Tri-Flow TFF230000 User Manual

TRI-FLOW® Foaming Citrus Cleaner Degreaser

Not available.
Aerosol.

[phone]

SAFETY DATA SHEET

Product name

Other means of
identification

Product type

Emergency telephone
number of the company

Section 1. Identification

:

:
:

:

Manufacturer

:

Tri-Flow Industrial Group
Cleveland, OH 44115

Relevant identified uses of the substance or mixture and uses advised against

Not applicable.

TFF230000

TFF230000

Product code

:

Product Information
Telephone Number

:

Not available.

Regulatory Information
Telephone Number

:

[phone]

Transportation Emergency
Telephone Number

:

[phone]

Section 2. Hazards identification

FLAMMABLE AEROSOLS - Category 1
GASES UNDER PRESSURE - Compressed gas
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A
SKIN SENSITIZATION - Category 1
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2

Classification of the
substance or mixture

:

Signal word

:

Danger

Hazard pictograms

:

Precautionary statements

Prevention

:

Wear protective gloves. Wear eye or face protection. Keep away from heat, hot
surfaces, sparks, open flames and other ignition sources. No smoking. Do not spray on
an open flame or other ignition source. Do not breathe dust or mist. Wash hands
thoroughly after handling. Contaminated work clothing must not be allowed out of the
workplace. Pressurized container: Do not pierce or burn, even after use.

GHS label elements

Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 1.6%

OSHA/HCS status

:

This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).

Extremely flammable aerosol.
Contains gas under pressure; may explode if heated.
Causes serious eye irritation.
May cause an allergic skin reaction.
May cause damage to organs through prolonged or repeated exposure.

:

Hazard statements

Date of issue/Date of revision

:

6/28/2016

Date of previous issue

:

6/4/2016

Version

:

2.01

1/13

Section 2. Hazards identification

Response

:

Get medical attention if you feel unwell. IF ON SKIN: Wash with plenty of soap and
water. Wash contaminated clothing before reuse. If skin irritation or rash occurs: Get
medical attention. IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation
persists: Get medical attention.

Storage

:

Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F. Store in
a well-ventilated place.

Disposal

Dispose of contents and container in accordance with all local, regional, national and
international regulations.

Hazards not otherwise
classified

:

None known.

Please refer to the SDS for additional information. Keep out of reach of children. Keep
upright in a cool, dry place. Do not discard empty can in trash compactor.

Supplemental label
elements

DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which
can cause permanent brain and nervous system damage. Intentional misuse by
deliberately concentrating and inhaling the contents can be harmful or fatal. FOR
INDUSTRIAL USE ONLY.

:

Section 3. Composition/information on ingredients

Butane

3.42

106-97-8

d-Limonene

3

5989-27-5

2-Butoxyethanol

2

111-76-2

Propane

1.58

74-98-6

Tetrasodium Ethylenediaminetetraacetate

1.17

64-02-8

Ingredient name

CAS number

% by weight

There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health and hence require reporting in this section.

Other means of
identification

:

Not available.

Substance/mixture

CAS number/other identifiers

:

Occupational exposure limits, if available, are listed in Section 8.

Mixture

Any concentration shown as a range is to protect confidentiality or is due to batch variation.

Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.

Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash
contaminated clothing thoroughly with water before removing it, or wear gloves.
Continue to rinse for at least 10 minutes. Get medical attention. In the event of any
complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean
shoes thoroughly before reuse.

Remove victim to fresh air and keep at rest in a position comfortable for breathing. If
not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial
respiration or oxygen by trained personnel. It may be dangerous to the person providing
aid to give mouth-to-mouth resuscitation. Get medical attention following exposure or if
feeling unwell. If unconscious, place in recovery position and get medical attention
immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt
or waistband. In case of inhalation of decomposition products in a fire, symptoms may
be delayed. The exposed person may need to be kept under medical surveillance for
48 hours.

Section 4. First aid measures

Eye contact

Skin contact

Inhalation

:

:

:

Description of necessary first aid measures

Date of issue/Date of revision

:

6/28/2016

Date of previous issue

:

6/4/2016

Version

:

2.01

2/13

Section 4. First aid measures

Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and
keep at rest in a position comfortable for breathing. If material has been swallowed and
the exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention following
exposure or if feeling unwell. Never give anything by mouth to an unconscious person.
If unconscious, place in recovery position and get medical attention immediately.
Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Ingestion

:

Protection of first-aiders

:

No action shall be taken involving any personal risk or without suitable training. It may
be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash
contaminated clothing thoroughly with water before removing it, or wear gloves.

Notes to physician

:

In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.

Specific treatments

:

No specific treatment.

Most important symptoms/effects, acute and delayed

Inhalation

:

No known significant effects or critical hazards.

No known significant effects or critical hazards.

:

Ingestion

Skin contact

:

May cause an allergic skin reaction.

Causes serious eye irritation.

:

Eye contact

Over-exposure signs/symptoms

Skin contact

Ingestion

Inhalation

Adverse symptoms may include the following:
respiratory tract irritation
coughing

No specific data.

Adverse symptoms may include the following:
irritation
redness

:

:

:

Eye contact

:

Adverse symptoms may include the following:
pain or irritation
watering
redness

Potential acute health effects

See toxicological information (Section 11)

Indication of immediate medical attention and special treatment needed, if necessary

Section 5. Fire-fighting measures

Specific hazards arising
from the chemical

Extremely flammable aerosol. In a fire or if heated, a pressure increase will occur and
the container may burst, with the risk of a subsequent explosion. Gas may accumulate
in low or confined areas or travel a considerable distance to a source of ignition and
flash back, causing fire or explosion. Bursting aerosol containers may be propelled from
a fire at high speed. Runoff to sewer may create fire or explosion hazard.

Use an extinguishing agent suitable for the surrounding fire.

Extinguishing media

:

None known.

Suitable extinguishing
media

:

Unsuitable extinguishing
media

:

Date of issue/Date of revision

:

6/28/2016

Date of previous issue

:

6/4/2016

Version

:

2.01

3/13

Section 5. Fire-fighting measures

Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.

Hazardous thermal
decomposition products

Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
nitrogen oxides
metal oxide/oxides

Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Special protective
equipment for fire-fighters

:

:

Special protective actions
for fire-fighters

:

Section 6. Accidental release measures

Environmental precautions

Personal precautions, protective equipment and emergency procedures

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.

:

:

No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. In the case of aerosols being ruptured, care should be taken due to the rapid
escape of the pressurized contents and propellant. If a large number of containers are
ruptured, treat as a bulk material spillage according to the instructions in the clean-up
section. Do not touch or walk through spilled material. Shut off all ignition sources. No
flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).

Large spill

:

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.

Small spill

:

Methods and materials for containment and cleaning up

For non-emergency
personnel

For emergency responders

:

If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non­emergency personnel".

Section 7. Handling and storage

Precautions for safe handling

Date of issue/Date of revision

:

6/28/2016

Date of previous issue

:

6/4/2016

Version

:

2.01

4/13

Section 7. Handling and storage

Advice on general
occupational hygiene

Conditions for safe storage,
including any
incompatibilities

Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.

Store in accordance with local regulations. Store away from direct sunlight in a dry, cool
and well-ventilated area, away from incompatible materials (see Section 10) and food
and drink. Protect from sunlight. Eliminate all ignition sources. Use appropriate
containment to avoid environmental contamination.

:
:

Protective measures

Put on appropriate personal protective equipment (see Section 8). Persons with a
history of skin sensitization problems should not be employed in any process in which
this product is used. Pressurized container: protect from sunlight and do not expose to
temperatures exceeding 50°C. Do not pierce or burn, even after use. Do not get in
eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. Avoid
breathing gas. Use only with adequate ventilation. Wear appropriate respirator when
ventilation is inadequate. Store and use away from heat, sparks, open flame or any
other ignition source. Use explosion-proof electrical (ventilating, lighting and material
handling) equipment. Use only non-sparking tools. Empty containers retain product
residue and can be hazardous.

:

Butane

NIOSH REL (United States, 10/2013).

TWA: 800 ppm 10 hours.
TWA: 1900 mg/m³ 10 hours.

ACGIH TLV (United States, 3/2015).

STEL: 1000 ppm 15 minutes.

d-Limonene

None.

2-Butoxyethanol

ACGIH TLV (United States, 3/2015).

TWA: 20 ppm 8 hours.

NIOSH REL (United States, 10/2013).
Absorbed through skin.

TWA: 5 ppm 10 hours.
TWA: 24 mg/m³ 10 hours.

OSHA PEL (United States, 2/2013).
Absorbed through skin.

TWA: 50 ppm 8 hours.
TWA: 240 mg/m³ 8 hours.

Propane

NIOSH REL (United States, 10/2013).

TWA: 1000 ppm 10 hours.
TWA: 1800 mg/m³ 10 hours.

OSHA PEL (United States, 2/2013).

TWA: 1000 ppm 8 hours.
TWA: 1800 mg/m³ 8 hours.

tetrasodium ethylene diamine tetraacetate

None.

Section 8. Exposure controls/personal protection

Ingredient name

Exposure limits

Control parameters

Occupational exposure limits (OSHA United States)

None.

Ingredient name

Exposure limits

Occupational exposure limits (Canada)

Date of issue/Date of revision

:

6/28/2016

Date of previous issue

:

6/4/2016

Version

:

2.01

5/13

Section 8. Exposure controls/personal protection

Hand protection

Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.

Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.

Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.

Eye/face protection

Respiratory protection

:

:

:

Body protection

Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti­static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.

:

Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.

Appropriate engineering
controls

:

Use only with adequate ventilation. If user operations generate dust, fumes, gas, vapor
or mist, use process enclosures, local exhaust ventilation or other engineering controls
to keep worker exposure to airborne contaminants below any recommended or statutory
limits. The engineering controls also need to keep gas, vapor or dust concentrations
below any lower explosive limits. Use explosion-proof ventilation equipment.

Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.

Hygiene measures

:

Individual protection measures

Skin protection

Other skin protection

:

Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.

Environmental exposure
controls

:

Section 9. Physical and chemical properties

Physical state

Melting point

Liquid.

Not available.

Not available.

Odor

pH

Not available.

Color

Evaporation rate

0.09 (butyl acetate = 1)

Flash point

Closed cup: -29°C (-20.2°F) [Pensky-Martens Closed Cup]

7

Not available.

Odor threshold

:

:::

:::

:

Appearance

Boiling point

:

Not available.

Flammability (solid, gas)

:

Not available.

Date of issue/Date of revision

:

6/28/2016

Date of previous issue

:

6/4/2016

Version

:

2.01

6/13

Section 9. Physical and chemical properties

Vapor pressure

Relative density

Vapor density

Solubility

0.96

0.012 [Air = 1]

13.5 kPa (101.325 mm Hg) [at 20°C]

Not available.

Auto-ignition temperature

Not available.

Not available.

Viscosity

Kinematic (room temperature): >0.205 cm2/s (>20.5 cSt)
Kinematic (40°C (104°F)): >0.205 cm2/s (>20.5 cSt)

Partition coefficient: n­octanol/water

:

:

:

:
:

:

:

Lower and upper explosive
(flammable) limits

:

Lower: 0.7%
Upper: 10.6%

Decomposition temperature

:

Not available.

Type of aerosol

:

Spray

Heat of combustion

:

4.792 kJ/g

Aerosol product

Molecular weight

:

Not applicable.

Section 10. Stability and reactivity

Hazardous decomposition
products

Conditions to avoid

Avoid all possible sources of ignition (spark or flame).

Under normal conditions of storage and use, hazardous decomposition products should
not be produced.

The product is stable.

Chemical stability

No specific data.

:

:

:

Incompatible materials

:

Possibility of hazardous
reactions

:

Under normal conditions of storage and use, hazardous reactions will not occur.

Reactivity

:

No specific test data related to reactivity available for this product or its ingredients.

Section 11. Toxicological information

Acute toxicity

Butane

LC50 Inhalation Vapor

Rat

658000 mg/m³

4 hours

d-Limonene

LD50 Dermal

Rabbit

>5000 mg/kg

-

LD50 Oral

Rat

4400 mg/kg

-

2-Butoxyethanol

LCLo Inhalation Vapor

Guinea pig

>3.1 mg/l

1 hours

LD50 Dermal

Guinea pig

>2000 mg/kg

-

LD50 Oral

Rat

1300 mg/kg

-

tetrasodium ethylene diamine
tetraacetate

LD50 Oral

Rat

10 g/kg

-

Product/ingredient name

Result

Species

Dose

Exposure

Irritation/Corrosion

Information on toxicological effects

Date of issue/Date of revision

:

6/28/2016

Date of previous issue

:

6/4/2016

Version

:

2.01

7/13

Section 11. Toxicological information

Carcinogenicity

Not available.

Mutagenicity

Not available.

Teratogenicity

Not available.

Reproductive toxicity

Not available.

d-Limonene

Skin - Mild irritant

Rabbit

-

24 hours 10
Percent

-

2-Butoxyethanol

Eyes - Moderate irritant

Rabbit

-

24 hours 100
milligrams

-

Eyes - Severe irritant

Rabbit

-

100
milligrams

-

Skin - Mild irritant

Rabbit

-

500
milligrams

-

tetrasodium ethylene diamine
tetraacetate

Eyes - Moderate irritant

Rabbit

-

24 hours 100
milligrams

-

Skin - Moderate irritant

Rabbit

-

24 hours 500
milligrams

-

Product/ingredient name

Result

Score

Exposure

Observation

Sensitization

Not available.

Species

Specific target organ toxicity (single exposure)

Specific target organ toxicity (repeated exposure)

Butane

Category 3

Not applicable.

Respiratory tract
irritation and
Narcotic effects

d-Limonene

Category 3

Not applicable.

Respiratory tract
irritation and
Narcotic effects

2-Butoxyethanol

Category 3

Not applicable.

Respiratory tract
irritation and
Narcotic effects

Propane

Category 3

Not applicable.

Respiratory tract
irritation and
Narcotic effects

Name

Category

Name

Category

Butane

Category 2

Not determined

Not determined

d-Limonene

Category 2

Not determined

Not determined

2-Butoxyethanol

Category 2

Not determined

Not determined

Propane

Category 2

Not determined

Not determined

Aspiration hazard

Route of
exposure

Target organs

Route of
exposure

Target organs
Classification

d-Limonene

-3-

2-Butoxyethanol

-3-

Product/ingredient name

NTP

IARC

OSHA

Date of issue/Date of revision

:

6/28/2016

Date of previous issue

:

6/4/2016

Version

:

2.01

8/13

Section 11. Toxicological information

Name

Result

Butane

ASPIRATION HAZARD - Category 1

d-Limonene

ASPIRATION HAZARD - Category 1

Propane

ASPIRATION HAZARD - Category 1

Not available.

Information on the likely
routes of exposure

Inhalation

:

No known significant effects or critical hazards.

No known significant effects or critical hazards.

:

Ingestion

Skin contact

:

May cause an allergic skin reaction.

Causes serious eye irritation.

:

Eye contact

May cause damage to organs through prolonged or repeated exposure. Once
sensitized, a severe allergic reaction may occur when subsequently exposed to very low
levels.

General

:

No known significant effects or critical hazards.

Carcinogenicity

:

No known significant effects or critical hazards.

Mutagenicity

:

No known significant effects or critical hazards.

Teratogenicity

:

Developmental effects

:

No known significant effects or critical hazards.

Fertility effects

:

No known significant effects or critical hazards.

Symptoms related to the physical, chemical and toxicological characteristics

Skin contact

Ingestion

Inhalation

Adverse symptoms may include the following:
respiratory tract irritation
coughing

No specific data.

Adverse symptoms may include the following:
irritation
redness

:

:

:

Eye contact

:

Adverse symptoms may include the following:
pain or irritation
watering
redness

Potential chronic health effects

Delayed and immediate effects and also chronic effects from short and long term exposure

Numerical measures of toxicity

Acute toxicity estimates

:

Not available.

Potential acute health effects

Potential immediate
effects

:

Not available.

Short term exposure

Potential delayed effects

:

Not available.

Potential immediate
effects

:

Not available.

Long term exposure

Potential delayed effects

:

Not available.

Date of issue/Date of revision

:

6/28/2016

Date of previous issue

:

6/4/2016

Version

:

2.01

9/13

Oral

21928.5 mg/kg

Route

ATE value

Section 12. Ecological information

LogP

ow

BCF

Potential

Bioaccumulative potential

Other adverse effects

:

No known significant effects or critical hazards.

Product/ingredient name

tetrasodium ethylene diamine
tetraacetate

-

1.8

low

Product/ingredient name

Aquatic half-life

Photolysis

Biodegradability

2-Butoxyethanol

--Readily

Toxicity

d-Limonene

Acute EC50 421 µg/l Fresh water

Daphnia - Daphnia magna

48 hours

Acute EC50 688 µg/l Fresh water

Fish - Pimephales promelas ­Juvenile (Fledgling, Hatchling,
Weanling)

96 hours

2-Butoxyethanol

Acute EC50 >1000 mg/l Fresh water

Daphnia - Daphnia magna

48 hours

Acute LC50 800000 µg/l Marine water

Crustaceans - Crangon crangon

48 hours

Acute LC50 1250000 µg/l Marine water

Fish - Menidia beryllina

96 hours

tetrasodium ethylene diamine
tetraacetate

Acute LC50 486000 µg/l Fresh water

Fish - Lepomis macrochirus

96 hours

Product/ingredient name

Species

Result

Exposure

Persistence and degradability

Soil/water partition
coefficient (KOC)

:

Not available.

Mobility in soil

Section 13. Disposal considerations

The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Empty containers or liners may retain some product residues. Do not
puncture or incinerate container.

:

Disposal methods

Date of issue/Date of revision

:

6/28/2016

Date of previous issue

:

6/4/2016

Version

:

2.01

10/13

Section 14. Transport information

AEROSOLS

2.2

-

AEROSOLS

2.2

-

UN1950

UN1950

-

Emergency
schedules (EmS)

LIMITED
QUANTITY, F-D,
S-U

DOT

Classification

IMDG

UN number

UN proper
shipping name

Transport
hazard class(es)

Packing group

Additional
information

Environmental
hazards

Special precautions for user

Transport in bulk according
to Annex II of MARPOL and
the IBC Code

No.

No.
Not available.

:

Proper shipping name

:

Ship type

:

Not available.

Pollution category

:

Not available.

Not available.

:

TDG

Classification

UN1950

AEROSOLS

2.2

-

No.

Product classified
as per the
following sections
of the
Transportation of
Dangerous Goods
Regulations: 2.
13-2.17 (Class 2).

Mexico

Classification

UN1950

AEROSOLS

2.2

-

No.

-

Multi-modal shipping descriptions are provided for informational purposes and do not
consider container sizes. The presence of a shipping description for a particular
mode of transport (sea, air, etc.), does not indicate that the product is packaged
suitably for that mode of transport. All packaging must be reviewed for suitability
prior to shipment, and compliance with the applicable regulations is the sole
responsibility of the person offering the product for transport. People loading and
unloading dangerous goods must be trained on all of the risks deriving from the
substances and on all actions in case of emergency situations.

IATA

UN1950

Aerosols, non­flammable

2.2

-

No.

-

Section 15. Regulatory information

SARA 313

SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet.

Not applicable.

California Prop. 65

Date of issue/Date of revision

:

6/28/2016

Date of previous issue

:

6/4/2016

Version

:

2.01

11/13

Section 16. Other information

6/28/2016

History

Date of printing

Date of issue/Date of
revision

Version

It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult
resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and
any hazards associated with the product. This information is provided in good faith and believed to be accurate
as of the effective date herein. However, no warranty, express or implied, is given. The information presented
here applies only to the product as shipped. The addition of any material can change the composition, hazards
and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed
by Sherwin-Williams, including but not limited to the incorporation of non Sherwin-Williams products or the use
or addition of products in proportions not specified by Sherwin-Williams. Regulatory requirements are subject
to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to
ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use
of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to
determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the
product for any purpose other than the purpose shown in the applicable section of this SDS without first
referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for
information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from

Notice to reader

Date of previous issue

:::

:

Key to abbreviations

:

ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations

6/28/2016

6/4/2016

2.01

Hazardous Material Information System (U.S.A.)

2

2

0

Health

Flammability

Physical hazards

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910.
1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS®
program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may
be purchased exclusively from J. J. Keller [phone].

The customer is responsible for determining the PPE code for this material.

Procedure used to derive the classification

Classification

Justification

FLAMMABLE AEROSOLS - Category 1

On basis of test data

GASES UNDER PRESSURE - Compressed gas

Calculation method

SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A

Calculation method

SKIN SENSITIZATION - Category 1

Calculation method

SPECIFIC TARGET ORGAN TOXICITY (REPEATED
EXPOSURE) - Category 2

Calculation method

Date of issue/Date of revision

:

6/28/2016

Date of previous issue

:

6/4/2016

Version

:

2.01

12/13

Section 16. Other information

any other source.

Date of issue/Date of revision

:

6/28/2016

Date of previous issue

:

6/4/2016

Version

:

2.01

13/13