
Safety Data Sheet
acc. to OSHA HCS
Printing date 12/10/2014
Reviewed on 12/10/2014
Page 1/8
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1 Identification
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Product identifier
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Trade name: DOCUFLUIDAL
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Article number:
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Relevant identified uses of the substance or mixture and uses advised against
100000001225
®
EF 121 red
Currently no such applications are identified
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Application of the substance / the mixture
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Details of the supplier of the safety data sheet
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Manufacturer/Supplier:
Ball Pen Ink
DOKUMENTAL GmbH & Co KG Schreibfarben
Woellnerstraße 26
D-67065 Ludwigshafen
Phone + 49 (0)621/5402321
Fax + 49 (0)621/5402391
www. dokumental.de
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Information department:
Technical Service, Dr. B. Polzin
Tel.: +49-621-5402322
Mobile +49-1726204412
E-Mail: bernd.polzin@dokumental.de
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Emergency telephone number:
24-hour-Emergency- Telephone-Number (GBK Contract ID: 94050): (001) 352 323 3500
2 Hazard(s) identification
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Classification of the substance or mixture
GHS08 Health hazard
Carc. 2 H351 Suspected of causing cancer.
GHS05 Corrosion
Eye Dam. 1 H318 Causes serious eye damage.
GHS09 Environment
Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects.
GHS07
Skin Irrit. 2 H315 Causes skin irritation.
Skin Sens. 1 H317 May cause an allergic skin reaction.
H227 Combustible liquid.
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Label elements
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GHS label elements
The product is classified and labeled according to the Globally Harmonized System (GHS).
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Hazard pictograms
GHS05 GHS07 GHS08 GHS09
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Signal word
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Hazard-determining components of labeling:
Danger
Phosphoric acid mono-bis-(2-ethylhexyl)-ester
C. I. Solvent Red 49
C. I. Solvent Orange 3
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Hazard statements
Combustible liquid.
Causes skin irritation.
Causes serious eye damage.
May cause an allergic skin reaction.
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(Contd. on page 2)
USA

Safety Data Sheet
acc. to OSHA HCS
Trade name: DOCUFLUIDAL ® EF 121 red
Printing date 12/10/2014
Reviewed on 12/10/2014
Page 2/8
Suspected of causing cancer.
(Contd. of page 1)
Toxic to aquatic life with long lasting effects.
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Precautionary statements
Keep away from flames and hot surfaces. – No smoking.
Avoid breathing dust/fume/gas/mist/vapors/spray
Wear protective gloves / eye protection / face protection.
Wear protective gloves.
Wear eye protection / face protection.
Avoid release to the environment.
Wash thoroughly after handling.
Contaminated work clothing must not be allowed out of the workplace.
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing.
Immediately call a poison center/doctor.
Specific treatment (see on this label).
Wash contaminated clothing before reuse.
IF exposed or concerned: Get medical advice/attention.
If skin irritation or rash occurs: Get medical advice/attention.
In case of fire: Use for extinction: CO2, powder or water spray.
If on skin: Wash with plenty of water.
Collect spillage.
Take off contaminated clothing and wash it before reuse.
Store locked up.
Store in a well-ventilated place. Keep cool.
Dispose of contents/container in accordance with local/regional/national/international regulations.
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Classification system:
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NFPA ratings (scale 0 - 4)
Health = 1
Fire = 1
110
Reactivity = 0
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HMIS-ratings (scale 0 - 4)
HEALTH
FIRE
REACTIVITY
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Other hazards
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Results of PBT and vPvB assessment
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PBT:
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vPvB:
1
1
0
Not applicable.
Not applicable.
Health = 1
Fire = 1
Reactivity = 0
3 Composition/information on ingredients
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Chemical characterization: Mixtures
Mixture of the following substances, containing non-hazardous substances and colouring agents.
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Description:
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Dangerous components:
Mixture of the substances listed below with nonhazardous additions.
122-99-6 2-Phenoxyethanol 25-50%
100-51-6 Benzyl alcohol 10-25%
107-41-5 2-methylpentane-2,4-diol 10-25%
12645-31-7 Phosphoric acid mono-bis-(2-ethylhexyl)-ester
509-34-2 C. I. Solvent Red 49
495-54-5 C. I. Solvent Orange 3
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Additional information:
For the wording of the listed risk phrases refer to section 16.
4 First-aid measures
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Description of first aid measures
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General information:
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least
48 hours after the accident.
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After inhalation:
In case of unconsciousness place patient stably in side position for transportation.
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After skin contact:
Immediately wash with water and soap and rinse thoroughly.
Immediately rinse with water.
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After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
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After swallowing:
Immediately call a doctor.
(Contd. on page 3)
2.5%
2.5%
1.0%
USA
40.0

Safety Data Sheet
acc. to OSHA HCS
Trade name: DOCUFLUIDAL ® EF 121 red
Printing date 12/10/2014
Reviewed on 12/10/2014
Page 3/8
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Most important symptoms and effects, both acute and delayed
(Contd. of page 2)
No further relevant information available.
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Indication of any immediate medical attention and special treatment needed
No further relevant information available.
5 Fire-fighting measures
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Extinguishing media
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Suitable extinguishing agents:
CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant
foam.
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Special hazards arising from the substance or mixture
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Advice for firefighters
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Protective equipment:
No special measures required.
No further relevant information available.
6 Accidental release measures
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Personal precautions, protective equipment and emergency procedures
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Environmental precautions:
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water.
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Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
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Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
Wear protective clothing.
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7 Handling and storage
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Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
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Information about protection against explosions and fires:
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Conditions for safe storage, including any incompatibilities
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Storage:
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Requirements to be met by storerooms and receptacles:
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Information about storage in one common storage facility:
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Further information about storage conditions:
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Specific end use(s)
No further relevant information available.
Keep receptacle tightly sealed.
No special measures required.
No special requirements.
Not required.
8 Exposure controls/personal protection
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Additional information about design of technical systems:
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Control parameters
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Components with limit values that require monitoring at the workplace:
100-51-6 Benzyl alcohol (10-25%)
WEEL Long-term value: 10 ppm
107-41-5 2-methylpentane-2,4-diol (10-25%)
REL Ceiling limit value: 125 mg/m³, 25 ppm
TLV Ceiling limit value: 121 mg/m³, 25 ppm
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Additional information:
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Exposure controls
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Personal protective equipment:
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General protective and hygienic measures:
The lists that were valid during the creation were used as basis.
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
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Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or
longer exposure use respiratory protective device that is independent of circulating air.
No further data; see item 7.
(Contd. on page 4)
USA
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