TRI-FLOW® Red Grease
Not available.
Spray
(216) 566-2917
SAFETY DATA SHEET
Product name
Other means of
identification
Product type
Emergency telephone
number of the company
Section 1. Identification
:
:
:
:
Manufacturer
:
Tri-Flow Industrial Group
Cleveland, OH 44115
Relevant identified uses of the substance or mixture and uses advised against
Not applicable.
TFBP20030
TFBP20030
Product code
:
Product Information
Telephone Number
:
Not available.
Regulatory Information
Telephone Number
:
(216) 566-2902
Transportation Emergency
Telephone Number
:
(800) 424-9300
Section 2. Hazards identification
FLAMMABLE AEROSOLS - Category 1
GASES UNDER PRESSURE - Compressed gas
SKIN CORROSION/IRRITATION - Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2
Classification of the
substance or mixture
:
Signal word
:
Danger
Hazard pictograms
:
Precautionary statements
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 28%
OSHA/HCS status
:
This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Extremely flammable aerosol.
Contains gas under pressure; may explode if heated.
Causes serious eye irritation.
Causes skin irritation.
May cause respiratory irritation.
May cause drowsiness or dizziness.
May cause damage to organs through prolonged or repeated exposure.
:
Hazard statements
Date of issue/Date of revision
:
6/28/2016
Date of previous issue
:
6/4/2016
Version
:
2.01
1/11
Section 2. Hazards identification
Prevention
:
Wear protective gloves. Wear eye or face protection. Keep away from heat, hot
surfaces, sparks, open flames and other ignition sources. No smoking. Do not spray on
an open flame or other ignition source. Use only outdoors or in a well-ventilated area.
Do not breathe vapor. Wash hands thoroughly after handling. Pressurized container:
Do not pierce or burn, even after use.
Response
:
Get medical attention if you feel unwell. IF INHALED: Remove person to fresh air and
keep comfortable for breathing. Call a POISON CENTER or physician if you feel unwell.
IF ON SKIN: Wash with plenty of soap and water. Take off contaminated clothing and
wash it before reuse. If skin irritation occurs: Get medical attention. IF IN EYES:
Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing. If eye irritation persists: Get medical attention.
Storage
:
Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50
°C/122 °F. Store in a well-ventilated place.
Disposal
Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Hazards not otherwise
classified
:
None known.
Please refer to the SDS for additional information. Keep out of reach of children. Keep
upright in a cool, dry place. Do not discard empty can in trash compactor.
Supplemental label
elements
DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which
can cause permanent brain and nervous system damage. Intentional misuse by
deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING:
This product contains a chemical known to the State of California to cause cancer.
FOR INDUSTRIAL USE ONLY.
:
Section 3. Composition/information on ingredients
Heavy Naphthenic Petroleum Oil
63.45
64742-52-5
Petroleum Oil
18
1,1-Difluoroethane
10
75-37-6
Ingredient name
CAS number
% by weight
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health and hence require reporting in this section.
Other means of
identification
:
Not available.
Substance/mixture
CAS number/other identifiers
:
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Get medical attention. If necessary, call a poison center or physician.
Get medical attention.
Continue to rinse for at least 10 minutes. Get medical attention.
If it is suspected that fumes are still present, the rescuer should wear an appropriate
mask or self-contained breathing apparatus. It may be dangerous to the person
providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary,
call a poison center or physician. In case of inhalation of decomposition products in a
fire, symptoms may be delayed. The exposed person may need to be kept under
medical surveillance for 48 hours.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion
:
:::
Description of necessary first aid measures
Date of issue/Date of revision
:
6/28/2016
Date of previous issue
:
6/4/2016
Version
:
2.01
2/11
Section 4. First aid measures
Protection of first-aiders
:
No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation.
Notes to physician
:
In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments
:
No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation
:
Can cause central nervous system (CNS) depression. May cause drowsiness or
dizziness. May cause respiratory irritation.
Can cause central nervous system (CNS) depression.
:
Ingestion
Skin contact
:
Causes skin irritation.
Causes serious eye irritation.
:
Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation
Adverse symptoms may include the following:
respiratory tract irritation
coughing
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact
:
Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential acute health effects
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Section 5. Fire-fighting measures
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
halogenated compounds
carbonyl halides
Extremely flammable aerosol. In a fire or if heated, a pressure increase will occur and
the container may burst, with the risk of a subsequent explosion. Gas may accumulate
in low or confined areas or travel a considerable distance to a source of ignition and
flash back, causing fire or explosion. Bursting aerosol containers may be propelled from
a fire at high speed. Runoff to sewer may create fire or explosion hazard.
Use an extinguishing agent suitable for the surrounding fire.
Extinguishing media
:
:
None known.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Date of issue/Date of revision
:
6/28/2016
Date of previous issue
:
6/4/2016
Version
:
2.01
3/11
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Special protective
equipment for fire-fighters
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Use spark-proof tools and explosion-proof equipment. Note: see Section 1 for
emergency contact information and Section 13 for waste disposal.
:
:
In the case of aerosols being ruptured, care should be taken due to the rapid escape of
the pressurized contents and propellant. If a large number of containers are ruptured,
treat as a bulk material spillage according to the instructions in the clean-up section.
Shut off all ignition sources. No flares, smoking or flames in hazard area.
No specific hazard.
Large spill
:
Use spark-proof tools and explosion-proof equipment.
Small spill
:
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders
:
If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For nonemergency personnel".
Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Workers should wash hands and face before eating, drinking and smoking. Remove
contaminated clothing and protective equipment before entering eating areas. See also
Section 8 for additional information on hygiene measures.
Store in accordance with local regulations. Protect from sunlight. Store locked up.
Eliminate all ignition sources.
:
:
Protective measures
Pressurized container: protect from sunlight and do not expose to temperatures
exceeding 50°C. Do not pierce or burn, even after use. Use only with adequate
ventilation. Wear appropriate respirator when ventilation is inadequate. Store and use
away from heat, sparks, open flame or any other ignition source. Use explosion-proof
electrical (ventilating, lighting and material handling) equipment. Use only non-sparking
tools.
:
Precautions for safe handling
Heavy Naphthenic Petroleum Oil
ACGIH TLV (United States, 3/2015).
TWA: 5 mg/m³ 8 hours. Form: Inhalable
fraction
NIOSH REL (United States, 10/2013).
TWA: 5 mg/m³ 10 hours. Form: Mist
STEL: 10 mg/m³ 15 minutes. Form: Mist
OSHA PEL (United States, 2/2013).
TWA: 5 mg/m³ 8 hours.
Section 8. Exposure controls/personal protection
Ingredient name
Exposure limits
Control parameters
Occupational exposure limits (OSHA United States)
Date of issue/Date of revision
:
6/28/2016
Date of previous issue
:
6/4/2016
Version
:
2.01
4/11
Section 8. Exposure controls/personal protection
Petroleum Oil
None.
1,1-Difluoroethane
AIHA WEEL (United States, 10/2011).
TWA: 1000 ppm 8 hours.
Hand protection
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Eye/face protection
Respiratory protection
:
:
:
Body protection
Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear antistatic protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
:
Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:
Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures
:
Individual protection measures
Skin protection
Other skin protection
:
Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Heavy Naphthenic Petroleum Oil
CA Alberta Provincial (Canada, 4/2009).
8 hrs OEL: 5 mg/m³ 8 hours. Form: Mist
15 min OEL: 10 mg/m³ 15 minutes. Form:
Mist
CA Quebec Provincial (Canada, 1/2014).
TWAEV: 5 mg/m³ 8 hours. Form: mist
STEV: 10 mg/m³ 15 minutes. Form: mist
Ingredient name
Exposure limits
Occupational exposure limits (Canada)
Environmental exposure
controls
:
Section 9. Physical and chemical properties
Physical state
Liquid.
Not available.
Odor
pH
Not available.
Color
Not available.
Not available.
Odor threshold
:::
::Appearance
Date of issue/Date of revision
:
6/28/2016
Date of previous issue
:
6/4/2016
Version
:
2.01
5/11
Section 9. Physical and chemical properties
Melting point
Vapor pressure
Relative density
Vapor density
Solubility
Not available.
0.91
2.4 [Air = 1]
13.5 kPa (101 mm Hg) [at 20°C]
Not available.
Evaporation rate
Not available.
Auto-ignition temperature
Flash point
Not available.
Closed cup: -29°C (-20.2°F) [Pensky-Martens Closed Cup]
Not available.
Viscosity
Kinematic (room temperature): <0.205 cm2/s (<20.5 cSt)
Kinematic (40°C (104°F)): <0.205 cm2/s (<20.5 cSt)
Partition coefficient: noctanol/water
:
:::
::::::Boiling point
:
Not available.
Flammability (solid, gas)
:
Not available.
Lower and upper explosive
(flammable) limits
:
Lower: 3.9%
Upper: 16.9%
Decomposition temperature
:
Not available.
Type of aerosol
:
Spray
Heat of combustion
:
30.04 kJ/g
Aerosol product
Molecular weight
:
Not applicable.
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid
Avoid all possible sources of ignition (spark or flame).
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
The product is stable.
Chemical stability
No specific data.
:
:
:
Incompatible materials
:
Possibility of hazardous
reactions
:
Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity
:
No specific test data related to reactivity available for this product or its ingredients.
Section 11. Toxicological information
Acute toxicity
Heavy Naphthenic Petroleum
Oil
LD50 Oral
Rat
>5000 mg/kg
-
Product/ingredient name
Result
Species
Dose
Exposure
Irritation/Corrosion
Heavy Naphthenic Petroleum
Oil
Skin - Severe irritant
Rabbit
-
500
milligrams
-
Product/ingredient name
Result
Score
Exposure
Observation
Species
Information on toxicological effects
Date of issue/Date of revision
:
6/28/2016
Date of previous issue
:
6/4/2016
Version
:
2.01
6/11
Section 11. Toxicological information
Carcinogenicity
Not available.
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Sensitization
Not available.
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
Petroleum Oil
Category 3
Not applicable.
Respiratory tract
irritation and
Narcotic effects
1,1-Difluoroethane
Category 3
Not applicable.
Respiratory tract
irritation and
Narcotic effects
Name
Category
Name
Category
Petroleum Oil
Category 2
Not determined
Not determined
1,1-Difluoroethane
Category 2
Not determined
Not determined
Aspiration hazard
Not available.
Route of
exposure
Target organs
Route of
exposure
Target organs
Information on the likely
routes of exposure
Inhalation
:
Can cause central nervous system (CNS) depression. May cause drowsiness or
dizziness. May cause respiratory irritation.
Can cause central nervous system (CNS) depression.
:
Ingestion
Skin contact
:
Causes skin irritation.
Causes serious eye irritation.
:
Eye contact
Symptoms related to the physical, chemical and toxicological characteristics
Eye contact
:
Adverse symptoms may include the following:
pain or irritation
watering
redness
:
Not available.
Potential acute health effects
Date of issue/Date of revision
:
6/28/2016
Date of previous issue
:
6/4/2016
Version
:
2.01
7/11
Not available.
May cause damage to organs through prolonged or repeated exposure.
General
:
No known significant effects or critical hazards.
Carcinogenicity
:
No known significant effects or critical hazards.
Mutagenicity
:
No known significant effects or critical hazards.
Teratogenicity
:
Developmental effects
:
No known significant effects or critical hazards.
Fertility effects
:
No known significant effects or critical hazards.
Skin contact
Ingestion
Inhalation
Adverse symptoms may include the following:
respiratory tract irritation
coughing
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
::Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Numerical measures of toxicity
Not available.
Acute toxicity estimates
Potential immediate
effects
:
Not available.
Short term exposure
Potential delayed effects
:
Not available.
Potential immediate
effects
:
Not available.
Long term exposure
Potential delayed effects
:
Not available.
Section 12. Ecological information
Bioaccumulative potential
Not available.
Toxicity
Not available.
Persistence and degradability
Soil/water partition
coefficient (KOC)
:
Not available.
Mobility in soil
Not available.
Date of issue/Date of revision
:
6/28/2016
Date of previous issue
:
6/4/2016
Version
:
2.01
8/11
Section 12. Ecological information
Other adverse effects
:
No known significant effects or critical hazards.
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Empty containers or liners may retain some product residues.
:
Disposal methods
Section 14. Transport information
AEROSOLS
2.1
-
AEROSOLS
2.1
-
UN1950
UN1950
-
Emergency
schedules (EmS)
LIMITED
QUANTITY, F-D,
S-U
DOT
Classification
IMDG
UN number
UN proper
shipping name
Transport
hazard class(es)
Packing group
Additional
information
Environmental
hazards
Special precautions for user
Transport in bulk according
to Annex II of MARPOL and
the IBC Code
No.
No.
Not available.
:
Proper shipping name
:
Ship type
:
Not available.
Pollution category
:
Not available.
Not available.
:
TDG
Classification
UN1950
AEROSOLS
2.1
-
No.
Product classified
as per the
following sections
of the
Transportation of
Dangerous Goods
Regulations: 2.
13-2.17 (Class 2).
Mexico
Classification
UN1950
AEROSOLS
2.1
-
No.
-
Multi-modal shipping descriptions are provided for informational purposes and do not
consider container sizes. The presence of a shipping description for a particular
mode of transport (sea, air, etc.), does not indicate that the product is packaged
suitably for that mode of transport. All packaging must be reviewed for suitability
prior to shipment, and compliance with the applicable regulations is the sole
responsibility of the person offering the product for transport. People loading and
unloading dangerous goods must be trained on all of the risks deriving from the
substances and on all actions in case of emergency situations.
IATA
UN1950
AEROSOLS,
flammable
2.1
-
No.
-
Date of issue/Date of revision
:
6/28/2016
Date of previous issue
:
6/4/2016
Version
:
2.01
9/11
Section 15. Regulatory information
SARA 313
SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet.
WARNING: This product contains a chemical known to the State of California to cause cancer.
California Prop. 65
Section 16. Other information
6/28/2016
History
Date of printing
Date of issue/Date of
revision
Version
Notice to reader
Date of previous issue
:
:
:
:
Key to abbreviations
:
ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
6/28/2016
6/4/2016
2.01
Hazardous Material Information System (U.S.A.)
2
4
0
Health
Flammability
Physical hazards
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910.
1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS®
program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may
be purchased exclusively from J. J. Keller (800) 327-6868.
The customer is responsible for determining the PPE code for this material.
Procedure used to derive the classification
Classification
Justification
FLAMMABLE AEROSOLS - Category 1
On basis of test data
GASES UNDER PRESSURE - Compressed gas
Calculation method
SKIN CORROSION/IRRITATION - Category 2
Calculation method
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A
Calculation method
SPECIFIC TARGET ORGAN TOXICITY (SINGLE
EXPOSURE) (Respiratory tract irritation) - Category 3
Calculation method
SPECIFIC TARGET ORGAN TOXICITY (SINGLE
EXPOSURE) (Narcotic effects) - Category 3
Calculation method
SPECIFIC TARGET ORGAN TOXICITY (REPEATED
EXPOSURE) - Category 2
Calculation method
Date of issue/Date of revision
:
6/28/2016
Date of previous issue
:
6/4/2016
Version
:
2.01
10/11
Section 16. Other information
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult
resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and
any hazards associated with the product. This information is provided in good faith and believed to be accurate
as of the effective date herein. However, no warranty, express or implied, is given. The information presented
here applies only to the product as shipped. The addition of any material can change the composition, hazards
and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed
by Sherwin-Williams, including but not limited to the incorporation of non Sherwin-Williams products or the use
or addition of products in proportions not specified by Sherwin-Williams. Regulatory requirements are subject
to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to
ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use
of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to
determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the
product for any purpose other than the purpose shown in the applicable section of this SDS without first
referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for
information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from
any other source.
Date of issue/Date of revision
:
6/28/2016
Date of previous issue
:
6/4/2016
Version
:
2.01
11/11
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