Page 1
Safety Data Sheet
acc. to OSHA HCS
Printing date 12/10/2014
Reviewed on 12/10/2014
Page 1/8
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1 Identification
·
Product identifier
·
Trade name: DOCUFLUIDAL
·
Article number:
·
Relevant identified uses of the substance or mixture and uses advised against
100000001225
®
EF 121 red
Currently no such applications are identified
·
Application of the substance / the mixture
·
Details of the supplier of the safety data sheet
·
Manufacturer/Supplier:
Ball Pen Ink
DOKUMENTAL GmbH & Co KG Schreibfarben
Woellnerstraße 26
D-67065 Ludwigshafen
Phone + 49 (0)621/5402321
Fax + 49 (0)621/5402391
www. dokumental.de
·
Information department:
Technical Service, Dr. B. Polzin
Tel.: +49-621-5402322
Mobile +49-1726204412
E-Mail: bernd.polzin@dokumental.de
·
Emergency telephone number:
24-hour-Emergency- Telephone-Number (GBK Contract ID: 94050): (001) 352 323 3500
2 Hazard(s) identification
·
Classification of the substance or mixture
GHS08 Health hazard
Carc. 2 H351 Suspected of causing cancer.
GHS05 Corrosion
Eye Dam. 1 H318 Causes serious eye damage.
GHS09 Environment
Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects.
GHS07
Skin Irrit. 2 H315 Causes skin irritation.
Skin Sens. 1 H317 May cause an allergic skin reaction.
H227 Combustible liquid.
·
Label elements
·
GHS label elements
The product is classified and labeled according to the Globally Harmonized System (GHS).
·
Hazard pictograms
GHS05 GHS07 GHS08 GHS09
·
Signal word
·
Hazard-determining components of labeling:
Danger
Phosphoric acid mono-bis-(2-ethylhexyl)-ester
C. I. Solvent Red 49
C. I. Solvent Orange 3
·
Hazard statements
Combustible liquid.
Causes skin irritation.
Causes serious eye damage.
May cause an allergic skin reaction.
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(Contd. on page 2)
USA
Page 2
Safety Data Sheet
acc. to OSHA HCS
Trade name: DOCUFLUIDAL ® EF 121 red
Printing date 12/10/2014
Reviewed on 12/10/2014
Page 2/8
Suspected of causing cancer.
(Contd. of page 1)
Toxic to aquatic life with long lasting effects.
·
Precautionary statements
Keep away from flames and hot surfaces. – No smoking.
Avoid breathing dust/fume/gas/mist/vapors/spray
Wear protective gloves / eye protection / face protection.
Wear protective gloves.
Wear eye protection / face protection.
Avoid release to the environment.
Wash thoroughly after handling.
Contaminated work clothing must not be allowed out of the workplace.
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing.
Immediately call a poison center/doctor.
Specific treatment (see on this label).
Wash contaminated clothing before reuse.
IF exposed or concerned: Get medical advice/attention.
If skin irritation or rash occurs: Get medical advice/attention.
In case of fire: Use for extinction: CO2, powder or water spray.
If on skin: Wash with plenty of water.
Collect spillage.
Take off contaminated clothing and wash it before reuse.
Store locked up.
Store in a well-ventilated place. Keep cool.
Dispose of contents/container in accordance with local/regional/national/international regulations.
·
Classification system:
·
NFPA ratings (scale 0 - 4)
Health = 1
Fire = 1
110
Reactivity = 0
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*
·
HMIS-ratings (scale 0 - 4)
HEALTH
FIRE
REACTIVITY
·
Other hazards
·
Results of PBT and vPvB assessment
·
PBT:
·
vPvB:
1
1
0
Not applicable.
Not applicable.
Health = 1
Fire = 1
Reactivity = 0
3 Composition/information on ingredients
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Chemical characterization: Mixtures
Mixture of the following substances, containing non-hazardous substances and colouring agents.
·
Description:
·
Dangerous components:
Mixture of the substances listed below with nonhazardous additions.
122-99-6 2-Phenoxyethanol 25-50%
100-51-6 Benzyl alcohol 10-25%
107-41-5 2-methylpentane-2,4-diol 10-25%
12645-31-7 Phosphoric acid mono-bis-(2-ethylhexyl)-ester
509-34-2 C. I. Solvent Red 49
495-54-5 C. I. Solvent Orange 3
·
Additional information:
For the wording of the listed risk phrases refer to section 16.
4 First-aid measures
·
Description of first aid measures
·
General information:
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least
48 hours after the accident.
·
After inhalation:
In case of unconsciousness place patient stably in side position for transportation.
·
After skin contact:
Immediately wash with water and soap and rinse thoroughly.
Immediately rinse with water.
·
After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
·
After swallowing:
Immediately call a doctor.
(Contd. on page 3)
2.5%
2.5%
1.0%
USA
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Page 3
Safety Data Sheet
acc. to OSHA HCS
Trade name: DOCUFLUIDAL ® EF 121 red
Printing date 12/10/2014
Reviewed on 12/10/2014
Page 3/8
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Most important symptoms and effects, both acute and delayed
(Contd. of page 2)
No further relevant information available.
·
Indication of any immediate medical attention and special treatment needed
No further relevant information available.
5 Fire-fighting measures
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Extinguishing media
·
Suitable extinguishing agents:
CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant
foam.
·
Special hazards arising from the substance or mixture
·
Advice for firefighters
·
Protective equipment:
No special measures required.
No further relevant information available.
6 Accidental release measures
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Personal precautions, protective equipment and emergency procedures
·
Environmental precautions:
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water.
·
Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
·
Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
Wear protective clothing.
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7 Handling and storage
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Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
·
Information about protection against explosions and fires:
·
Conditions for safe storage, including any incompatibilities
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Storage:
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Requirements to be met by storerooms and receptacles:
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Information about storage in one common storage facility:
·
Further information about storage conditions:
·
Specific end use(s)
No further relevant information available.
Keep receptacle tightly sealed.
No special measures required.
No special requirements.
Not required.
8 Exposure controls/personal protection
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Additional information about design of technical systems:
·
Control parameters
·
Components with limit values that require monitoring at the workplace:
100-51-6 Benzyl alcohol (10-25%)
WEEL Long-term value: 10 ppm
107-41-5 2-methylpentane-2,4-diol (10-25%)
REL Ceiling limit value: 125 mg/m³, 25 ppm
TLV Ceiling limit value: 121 mg/m³, 25 ppm
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Additional information:
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Exposure controls
·
Personal protective equipment:
·
General protective and hygienic measures:
The lists that were valid during the creation were used as basis.
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
·
Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or
longer exposure use respiratory protective device that is independent of circulating air.
No further data; see item 7.
(Contd. on page 4)
USA
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Page 4
Safety Data Sheet
acc. to OSHA HCS
Trade name: DOCUFLUIDAL ® EF 121 red
Printing date 12/10/2014
Reviewed on 12/10/2014
Page 4/8
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Protection of hands:
(Contd. of page 3)
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the
preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the
preparation/ the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and
the degradation
·
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks
of quality and varies from manufacturer to manufacturer. As the product is a preparation of several
substances, the resistance of the glove material can not be calculated in advance and has therefore
to be checked prior to the application.
·
Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has
to be observed.
·
Eye protection:
Tightly sealed goggles
9 Physical and chemical properties
·
Information on basic physical and chemical properties
·
General Information
·
Appearance:
Form:
Color:
·
Odor:
·
Odour threshold:
·
Important information on protection of health and
environment, and on safety.
·
pH-value:
·
Change in condition
Melting point/Melting range:
Boiling point/Boiling range:
·
Flash point:
·
Flammability (solid, gaseous):
·
Ignition temperature:
·
Decomposition temperature:
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Auto igniting:
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Danger of explosion:
·
Explosion limits:
Lower:
Upper:
·
Vapor pressure at 20 °C (68 °F):
·
Density:
·
Relative density
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Vapour density
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Evaporation rate
·
Solubility in / Miscibility with
Water:
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Partition coefficient (n-octanol/water):
·
Viscosity:
Dynamic:
Kinematic:
·
Solvent content:
Organic solvents:
Fluid
According to product specification
Product specific
Not determined.
Not determined.
n.d. °C
Undetermined.
93 °C (199 °F)
Not applicable.
260 °C (500 °F)
Not determined.
Product is not selfigniting.
Not determined.
1.0 Vol %
13.0 Vol %
0.1 hPa
Not determined.
Not determined.
Not determined.
Not determined.
Not miscible or difficult to mix.
Not determined.
Not determined.
Not determined.
63.1 %
(Contd. on page 5)
USA
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Page 5
Safety Data Sheet
acc. to OSHA HCS
Trade name: DOCUFLUIDAL ® EF 121 red
·
Other information
*
10 Stability and reactivity
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Reactivity
·
Chemical stability
·
Thermal decomposition / conditions to be avoided:
No decomposition if used according to specifications.
·
Possibility of hazardous reactions
·
Conditions to avoid
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Incompatible materials:
·
Hazardous decomposition products:
*
11 Toxicological information
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Information on toxicological effects
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Acute toxicity:
·
LD/LC50 values that are relevant for classification:
122-99-6 2-Phenoxyethanol
Oral LD50 2740 mg/kg (rat)
·
Primary irritant effect:
·
on the skin:
·
on the eye:
·
Sensitization:
·
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for
preparations:
Harmful
Irritant
·
Carcinogenic categories
·
IARC (International Agency for Research on Cancer)
None of the ingredients is listed.
·
NTP (National Toxicology Program)
None of the ingredients is listed.
·
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
Irritant to skin and mucous membranes.
Irritating effect.
No sensitizing effects known.
No further relevant information available.
No dangerous reactions known.
No further relevant information available.
No further relevant information available.
No dangerous decomposition products known.
Printing date 12/10/2014
Reviewed on 12/10/2014
(Contd. of page 4)
Page 5/8
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12 Ecological information
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Toxicity
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Aquatic toxicity:
107-41-5 2-methylpentane-2,4-diol
LC50 / 96h 8.510 mg/l (Fish)
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Persistence and degradability
·
Bioaccumulative potential
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Mobility in soil
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Ecotoxical effects:
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Remark:
·
Additional ecological information:
·
General notes:
Harmful to fish
Water hazard class 2 (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
Harmful to aquatic organisms
·
Results of PBT and vPvB assessment
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PBT:
·
·
Not applicable.
vPvB:
Not applicable.
Other adverse effects
13 Disposal considerations
·
Waste treatment methods
·
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage
system.
No further relevant information available.
No further relevant information available.
No further relevant information available.
No further relevant information available.
(Contd. on page 6)
USA
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Page 6
Safety Data Sheet
acc. to OSHA HCS
Trade name: DOCUFLUIDAL ® EF 121 red
·
Uncleaned packagings:
·
Recommendation:
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14 Transport information
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UN-Number
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DOT, ADR, ADN, IMDG, IATA
·
UN proper shipping name
·
DOT, ADR, ADN, IMDG, IATA
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Transport hazard class(es)
·
DOT, ADR, ADN, IMDG, IATA
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Class
·
Packing group
·
DOT, ADR, IMDG, IATA
·
Environmental hazards:
·
Marine pollutant:
·
Special precautions for user
·
Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code
·
Transport/Additional information:
·
IMDG
·
Limited quantities (LQ)
·
Excepted quantities (EQ)
·
UN "Model Regulation":
Disposal must be made according to official regulations.
Printing date 12/10/2014
Reviewed on 12/10/2014
(Contd. of page 5)
Void
Void
Void
Void
Product contains environmentally hazardous substances:
C. I. Solvent Orange 3
No
Not applicable.
Not applicable.
5L
Code: E1
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 1000 ml
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15 Regulatory information
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Safety, health and environmental regulations/legislation specific for the substance or mixture
·
Sara
·
Section 355 (extremely hazardous substances):
None of the ingredient is listed.
·
Section 313 (Specific toxic chemical listings):
None of the ingredients is listed.
·
TSCA (Toxic Substances Control Act):
All ingredients are listed.
·
Proposition 65
·
Chemicals known to cause cancer:
None of the ingredients is listed.
·
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
·
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
·
Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
·
DSL/NDSL (Canada)
·
Cancerogenity categories
·
EPA (Environmental Protection Agency)
None of the ingredients is listed.
·
TLV (Threshold Limit Value established by ACGIH)
None of the ingredients is listed.
·
MAK (German Maximum Workplace Concentration)
None of the ingredients is listed.
·
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
·
GHS label elements
The product is classified and labeled according to the Globally Harmonized System (GHS).
All ingredients are listed
(Contd. on page 7)
USA
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Page 7
Safety Data Sheet
acc. to OSHA HCS
Trade name: DOCUFLUIDAL ® EF 121 red
Printing date 12/10/2014
Reviewed on 12/10/2014
Page 7/8
·
Hazard pictograms
(Contd. of page 6)
GHS05 GHS07 GHS08 GHS09
·
Signal word
·
Hazard-determining components of labeling:
Danger
Phosphoric acid mono-bis-(2-ethylhexyl)-ester
C. I. Solvent Red 49
C. I. Solvent Orange 3
·
Hazard statements
Combustible liquid.
Causes skin irritation.
Causes serious eye damage.
May cause an allergic skin reaction.
Suspected of causing cancer.
Toxic to aquatic life with long lasting effects.
·
Precautionary statements
Keep away from flames and hot surfaces. – No smoking.
Avoid breathing dust/fume/gas/mist/vapors/spray
Wear protective gloves / eye protection / face protection.
Wear protective gloves.
Wear eye protection / face protection.
Avoid release to the environment.
Wash thoroughly after handling.
Contaminated work clothing must not be allowed out of the workplace.
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing.
Immediately call a poison center/doctor.
Specific treatment (see on this label).
Wash contaminated clothing before reuse.
IF exposed or concerned: Get medical advice/attention.
If skin irritation or rash occurs: Get medical advice/attention.
In case of fire: Use for extinction: CO2, powder or water spray.
If on skin: Wash with plenty of water.
Collect spillage.
Take off contaminated clothing and wash it before reuse.
Store locked up.
Store in a well-ventilated place. Keep cool.
Dispose of contents/container in accordance with local/regional/national/international regulations.
·
National regulations:
·
Technical instructions (air):
Class Share in %
NK 50-100
·
Water hazard class:
·
Chemical safety assessment:
Water hazard class 2 (Self-assessment): hazardous for water.
A Chemical Safety Assessment has not been carried out.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee
for any specific product features and shall not establish a legally valid contractual relationship.
·
Date of preparation / last revision
·
Abbreviations and acronyms:
RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the
International Transport of Dangerous Goods by Rail)
IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA)
ICAO: International Civil Aviation Organisation
ICAO-TI: Technical Instructions by the "International Civil Aviation Organisation" (ICAO)
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage
of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
: Flammable liquids, Hazard Category 4
Skin Irrit. 2: Skin corrosion/irritation, Hazard Category 2
Eye Dam. 1: Serious eye damage/eye irritation, Hazard Category 1
Skin Sens. 1: Sensitisation - Skin, Hazard Category 1
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(Contd. on page 8)
USA
Page 8
Safety Data Sheet
acc. to OSHA HCS
Trade name: DOCUFLUIDAL ® EF 121 red
Printing date 12/10/2014
Reviewed on 12/10/2014
Page 8/8
Carc. 2: Carcinogenicity, Hazard Category 2
Aquatic Chronic 2: Hazardous to the aquatic environment - Chronic Hazard, Category 2
·
* Data compared to the previous version altered.
(Contd. of page 7)
USA
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