ITW Permatex
Versachem Brand
10 Columbus Blvd.
Hartford, CT 06106 USA
Telephone: 1-87-Permatex
(877) 376-2839
Emergency: 800-255-3924 (ChemTel)
International Emergency: +01-813-248-0585
Material Safety Data Sheet
1.PRODUCT IDENTIFICATION
Product Name: VERSACHEM H2 HOLD ALL PURPOSE FLEXIBLE EPOXY (HARDENER)
Product Type: Epoxy hardener
This product appears in the following stock number(s):
22429
2. COMPOSITION/INFORMATION ON INGREDIENTS
Component Weight% ACGIH; TLV-TWA OSHA PEL
AMINOETHYLPIPERAZINE
140-31-8
TETA, REACTION PRODUCTS
WITH PROPYLENE OXIDE
26950-63-0
DIONYLPHENOL
84962-08-3
TRIETHANOLAMINE
102-71-6
PIPERAZINE
110-85-0
TRIETHYLENETETRAMINE
112-24-3
5-15 Not listed Not listed
5-15 Not listed Not listed
5-15 Not listed Not listed
<5 5 mg/m
3
Not listed
<5 Not listed Not listed
<5 Not listed Not listed
3. HAZARDS IDENTIFICATION
Toxicity:
Primary Routes of Entry:
Signs and Symptoms of Exposure:
Component Weight% NTP ACGIH Carcinogens IARC Carcinogen
TRIETHANOLAMINE
102-71-6
Aggravated Medical Condition:
Corrosive. Product can be absorbed through the skin and may cause nausea, headache and general
discomfort. May cause skin sensitization.
Eye and skin contact, ingestion, inhalation. Absorption through skin.
Contact causes severe skin irritation and possible burns. Repeated skin contact may cause allergic skin
reactions. Eye irritation may be severe and result in injury. Inhalation of mist or vapor can cause damage to
the upper respiratory tract and to the tissue depending on severity of exposure. Effects can range from
mild irritation of mucous membranes to severe pneumonitis and destruction of lung tissue. Ingestion can
cause very serious damage to the mucous membranes or other tissues with which contact is made.
<5 male rat-equivocal
evidence; female rat-
no evidence; male
mice-inadequate;
female mice-
inadequate
Preexisting eye, skin and respiratory disorders may be aggravated by overexposure to this product.
Group 3; Monograph 77, 2000
4. FIRST AID MEASURES
Ingestion:
Inhalation:
Skin Contact:
Eye Contact:
Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek medical attention. Never
give anything by mouth to an unconscious person
Move to fresh air in case of accidental inhalation of vapours. Oxygen or artificial respiration if needed.
Seek immediate medical attention.
Take off all contaminated clothing immediately. Rinse immediately with plenty of water for at least 15
minutes. Obtain medical attention.
Flush eyes with clean water for at least 20 minutes while gently holding eyelids open, lifting upper and
lower lids.
5. FIRE FIGHTING MEASURES
Flash Point °F(C°):
>190°F (>88°C)
5. FIRE FIGHTING MEASURES
Recommended Extinguishing Media:
Special Fire-Fighting Procedures:
Hazardous Products of Combustion:
Unusual Fire/Explosion Hazards:
Carbon dioxide, Dry chemical, Foam
Firefighters shoud wear self-contained breathing apparatus and protective clothing to prevent all skin and
eye contact
Oxides of carbon, Oxides of nitrogen, Amines, Ammonia
Irritating or toxic gases or fumes may be generated by thermal decomposition or combustion.
Lower Explosive Limit:
Upper Explosive Limit:
n/d
n/d
6. ACCIDENTAL RELEASE MEASURES
Spill Procedures:
Maintain good ventilation. Take up with an inert absorbent. Store in a closed waste container until disposal.
Wear appropriate protective and respiratory equipment.
7. HANDLING AND STORAGE
Storage:
Handling:
Store in a cool, dry area. Keep away from acids and oxidizers.
Avoid contact with skin and eyes. Do not inhale vapors. Wash hands before eating and smoking. Discard
contaminated leather gloves and shoes.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Eyes:
Skin:
Ventilation:
Respiratory Protection:
Safety glasses
Neoprene or nitrile gloves recommended
General; local exhaust ventilation as necessary to control any air contaminants to within their exposure
limits (or to the lowest feasible levels when limits have not been established) during the use of this product
An approved organic vapor respirator should be worn when exposures are expected to exceed the
applicable limits
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance:
Odor:
Boiling Point:
pH:
Solubility in Water:
Specific Gravity:
VOC(Wt.%):
Vapor Pressure:
Vapor Density (Air=1):
Evaporation Rate:
Amber liquid
Ammonia
~212ºF/~100ºC
Alkaline
Slight
n/d
0
~18 mm Hg
>1
<1 (butyl acetate = 1)
10. STABILITY AND REACTIVITY
Chemical Stability:
Hazardous Polymerization:
Incompatabilities:
Conditions to Avoid:
Hazardous Products of Combustion:
Stable at normal conditions
Will not occur
Strong oxidizers, Acids, Chlorinated organic compounds, Reactive metals (e.g. Na, Ca, zinc), Materials
reactive with hydroxyl compounds, Sodium/calcium hypochlorite, Peroxides
Excessive heat.
Oxides of carbon, Oxides of nitrogen, Amines, Ammonia
11. TOXICOLOGICAL INFORMATION
See Section 3
12. ECOLOGICAL INFORMATION
No data available
13. DISPOSAL CONSIDERATIONS
Recommended Method of Disposal:
US EPA Waste Number:
Disposal should be made in accordance with federal, state and local regulations
NH - Not a RCRA Hazardous Waste Material
14. TRANSPORTATION INFORMATION
DOT (49CFR 172)
U.S. Department of Transportation - DOT - 49 CFR (Ground)
DOT Shipping Name:
Not regulated
14. TRANSPORTATION INFORMATION
Hazard Class:
UN/ID Number:
IATA (Air)
Proper Shipping Name:
Class or Division:
UN/ID Number:
IMDG (Vessel)
Proper Shipping Name:
Hazard Class:
UN Number:
None
None
Not regulated
None
None
Not regulated
None
None
15. REGULATORY INFORMATION
SARA 313 Chemicals: The following component(s) is listed as a SARA Section 313 Toxic Chemical.
None
California Proposition 65:
TSCA Inventory Status:
No California Prop 65 chemicals are known to be present at or above the No Significant Risk Level.
All components of this product are listed (or exempt) on the EPA TSCA inventory.
16. OTHER INFORMATION
Estimated NFPA Rating:
Estimated HMIS Classification:
(NFPA is a registered trademark of the National Fire Protection Association)
(HMIS is a registered trademark of the National Paint and Coatings Association)
Prepared By:
Company:
Telephone No.:
ITW Permatex 10 Columbus Blvd. Hartford, CT USA 06106
1-87-Permatex (877) 376-2839
HEALTH 2, FLAMMABILITY 2 , REACTIVITY 1
HEALTH 2, FLAMMABILITY 2, PHYSICAL HAZARD 0
Revision Date:
September 18, 2012Denise Boyd, Manager-Environmental, Health & Safety
Revision Number:
1
ITW Permatex
Versachem Brand
10 Columbus Blvd.
Hartford, CT 06106 USA
Telephone: 1-87-Permatex
(877) 376-2839
Emergency: 800-255-3924 (ChemTel)
International Emergency: +01-813-248-0585
Material Safety Data Sheet
1.PRODUCT IDENTIFICATION
Product Name: VERSACHEM H2 HOLD ALL PURPOSE FLEXIBLE EPOXY (RESIN)
Product Type: Epoxy resin
This product appears in the following stock number(s):
22429
2. COMPOSITION/INFORMATION ON INGREDIENTS
Component Weight% ACGIH; TLV-TWA OSHA PEL
BISPHENOL A/EPICHLOROHYDRIN
BASED EPOXY RESIN
25068-38-6
DIONYLPHENOL
84962-08-3
BUTYLATED BISPHENOL A EPOXY
RESIN
71033-08-4
CRYSTALLINE SILICA
14808-60-7
40-70 Not listed Not listed
10-20 Not listed Not listed
5-15 Not listed Not listed
0.1-1.0 0.025 mg/m
3
Not listed
3. HAZARDS IDENTIFICATION
Toxicity:
Primary Routes of Entry:
Signs and Symptoms of Exposure:
Component Weight% NTP ACGIH Carcinogens IARC Carcinogen
CRYSTALLINE SILICA
14808-60-7
Aggravated Medical Condition:
May cause eye and skin irritation. May cause skin sensitization.
Eye and skin contact, ingestion, inhalation
May cause pain, redness or swelling of the eyes and excessive blinking and tear production. Skin redness.
Repeated skin contact may cause allergic skin reactions. Ingestion may cause nausea and vomiting.
0.1-1.0 A2 - Suspected
Human Carcinogen
May aggrevate preexisting dermatitis.
Group 1 Monograph 68, 1997
(inhalation of quartz)
4. FIRST AID MEASURES
Ingestion:
Inhalation:
Skin Contact:
Eye Contact:
Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek medical attention. Never
give anything by mouth to an unconscious person
Move to fresh air in case of accidental inhalation of vapours. If symptoms persist, call a physician.
Remove contaminated clothing and launder before reuse. Wash with soap and water. If skin irritation
persists, call a physician.
In case of contact, immediately flush eyes with plenty of water for at least 15 minutes and get medical
attention if irritation persists
5. FIRE FIGHTING MEASURES
Flash Point °F(C°):
Recommended Extinguishing Media:
Special Fire-Fighting Procedures:
Hazardous Products of Combustion:
Unusual Fire/Explosion Hazards:
>300°F (>149°C)
Carbon dioxide, Dry chemical, Foam
Firefighters shoud wear self-contained breathing apparatus and protective clothing to prevent all skin and
eye contact
Oxides of carbon, Chlorine
Heating above 149°C (300°F) in the presence of air may cause slow oxidation decomposition and above
260°C (500°F) may cause polymerization.
Lower Explosive Limit:
Upper Explosive Limit:
n/d
n/d
6. ACCIDENTAL RELEASE MEASURES
Spill Procedures:
Maintain good ventilation. Take up with an inert absorbent. Store in a closed waste container until disposal
7. HANDLING AND STORAGE
Storage:
Handling:
Store in a cool, dry area.
Avoid contact with skin and eyes. Wash hands before eating and smoking. Discard contaminated leather
gloves and shoes.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Eyes:
Skin:
Ventilation:
Respiratory Protection:
Safety glasses
Neoprene or nitrile gloves recommended
General; local exhaust ventilation as necessary to control any air contaminants to within their exposure
limits (or to the lowest feasible levels when limits have not been established) during the use of this product
An approved organic vapor respirator should be worn when exposures are expected to exceed the
applicable limits
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance:
Odor:
Boiling Point:
pH:
Solubility in Water:
Specific Gravity:
VOC(Wt.%):
Vapor Pressure:
Vapor Density (Air=1):
Evaporation Rate:
Gray Viscous liquid
Phenolic odor
>500°F (>260°C)
Neutral
Negligible
n/d
0
<1.0 mmHg
>1
<1 (butyl acetate = 1)
10. STABILITY AND REACTIVITY
Chemical Stability:
Hazardous Polymerization:
Incompatabilities:
Conditions to Avoid:
Hazardous Products of Combustion:
Stable at normal conditions
Will not occur
Strong Lewis or mineral acids, strong oxidizing agents, strong mineral and organic bases (especially
primary and secondary aliphatic amines)
Excessive heat.
Oxides of carbon, Chlorine
11. TOXICOLOGICAL INFORMATION
See Section 3
12. ECOLOGICAL INFORMATION
No data available
13. DISPOSAL CONSIDERATIONS
Recommended Method of Disposal:
US EPA Waste Number:
Disposal should be made in accordance with federal, state and local regulations
NH - Not a RCRA Hazardous Waste Material
14. TRANSPORTATION INFORMATION
DOT (49CFR 172)
U.S. Department of Transportation - DOT - 49 CFR (Ground)
DOT Shipping Name:
Hazard Class:
UN/ID Number:
IATA (Air)
Proper Shipping Name:
Class or Division:
UN/ID Number:
IMDG (Vessel)
Proper Shipping Name:
Hazard Class:
UN Number:
Not regulated
None
None
Not regulated
None
None
Not regulated
None
None
15. REGULATORY INFORMATION
SARA 313 Chemicals: The following component(s) is listed as a SARA Section 313 Toxic Chemical.
None
California Proposition 65:
TSCA Inventory Status:
WARNING: This product contains chemicals known to the State of California to cause cancer and birth
defects or other reproductive harm.
All components of this product are listed (or exempt) on the EPA TSCA inventory.
16. OTHER INFORMATION
Estimated NFPA Rating:
Estimated HMIS Classification:
(NFPA is a registered trademark of the National Fire Protection Association)
(HMIS is a registered trademark of the National Paint and Coatings Association)
Prepared By:
Company:
Telephone No.:
ITW Permatex 10 Columbus Blvd. Hartford, CT USA 06106
1-87-Permatex (877) 376-2839
HEALTH 2, FLAMMABILITY 1 , REACTIVITY 0
HEALTH 2, FLAMMABILITY 1, PHYSICAL HAZARD 0
Revision Date:
September 18, 2012Denise Boyd, Manager-Environmental, Health & Safety
Revision Number:
1
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