SAFETY DATA SHEET
Revision Date 21-Oct-2016 Version 4
1. IDENTIFICATION
Product identifier
Product Name
Other means of identification
Product Code
Synonyms
Recommended use of the chemical and restrictions on use
Recommended Use
Uses advised against
Details of the supplier of the safety data sheet
Manufactured and Distributed by:
ITW Permatex
6875 Parkland Blvd.
Solon, OH 44139 USA
127MA DISC BRAKE QUIET 9OZ AE
80077
None
Adhesive
No information available
May Also Be Distributed by:
ITW Permatex Canada
35 Brownridge Road, Unit 1
Halton Hills, ON Canada L7G 0C6
Telephone: (800) 924-6994
Company Phone Number
24 Hour Emergency Phone Number
E-mail address
1-87-Permatex
(877) 376-2839
Chem-Tel: 800-255-3924
International Emergency:
00+1+ 813-248-0585
Contract Number: MIS0003453
mail@permatex.com
2. HAZARDS IDENTIFICATION
Classification
OSHA Regulatory Status
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Skin corrosion/irritation Category 2
Serious eye damage/eye irritation Category 2
Reproductive toxicity Category 2
Specific target organ toxicity (single exposure) Category 3
Specific target organ toxicity (repeated exposure) Category 2
Aspiration toxicity Category 1
Flammable aerosols
Gases under pressure
Label elements
Category 1
Liquefied gas
Emergency Overview
Danger
Causes skin irritation
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Causes serious eye irritation
Suspected of damaging fertility or the unborn child
May cause drowsiness or dizziness
May cause damage to organs through prolonged or repeated exposure
May be fatal if swallowed and enters airways
Extremely flammable aerosol
Contains gas under pressure; may explode if heated
Appearance Blue Physical state Liquid
Precautionary Statements - Prevention
Obtain special instructions before use
Do not handle until all safety precautions have been read and understood
Use personal protective equipment as required
Wash face, hands and any exposed skin thoroughly after handling
Wear eye/face protection
Do not breathe dust/fume/gas/mist/vapors/spray
Use only outdoors or in a well-ventilated area
Keep away from heat/sparks/open flames/hot surfaces. - No smoking
Do not spray on an open flame or other ignition source
Pressurized container: Do not pierce or burn, even after use
Precautionary Statements - Response
IF exposed or concerned: Get medical advice/attention
Specific treatment (see supplemental first aid instructions on this label)
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
If eye irritation persists: Get medical advice/attention
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
If skin irritation occurs: Get medical advice/attention
Take off contaminated clothing and wash before reuse
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician
Do NOT induce vomiting
In case of fire: Use CO2, dry chemical, or foam for extinction
Precautionary Statements - Storage
Store locked up
Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F
Odor Solvent
Precautionary Statements - Disposal
Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC)
Not applicable
Other Information
- The classification as a carcinogen or mutagen need not apply if it can be shown that the substance contains less than 0.1 % w/w
1,3-butadiene (EINECS No. 203-450-8). If the substance is not classified as a carcinogen or mutagen, at least the S-phrases
(2-)9-16 (Table 3.2) should apply. This note applies only to certain complex oil-derived substances in Part 3
- The classification as a carcinogen or mutagen need not apply if it can be shown that the substance contains less than 0,1 % w/w
benzene (EINECS No 200-753-7).
Unknown acute toxicity 15 % of the mixture consists of ingredient(s) of unknown toxicity
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3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance(s)
Chemical Name CAS No Weight-% Trade Secret
ACETONE 67-64-1 15 - 40 *
PETROLEUM GASES, LIQUEFIED, SWEETENED 68476-86-8 10 - 30 *
N-HEXANE 110-54-3 10 - 30 *
SOLVENT NAPHTHA (PETROLEUM), LIGHT
ALIPH.
ETHYL ACETATE 141-78-6 3 - 7 *
64742-89-8 3 - 7 *
4. FIRST AID MEASURES
Description of first aid measures
General advice
Eye contact
Skin contact
Inhalation
Ingestion
Self-protection of the first aider
Most important symptoms and effects, both acute and delayed
Symptoms
Indication of any immediate medical attention and special treatment needed
Note to physicians
Get medical advice/attention if you feel unwell.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. If eye irritation persists: Get medical
advice/attention.
IF ON SKIN:. Wash skin with soap and water. If skin irritation persists, call a physician.
Wash contaminated clothing before reuse.
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
breathing. If symptoms persist, call a physician.
IF SWALLOWED:. Call a physician or poison control center immediately. Do NOT induce
vomiting.
Use personal protective equipment as required. Avoid contact with skin, eyes or clothing.
See section 2 for more information.
Treat symptomatically.
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media
Carbon dioxide (CO2), Dry chemical, Foam
Unsuitable extinguishing media
None.
Specific hazards arising from the chemical
Extremely flammable. Contains gas under pressure; may explode if heated.
Explosion data
Sensitivity to Mechanical Impact
Sensitivity to Static Discharge
Protective equipment and precautions for firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear.
None.
None.
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6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal precautions
Ensure adequate ventilation, especially in confined areas. Avoid contact with skin, eyes or
clothing. Use personal protective equipment as required. Wash thoroughly after handling.
Remove all sources of ignition. Contents under pressure. Do not puncture or incinerate
cans.
Environmental precautions
Environmental precautions
Do not flush into surface water or sanitary sewer system. See Section 12 for additional
ecological Information.
Methods and material for containment and cleaning up
Methods for containment
Methods for cleaning up
Prevent further leakage or spillage if safe to do so.
Eliminate all ignition sources if safe to do so. Ensure adequate ventilation. Soak up with
inert absorbent material. Sweep up and shovel into suitable containers for disposal.
Prevention of secondary hazards
Clean contaminated objects and areas thoroughly observing environmental regulations.
7. HANDLING AND STORAGE
Precautions for safe handling
Advice on safe handling
Conditions for safe storage, including any incompatibilities
Avoid contact with skin, eyes or clothing. Avoid breathing vapors or mists. Ensure adequate
ventilation, especially in confined areas. Do not puncture or incinerate cans. Use personal
protective equipment as required.
Storage Conditions
Incompatible materials
Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F.
Strong oxidizing agents, Alkalis, Chlorinated compounds, Acids
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Exposure Guidelines
Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH
ACETONE
67-64-1
N-HEXANE
110-54-3
ETHYL ACETATE
141-78-6
NIOSH IDLH Immediately Dangerous to Life or Health
.
STEL: 500 ppm
TWA: 250 ppm
TWA: 50 ppm
S*
TWA: 400 ppm TWA: 400 ppm
TWA: 1000 ppm
TWA: 2400 mg/m
(vacated) TWA: 750 ppm
(vacated) TWA: 1800 mg/m
(vacated) STEL: 2400 mg/m3 The
acetone STEL does not apply to the
cellulose acetate fiber industry. It is
in effect for all other sectors
(vacated) STEL: 1000 ppm
TWA: 500 ppm
TWA: 1800 mg/m
(vacated) TWA: 50 ppm
(vacated) TWA: 180 mg/m
TWA: 1400 mg/m
(vacated) TWA: 400 ppm
(vacated) TWA: 1400 mg/m
3
3
3
3
3
3
IDLH: 2500 ppm
TWA: 250 ppm
TWA: 590 mg/m
IDLH: 1100 ppm
TWA: 50 ppm
TWA: 180 mg/m
IDLH: 2000 ppm
TWA: 400 ppm
TWA: 1400 mg/m
3
3
3
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Other Information
Appropriate engineering controls
Engineering Controls
Individual protection measures, such as personal protective equipment
Eye/face protection
Skin and body protection
Respiratory protection
General Hygiene Considerations
Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962
(11th Cir., 1992).
Showers
Eyewash stations
Ventilation systems
Wear safety glasses with side shields (or goggles).
Wear protective natural rubber, nitrile rubber, Neoprene™ or PVC gloves.
Use NIOSH-approved air-purifying respirator with organic vapor cartridge or canister, as
appropriate.
Handle in accordance with good industrial hygiene and safety practice. Regular cleaning of
equipment, work area and clothing is recommended.
9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Physical state
Appearance
Odor
Odor threshold
Liquid
Blue
Solvent
No information available
Property Values Remarks • Method
pH
Melting point / freezing point
Boiling point / boiling range
Flash point
Evaporation rate
Flammability (solid, gas)
Flammability Limit in Air
Upper flammability limit:
Lower flammability limit:
Vapor pressure
Vapor density
Relative density
Water solubility
Solubility in other solvents
Partition coefficient
Autoignition temperature
Decomposition temperature
Kinematic viscosity
Dynamic viscosity
Explosive properties
Oxidizing properties
Other Information
Softening point
Molecular weight
VOC Content (%)
Density
Bulk density
No information available
No information available
> 38 °C / >100 °F
No information available Gives a flame projection at full valve opening or
flashback at any degree of valve opening
> 1 Butyl acetate = 1
No information available
No information available
No information available
No information available
>1 Air = 1
0.795-0.805
Insoluble in water
No information available
No information available
No information available
No information available
No information available
No information available
No information available
No information available
No information available
No information available
61.65%
No information available
No information available
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10. STABILITY AND REACTIVITY
Reactivity
No data available
Chemical stability
Stable under recommended storage conditions
Possibility of Hazardous Reactions
None under normal processing.
Conditions to avoid
Heat, flames and sparks.
Incompatible materials
Strong oxidizing agents, Alkalis, Chlorinated compounds, Acids
Hazardous Decomposition Products
Carbon oxides
11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Inhalation
Eye contact
Skin contact
Ingestion
Harmful by inhalation. May cause drowsiness or dizziness.
Contact with eyes may cause irritation. May cause redness and tearing of the eyes.
May cause skin irritation and/or dermatitis.
Harmful if swallowed. Potential for aspiration if swallowed. Aspiration may cause pulmonary
edema and pneumonitis.
Chemical Name Oral LD50 Dermal LD50 Inhalation LC50
ACETONE
67-64-1
N-HEXANE
110-54-3
SOLVENT NAPHTHA
(PETROLEUM), LIGHT ALIPH.
64742-89-8
ETHYL ACETATE
141-78-6
= 5800 mg/kg ( Rat ) - = 50100 mg/m3 ( Rat ) 8 h
= 25 g/kg ( Rat ) = 3000 mg/kg ( Rabbit ) = 48000 ppm ( Rat ) 4 h
- = 3000 mg/kg ( Rabbit ) -
= 5620 mg/kg ( Rat ) > 18000 mg/kg ( Rabbit ) > 20
mL/kg ( Rabbit )
-
Information on toxicological effects
Symptoms
No information available.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Sensitization
Germ cell mutagenicity
Carcinogenicity
Target Organ Effects
No information available.
No information available.
No information available.
Central nervous system, Eyes, Peripheral Nervous System (PNS), Respiratory system,
Skin.
The following values are calculated based on chapter 3.1 of the GHS document .
ATEmix (oral)
ATEmix (dermal)
ATEmix (inhalation-gas)
ATEmix (inhalation-dust/mist)
ATEmix (inhalation-vapor)
12387 mg/kg
9871 mg/kg
962077 mg/l
283.9 mg/l
204000 mg/l
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12. ECOLOGICAL INFORMATION
Ecotoxicity
40 % of the mixture consists of components(s) of unknown hazards to the aquatic environment
Persistence and degradability
No information available.
Bioaccumulation
No information available.
Mobility
No information available.
Chemical Name Partition coefficient
ACETONE
67-64-1
PETROLEUM GASES, LIQUEFIED, SWEETENED
68476-86-8
ETHYL ACETATE
141-78-6
Other adverse effects
No information available
-0.24
<=2.8
0.6
13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Disposal of wastes
Disposal should be in accordance with applicable regional, national and local laws and
regulations.
Contaminated packaging
US EPA Waste Number
Do not reuse container.
D001
This product contains one or more substances that are listed with the State of California as a hazardous waste.
Chemical Name California Hazardous Waste Status
ACETONE
67-64-1
N-HEXANE
110-54-3
ETHYL ACETATE
141-78-6
Ignitable
Toxic
Ignitable
Toxic
Ignitable
14. TRANSPORT INFORMATION
DOT
UN/ID no
Proper shipping name:
Hazard Class
Emergency Response Guide
Number
1950
Aerosols, Limited Quantity (LQ)
2.1
126
IATA
UN/ID no
Proper shipping name:
ID 8000
Consumer commodity
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Hazard Class
ERG Code
9
9L
IMDG
UN/ID no
Proper shipping name:
Hazard Class
EmS-No
1950
Aerosols, Limited Quantity (LQ)
2.1
F-D, S-U
15. REGULATORY INFORMATION
International Inventories
TSCA
DSL/NDSL
EINECS/ELINCS
ENCS
IECSC
KECL
PICCS
AICS
Legend:
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS - Japan Existing and New Chemical Substances
IECSC - China Inventory of Existing Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances
AICS - Australian Inventory of Chemical Substances
Complies
Complies
Complies
Not determined
Complies
Complies
Complies
Complies
US Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical
or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372
Chemical Name SARA 313 - Threshold Values %
N-HEXANE - 110-54-3 1.0
SARA 311/312 Hazard Categories
Acute health hazard
Chronic Health Hazard
Fire hazard
Sudden release of pressure hazard
Reactive Hazard
Yes
Yes
Yes
No
No
CWA (Clean Water Act)
This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40
CFR 122.42)
CERCLA
This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302)
Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ)
ACETONE
67-64-1
N-HEXANE
110-54-3
ETHYL ACETATE
141-78-6
5000 lb - RQ 5000 lb final RQ
RQ 2270 kg final RQ
5000 lb - RQ 5000 lb final RQ
RQ 2270 kg final RQ
5000 lb - RQ 5000 lb final RQ
RQ 2270 kg final RQ
US State Regulations
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California Proposition 65
This product does not contain any Proposition 65 chemicals
U.S. State Right-to-Know Regulations
Chemical Name New Jersey Massachusetts Pennsylvania
ACETONE
67-64-1
N-HEXANE
110-54-3
ETHYL ACETATE
141-78-6
X X X
X X X
X X X
U.S. EPA Label Information
EPA Pesticide Registration Number
Not applicable
WHMIS Hazard Class
A Compressed gases, B5 - Flammable aerosol, D2B - Toxic materials
16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OF THE LAST REVISION
NFPA Health hazards 2 Flammability 4 Instability 0
-
HMIS Health hazards 2 Flammability 4 Physical hazards 0 Personal protection B
NFPA (National Fire Protection Association)
HMIS (Hazardous Material Information System)
Revision Date
21-Oct-2016
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the
date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.
End of Safety Data Sheet
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