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SAFETY DATA SHEET
UNV43660 DRY ERASE CLEANING WET WIPES 5 X 10 50PK
The safety data sheet is in accordance with Commission Regulation (EU) 2015/830 of 28 May 2015 amending
Regulation (EC) No 1907/2006 of the European Parliament and of the Council on the Registration, Evaluation,
Authorisation and Restriction of Chemicals (REACH)
SECTION 1: Identification of the substance / mixture and of the company / undertaking
Date issued
Revision date
12.01.2015
17.05.2018
1.1. Product identifier
Product name
Article no.
UNV43660 DRY ERASE CLEANING WET WIPES 5 X 10 50PK
L03000000094
1.2. Relevant identified uses of the substance or mixture and uses advised against
Product group
Relevant identified uses
Uses advised against
Whiteboardcleaner
SU21 Consumer uses: Private households (= general public = consumers)SU22
Professional uses: publicly accessible (administration, education, entertainment,
services, craftsmen)PC35 Washing and cleaning products (including solvent based
products)PROC10 Roller application or brushingERC11B Wide dispersive indoor use of
long-life articles and materials with high or intended release (including abrasive
processing)
No specific uses advised against are identified.
1.3. Details of the supplier of the safety data sheet
Producer
Company name
Kleinmann GmbH
Postal address
Postcode
City
Country
Telephone number
Fax
Email
Website
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Am Trieb 13
D-72820
Sonnenbuehl
Germany
+49(0)7128/9292-15
+49(0)7128/9292-415
chemie@kleinmann.net
http://www.kleinmann.net
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Enterprise No.
DE 146 487
1.4. Emergency telephone number
Emergency telephone
Description: 8-12, Mo.-Fr. +49(0)7128/9292-15
SECTION 2: Hazards identification
2.1. Classification of substance or mixture
Substance / mixture hazardous properties
The product is not classified.
Not regarded as a health or environmental hazard under current legislation.
2.2. Label elements
Hazard statements
EUH 210 Safety data sheet available on request.
2.3. Other hazards
Health effect
Environmental effects
The product contains organic solvents.
This product does not contain any PBT or vPvB substances.
SECTION 3: Composition / information on ingredients
3.2. Mixtures
Substance Identification Classification Contents
Propan-2-ol CAS No.: 67-63-0
EC No.: 200-661-7
Index No.: 603-117-00-0
REACH Reg. No.:
01-2119457558-25-XXXX
2-Butoxyethanol CAS No.: 111-76-2
EC No.: 203-905-0
Index No.: 603-014-00-0
REACH Reg. No.:
01-2119475108-36-xxxx
Substance comments
<1% Perfume
The full text for all hazard statements is displayed in section 16.
Flam. Liq. 2; H225
Eye Irrit. 2; H319
STOT SE 3; H336
Acute tox. 4; H332
Acute tox. 4; H312
Acute tox. 4; H302
Eye Irrit. 2; H319
Skin Irrit. 2; H315
1 – 5 %
1 – 5 %
SECTION 4: First aid measures
4.1. Description of first aid measures
General
Inhalation
Skin contact
Remove affected person from source of contamination.
Fresh air. Get medical attention if any discomfort continues.
Rinse with water. Get medical attention if any discomfort continues.
Eye contact
Ingestion
Rinse with water. Contact physician if discomfort continues.
Rinse mouth with water. Get medical attention if any discomfort continues.
4.2. Most important symptoms and effects, both acute and delayed
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Acute symptoms and effects
Delayed symptoms and effects
No specific symptoms noted.
No known long term effects.
4.3. Indication of any immediate medical attention and special treatment needed
Other information
If unconscious: Call an ambulance/physician immediately. Show this Safety Data
Sheet.
SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media
5.2. Special hazards arising from the substance or mixture
Fire and explosion hazards
5.3. Advice for firefighters
Personal protective equipment
Use fire-extinguishing media appropriate for surrounding materials.
Follow the general fire precautions indicated by the workplace.
Wear necessary protective equipment. For personal protection, see section 8.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Personal protection measures
Avoid contact with eyes and prolonged skin contact.
6.2. Environmental precautions
Environmental precautionary
measures
Avoid discharge into water courses or onto the ground.
6.3. Methods and material for containment and cleaning up
Cleaning method
Recover the product and place in a suitable container for reuse. Flush contaminated
area with plenty of water.
6.4. Reference to other sections
Other instructions
See section 8 and section 13.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Handling
No specific usage precautions noted.
7.2. Conditions for safe storage, including any incompatibilities
Storage
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Store in closed original container in a dry place.
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Conditions for safe storage
Technical measures and
storage conditions
Storage temperature
Storage stabilit
Lagerklasse: 12
Value: 0 – 35 °C
Durability: 24 months.
7.3. Specific end use(s)
Specific use(s)
The identified uses for this product are detailed in Section 1.2.
SECTION 8: Exposure controls / personal protection
8.1. Control parameters
Substance Identification Value TWA Year
Propan-2-ol CAS No.: 67-63-0 TWA (8h) : 200 ppm
TWA (8h) : 490 mg/m3
TWA (8h) : 400 ppm
OEL short term value
Value: 1250 mg/m³
2-Butoxyethanol CAS No.: 111-76-2 TWA (8h) : 98 mg/m3; H
TWA (8h) : 20 ppm; H
DNEL / PNEC
TWA Year: 2011
TWA Year: 2011
Substance
DNEL
Propan-2-ol
Group: Consumer
Route of exposure: Long-term inhalation (systemic)
Value: 89 mg/m³
Comments: ECHA
Group: Professional
Route of exposure: Long-term dermal (systemic)
Value: 888 mg/kg bw/day
Comments: ECHA
Group: Professional
Route of exposure: Long-term inhalation (systemic)
Value: 500 mg/m³
Comments: ECHA
Group: Consumer
Route of exposure: Long-term dermal (systemic)
Value: 319 mg/kg bw/day
Comments: ECHA
Group: Consumer
Route of exposure: Long-term oral (systemic)
Value: 26 mg/kg bw/day
Comments: ECHA
PNEC
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Route of exposure: Sewage treatment plant STP
Value: 2251 mg/l
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Route of exposure: Soil
Value: 25 mg/kg
Route of exposure: Freshwater
Value: 140,9 mg/l
Route of exposure: Saltwater sediments
Value: 552 mh/kg
Route of exposure: Freshwater sediments
Value: 552 mg/kg
Route of exposure: Saltwater
Value: 140,9 mg/l
Value: 140,9
Comments: Intermittent releases
Substance
DNEL
2-Butoxyethanol
Group: Industrial
Route of exposure: Long-term dermal (systemic)
Value: 75 mg/kg/d
Group: Consumer
Route of exposure: Acute inhalation (systemic)
Value: 426 mg/m³
Group: Consumer
Route of exposure: Acute oral (systemic)
Value: 13.4 mg/kg/d
Group: Consumer
Route of exposure: Long-term dermal (systemic)
Value: 38 mg/kg/d
Group: Consumer
Route of exposure: Acute dermal (systemic)
Value: 44.5 mg/kg/d
Group: Industrial
Route of exposure: Long-term inhalation (systemic)
Value: 98 mg/m³
Group: Industrial
Route of exposure: Acute inhalation (systemic)
Value: 652 mg/m³
Group: Industrial
Route of exposure: Acute dermal (systemic)
Value: 89 mg/kg/d
Group: Consumer
Route of exposure: Long-term oral (systemic)
Value: 3.2 mg/kg/d
PNEC
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Route of exposure: Saltwater
Value: 0.88 mg/l
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Route of exposure: Sewage treatment plant STP
Value: 463 mg/l
Route of exposure: Freshwater
Value: 8.8 mg/l
Route of exposure: Soil
Value: 2.8 mg/kg
Route of exposure: Freshwater sediments
Value: 34.6 mg/kg
Route of exposure: Saltwater sediments
Value: 3.46 mg/kg
8.2. Exposure controls
Precautionary measures to prevent exposure
Technical measures to prevent exposure
Eye / face protection
Suitable eye protection
Hand protection
Skin- / hand protection, long
term contact
Skin protection
Additional skin protection
measures
Respiratory protection
Respiratory protection necessary at
Thermal hazards
Thermal hazards
No special precautions.
Eye protection is not required under normal conditions.
Hand protection is not required for normal use.
No special precautions.
Under normal conditions of use respiration protection should not be required.
No recommendation given.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state
Colour
Odour
pH
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Fluid.
Colourless.
Perfume.
Status: In delivery state
Value: ~ 7,0
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Status: In aqueous solution
Comments: Not relevant.
Melting point / melting range
Boiling point / boiling range
Flash point
Evaporation rate
Flammability (solid, gas)
Explosion limit
Vapour pressure
Specific gravity
Solubility
Partition coefficient: n-octanol/water
Spontaneous combustability
Decomposition temperature
Viscosity
Comments: Not relevant.
Comments: Not relevant.
Value: 49 °C
Comments: Negative results are obtained in sustained combustibility test L.2., Part III,
section 32 of the UN RTDG, Manual of Tests and Criteria, and classification as
Flammable liquid and vapour in Category 3, is not needed.
Comments: Not relevant.
Not relevant.
Comments: Not relevant.
Comments: Not relevant.
Value: 0,98 – 0,99 g/ml
Medium: Water
Comments: Completely soluble in water.
Comments: Not relevant.
Comments: Not relevant.
Comments: Not relevant.
Value: < 50 mPa s
Explosive properties
Oxidising properties
Not explosive.
Does not meet the criteria for oxidising.
9.2. Other information
Other physical and chemical properties
Comments
No data recorded.
SECTION 10: Stability and reactivity
10.1. Reactivity
Reactivity
10.2. Chemical stability
Stability
10.3. Possibility of hazardous reactions
Possibility of hazardous reactions
There are no known reactivity hazards associated with this product.
Stable under normal temperature conditions and recommended use.
See section 10.4 and section 10.5.
10.4. Conditions to avoid
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Conditions to avoid
No recommendation given.
10.5. Incompatible materials
Materials to avoid
None in particular.
10.6. Hazardous decomposition products
Hazardous decomposition
products
During fire, toxic gases (CO, CO2) are formed.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Substance
Acute toxicity
Propan-2-ol
Type of toxicity: Acute
Effect tested: LD50
Route of exposure: Oral
Value: 5840 mg/kg
Animal test species: Rat
Test reference: OECD Guideline 401
Comments: ECHA
Substance
Acute toxicity
Type of toxicity: Acute
Effect tested: LC50
Route of exposure: Inhalation.
Duration: 6 hour(s)
Value: > 10000 ppm
Animal test species: Rat
Test reference: OECD Guideline 403
Comments: ECHA
Type of toxicity: Acute
Effect tested: LD50
Route of exposure: Dermal
Duration: 24 hour(s)
Value: 16,4 ml/kg
Animal test species: Rabbit
Test reference: OECD Guideline 402
Comments: ECHA
2-Butoxyethanol
Type of toxicity: Acute
Effect tested: LD50
Route of exposure: Oral
Value: 1300 mg/kg
Animal test species: Rat
Type of toxicity: Acute
Effect tested: LD50
Route of exposure: Dermal
Value: 1100 mg/kg
Test reference: OECD Guideline 402
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Type of toxicity: Acute
Effect tested: LC50
Route of exposure: Inhalation.
Value: 1,5 mg/l
Other toxicological data
Toxicological tests on the product has not been performed.
Other information regarding health hazards
Assessment of acute toxicity, classification
Substance
Eye damage or irritation,
test results
Inhalation
Skin contact
Eye contact
Ingestion
Sensitisation
Mutagenicity
Carcinogenicity, other information
Reproductive toxicity
No evidence for acute toxicity.
Propan-2-ol
Toxicity type: Eye irritation
Method: OECD 405
Species: Rabbit
Evaluation result: Result: Irritation to eye.
No specific symptoms noted.
Skin irritation is not anticipated when used normally.
May cause temporary eye irritation.
Not likely, due to the packaging.
No evidence for respiratory nor skin sensitization.
No evidence for germ cell mutagenicity.
No evidence for carcinogenicity.
No evidence for reproductive toxicity.
Assessment of specific target organ SE, classification
Assessment of specific target organ toxicity RE, classification
Assessment of aspiration
hazard, classification
No evidence for STOT-single exposure.
No evidence for STOT-repeated exposure.
No evidence for aspiration hazard.
Symptoms of exposure
Symptoms of overexposure
No specific symptoms noted.
SECTION 12: Ecological information
12.1. Toxicity
Substance
Acute aquatic, fish
Substance
Propan-2-ol
Value: 8970 – 9280 mg/l
Test duration: 48 hour(s)
Species: Leuciscus idus melanotus
Method: LC50
2-Butoxyethanol
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Acute aquatic, fish
Substance
Acute aquatic, algae
Substance
Acute aquatic, algae
Substance
Acute aquatic, Daphnia
Substance
Value: 1474 mg/l
Test duration: 96h
Species: Oncorhynchus mykiss
Method: OECD TG 203
Propan-2-ol
Value: 1800 mg/l
Test duration: 8 day(s)
Species: Scenedesmus quadricauda
Method: TGK
2-Butoxyethanol
Value: 1840 mg/l
Test duration: 72 hour(s)
Species: Pseudokirchneriella subcapitata
Method: OECD TG 201
Propan-2-ol
Value: 9715 mg/l
Test duration: 24 hour(s)
Species: Daphnia magna
Method: LC50
2-Butoxyethanol
Acute aquatic, Daphnia
Aquatic, comments
Toxicity type: Acute
Value: 100 mg/l
Exposure time: 21 day(s)
Species: Daphnia magna
Method: NOEC
Value: 1550 mg/l
Test duration: 4h
Species: Daphnia magna
Method: OECD TG 202
No data available for the product.
12.2. Persistence and degradability
Substance
Biodegradability
Substance
Biodegradability
Propan-2-ol
Value: 95 %
Method: OECD 301E
Test period: 21 day(s)
2-Butoxyethanol
Value: 90 %
Method: OECD 301B
Test period: 28 day(s)
Persistence and degradability, comments
The product is easily biodegradable.
12.3. Bioaccumulative potential
Bioaccumulative potential
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The product is not bioaccumulating.
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12.4. Mobility in soil
Mobility
The product is water soluble and may spread in water systems.
12.5. Results of PBT and vPvB assessment
PBT assessment results
Not Classified as PBT/vPvB by current EU criteria.
12.6. Other adverse effects
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Specify the appropriate
methods of disposal
EWC waste code
EWL packing
Other information
Do not empty into drains; dispose of this material and its container in a safe way.
Dispose of waste and residues in accordance with local authority requirements.
EWC waste code: 0706
Classified as hazardous waste: No
EWC waste code: 0706
Classified as hazardous waste: No
Waste code applies to product remnants in pure form. When handling waste,
consideration should be made to the safety precautions applying to handling of the
product.
SECTION 14: Transport information
14.1. UN number
Comments
14.2. UN proper shipping name
Comments
14.3. Transport hazard class(es)
Comments
14.4. Packing group
Comments
14.5. Environmental hazards
Comments
14.6. Special precautions for user
The product is not covered by international regulation on the transport of dangerous
goods (IMDG, IATA, ADR/RID).
Not relevant.
Not relevant.
Not relevant.
Not relevant.
Special safety precautions
for user
No data recorded.
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
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ADN - Other information
Special provisions
Not relevant.
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations / legislation specific for the substance or mixture
Legislation and regulations
The Management of Health and Safety at Work Regulations 1999 (SI 1999 No. 3242).
EH40/2005, Workplace exposure limits 2005, with amendments.
The List of Wastes (England) (Amendment) Regulations 2005. (SI 2005 No. 895).
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18
December 2006 concerning the Registration, Evaluation, Authorisation and Restriction
of Chemicals (REACH), establishing a European Chemicals Agency, amending
Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and
Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and
Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including
amendments.
REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE
COUNCIL of 16 December 2008 on classification, labelling and packaging of
substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/
45/EC, and amending Regulation (EC) No 1907/2006.
REGULATION (EC) No 648/2004 OF THE EUROPEAN PARLIAMENT AND OF THE
COUNCIL of 31 March 2004 on detergents.
15.2. Chemical safety assessment
Chemical safety assessment
performed
No
SECTION 16: Other information
List of relevant H-phrases
(Section 2 and 3)
Training advice
Information added, deleted
or revised
Version
Prepared by
H225 Highly flammable liquid and vapour.
H302 Harmful if swallowed.
H312 Harmful in contact with skin.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H336 May cause drowsiness or dizziness.
No particular training or education is required but the user must be familiar with this
SDS.
Change to Sections: 1, 3, 4, 8, 11, 12, 13, 16
7
MP
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