
Professional Vani-Sol Bulk Disinfectant W ashroom Cleaner II
1. Product and company identification
0 36241 00294 7 [128 FL. OZ. (1 GAL.) 3.79 L]
Professional Vani-Sol Bulk Disinfectant Washroom Cleaner II
Emergency telephone
number (Medical)
Emergency telephone
number (Transport)
1-800-424-9300 (U.S. & Canada) CHEMTREC
Outside U.S. and Canada (North America), call Chemtrec:703-527-3887
This SDS is designed for workplace employees, emergency personnel and for other conditions and situations
where there is greater potential for large-scale or prolonged exposure, in accordance with the requirements of
USDOL Occupational Safety and Health Administration.
This SDS is not applicable for consumer use of our products. For consum er use, all precautionary and first aid
language is provided on the product label in accordance with the applicable government regulations, and shown
in Section 15 of this SDS.
Reckitt Benckiser LLC.
Morris Corporate Center IV
399 Interpace Parkway (P.O. Box 225)
Parsippany, New Jersey 07054-0225
+1 973 404 2600
Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM
2. Hazards identification
Classification of the
substance or m ixture
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2B
SKIN SENSITIZATION - Category 1
Causes eye irritation.
May cause an allergic skin reaction.
Read label before use. Keep out of reach of children. If medical advice is needed, have
product container or label at hand.
Precautionary statem ents

Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM
2. Hazards identification
Supplemental label
elements
Hazards not otherwise
classified
Wear protective gloves. W ear eye or face protection. Avoid breathing vapor. Wash
hands thoroughly after handling. Contaminated work clothing should not be allowed out
of the workplace.
IF ON SKIN: W ash with plenty of soap and water. Wash contaminated clothing before
reuse. If skin irritation or rash occurs: Get medical attention. IF IN EYES: Rinse
cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. If eye irritation persists: Get medical attention.
Dispose of contents and container in accordance with all local, regional, national and
international regulations.
3. Composition/information on ingredients
dodecyldimethylamine oxide
Quaternary ammonium compounds, benzyl-C12-16-alkyldimethyl, chlorides
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environm ent and hence require reporting
in this section.
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. If irritation persists, get medical attention.
Wash with plenty of soap and water. Remove contaminated clothing and shoes. W ash
contaminated clothing thoroughly with water before removing it, or wear gloves.
Continue to rinse for at least 10 minutes. Get medical attention. In the event of any
complaints or symptoms, avoid further exposure. W ash clothing before reuse. Clean
shoes thoroughly before reuse.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not
breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial
respiration or oxygen by trained personnel. It may be dangerous to the person providing
aid to give mouth-to-mouth resuscitation. Get medical attention if adverse health effects
persist or are severe. If unconscious, place in recovery position and get medical
attention immediately. Maintain an open airway. Loosen tight clothing such as a collar,
tie, belt or waistband. In case of inhalation of decomposition products in a fire,
symptoms may be delayed. The exposed person may need to be kept under medical
surveillance for 48 hours.
Description of necessary first aid measures

Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM
Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and
keep at rest in a position comfortable for breathing. If material has been swallowed and
the exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention if adverse health
effects persist or are severe. Never give anything by mouth to an unconscious person.
If unconscious, place in recovery position and get medical attention immediately.
Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Protection of first-aiders
No action shall be taken involving any personal risk or without suitable training. It may
be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash
contaminated clothing thoroughly with water before removing it, or wear gloves.
In case of inhalation of decomposition products in a fire, symptoms may be delayed. The
exposed person may need to be kept under medical surveillance for 48 hours.
Most important symptoms/effects, acute and delayed
Exposure to decomposition products may cause a health hazard. Serious effects may be
delayed following exposure.
May be irritating to mouth, throat and stomach.
May cause an allergic skin reaction.
Over-exposure signs/symptom s
Adverse symptoms may include the following:
irritation
redness
Adverse symptoms may include the following:
irritation
watering
redness
Potential acute health effects
See toxicological information (Section 11)
Indication of im mediate medical attention and special treatm ent needed, if necessary
5. Fire-fighting measures
Specific hazards arising
from the chemical
In a fire or if heated, a pressure increase will occur and the container may burst.
Use an extinguishing agent suitable for the surrounding fire.
Suitable extinguishing
media
Unsuitable extinguishing
media:3/12

Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM
5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training.
Hazardous thermal
decomposition products
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
nitrogen oxides
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
Special protective actions
for fire-fighters
6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Stop leak if without risk. Move containers from spill area. Approach release from upwind.
Prevent entry into sewers, water courses, basements or confined areas. Wash spillages
into an effluent treatment plant or proceed as follows. Contain and collect spillage with
non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth
and place in container for disposal according to local regulations (see Section 13).
Dispose of via a licensed waste disposal contractor. Contaminated absorbent material
may pose the same hazard as the spilled product. Note: see Section 1 for emergency
contact information and Section 13 for waste disposal.
No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist.
Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate.
Put on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and
sewers. Inform the relevant authorities if the product has caused environmental pollution
(sewers, waterways, soil or air).
Stop leak if without risk. Move containers from spill area. Dilute with water and mop up
if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and
place in an appropriate waste disposal container. Dispose of via a licensed waste
disposal contractor.
Methods and materials for containment and cleaning up
For non-em ergency
personnel
For emergency responders
If specialised clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For nonemergency personnel".
Put on appropriate personal protective equipment (see Section 8). Persons with a history
of skin sensitization problems should not be employed in any process in which this
product is used. Do not get in eyes or on skin or clothing. Do not ingest. Avoid
breathing vapor or mist. Keep in the original container or an approved alternative made
from a compatible material, kept tightly closed when not in use. Empty containers retain
product residue and can be hazardous. Do not reuse container.
Precautions for safe handling

Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM
Conditions for safe storage,
including any
incom patibilities
Store in accordance with local regulations. Store in original container protected from
direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials
(see Section 10) and food and drink. Keep container tightly closed and sealed until
ready for use. Containers that have been opened must be carefully resealed and kept
upright to prevent leakage. Do not store in unlabeled containers. Use appropriate
containment to avoid environmental contamination.
ACGIH TLV (United States, 6/2013).
STEL: 15 mg/m³ 15 minutes.
OSHA PEL 1989 (United States, 3/1989).
STEL: 15 mg/m³ 15 minutes.
NIOSH REL (United States, 10/2013).
STEL: 15 mg/m³ 15 minutes.
OSHA PEL (United States, 2/2013).
8. Exposure controls/personal protection
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Environmental exposure
controls
Emissions from ventilation or work process equipment should be checked to ensure they
comply with the requirements of environmental protection legislation. In some cases,
fume scrubbers, filters or engineering modifications to the process equipment will be
necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
Good general ventilation should be sufficient to control worker exposure to airborne
contaminants.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period. Appropriate
techniques should be used to remove potentially contaminated clothing. Contaminated
work clothing should not be allowed out of the workplace. Wash contaminated clothing
before reusing. Ensure that eyewash stations and safety showers are close to the
workstation location.
Individual protection m easures
Occupational exposure limits

Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM
8. Exposure controls/personal protection
Use a properly fitted, air-purifying or air-fed respirator complying with an approved
standard if a risk assessment indicates this is necessary. Respirator selection must be
based on known or anticipated exposure levels, the hazards of the product and the safe
working limits of the selected respirator.
Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before handling
this product.
Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
9. Physical and chemical properties
Easily soluble in the following materials: cold water and hot water.
Auto-ignition temperature
Closed cup: >93.3°C (>199.9°F)
10.5 to 11.3 [Conc. (% w/w): 100%]
Partition coefficient: noctanol/water
Flammability (solid, gas)
Lower and upper explosive
(flammable) limits
Decomposition temperature

Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM
10. Stability and reactivity
Hazardous decomposition
products
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
Do not mix with household chemicals.
Possibility of hazardous
reactions
Under normal conditions of storage and use, hazardous reactions will not occur.
No specific test data related to reactivity available for this product or its ingredients.
11. Toxicological information
Quaternary ammonium
compounds, benzylC12-16-alkyldimethyl,
chlorides
dodecyldimethylamine oxide
*Professional Vani-Sol Bulk
Disinfectant Washroom
Cleaner II
Irritating to eyes. *Information is based on toxicity test result of a similar product.
Information on toxicological effects
*Professional Vani-Sol Bulk
Disinfectant Washroom
Cleaner II
Result
Conclusion/Summary
Skin sensitizer *Information is based on toxicity test result of a similar product.
Quaternary ammonium
compounds, benzylC12-16-alkyldimethyl,
chlorides

Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM
11. Toxicological information
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
Information on the likely
routes of exposure
Exposure to decomposition products may cause a health hazard. Serious effects may be
delayed following exposure.
May be irritating to mouth, throat and stomach.
May cause an allergic skin reaction.
Symptoms related to the physical, chemical and toxicological characteristics
Adverse symptoms may include the following:
irritation
redness
Adverse symptoms may include the following:
irritation
watering
redness
Potential chronic health effects
Delayed and imm ediate effects and also chronic effects from short and long term exposure
Potential acute health effects
Potential immediate
effects
Potential delayed effects
Potential immediate
effects
Potential delayed effects

Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM
11. Toxicological information
Once sensitized, a severe allergic reaction may occur when subsequently exposed to
very low levels.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
Numerical measures of toxicity
12. Ecological information
Acute EC50 8.42 mg/l Fresh water
Algae - Desmodesmus
subspicatus
Acute LC50 >100000 µg/l Marine water
Crustaceans - Crangon crangon Adult
Acute LC50 170000 µg/l Fresh water
Quaternary ammonium
compounds, benzylC12-16-alkyldimethyl,
chlorides
Acute LC50 64 ppb Fresh water
Fish - Oncorhynchus mykiss
Bioaccumulative potential
No known significant effects or critical hazards.
Persistence and degradability
Soil/water partition
coefficient (KOC)

Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM
13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal of
this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any regional
local authority requirements. Dispose of surplus and non-recyclable products via a
licensed waste disposal contractor. W aste should not be disposed of untreated to the
sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and
sewers.
14. Transport information
Not a DOT controlled material (United States). Not a TDG-controlled material. This preparation is not classified as
dangerous according to international transport regulations (ADR/RID, IMDG or ICAO/IATA).
15. Regulatory information
TSCA 4(a) proposed test rules: Quaternary ammonium compounds, benzyl-
C12-16-alkyldimethyl, chlorides
Clean Water Act (CWA) 307: disodium [29H,31H-phthalocyaninedisulphonato(4-)-N29,
N30,N31,N32]cuprate(2-)
TSCA 8(a) PAIR: 1-(2-butoxy-1-methylethoxy)propan-2-ol
TSCA 8(a) CDR Exempt/Partial exemption: Not determined
United States inventory (T SCA 8b): All components are listed or exempted.
Clean Air Act Section 112
(b) Hazardous Air
Pollutants (HAPs)
Clean Air Act Section 602
Class I Substances
Clean Air Act Section 602
Class II Substances
DEA List I Chemicals
(Precursor Chem icals)
DEA List II Chemicals
(Essential Chemicals)
Composition/information on ingredients
Immediate (acute) health hazard
Composition/information on ingredients

Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM
15. Regulatory information
Prolonged or frequently repeated skin contact may cause allergic reactions in some
individuals
Causes substantial but temporary eye injury. Prolonged or frequently repeated skin
contact may cause allergic reactions in some individuals.
Wash thoroughly with soap and water after handling and before eating, drinking, chewing
gum, using tobacco or using the toilet. Keep out of reach of children.
Do not get in eyes, on skin or on clothing.
None of the components are listed.
None of the components are listed.
None of the components are listed.
None of the components are listed.
dodecyldimethylamine oxide
Sudden
release of
pressure
Immediate
(acute)
health
hazard
Delayed
(chronic)
health
hazard
Hazardous Material
Information System (U.S.A.)
National Fire Protection
Association (U.S.A.)
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks Although HMIS® ratings are not required on MSDSs under 29 CFR 1910.
1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS®
program. HMIS® is a registered m ark of the National Paint & Coatings Association (NPCA). HMIS® materials m ay
be purchased exclusively from J. J. Keller (800) 327-6868.
The custom er is responsible for determining the PPE code for this material.
Reprinted with perm ission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency
Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not
the com plete and official position of the National Fire Protection Association, on the referenced subject which is
represented only by the standard in its entirety.

Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM
To the best of our knowledge, the information contained herein is accurate. However, neither the above-nam ed
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determ ination of suitability of any material is the sole responsibility of the user. All materials m ay present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.
Indicates information that has changed from previously issued version.
Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be
interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of
chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA
49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not,
anyone using the 704 system s to classify chemicals does so at their own risk.
Reckitt Benckiser LLC.
Product Safety Department
1 Philips Parkway
Montvale, New Jersey 07646-1810 USA.
FAX: 201-476-7770
RB is a member of the CSPA Product Care Product Stewardship Program.
ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships,
1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations