Tri-Flow TFF230000 User Manual
TRI-FLOW® Foaming Citrus Cleaner Degreaser
Not available.
Aerosol.
(216) 566-2917
SAFETY DATA SHEET
Product name
Other means of
identification
Product type
Emergency telephone
number of the company
Section 1. Identification
:
:
:
:
Manufacturer
:
Tri-Flow Industrial Group
Cleveland, OH 44115
Relevant identified uses of the substance or mixture and uses advised against
Not applicable.
TFF230000
TFF230000
Product code
:
Product Information
Telephone Number
:
Not available.
Regulatory Information
Telephone Number
:
(216) 566-2902
Transportation Emergency
Telephone Number
:
(800) 424-9300
Section 2. Hazards identification
FLAMMABLE AEROSOLS - Category 1
GASES UNDER PRESSURE - Compressed gas
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A
SKIN SENSITIZATION - Category 1
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2
Classification of the
substance or mixture
:
Signal word
:
Danger
Hazard pictograms
:
Precautionary statements
Prevention
:
Wear protective gloves. Wear eye or face protection. Keep away from heat, hot
surfaces, sparks, open flames and other ignition sources. No smoking. Do not spray on
an open flame or other ignition source. Do not breathe dust or mist. Wash hands
thoroughly after handling. Contaminated work clothing must not be allowed out of the
workplace. Pressurized container: Do not pierce or burn, even after use.
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 1.6%
OSHA/HCS status
:
This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Extremely flammable aerosol.
Contains gas under pressure; may explode if heated.
Causes serious eye irritation.
May cause an allergic skin reaction.
May cause damage to organs through prolonged or repeated exposure.
:
Hazard statements
Date of issue/Date of revision
:
6/28/2016
Date of previous issue
:
6/4/2016
Version
:
2.01
1/13
Section 2. Hazards identification
Response
:
Get medical attention if you feel unwell. IF ON SKIN: Wash with plenty of soap and
water. Wash contaminated clothing before reuse. If skin irritation or rash occurs: Get
medical attention. IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation
persists: Get medical attention.
Storage
:
Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F. Store in
a well-ventilated place.
Disposal
Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Hazards not otherwise
classified
:
None known.
Please refer to the SDS for additional information. Keep out of reach of children. Keep
upright in a cool, dry place. Do not discard empty can in trash compactor.
Supplemental label
elements
DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which
can cause permanent brain and nervous system damage. Intentional misuse by
deliberately concentrating and inhaling the contents can be harmful or fatal. FOR
INDUSTRIAL USE ONLY.
:
Section 3. Composition/information on ingredients
Butane
3.42
106-97-8
d-Limonene
3
5989-27-5
2-Butoxyethanol
2
111-76-2
Propane
1.58
74-98-6
Tetrasodium Ethylenediaminetetraacetate
1.17
64-02-8
Ingredient name
CAS number
% by weight
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health and hence require reporting in this section.
Other means of
identification
:
Not available.
Substance/mixture
CAS number/other identifiers
:
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash
contaminated clothing thoroughly with water before removing it, or wear gloves.
Continue to rinse for at least 10 minutes. Get medical attention. In the event of any
complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean
shoes thoroughly before reuse.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If
not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial
respiration or oxygen by trained personnel. It may be dangerous to the person providing
aid to give mouth-to-mouth resuscitation. Get medical attention following exposure or if
feeling unwell. If unconscious, place in recovery position and get medical attention
immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt
or waistband. In case of inhalation of decomposition products in a fire, symptoms may
be delayed. The exposed person may need to be kept under medical surveillance for
48 hours.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
:
:
:
Description of necessary first aid measures
Date of issue/Date of revision
:
6/28/2016
Date of previous issue
:
6/4/2016
Version
:
2.01
2/13
Section 4. First aid measures
Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and
keep at rest in a position comfortable for breathing. If material has been swallowed and
the exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention following
exposure or if feeling unwell. Never give anything by mouth to an unconscious person.
If unconscious, place in recovery position and get medical attention immediately.
Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Ingestion
:
Protection of first-aiders
:
No action shall be taken involving any personal risk or without suitable training. It may
be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash
contaminated clothing thoroughly with water before removing it, or wear gloves.
Notes to physician
:
In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments
:
No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation
:
No known significant effects or critical hazards.
No known significant effects or critical hazards.
:
Ingestion
Skin contact
:
May cause an allergic skin reaction.
Causes serious eye irritation.
:
Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation
Adverse symptoms may include the following:
respiratory tract irritation
coughing
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact
:
Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential acute health effects
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Section 5. Fire-fighting measures
Specific hazards arising
from the chemical
Extremely flammable aerosol. In a fire or if heated, a pressure increase will occur and
the container may burst, with the risk of a subsequent explosion. Gas may accumulate
in low or confined areas or travel a considerable distance to a source of ignition and
flash back, causing fire or explosion. Bursting aerosol containers may be propelled from
a fire at high speed. Runoff to sewer may create fire or explosion hazard.
Use an extinguishing agent suitable for the surrounding fire.
Extinguishing media
:
None known.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Date of issue/Date of revision
:
6/28/2016
Date of previous issue
:
6/4/2016
Version
:
2.01
3/13
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Hazardous thermal
decomposition products
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
nitrogen oxides
metal oxide/oxides
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
:
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.
:
:
No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. In the case of aerosols being ruptured, care should be taken due to the rapid
escape of the pressurized contents and propellant. If a large number of containers are
ruptured, treat as a bulk material spillage according to the instructions in the clean-up
section. Do not touch or walk through spilled material. Shut off all ignition sources. No
flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Large spill
:
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Small spill
:
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders
:
If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For nonemergency personnel".
Section 7. Handling and storage
Precautions for safe handling
Date of issue/Date of revision
:
6/28/2016
Date of previous issue
:
6/4/2016
Version
:
2.01
4/13
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