Tri-Flow TFBP20030 User Manual

TRI-FLOW® Red Grease

Not available.
Spray

[phone]

SAFETY DATA SHEET

Product name

Other means of
identification

Product type

Emergency telephone
number of the company

Section 1. Identification

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:
:

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Manufacturer

:

Tri-Flow Industrial Group
Cleveland, OH 44115

Relevant identified uses of the substance or mixture and uses advised against

Not applicable.

TFBP20030

TFBP20030

Product code

:

Product Information
Telephone Number

:

Not available.

Regulatory Information
Telephone Number

:

[phone]

Transportation Emergency
Telephone Number

:

[phone]

Section 2. Hazards identification

FLAMMABLE AEROSOLS - Category 1
GASES UNDER PRESSURE - Compressed gas
SKIN CORROSION/IRRITATION - Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) ­Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2

Classification of the
substance or mixture

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Signal word

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Danger

Hazard pictograms

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Precautionary statements

GHS label elements

Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 28%

OSHA/HCS status

:

This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).

Extremely flammable aerosol.
Contains gas under pressure; may explode if heated.
Causes serious eye irritation.
Causes skin irritation.
May cause respiratory irritation.
May cause drowsiness or dizziness.
May cause damage to organs through prolonged or repeated exposure.

:

Hazard statements

Date of issue/Date of revision

:

6/28/2016

Date of previous issue

:

6/4/2016

Version

:

2.01

1/11

Section 2. Hazards identification

Prevention

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Wear protective gloves. Wear eye or face protection. Keep away from heat, hot
surfaces, sparks, open flames and other ignition sources. No smoking. Do not spray on
an open flame or other ignition source. Use only outdoors or in a well-ventilated area.
Do not breathe vapor. Wash hands thoroughly after handling. Pressurized container:
Do not pierce or burn, even after use.

Response

:

Get medical attention if you feel unwell. IF INHALED: Remove person to fresh air and
keep comfortable for breathing. Call a POISON CENTER or physician if you feel unwell.
IF ON SKIN: Wash with plenty of soap and water. Take off contaminated clothing and
wash it before reuse. If skin irritation occurs: Get medical attention. IF IN EYES:
Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing. If eye irritation persists: Get medical attention.

Storage

:

Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50
°C/122 °F. Store in a well-ventilated place.

Disposal

Dispose of contents and container in accordance with all local, regional, national and
international regulations.

Hazards not otherwise
classified

:

None known.

Please refer to the SDS for additional information. Keep out of reach of children. Keep
upright in a cool, dry place. Do not discard empty can in trash compactor.

Supplemental label
elements

DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which
can cause permanent brain and nervous system damage. Intentional misuse by
deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING:
This product contains a chemical known to the State of California to cause cancer.
FOR INDUSTRIAL USE ONLY.

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Section 3. Composition/information on ingredients

Heavy Naphthenic Petroleum Oil

63.45

64742-52-5

Petroleum Oil

18

1,1-Difluoroethane

10

75-37-6

Ingredient name

CAS number

% by weight

There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health and hence require reporting in this section.

Other means of
identification

:

Not available.

Substance/mixture

CAS number/other identifiers

:

Occupational exposure limits, if available, are listed in Section 8.

Mixture

Any concentration shown as a range is to protect confidentiality or is due to batch variation.

Get medical attention. If necessary, call a poison center or physician.

Get medical attention.

Continue to rinse for at least 10 minutes. Get medical attention.

If it is suspected that fumes are still present, the rescuer should wear an appropriate
mask or self-contained breathing apparatus. It may be dangerous to the person
providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary,
call a poison center or physician. In case of inhalation of decomposition products in a
fire, symptoms may be delayed. The exposed person may need to be kept under
medical surveillance for 48 hours.

Section 4. First aid measures

Eye contact

Skin contact

Inhalation

Ingestion

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:::

Description of necessary first aid measures

Date of issue/Date of revision

:

6/28/2016

Date of previous issue

:

6/4/2016

Version

:

2.01

2/11

Section 4. First aid measures

Protection of first-aiders

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No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation.

Notes to physician

:

In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.

Specific treatments

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No specific treatment.

Most important symptoms/effects, acute and delayed

Inhalation

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Can cause central nervous system (CNS) depression. May cause drowsiness or
dizziness. May cause respiratory irritation.

Can cause central nervous system (CNS) depression.

:

Ingestion

Skin contact

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Causes skin irritation.

Causes serious eye irritation.

:

Eye contact

Over-exposure signs/symptoms

Skin contact

Ingestion

Inhalation

Adverse symptoms may include the following:
respiratory tract irritation
coughing
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness

No specific data.

Adverse symptoms may include the following:
irritation
redness

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:

:

Eye contact

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Adverse symptoms may include the following:
pain or irritation
watering
redness

Potential acute health effects

See toxicological information (Section 11)

Indication of immediate medical attention and special treatment needed, if necessary

Section 5. Fire-fighting measures

Hazardous thermal
decomposition products

Specific hazards arising
from the chemical

Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
halogenated compounds
carbonyl halides

Extremely flammable aerosol. In a fire or if heated, a pressure increase will occur and
the container may burst, with the risk of a subsequent explosion. Gas may accumulate
in low or confined areas or travel a considerable distance to a source of ignition and
flash back, causing fire or explosion. Bursting aerosol containers may be propelled from
a fire at high speed. Runoff to sewer may create fire or explosion hazard.

Use an extinguishing agent suitable for the surrounding fire.

Extinguishing media

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:

None known.

Suitable extinguishing
media

:

Unsuitable extinguishing
media

:

Date of issue/Date of revision

:

6/28/2016

Date of previous issue

:

6/4/2016

Version

:

2.01

3/11

Section 5. Fire-fighting measures

Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.

Special protective
equipment for fire-fighters

:

Special protective actions
for fire-fighters

:

Section 6. Accidental release measures

Environmental precautions

Personal precautions, protective equipment and emergency procedures

Use spark-proof tools and explosion-proof equipment. Note: see Section 1 for
emergency contact information and Section 13 for waste disposal.

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:

In the case of aerosols being ruptured, care should be taken due to the rapid escape of
the pressurized contents and propellant. If a large number of containers are ruptured,
treat as a bulk material spillage according to the instructions in the clean-up section.
Shut off all ignition sources. No flares, smoking or flames in hazard area.

No specific hazard.

Large spill

:

Use spark-proof tools and explosion-proof equipment.

Small spill

:

Methods and materials for containment and cleaning up

For non-emergency
personnel

For emergency responders

:

If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non­emergency personnel".

Section 7. Handling and storage

Advice on general
occupational hygiene

Conditions for safe storage,
including any
incompatibilities

Workers should wash hands and face before eating, drinking and smoking. Remove
contaminated clothing and protective equipment before entering eating areas. See also
Section 8 for additional information on hygiene measures.

Store in accordance with local regulations. Protect from sunlight. Store locked up.
Eliminate all ignition sources.

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Protective measures

Pressurized container: protect from sunlight and do not expose to temperatures
exceeding 50°C. Do not pierce or burn, even after use. Use only with adequate
ventilation. Wear appropriate respirator when ventilation is inadequate. Store and use
away from heat, sparks, open flame or any other ignition source. Use explosion-proof
electrical (ventilating, lighting and material handling) equipment. Use only non-sparking
tools.

:

Precautions for safe handling

Heavy Naphthenic Petroleum Oil

ACGIH TLV (United States, 3/2015).

TWA: 5 mg/m³ 8 hours. Form: Inhalable
fraction

NIOSH REL (United States, 10/2013).

TWA: 5 mg/m³ 10 hours. Form: Mist
STEL: 10 mg/m³ 15 minutes. Form: Mist

OSHA PEL (United States, 2/2013).

TWA: 5 mg/m³ 8 hours.

Section 8. Exposure controls/personal protection

Ingredient name

Exposure limits

Control parameters

Occupational exposure limits (OSHA United States)

Date of issue/Date of revision

:

6/28/2016

Date of previous issue

:

6/4/2016

Version

:

2.01

4/11