Safety Data Sheet
acc. to OSHA HCS
Printing date 12/10/2014
Reviewed on 12/10/2014
Page 1/7
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1 Identification
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Product identifier
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Trade name: DOCUFLUIDAL
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Article number:
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Relevant identified uses of the substance or mixture and uses advised against
100000001160
®
EF 110 black
Currently no such applications are identified
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Application of the substance / the mixture
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Details of the supplier of the safety data sheet
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Manufacturer/Supplier:
Ball Pen Ink
DOKUMENTAL GmbH & Co KG Schreibfarben
Woellnerstraße 26
D-67065 Ludwigshafen
Phone + 49 (0)621/5402321
Fax + 49 (0)621/5402391
www. dokumental.de
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Information department:
Technical Service, Dr. B. Polzin
Tel.: +49-621-5402322
Mobile +49-1726204412
E-Mail: bernd.polzin@dokumental.de
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Emergency telephone number:
24-hour-Emergency- Telephone-Number (GBK Contract ID: 94050): (001) 352 323 3500
2 Hazard(s) identification
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Classification of the substance or mixture
GHS05 Corrosion
Eye Dam. 1 H318 Causes serious eye damage.
GHS07
Acute Tox. 4 H302 Harmful if swallowed.
Skin Irrit. 2 H315 Causes skin irritation.
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Label elements
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GHS label elements
The product is classified and labeled according to the Globally Harmonized System (GHS).
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Hazard pictograms
GHS05 GHS07
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Signal word
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Hazard-determining components of labeling:
Danger
2-Phenoxyethanol
C. I. Solvent Black 46
Phosphoric acid mono-bis-(2-ethylhexyl)-ester
Benzyl alcohol
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Hazard statements
Harmful if swallowed.
Causes skin irritation.
Causes serious eye damage.
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Precautionary statements
Wear protective gloves.
Wear eye protection / face protection.
Wash thoroughly after handling.
Do not eat, drink or smoke when using this product.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing.
Immediately call a poison center/doctor.
Specific treatment (see on this label).
If swallowed: Call a poison center/doctor if you feel unwell.
If skin irritation occurs: Get medical advice/attention.
Rinse mouth.
If on skin: Wash with plenty of water.
Take off contaminated clothing and wash it before reuse.
Dispose of contents/container in accordance with local/regional/national/international regulations.
(Contd. on page 2)
USA
40.0
Safety Data Sheet
acc. to OSHA HCS
Trade name: DOCUFLUIDAL ® EF 110 black
Printing date 12/10/2014
Reviewed on 12/10/2014
Page 2/7
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Classification system:
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NFPA ratings (scale 0 - 4)
(Contd. of page 1)
Health = 2
Fire = 1
210
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HMIS-ratings (scale 0 - 4)
HEALTH
FIRE
REACTIVITY
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Other hazards
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Results of PBT and vPvB assessment
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PBT:
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Not applicable.
vPvB:
Not applicable.
Reactivity = 0
2
1
0
Health = 2
Fire = 1
Reactivity = 0
3 Composition/information on ingredients
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Chemical characterization: Mixtures
Mixture of the following substances, containing non-hazardous substances and colouring agents.
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Description:
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Dangerous components:
122-99-6 2-Phenoxyethanol 25-50%
65113-55-5 C. I. Solvent Black 46 10-25%
100-51-6 Benzyl alcohol 10-25%
12645-31-7 Phosphoric acid mono-bis-(2-ethylhexyl)-ester
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Additional information:
Mixture of the substances listed below with nonhazardous additions.
For the wording of the listed risk phrases refer to section 16.
2.5%
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4 First-aid measures
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Description of first aid measures
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General information:
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least
48 hours after the accident.
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After inhalation:
In case of unconsciousness place patient stably in side position for transportation.
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After skin contact:
Immediately wash with water and soap and rinse thoroughly.
Immediately rinse with water.
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After eye contact:
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After swallowing:
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Most important symptoms and effects, both acute and delayed
Rinse opened eye for several minutes under running water. Then consult a doctor.
Immediately call a doctor.
No further relevant information available.
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Indication of any immediate medical attention and special treatment needed
No further relevant information available.
5 Fire-fighting measures
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Extinguishing media
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Suitable extinguishing agents:
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Special hazards arising from the substance or mixture
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Advice for firefighters
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Protective equipment:
No special measures required.
Use fire fighting measures that suit the environment.
No further relevant information available.
6 Accidental release measures
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Personal precautions, protective equipment and emergency procedures
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Environmental precautions:
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Methods and material for containment and cleaning up:
Do not allow to enter sewers/ surface or ground water.
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
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Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
Wear protective clothing.
(Contd. on page 3)
USA
40.0
Safety Data Sheet
acc. to OSHA HCS
Trade name: DOCUFLUIDAL ® EF 110 black
Printing date 12/10/2014
Reviewed on 12/10/2014
Page 3/7
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See Section 13 for disposal information.
(Contd. of page 2)
7 Handling and storage
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Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
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Information about protection against explosions and fires:
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Conditions for safe storage, including any incompatibilities
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Storage:
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Requirements to be met by storerooms and receptacles:
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Information about storage in one common storage facility:
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Further information about storage conditions:
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Specific end use(s)
No further relevant information available.
None.
No special measures required.
No special requirements.
Not required.
8 Exposure controls/personal protection
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Additional information about design of technical systems:
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Control parameters
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Components with limit values that require monitoring at the workplace:
100-51-6 Benzyl alcohol (10-25%)
WEEL Long-term value: 10 ppm
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Additional information:
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Exposure controls
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Personal protective equipment:
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General protective and hygienic measures:
The lists that were valid during the creation were used as basis.
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the skin.
Avoid contact with the eyes and skin.
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Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or
longer exposure use respiratory protective device that is independent of circulating air.
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Protection of hands:
No further data; see item 7.
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Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the
preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the
preparation/ the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and
the degradation
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Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks
of quality and varies from manufacturer to manufacturer. As the product is a preparation of several
substances, the resistance of the glove material can not be calculated in advance and has therefore
to be checked prior to the application.
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Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has
to be observed.
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Eye protection:
Tightly sealed goggles
9 Physical and chemical properties
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Information on basic physical and chemical properties
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General Information
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Appearance:
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Form:
Color:
Odor:
Fluid
According to product specification
Product specific
(Contd. on page 4)
USA
40.0