposure
Persistence and degradability
Not available.
Date of issue/Date of revision
:
7/26/2016
Date of previous issue
:
No previous validation
Version
:19/12
Section 12. Ecological information
BCF
Potential
:
No known significant effects or critical hazards.
Product/ingredient name
Acetic Acid
-
3.16
low
Octamethylcyclotetrasiloxane
-
13400
high
Soil/water partition coefficient (KOC)
:
Not available.
Mobility in soil
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.
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Section 14. Transport information
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Not regulated.
Not regulated.
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DOT
Classification
IMDG
UN number
UN proper shipping name
Transport hazard class(es)
Packing group
Additional information
Environmental hazards
No.
No.
:
TDG
Classification
Not regulated.
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No.
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Mexico
Classification
Not regulated.
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No.
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Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (sea, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. People loading and unloading dangerous goods must be trained on all of the risks deriving from the substances and on all actions in case of emergency situations.
IATA
Not regulated.
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No.
-
Date of issue/Date of revision
:
7/26/2016
Date of previous issue
:
No previous validation
Version
:110/12
Section 14. Transport information
Not available.
:
Proper shipping name
:
Ship type
:
Not available.
Pollution category
:
Not available.
Not available.
Section 15. Regulatory information
SARA 313
SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet.
Not applicable.
California Prop. 65
Section 16. Other information
7/26/2016
History
Date of printing
Date of issue/Date of revision
Version
Notice to reader
Date of previous issue
:
:
:
:
Key to abbreviations
:
ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations
7/26/2016
No previous validation
1
Hazardous Material Information System (U.S.A.)
3
0
0
Health
Flammability
Physical hazards
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868.
The customer is responsible for determining the PPE code for this material.
Procedure used to derive the classification
Classification
Justification
SKIN CORROSION/IRRITATION - Category 1B
Calculation method
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1
Calculation method
TOXIC TO REPRODUCTION (Fertility) - Category 2
Calculation method
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2
Calculation method
Date of issue/Date of revision
:
7/26/2016
Date of previous issue
:
No previous validation
Version
:111/12
Section 16. Other information
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. This information is provided in good faith and believed to be accurate as of the effective date herein. However, no warranty, express or implied, is given. The information presented here applies only to the product as shipped. The addition of any material can change the composition, hazards and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed by Sherwin-Williams, including but not limited to the incorporation of non Sherwin-Williams products or the use or addition of products in proportions not specified by Sherwin-Williams. Regulatory requirements are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the product for any purpose other than the purpose shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from any other source.
Date of issue/Date of revision
:
7/26/2016
Date of previous issue
:
No previous validation
Version
:112/12
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