AllPurpose-RTV/WL
Material Safety Data Sheet
Document Code: AllPurpose-RTV/WL
Version: 11 August 11, 2011
Section 1 - Product and Company Identification
PRODUCT NAME, NUMBERS, & COLORS HMIS CODES
All Purpose RTV Silicone Sealant Health 2
Flammability 0
WL099110C WL099111C Clear Reactivity 0
WL099111B Black
WL099112W White
MANUFACTURER'S NAME
THE SHERWIN-WILLIAMS CO.
Consumer Group - Industrial
Cleveland, OH 44115
TELEPHONE NUMBERS and WEBSITES
Regulatory Information
(216) 566-2902 www.paintdocs.com
Medical Emergency
(216) 566-2917
Transportation Emergency for Chemical Emergency ONLY (spill, leak, exposure,
(800) 424-9300 fire, or accident)
Date of Preparation
Section 2 – Composition/Information on Ingredients
% WT. CAS No. Ingredient Name
--------------------------------------------------------------------------- 1-5 17689-77-9 Ethyl Triacetoxysilane
ACGIH TLV Not Established
OSHA PEL Not Established
1-5 4253-34-3 Methyl Triacetoxysilane
ACGIH TLV Not Established
OSHA PEL Not Established
5-10 7631-86-9 Amorphous Silica.
ACGIH TLV TWA 10 mg/m3 as Dust
OSHA PEL TWA 6 mg/m3 as Dust
<5 13463-67-7 Titanium Dioxide [in White only]
ACGIH TLV TWA 10 mg/m3 as Dust
OSHA PEL TWA 10 mg/m3 as Total Dust
OSHA PEL TWA 5 mg/m3 as Respirable Fraction
<2 1333-86-4 Carbon Black [in Black only]
ACGIH TLV TWA 3.5 mg/m3
OSHA PEL TWA 3.5 mg/m3
NOTE: These products may evolve trace quantities of Acetic Acid during curing.
Exposure limits for Acetic Acid are:
max. 5 64-19-7 Acetic Acid
ACGIH TLV TWA 10 ppm
ACGIH TLV STEL 15 ppm
OSHA PEL TWA 10 ppm
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AllPurpose-RTV /WL
Section 3 – Hazards Identification
ROUTES OF EXPOSURE
INHALATION of vapor or spray mist.
EYE or SKIN contact with the product, vapor or spray mist.
EFFECTS OF OVEREXPOSURE
EYES: Irritation.
SKIN: Prolonged or repeated exposure may cause irritation.
INHALATION: Irritation of the upper respiratory system.
In a confined area vapors in high concentration may cause headache,
nausea or dizziness.
EFFECTS OF OVEREXPOSURE
Irritation of eyes, skin and upper respiratory system. In a confined area
vapors in high concentration may cause headache, nausea or dizziness.
SIGNS AND SYMPTOMS OF OVEREXPOSURE
Redness and itching or burning sensation may indicate eye or excessive skin
exposure.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
None known.
CANCER INFORMATION
FOR COMPLETE DISCUSSION OF TOXICOLOGY DATA REFER TO SECTION 11.
Section 4 – First Aid Measures
EYES: Flush eyes with large amounts of water for 15 minutes.
Get medical attention.
SKIN: Wash affected area thoroughly with soap and water.
Remove contaminated clothing and launder before re-use.
INHALATION: If affected, remove from exposure. Restore breathing.
Keep warm and quiet.
INGESTION: Do not induce vomiting.
Get medical attention immediately.
Section 5 – Fire Fighting Measures
FLASH POINT LEL UEL
>200 °F N.Ap. N.Ap.
FLAMMABILITY CLASSIFICATION
Not Applicable
EXTINGUISHING MEDIA
Carbon Dioxide, Dry Chemical
UNUSUAL FIRE AND EXPLOSION HAZARDS
None known.
SPECIAL FIRE FIGHTING PROCEDURES
Full protective equipment including self-contained breathing apparatus should
be used. Water spray may be ineffective. If water is used, fog nozzles are
preferable. Water may be used to cool closed containers to prevent pressure
build-up and possible autoignition or explosion when exposed to extreme heat.
Section 6 – Accidental Release Measures
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Remove all sources of ignition. Ventilate and remove with inert absorbent.
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AllPurpose-RTV /WL
Section 7 – Handling and Storage
DOL STORAGE CATEGORY
Not Applicable
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
Keep container closed when not in use. Store product away from water or
moisture. Do not transfer to other containers. Do not take internally.
Keep out of the reach of children.
Section 8 – Exposure Controls/Personal Protection
PRECAUTIONS TO BE TAKEN IN USE
Use only with adequate ventilation. Avoid breathing vapor and spray mist.
Avoid contact with skin and eyes. Wash hands after using.
These products may contain materials classified as nuisance particulates
(listed "as Dust" in Section 2) which may be present at hazardous levels only
during sanding or abrading of the dried film. If no specific dusts are listed
in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3
(total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust),
5 mg/m3 (respirable fraction).
VENTILATION
Local exhaust preferable. General exhaust acceptable if the exposure to
materials in Section 2 is maintained below applicable exposure limits. Refer to
OSHA Standards 1910.94, 1910.107, 1910.108.
RESPIRATORY PROTECTION
If personal exposure cannot be controlled below applicable limits by
ventilation, wear a properly fitted organic vapor/particulate respirator approved
by NIOSH/MSHA for protection against materials in Section 2.
When sanding or abrading the dried film, wear a dust/mist respirator approved
by NIOSH/MSHA for dust which may be generated from this product, underlying paint,
or the abrasive.
PROTECTIVE GLOVES
Wear gloves which are recommended by glove supplier for protection against
materials in Section 2.
EYE PROTECTION
Wear safety spectacles with unperforated sideshields.
Section 9 – Physical and Chemical Properties
PRODUCT WEIGHT 8 lbs/gal EVAPORATION RATE Slower than Ether
SPECIFIC GRAVITY 0.96 VAPOR DENSITY Heavier than Air
BOILING POINT N.Ap. MELTING POINT N.Av.
VISCOSITY 350,000 cps SOLUBILITY IN WATER N.Av.
VOLATILE ORGANICS COMPOUNDS (VOC) 3.0 % by weight
Section 10 – Stability and Reactivity
STABILITY Stable
CONDITIONS TO AVOID -- None known.
INCOMPATIBILITY -- None known.
HAZARDOUS DECOMPOSITION PRODUCTS -- By fire: Carbon Dioxide, Carbon Monoxide,
Oxides of Nitrogen, Possibility of Hydrogen Chloride
HAZARDOUS POLYMERIZATION -- Will not occur
Section 11 – Toxicological Information
CHRONIC HEALTH HAZARDS
Carbon Black is classified by IARC as possibly carcinogenic to humans
(group 2B) based on experimental animal data, however, there is insufficient
evidence in humans for its carcinogenicity.
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IARC's Monograph No. 93 reports there is sufficient evidence of
carcinogenicity in experimental rats exposed to titanium dioxide but
inadequate evidence for carcinogenicity in humans and has assigned a Group
2B rating. In addition, the IARC summary concludes, "No significant
exposure to titanium dioxide is thought to occur during the use of products
in which titanium is bound to other materials, such as paint."
TOXICOLOGY DATA
CAS No. Ingredient Name
----------------------------------------------------------------------------
17689-77-9 Ethyl Triacetoxysilane
LC50 RAT 4HR Not Available
LD50 RAT Not Available
4253-34-3 Methyl Triacetoxysilane
LC50 RAT 4HR Not Available
LD50 RAT Not Available
7631-86-9 Amorphous Silica.
LC50 RAT 4HR Not Available
LD50 RAT Not Available
13463-67-7 Titanium Dioxide.
LC50 RAT 4HR Not Available
LD50 RAT >7500 mg/kg
1333-86-4 Carbon Black
LC50 RAT 4HR Not Available
LD50 RAT >15400 mg/kg
64-19-7 Acetic Acid
LC50 RAT 4HR Not Available
LD50 RAT 3310 mg/kg
AllPurpose-RTV /WL
Section 12 – Ecological Information
ECOTOXICOLOGICAL INFORMATION
No Data Available.
Section 13 – Disposal Considerations
WASTE DISPOSAL METHOD
Waste from these products is not hazardous as defined under the Resource
Conservation and Recovery Act (RCRA) 40 CFR 261.
Incinerate in approved facility. Do not incinerate closed container. Dispose
of in accordance with Federal, State, and Local regulations regarding pollution.
Section 14 – Transport Information
Multi-modal shipping descriptions are provided for informational purposes and
do not consider container sizes. The presence of a shipping description for a
particular mode of transport (ocean, air, etc.), does not indicate that the
product is packaged suitably for that mode of transport. All packaging must be
reviewed for suitability prior to shipment, and compliance with the applicable
regulations is the sole responsibility of the person offering the product for
transport.
US Ground (DOT)
Not Regulated for Transportation.
Canada (TDG)
Not Regulated for Transportation.
IMO
Not Regulated for Transportation.
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RTV-Silicone/WL
Section 15 – Regulatory Information
SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION
No ingredients in these products are subject to SARA 313 (40 CFR 372.65C)
Supplier Notification.
TSCA CERTIFICATION
All chemicals in these products are listed, or are exempt from listing, on the
TSCA Inventory.
Section 16 – Other Information
NOTE: These products have been classified in accordance with the hazard
criteria of the CPR and the MSDS contains all of the information required by the
CPR.
The above information pertains to these products as currently formulated, and
is based on the information available at this time. Addition of reducers or other
additives to these products may substantially alter the composition and hazards of
the products. Since conditions of use are outside our control, we make no
warranties, express or implied, and assume no liability in connection with any use
of this information.
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