Universal UNV43660 User Manual

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SAFETY DATA SHEET
UNV43660 DRY ERASE CLEANING WET WIPES 5 X 10 50PK
The safety data sheet is in accordance with Commission Regulation (EU) 2015/830 of 28 May 2015 amending Regulation (EC) No 1907/2006 of the European Parliament and of the Council on the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH)

SECTION 1: Identification of the substance / mixture and of the company / undertaking

Date issued
Revision date
12.01.2015
17.05.2018

1.1. Product identifier

Product name
Article no.
UNV43660 DRY ERASE CLEANING WET WIPES 5 X 10 50PK
L03000000094

1.2. Relevant identified uses of the substance or mixture and uses advised against

Product group
Relevant identified uses
Uses advised against
Whiteboardcleaner
SU21 Consumer uses: Private households (= general public = consumers)SU22 Professional uses: publicly accessible (administration, education, entertainment, services, craftsmen)PC35 Washing and cleaning products (including solvent based products)PROC10 Roller application or brushingERC11B Wide dispersive indoor use of long-life articles and materials with high or intended release (including abrasive processing)
No specific uses advised against are identified.

1.3. Details of the supplier of the safety data sheet

Company name
Kleinmann GmbH
Postal address
Postcode
City
Country
Telephone number
Fax
Email
Website
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Am Trieb 13
D-72820
Sonnenbuehl
Germany
+49(0)7128/9292-15
+49(0)7128/9292-415
chemie@kleinmann.net
http://www.kleinmann.net
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Enterprise No.
DE 146 487

1.4. Emergency telephone number

Emergency telephone
Description: 8-12, Mo.-Fr. +49(0)7128/9292-15

SECTION 2: Hazards identification

2.1. Classification of substance or mixture

Substance / mixture haz­ardous properties
The product is not classified. Not regarded as a health or environmental hazard under current legislation.

2.2. Label elements

Hazard statements
EUH 210 Safety data sheet available on request.

2.3. Other hazards

Health effect
Environmental effects
The product contains organic solvents.
This product does not contain any PBT or vPvB substances.

SECTION 3: Composition / information on ingredients

3.2. Mixtures

Substance Identification Classification Contents Propan-2-ol CAS No.: 67-63-0
EC No.: 200-661-7 Index No.: 603-117-00-0 REACH Reg. No.: 01-2119457558-25-XXXX
2-Butoxyethanol CAS No.: 111-76-2
EC No.: 203-905-0 Index No.: 603-014-00-0 REACH Reg. No.: 01-2119475108-36-xxxx
Substance comments
<1% Perfume The full text for all hazard statements is displayed in section 16.
Flam. Liq. 2; H225 Eye Irrit. 2; H319 STOT SE 3; H336
Acute tox. 4; H332 Acute tox. 4; H312 Acute tox. 4; H302 Eye Irrit. 2; H319 Skin Irrit. 2; H315
1 – 5 %
1 – 5 %

SECTION 4: First aid measures

4.1. Description of first aid measures

General
Inhalation
Skin contact
Remove affected person from source of contamination.
Fresh air. Get medical attention if any discomfort continues.
Rinse with water. Get medical attention if any discomfort continues.
Eye contact
Ingestion
Rinse with water. Contact physician if discomfort continues.
Rinse mouth with water. Get medical attention if any discomfort continues.

4.2. Most important symptoms and effects, both acute and delayed

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Acute symptoms and effects
Delayed symptoms and ef­fects
No specific symptoms noted.
No known long term effects.

4.3. Indication of any immediate medical attention and special treatment needed

Other information
If unconscious: Call an ambulance/physician immediately. Show this Safety Data Sheet.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media

5.2. Special hazards arising from the substance or mixture

Fire and explosion hazards

5.3. Advice for firefighters

Personal protective equip­ment
Use fire-extinguishing media appropriate for surrounding materials.
Follow the general fire precautions indicated by the workplace.
Wear necessary protective equipment. For personal protection, see section 8.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Personal protection mea­sures
Avoid contact with eyes and prolonged skin contact.

6.2. Environmental precautions

Environmental precautionary measures
Avoid discharge into water courses or onto the ground.

6.3. Methods and material for containment and cleaning up

Cleaning method
Recover the product and place in a suitable container for reuse. Flush contaminated area with plenty of water.

6.4. Reference to other sections

Other instructions
See section 8 and section 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Handling
No specific usage precautions noted.

7.2. Conditions for safe storage, including any incompatibilities

Storage
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Store in closed original container in a dry place.
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Conditions for safe storage

Technical measures and storage conditions
Storage temperature
Storage stabilit
Lagerklasse: 12
Value: 0 – 35 °C
Durability: 24 months.

7.3. Specific end use(s)

Specific use(s)
The identified uses for this product are detailed in Section 1.2.

SECTION 8: Exposure controls / personal protection

8.1. Control parameters

Substance Identification Value TWA Year Propan-2-ol CAS No.: 67-63-0 TWA (8h) : 200 ppm
TWA (8h) : 490 mg/m3 TWA (8h) : 400 ppm
OEL short term value
Value: 1250 mg/m³
2-Butoxyethanol CAS No.: 111-76-2 TWA (8h) : 98 mg/m3; H
TWA (8h) : 20 ppm; H

DNEL / PNEC

TWA Year: 2011
TWA Year: 2011
Substance
DNEL
Propan-2-ol
Group: Consumer Route of exposure: Long-term inhalation (systemic) Value: 89 mg/m³ Comments: ECHA
Group: Professional Route of exposure: Long-term dermal (systemic) Value: 888 mg/kg bw/day Comments: ECHA
Group: Professional Route of exposure: Long-term inhalation (systemic) Value: 500 mg/m³ Comments: ECHA
Group: Consumer Route of exposure: Long-term dermal (systemic) Value: 319 mg/kg bw/day Comments: ECHA
Group: Consumer Route of exposure: Long-term oral (systemic) Value: 26 mg/kg bw/day Comments: ECHA
PNEC
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Route of exposure: Sewage treatment plant STP Value: 2251 mg/l
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Route of exposure: Soil Value: 25 mg/kg
Route of exposure: Freshwater Value: 140,9 mg/l
Route of exposure: Saltwater sediments Value: 552 mh/kg
Route of exposure: Freshwater sediments Value: 552 mg/kg
Route of exposure: Saltwater Value: 140,9 mg/l
Value: 140,9 Comments: Intermittent releases
Substance
DNEL
2-Butoxyethanol
Group: Industrial Route of exposure: Long-term dermal (systemic) Value: 75 mg/kg/d
Group: Consumer Route of exposure: Acute inhalation (systemic) Value: 426 mg/m³
Group: Consumer Route of exposure: Acute oral (systemic) Value: 13.4 mg/kg/d
Group: Consumer Route of exposure: Long-term dermal (systemic) Value: 38 mg/kg/d
Group: Consumer Route of exposure: Acute dermal (systemic) Value: 44.5 mg/kg/d
Group: Industrial Route of exposure: Long-term inhalation (systemic) Value: 98 mg/m³
Group: Industrial Route of exposure: Acute inhalation (systemic) Value: 652 mg/m³
Group: Industrial Route of exposure: Acute dermal (systemic) Value: 89 mg/kg/d
Group: Consumer Route of exposure: Long-term oral (systemic) Value: 3.2 mg/kg/d
PNEC
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Route of exposure: Saltwater Value: 0.88 mg/l
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Route of exposure: Sewage treatment plant STP Value: 463 mg/l
Route of exposure: Freshwater Value: 8.8 mg/l
Route of exposure: Soil Value: 2.8 mg/kg
Route of exposure: Freshwater sediments Value: 34.6 mg/kg
Route of exposure: Saltwater sediments Value: 3.46 mg/kg

8.2. Exposure controls

Precautionary measures to prevent exposure

Technical measures to pre­vent exposure

Eye / face protection

Suitable eye protection

Hand protection

Skin- / hand protection, long term contact

Skin protection

Additional skin protection measures

Respiratory protection

Respiratory protection nec­essary at

Thermal hazards

Thermal hazards
No special precautions.
Eye protection is not required under normal conditions.
Hand protection is not required for normal use.
No special precautions.
Under normal conditions of use respiration protection should not be required.
No recommendation given.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Physical state
Colour
Odour
pH
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Fluid.
Colourless.
Perfume.
Status: In delivery state Value: ~ 7,0
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Status: In aqueous solution Comments: Not relevant.
Melting point / melting range
Boiling point / boiling range
Flash point
Evaporation rate
Flammability (solid, gas)
Explosion limit
Vapour pressure
Specific gravity
Solubility
Partition coefficient: n-oc­tanol/water
Spontaneous combustability
Decomposition temperature
Viscosity
Comments: Not relevant.
Comments: Not relevant.
Value: 49 °C Comments: Negative results are obtained in sustained combustibility test L.2., Part III, section 32 of the UN RTDG, Manual of Tests and Criteria, and classification as Flammable liquid and vapour in Category 3, is not needed.
Comments: Not relevant.
Not relevant.
Comments: Not relevant.
Comments: Not relevant.
Value: 0,98 – 0,99 g/ml
Medium: Water Comments: Completely soluble in water.
Comments: Not relevant.
Comments: Not relevant.
Comments: Not relevant.
Value: < 50 mPa s
Explosive properties
Oxidising properties
Not explosive.
Does not meet the criteria for oxidising.

9.2. Other information

Other physical and chemical properties

Comments
No data recorded.

SECTION 10: Stability and reactivity

10.1. Reactivity

Reactivity

10.2. Chemical stability

Stability

10.3. Possibility of hazardous reactions

Possibility of hazardous re­actions
There are no known reactivity hazards associated with this product.
Stable under normal temperature conditions and recommended use.
See section 10.4 and section 10.5.

10.4. Conditions to avoid

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Conditions to avoid
No recommendation given.

10.5. Incompatible materials

Materials to avoid
None in particular.

10.6. Hazardous decomposition products

Hazardous decomposition products
During fire, toxic gases (CO, CO2) are formed.

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Substance
Acute toxicity
Propan-2-ol
Type of toxicity: Acute Effect tested: LD50 Route of exposure: Oral Value: 5840 mg/kg Animal test species: Rat Test reference: OECD Guideline 401 Comments: ECHA
Substance
Acute toxicity
Type of toxicity: Acute Effect tested: LC50 Route of exposure: Inhalation. Duration: 6 hour(s) Value: > 10000 ppm Animal test species: Rat Test reference: OECD Guideline 403 Comments: ECHA
Type of toxicity: Acute Effect tested: LD50 Route of exposure: Dermal Duration: 24 hour(s) Value: 16,4 ml/kg Animal test species: Rabbit Test reference: OECD Guideline 402 Comments: ECHA
2-Butoxyethanol
Type of toxicity: Acute Effect tested: LD50 Route of exposure: Oral Value: 1300 mg/kg Animal test species: Rat
Type of toxicity: Acute Effect tested: LD50 Route of exposure: Dermal Value: 1100 mg/kg Test reference: OECD Guideline 402
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Type of toxicity: Acute Effect tested: LC50 Route of exposure: Inhalation. Value: 1,5 mg/l
Other toxicological data
Toxicological tests on the product has not been performed.

Other information regarding health hazards

Assessment of acute toxici­ty, classification
Substance
Eye damage or irritation, test results
Inhalation
Skin contact
Eye contact
Ingestion
Sensitisation
Mutagenicity
Carcinogenicity, other infor­mation
Reproductive toxicity
No evidence for acute toxicity.
Propan-2-ol
Toxicity type: Eye irritation Method: OECD 405 Species: Rabbit Evaluation result: Result: Irritation to eye.
No specific symptoms noted.
Skin irritation is not anticipated when used normally.
May cause temporary eye irritation.
Not likely, due to the packaging.
No evidence for respiratory nor skin sensitization.
No evidence for germ cell mutagenicity.
No evidence for carcinogenicity.
No evidence for reproductive toxicity.
Assessment of specific tar­get organ SE, classification
Assessment of specific tar­get organ toxicity RE, classi­fication
Assessment of aspiration hazard, classification
No evidence for STOT-single exposure.
No evidence for STOT-repeated exposure.
No evidence for aspiration hazard.

Symptoms of exposure

Symptoms of overexposure
No specific symptoms noted.

SECTION 12: Ecological information

12.1. Toxicity

Substance
Acute aquatic, fish
Substance
Propan-2-ol
Value: 8970 – 9280 mg/l Test duration: 48 hour(s) Species: Leuciscus idus melanotus Method: LC50
2-Butoxyethanol
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Acute aquatic, fish
Substance
Acute aquatic, algae
Substance
Acute aquatic, algae
Substance
Acute aquatic, Daphnia
Substance
Value: 1474 mg/l Test duration: 96h Species: Oncorhynchus mykiss Method: OECD TG 203
Propan-2-ol
Value: 1800 mg/l Test duration: 8 day(s) Species: Scenedesmus quadricauda Method: TGK
2-Butoxyethanol
Value: 1840 mg/l Test duration: 72 hour(s) Species: Pseudokirchneriella subcapitata Method: OECD TG 201
Propan-2-ol
Value: 9715 mg/l Test duration: 24 hour(s) Species: Daphnia magna Method: LC50
2-Butoxyethanol
Acute aquatic, Daphnia
Aquatic, comments
Toxicity type: Acute Value: 100 mg/l Exposure time: 21 day(s) Species: Daphnia magna Method: NOEC
Value: 1550 mg/l Test duration: 4h Species: Daphnia magna Method: OECD TG 202
No data available for the product.

12.2. Persistence and degradability

Substance
Biodegradability
Substance
Biodegradability
Propan-2-ol
Value: 95 % Method: OECD 301E Test period: 21 day(s)
2-Butoxyethanol
Value: 90 % Method: OECD 301B Test period: 28 day(s)
Persistence and degradabili­ty, comments
The product is easily biodegradable.

12.3. Bioaccumulative potential

Bioaccumulative potential
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The product is not bioaccumulating.
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12.4. Mobility in soil

Mobility
The product is water soluble and may spread in water systems.

12.5. Results of PBT and vPvB assessment

PBT assessment results
Not Classified as PBT/vPvB by current EU criteria.

12.6. Other adverse effects

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Specify the appropriate methods of disposal
EWC waste code
EWL packing
Other information
Do not empty into drains; dispose of this material and its container in a safe way. Dispose of waste and residues in accordance with local authority requirements.
EWC waste code: 0706 Classified as hazardous waste: No
EWC waste code: 0706 Classified as hazardous waste: No
Waste code applies to product remnants in pure form. When handling waste, consideration should be made to the safety precautions applying to handling of the product.

SECTION 14: Transport information

14.1. UN number

Comments

14.2. UN proper shipping name

Comments

14.3. Transport hazard class(es)

Comments

14.4. Packing group

Comments

14.5. Environmental hazards

Comments

14.6. Special precautions for user

The product is not covered by international regulation on the transport of dangerous goods (IMDG, IATA, ADR/RID).
Not relevant.
Not relevant.
Not relevant.
Not relevant.
Special safety precautions for user
No data recorded.

14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

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ADN - Other information

Special provisions
Not relevant.

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations / legislation specific for the substance or mixture

Legislation and regulations
The Management of Health and Safety at Work Regulations 1999 (SI 1999 No. 3242). EH40/2005, Workplace exposure limits 2005, with amendments. The List of Wastes (England) (Amendment) Regulations 2005. (SI 2005 No. 895). Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments. REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/ 45/EC, and amending Regulation (EC) No 1907/2006. REGULATION (EC) No 648/2004 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 31 March 2004 on detergents.

15.2. Chemical safety assessment

Chemical safety assessment performed
No

SECTION 16: Other information

List of relevant H-phrases (Section 2 and 3)
Training advice
Information added, deleted or revised
Version
Prepared by
H225 Highly flammable liquid and vapour. H302 Harmful if swallowed. H312 Harmful in contact with skin. H315 Causes skin irritation. H319 Causes serious eye irritation. H332 Harmful if inhaled. H336 May cause drowsiness or dizziness.
No particular training or education is required but the user must be familiar with this SDS.
Change to Sections: 1, 3, 4, 8, 11, 12, 13, 16
7
MP
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