SAFETY DATA SHEET
Revision Date 11-May-2015 Revision Number 2Issuing Date No data available
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The supplier identified below generated this SDS using the UL SDS template. UL did not test, certify, or approve the substance described in this SDS, and
all information in this SDS was provided by the supplier or was reproduced from publically available regulatory data sources. UL makes no representations
or warranties regarding the completeness or accuracy of the information in this SDS and disclaims all liability in connection with the use of this information
or the substance described in this SDS. The layout, appearance and format of this SDS is © 2014 UL LLC. All rights reserved.
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1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product identifier
Product Name ball point pen blue ink
Other means of identification
Synonyms
Recommended use of the chemical and restrictions on use
Recommended Use
Uses advised against
Details of the supplier of the safety data sheet
Supplier Name
Supplier Address
Supplier Phone Number
Supplier Email
Emergency telephone number
None
Pens
No information available
Wenzhou Aihao Pen Trade Co., Ltd
No.128, Wenchang Road, Longwan Zone
Wenzhou
Zhejiang
325011
CN
Phone:86-13524536325
Contact Phone86-021-68622126
732314056@qq.com
2. HAZARDS IDENTIFICATION
Classification
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Serious eye damage/eye irritation Category 2
GHS Label elements, including precautionary statements
Emergency Overview
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Signal word Warning
Hazard Statements
Causes serious eye irritation
Appearance / Physical state Solid Odor Odorless
Precautionary Statements - Prevention
Wash face, hands and any exposed skin thoroughly after handling
Wear protective gloves/protective clothing/eye protection/face protection
Wear eye/face protection
Precautionary Statements - Response
Eyes
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
If eye irritation persists: Get medical advice/attention
Precautionary Statements - Storage
None
Precautionary Statements - Disposal
None
Hazards not otherwise classified (HNOC)
Not applicable
Unknown Toxicity
26% of the mixture consists of ingredient(s) of unknown toxicity
Other information
May be harmful if swallowed
Harmful to aquatic life with long lasting effects
Interactions with Other Chemicals
No information available.
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3. COMPOSITION/INFORMATION ON INGREDIENTS
.
Chemical Name CAS No Weight-% Trade Secret
2-phenoxyethanol 122-99-6 10 - 30 *
Phthalocyanine blue
Benzyl alcohol 100-51-6 10 - 30 *
Triethanolamine 102-71-6 1 - 5 *
*The exact percentage (concentration) of composition has been withheld as a trade secret
147-14-8 10 - 30 *
4. FIRST AID MEASURES
First aid measures
Eye contact
Rinse immediately with plenty of water, also under the eyelids, for at least 15
minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Keep eye wide open while rinsing. Do not rub affected area. Get medical attention
if irritation develops and persists.
Skin contact
Inhalation
Ingestion
Wash with soap and water.
Remove to fresh air.
Rinse mouth immediately and drink plenty of water. Never give anything by mouth
to an unconscious person. Do NOT induce vomiting. Call a physician.
Most important symptoms and effects, both acute and delayed
Most Important Symptoms and
Burning sensation.
Effects
Indication of any immediate medical attention and special treatment needed
Notes to Physician
Treat symptomatically.
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5. FIRE-FIGHTING MEASURES
Suitable Extinguishing Media
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Unsuitable extinguishing media
CAUTION: Use of water spray when fighting fire may be inefficient.
Specific hazards arising from the chemical
No information available.
Uniform Fire Code
Hazardous Combustion Products
Carbon oxides.
Explosion Data
Sensitivity to Mechanical Impact
Sensitivity to Static Discharge
Protective equipment and precautions for firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear.
Irritant: Solid
No.
No.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal precautions
Other Information
Environmental precautions
Environmental precautions
Avoid contact with skin, eyes or clothing. Use personal protective equipment as required.
Refer to protective measures listed in Sections 7 and 8.
Refer to protective measures listed in Sections 7 and 8.
Methods and material for containment and cleaning up
Methods for containment
Methods for cleaning up
Prevent further leakage or spillage if safe to do so.
Pick up and transfer to properly labeled containers.
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7. HANDLING AND STORAGE
Precautions for safe handling
Handling
Handle in accordance with good industrial hygiene and safety practice. Avoid contact with
skin, eyes or clothing. Do not eat, drink or smoke when using this product.
Conditions for safe storage, including any incompatibilities
Storage
Incompatible Products
Keep containers tightly closed in a dry, cool and well-ventilated place.
None known based on information supplied.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Exposure Guidelines
Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH
Phthalocyanine blue
147-14-8
Triethanolamine
102-71-6
ACGIH TLV: American Conference of Governmental Industrial Hygienists - Threshold Limit Value OSHA PEL: Occupational Safety and Health
Administration - Permissible Exposure Limits Immediately Dangerous to Life or Health
Appropriate engineering controls
TWA: 1 mg/m3 Cu dust and mist - IDLH: 100 mg/m3 Cu dust and
TWA: 1 mg/m3 Cu dust and mist
TWA: 5 mg/m
3
-
mist
Engineering Measures
Showers
Eyewash stations
Ventilation systems
Individual protection measures, such as personal protective equipment
Eye/face protection
If splashes are likely to occur:. Wear safety glasses with side shields (or goggles). None
required for consumer use.
Skin and body protection
Respiratory protection
Wear protective gloves and protective clothing.
No protective equipment is needed under normal use conditions. If exposure limits are
exceeded or irritation is experienced, ventilation and evacuation may be required.
Hygiene Measures
Handle in accordance with good industrial hygiene and safety practice. Avoid contact with
skin, eyes or clothing. Wear suitable gloves and eye/face protection. Do not eat, drink or
smoke when using this product.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical and Chemical Properties
Physical state
Appearance
Color
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Solid
/
No information available
Odor
Odor Threshold
Odorless
No information available
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Property
pH
Melting / freezing point
Boiling point / boiling range
Flash Point
Evaporation Rate
Flammability (solid, gas)
Flammability Limit in Air
Upper flammability limit
Lower flammability limit
Vapor pressure
Vapor density
Specific Gravity
Water Solubility
Solubility in other solvents
Partition coefficient: n-octanol/water
Autoignition temperature
Decomposition temperature
Kinematic viscosity
Dynamic viscosity
Explosive properties
Oxidizing properties
Other Information
Softening Point
VOC Content (%)
Particle Size
Particle Size Distribution
Values
No data available
No data available
No data available
No data available
No data available
No data available
No data available
No data available
No data available
No data available
No data available
Difficult solubility
No data available
1.2
No data available None known
No data available
No data available
19
No data available
No data available
No data available
No data available
No data available
Remarks Method
None known
None known
None known
None known
None known
None known
None known
None known
None known
None known
None known
None known
None known
None known
None known
10. STABILITY AND REACTIVITY
Reactivity
No data available.
Chemical stability
Stable under recommended storage conditions.
Possibility of Hazardous Reactions
None under normal processing.
Hazardous Polymerization
Hazardous polymerization does not occur.
Conditions to avoid
None known based on information supplied.
Incompatible materials
None known based on information supplied.
Hazardous Decomposition Products
Carbon oxides.
11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Product Information
Inhalation
.
Specific test data for the substance or mixture is not available. May cause irritation of
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respiratory tract.
Eye contact
Specific test data for the substance or mixture is not available. Expected to be an irritant
based on components. May cause redness, itching, and pain. May cause temporary eye
irritation.
Skin contact
Specific test data for the substance or mixture is not available. May cause irritation.
Prolonged contact may cause redness and irritation.
Ingestion
Specific test data for the substance or mixture is not available. Ingestion may cause
irritation to mucous membranes. Ingestion may cause gastrointestinal irritation, nausea,
vomiting and diarrhea.
Component Information
Chemical Name Oral LD50 Dermal LD50 Inhalation LC50
2-phenoxyethanol
122-99-6
Benzyl alcohol
100-51-6
Triethanolamine
102-71-6
= 1260 mg/kg ( Rat ) = 5 mL/kg ( Rabbit ) -
= 1230 mg/kg ( Rat ) = 2 g/kg ( Rabbit ) = 8.8 mg/L ( Rat ) 4 h
= 4190 mg/kg ( Rat ) > 20 mL/kg ( Rabbit ) -
Information on toxicological effects
Symptoms
May cause redness and tearing of the eyes.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Sensitization
Mutagenic Effects
Carcinogenicity
Chemical Name ACGIH IARC NTP OSHA
Triethanolamine
102-71-6
IARC (International Agency for Research on Cancer)
Group 3 - Not Classifiable as to Carcinogenicity in Humans
Reproductive toxicity
STOT - single exposure
STOT - repeated exposure
Chronic Toxicity
No information available.
No information available.
The table below indicates whether each agency has listed any ingredient as a carcinogen.
Group 3
No information available.
No information available.
No information available.
No known effect based on information supplied. May cause adverse liver effects.
Carcinogenic potential is unknown.
Target Organ Effects
Aspiration Hazard
Eyes. Kidney. Liver. Respiratory system. Skin.
No information available.
Numerical measures of toxicity Product Information
The following values are calculated based on chapter 3.1 of the GHS document
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ATEmix (oral)
2,243.00 mg/kg
ATEmix (dermal)
6,163.00 mg/kg (ATE)
ATEmix (inhalation-dust/mist)
7.40 mg/l
12. ECOLOGICAL INFORMATION
Ecotoxicity
Harmful to aquatic life with long lasting effects.
Chemical Name Toxicity to Algae Toxicity to Fish Toxicity to
2-phenoxyethanol
122-99-6
Phthalocyanine blue
147-14-8
Benzyl alcohol
100-51-6
Triethanolamine
102-71-6
72h EC50: > 500 mg/L
(Desmodesmus
subspicatus)
3h EC50: = 35 mg/L
(Anabaena variabilis)
96h EC50: = 169 mg/L
(Desmodesmus
subspicatus) 72h EC50: =
216 mg/L (Desmodesmus
subspicatus)
96h LC50: 337 - 352 mg/L
(Pimephales promelas) 96h
LC50: 220 - 460 mg/L
(Leuciscus idus) 96h LC50:
= 366 mg/L (Pimephales
promelas)
48h LC50: > 100 mg/L
(Oryzias latipes)
96h LC50: = 10 mg/L
(Lepomis macrochirus) 96h
LC50: = 460 mg/L
(Pimephales promelas)
96h LC50: 10600 - 13000
mg/L (Pimephales promelas)
96h LC50: > 1000 mg/L
(Pimephales promelas) 96h
LC50: 450 - 1000 mg/L
(Lepomis macrochirus)
EC50 = 32.4 mg/L 5 min
EC50 = 880 mg/L 17 h
EC50 = 50 mg/L 5 min
EC50 = 63.7 mg/L 15 min
EC50 = 63.7 mg/L 5 min
EC50 = 71.4 mg/L 30 min
Persistence and Degradability
No information available.
Bioaccumulation
Chemical Name Log Pow
2-phenoxyethanol
122-99-6
Phthalocyanine blue
147-14-8
Benzyl alcohol
100-51-6
Triethanolamine
102-71-6
Microorganisms
1.13
6.6
1.1
-2.53
Daphnia Magna (Water
Flea)
48h EC50: > 500 mg/L
48h EC50: = 23 mg/L
24h EC50: = 1386 mg/L
Other adverse effects
No information available.
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13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Disposal methods
Contaminated Packaging
California Hazardous Waste Codes
This product contains one or more substances that are listed with the State of California as a hazardous waste.
Chemical Name California Hazardous Waste
Phthalocyanine blue
147-14-8
This material, as supplied, is not a hazardous waste according to Federal regulations (40
CFR 261). This material could become a hazardous waste if it is mixed with or otherwise
comes in contact with a hazardous waste, if chemical additions are made to this material, or
if the material is processed or otherwise altered. Consult 40 CFR 261 to determine whether
the altered material is a hazardous waste. Consult the appropriate state, regional, or local
regulations for additional requirements.
Dispose of contents/containers in accordance with local regulations.
331
Toxic
14. TRANSPORT INFORMATION
DOT
Proper Shipping Name
Hazard Class
TDG
NOT REGULATED
NON REGULATED
N/A
Not regulated
MEX
ICAO
IATA
Proper Shipping Name
Hazard Class
IMDG/IMO
Hazard Class
RID
ADR
ADN
Not regulated
Not regulated
Not regulated
NON REGULATED
N/A
Not regulated
N/A
Not regulated
Not regulated
Not regulated
15. REGULATORY INFORMATION
International Inventories
TSCA Complies
DSL All components are listed either on the DSL or NDSL.
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
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US Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical
or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372
Chemical Name CAS No Weight-% SARA 313 - Threshold
Phthalocyanine blue - 147-14-8 147-14-8 10 - 30 1.0
Values %
SARA 311/312 Hazard Categories
Acute Health Hazard
Chronic Health Hazard
Fire Hazard
Sudden release of pressure hazard
Reactive Hazard
Yes
No
No
No
No
CWA (Clean Water Act)
This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21
and 40 CFR 122.42)
Chemical Name CWA - Reportable
Quantities
Phthalocyanine blue
147-14-8
CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous
Substances
X
CERCLA
This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and
Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level
pertaining to releases of this material
US State Regulations
California Proposition 65
This product does not contain any Proposition 65 chemicals.
U.S. State Right-to-Know Regulations
.
Chemical Name New Jersey Massachusetts Pennsylvania Rhode Island Illinois
2-phenoxyethanol
122-99-6
Phthalocyanine blue
147-14-8
Benzyl alcohol
100-51-6
Triethanolamine
102-71-6
X X
X X X
X X X
X X
International Regulations
Canada
WHMIS Hazard Class
D2B - Toxic materials
16. OTHER INFORMATION
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NFPA
Health Hazards 2 Flammability 0
Instability 0
Physical and
Chemical Hazards -
HMIS
Health Hazards 2
Flammability 0 Physical Hazard 0 Personal Protection
X
Prepared By
Product Stewardship
23 British American Blvd.
Latham, NY 12110
1-800-572-6501
Revision Date
Revision Note
11-May-2015
No information available
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at
the date of its publication. The information given is designed only as a guidance for safe handling, use, processing,
storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The
information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process, unless specified in the text
End of Safety Data Sheet
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