Date printed 10.11.2014, Revision 10.11.2014
Version 01
Page 1 / 7
Trodat GmbH
Safety Data Sheet (SDS) conforms to ANSI Z400.1/Z129.1-2010 (29 CFR 1910) (US)
7011 Trodat Ideal Black
4600 Wels
SECTION 1: Identification of the substance/mixture and of the company/undertaking
Product identifier
7011 Trodat Ideal Black
Relevant identified uses of the substance
or mixture and uses advised against
Paint
Identified use
none
Company
Trodat GmbH
Linzerstr. 156
4600 Wels / AUSTRIA
Phone +43 (0) 7242 239 - 0
Fax +43 (0) 7242 239 - 940
Homepage www.trodat.net
E-mail trodat@trodat.net
Address enquiries to
Emergency telephone number Advisory
body
+43 (0) 1 406 43 43 (24h)
Emergency telephone number Company
+43 (0) 7242 239 - 0 Mo-Fr 8:00 - 16:00
Technical information
trodat@trodat.net
Safety Data Sheet
sdb@chemiebuero.de
SECTION 2: Hazards identification
Emergency Overview
Appearance, Odor:
liquid, black, characteristic
OSHA Regulatory Status
This product is classified as non-hazardous in accordance to OSHA Standard 29 CFR
1910.1200.
Potential health effects
Potential environmental effects
Does not contain any PBT or vPvB substances.
SECTION 3: Composition / Information on ingredients
The product is a mixture.
Range [%]
Substance
30 - < 50
CAS: 56-81-5
Glycerol
5 - < 10
CAS: 8005-03-6
Acid Black 2
1 - < 5
CAS: 1333-86-4
Carbon Black
< 1
CAS: 7757-82-6
Sodium sulphate
< 1
CAS: 25322-68-3
Polyethylene glycol
< 0,1
CAS: 62-53-3
Aniline
Comment on component parts
Substances of Very High Concern - SVHC: substances are not contained or are below 0,1%.
For full text of H-statements and R-phrases: see SECTION 16.
www.chemiebuero.de, Phone +49 (0)941-646 353-0, info@chemiebuero.de, 140812a
trk00061 US
Date printed 10.11.2014, Revision 10.11.2014
Version 01
Page 2 / 7
Trodat GmbH
Safety Data Sheet (SDS) conforms to ANSI Z400.1/Z129.1-2010 (29 CFR 1910) (US)
7011 Trodat Ideal Black
4600 Wels
SECTION 4: First aid measures
Description of first aid measures
Take off contaminated clothing and wash before reuse.
Inhalation
Ensure supply of fresh air.
In the event of symptoms seek for medical treatment.
Skin contact
When in contact with the skin, clean with soap and water.
Consult a doctor if skin irritation persists.
Eye contact
Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing.
If eye irritation persists: Get medical advice/attention.
Ingestion
Seek medical advice immediately.
Rinse out mouth and give plenty of water to drink.
Do not induce vomiting.
Indication of any immediate medical
attention and special treatment needed
Treat symptomatically.
SECTION 5: Fire-fighting measures
Suitable extinguishing media
Extinguish blanket.
Carbon dioxide.
Foam.
Extinguishing media that must not be used
Full water jet.
Special exposure hazards arising from the
substance or preparation itself or
combustion products
Risk of formation of toxic pyrolysis products.
Carbon monoxide (CO)
Special protective equipment for
firefighters
Use self-contained breathing apparatus.
Additional information
Fire residues and contaminated firefighting water must be disposed of in accordance within
the local regulations.
SECTION 6: Accidental release measures
Personal precautions, protective
equipment and emergency procedures
High risk of slipping due to leakage/spillage of product.
Ensure adequate ventilation.
Keep away from all sources of ignition.
Environmental precautions
Prevent spread over a wide area (e.g. by containment or oil barriers).
Do not discharge into the drains/surface waters/groundwater.
Methods and material for containment and
cleaning up
Pick up with absorbent material (e.g. sand, sawdust, universal absorbent, diatomaceous
earth).
Dispose of absorbed material in accordance within the regulations.
SECTION 7: Handling and storage
Precautions for safe handling
Use only in well-ventilated areas.
Requirements for storage rooms and
vessels
Keep only in original container.
Prevent penetration into the ground.
Provide floor with bunding.
Advice on storage compatibility
Do not store together with oxidizing agents.
Further information on storage conditions
Keep container in a well-ventilated place.
Keep container tightly closed.
Protect from heat/overheating.
www.chemiebuero.de, Phone +49 (0)941-646 353-0, info@chemiebuero.de, 140812a
trk00061 US
Date printed 10.11.2014, Revision 10.11.2014
Version 01
Page 3 / 7
Trodat GmbH
Safety Data Sheet (SDS) conforms to ANSI Z400.1/Z129.1-2010 (29 CFR 1910) (US)
7011 Trodat Ideal Black
4600 Wels
SECTION 8: Exposure controls / personal protection
Additional advice on system design
Ensure adequate ventilation on workstation.
Ingredients with occupational exposure
limits to be monitored (US)
Range [%]
Substance
35 - < 50
Glycerol
CAS: 56-81-5, EINECS/ELINCS: 200-289-5
Long-term exposure: 15 mg/m³, (mist) total dust
1 - < 3
Carbon Black
CAS: 1333-86-4, EINECS/ELINCS: 215-609-9
Long-term exposure: 3,5 mg/m³, OSHA
< 0,1
Aniline
CAS: 62-53-3, EINECS/ELINCS: 200-539-3, EU-INDEX: 612-008-00-7
Long-term exposure: 2 ppm, 7,6 mg/m³, ACGIH
Respiratory protection
Breathing apparatus in the event of high concentrations.
Short term: filter apparatus, combination filter A-P2.
Hand protection
Butyl rubber, >480 min (EN 374).
The details concerned are recommendations. Please contact the glove supplier for further
information.
Eye protection
If there is a risk of splashing:
Safety glasses.
Skin protection
light protective clothing
General protective measures
Avoid contact with eyes and skin.
Personal protective equipment should be selected specifically for the working place,
depending on concentration and quantity of the hazardous substances handled. The
resistance of these equipments to chemicals should be ascertained with the respective
supplier.
Hygiene measures
Take off contaminated clothing and wash before reuse.
Do not eat, drink or smoke when using this product.
Wash face and/or hands before break and end of work.
Use barrier skin cream.
Delimitation and monitoring of the
environmental exposition
Comply with applicable environmental regulations limiting discharge to air, water and soil.
SECTION 9: Physical and chemical properties
Form
liquid
Color
black
Odor
characteristic
pH-value
not determined
pH-value [1%]
not determined
Boiling point [°C]
not determined
Flash point [°C]
> 146
Flammability [°C]
ca. 225
Lower explosion limit
not applicable
Upper explosion limit
not applicable
Oxidizing properties
no
Vapour pressure/gas pressure [kPa]
ca. 0,01 (20 °C)
Density [g/ml]
not determined
Bulk density [kg/m³]
not applicable
Solubility in water
completely miscible
Partition coefficient [n-octanol/water]
not determined
Viscosity
not determined
Relative vapour density determined in air
not determined
Evaporation speed
not determined
Melting point [°C]
not determined
Autoignition temperature [°C]
not determined
Decomposition temperature [°C]
not determined
www.chemiebuero.de, Phone +49 (0)941-646 353-0, info@chemiebuero.de, 140812a
trk00061 US
Date printed 10.11.2014, Revision 10.11.2014
Version 01
Page 4 / 7
Trodat GmbH
Safety Data Sheet (SDS) conforms to ANSI Z400.1/Z129.1-2010 (29 CFR 1910) (US)
7011 Trodat Ideal Black
4600 Wels
SECTION 10: Stability and reactivity
Reactivity
No dangerous reactions known if used as directed.
Chemical stability
Stable under normal ambient conditions (ambient temperature).
Possibility of hazardous reactions
Reactions with oxidizing agents.
Conditions to avoid
See SECTION 7.2.
Incompatible materials
No information available.
Hazardous decomposition products
No hazardous decomposition products known.
In the event of fire: See SECTION 5.
SECTION 11: Toxicological information
Information on toxicological effects
Acute toxicity
Range [%]
Substance
< 0,1
Aniline, CAS: 62-53-3
LD50, dermal, Rabbit: 837 mg/kg (GESTIS).
LD50, oral, Rat: 250 mg/kg (GESTIS).
LD50, oral, Rat: 200-2000 mg/kg (IUCLID).
30 - < 50
Glycerol, CAS: 56-81-5
LD50, dermal, Rabbit: > 18700 mg/kg (IUCLID).
LD50, oral, Rat: 12600 mg/kg (IUCLID).
Serious eye damage/irritation
not determined
Skin corrosion/irritation
not determined
Respiratory or skin sensitisation
not determined
Specific target organ toxicity — single
exposure
not determined
Specific target organ toxicity — repeated
exposure
not determined
Mutagenicity
not determined
Reproduction toxicity
not determined
Carcinogenicity
not determined
General remarks
Toxicological data of complete product are not available.
No classification on the basis of the calculation procedure of the preparation directive.
www.chemiebuero.de, Phone +49 (0)941-646 353-0, info@chemiebuero.de, 140812a
trk00061 US
Date printed 10.11.2014, Revision 10.11.2014
Version 01
Page 5 / 7
Trodat GmbH
Safety Data Sheet (SDS) conforms to ANSI Z400.1/Z129.1-2010 (29 CFR 1910) (US)
7011 Trodat Ideal Black
4600 Wels
SECTION 12: Ecological information
Toxicity
Range [%]
Substance
< 0,1
Aniline, CAS: 62-53-3
LC50, (96h), fish: 57,6 mg/l (GESTIS).
LC50, (48h), Daphnia sp.: 0,193 mg/l (GESTIS).
EC50, (72h), Algae: 20 mg/l (GESTIS).
1 - < 5
Carbon Black, CAS: 1333-86-4
EC50, (24h), Daphnia magna: >5600 mg/L (IUCLID).
LC0, (96h), Brachidanio rerio: 1000 mg/L (IUCLID).
30 - < 50
Glycerol, CAS: 56-81-5
LC50, (24h), Carassius auratus: > 5000 mg/l.
EC50, (72h), Bacteria: > 10000 mg/l.
EC50, (48h), Algae: > 2900 mg/l.
EC50, (24h), Daphnia magna: > 10000 mg/l.
Behaviour in environment compartments
not determined
Behaviour in sewage plant
not determined
Bacteria toxicity
not determined
Biological degradability
not determined
COD
not determined
BOD 5
not determined
Other adverse effects
Ecological data of complete product are not available.
No classification on the basis of the calculation procedure of the preparation directive.
SECTION 13: Disposal considerations
Product
Coordinate disposal with the authorities if necessary.
Disposal in an incineration plant in accordance with the regulations of the local authorities.
Contaminated packaging
Packaging that cannot be cleaned should be disposed of as for product.
Uncontaminated packaging may be taken for recycling.
RCRA Hazard Class (40CFR 261)
Waste must be disposed of in accordance with federal, state and local environmental control
regulations. Consult your local or regional authorities.
SECTION 14: Transport information
Transport by land according to ADR/RID
NO DANGEROUS GOODS
Inland navigation (ADN)
NO DANGEROUS GOODS
Marine transport in accordance with IMDG
NOT CLASSIFIED AS "DANGEROUS GOODS"
Air transport in accordance with IATA
NOT CLASSIFIED AS "DANGEROUS GOODS"
DOT Road Shipment Information (49 CFR)
NOT CLASSIFIED AS "DANGEROUS GOODS"
www.chemiebuero.de, Phone +49 (0)941-646 353-0, info@chemiebuero.de, 140812a
trk00061 US
Date printed 10.11.2014, Revision 10.11.2014
Version 01
Page 6 / 7
Trodat GmbH
Safety Data Sheet (SDS) conforms to ANSI Z400.1/Z129.1-2010 (29 CFR 1910) (US)
7011 Trodat Ideal Black
4600 Wels
SECTION 15: Regulatory information
US Regulations
National regulations
29 CFR 1910.1200, ANSI Z400.1-2010, OSHA-PEL, ACGIH-TLV, NTP, IARC, SARA Title III,
NFPA, TSCA, California - Prop. 65
- SARA, 302
One or some ingredient(s) are listed under this regulation.
(Aniline)
- SARA, 311
This product is not classified as hazardous under SARA 311.
- SARA, 313
This product contain one ingredient regulated under this list(40 CFR part 372.65): Aniline
- CA Proposition 65
Some chemical substances Carbon Black, Aniline in this material are named in California-P65
list.
- TSCA
All chemical substances in this material are included on or exempted from listing on the
TSCA Inventory.
- FDA
not applicable
American Conference of Governmental
Industrial Hygienists - ACGIH
Carbon Black - A4: Not classifiable as a human carcinogen.
Aniline - A3: Confirmed Animal Carcinogen
International Agency for Research on
Cancer IARC
IARC: Group 2B carcinogen Carbon Black
National Toxicology Program - NTP
Glycerol (Testing Status)
Aniline (Testing Status)
HAP-VOC
HAP's-content: Aniline
Transport-regulations
DOT-Classification, ADR (2013); IMDG-Code (2013, 36. Amdt.); IATA-DGR (2013).
Other Right to Know Laws
EC Regulations
1967/548 (1999/45); 1991/689 (2001/118); 1999/13; 2004/42; 648/2004; 1907/2006 (Reach);
1272/2008; 75/324/EEC (2008/47/EC); 453/2010/EC
Hazard pictograms
none
Signal word
none
Hazard statements
none
Precautionary statements
none
Labelling
Hazard symbols
none
R-phrases
none
S-phrases
none
Special labelling
none
SECTION 16: Other information
Observe employment restrictions for
people
none
HMIS Ratings
HEALTH
1* - Slight chronic Hazard
1*
1 - Slight Hazard
FLAMMABILITY
1
0 - Minimal Hazard
REACTIVITY
0
X - Personal protection rating to be supplied by user depending on use conditions
PERSONAL PROTECTION
X
NFPA Ratings
1
TOP, FLAMMABILITY: 1 - Slight Hazard
01LEFT, HEALTH: 1* - Slight chronic Hazard RIGHT, REACTIVITY: 0 - Minimal Hazard
-
BOTTOM, SPECIAL NOTICE: -
Modified position
none
www.chemiebuero.de, Phone +49 (0)941-646 353-0, info@chemiebuero.de, 140812a
trk00061 US
Date printed 10.11.2014, Revision 10.11.2014
Version 01
Page 7 / 7
Trodat GmbH
Safety Data Sheet (SDS) conforms to ANSI Z400.1/Z129.1-2010 (29 CFR 1910) (US)
7011 Trodat Ideal Black
4600 Wels
Key / Legende:
ACGIH = American Conference of Governmental Industrial Hygienists; CAS = Chemical Abstracts Service; CERCLA = Comprehensive
Enviromental Response, Compensation, and Liability Act; CFR = Code of Federal Regulations; CPR = Controlled Products Regulations;
DOT = Department of Transportation; EINCES = European Inventory of Existing Commercial Chemical Substances; EPA = Environmental
Protection Agency; IARC = International Agency for Research on Cancer; IATA = International Air Transport Association; NIOSH = National
Institute for Occupational Safety and Health; NTP = National Toxicology Program; OSHA = Occupational Safety and Health Administration;
SARA = Superfund Amendments and Reauthorization Act; STEL = Short Term Exposure Limit; TSCA = Toxic Substances Control Act
Copyright: Chemiebüro®
www.chemiebuero.de, Phone +49 (0)941-646 353-0, info@chemiebuero.de, 140812a
trk00061 US
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