
TRI-FLOW® Industrial Lubricant
Other means of
identification
Emergency telephone
number of the company
Section 1. Identification
Tri-Flow Industrial Group
Cleveland, OH 44115
Relevant identified uses of the substance or mixture and uses advised against
Product Information
Telephone Number
Regulatory Information
Telephone Number
Transportation Emergency
Telephone Number
Section 2. Hazards identification
FLAMMABLE LIQUIDS - Category 4
SKIN CORROSION/IRRITATION - Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2
Classification of the
substance or mixture
Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 33.5%
This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Combustible liquid.
Causes serious eye irritation.
Causes skin irritation.
May cause respiratory irritation.
May cause drowsiness or dizziness.
May cause damage to organs through prolonged or repeated exposure.
Date of issue/Date of revision

Section 2. Hazards identification
Wear protective gloves. Wear eye or face protection. Keep away from flames and hot
surfaces. - No smoking. Use only outdoors or in a well-ventilated area. Do not breathe
vapor. Wash hands thoroughly after handling.
Get medical attention if you feel unwell. IF INHALED: Remove person to fresh air and
keep comfortable for breathing. Call a POISON CENTER or physician if you feel unwell.
IF ON SKIN: Wash with plenty of soap and water. Take off contaminated clothing and
wash it before reuse. If skin irritation occurs: Get medical attention. IF IN EYES:
Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing. If eye irritation persists: Get medical attention.
Store locked up. Store in a well-ventilated place. Keep cool.
Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Hazards not otherwise
classified
Please refer to the SDS for additional information. Keep out of reach of children. Do
not transfer contents to other containers for storage.
Supplemental label
elements
DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which
can cause permanent brain and nervous system damage. Intentional misuse by
deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING:
This product contains chemicals known to the State of California to cause cancer and
birth defects or other reproductive harm. FOR INDUSTRIAL USE ONLY.
Section 3. Composition/information on ingredients
Heavy Naphthenic Petroleum Oil
Barium Dinonyl Naphthalene Sulfonate
Tetrafluoroethene Polymer
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health and hence require reporting in this section.
Other means of
identification
CAS number/other identifiers
Occupational exposure limits, if available, are listed in Section 8.
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it
is suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Get medical attention. If necessary, call a poison center or physician. If unconscious,
place in recovery position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Section 4. First aid measures
Description of necessary first aid measures
Date of issue/Date of revision

Section 4. First aid measures
Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and
keep at rest in a position comfortable for breathing. If material has been swallowed and
the exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention. If necessary,
call a poison center or physician. Never give anything by mouth to an unconscious
person. If unconscious, place in recovery position and get medical attention
immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt
or waistband.
Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing
before reuse. Clean shoes thoroughly before reuse.
Protection of first-aiders
No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation.
Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Most important symptoms/effects, acute and delayed
Can cause central nervous system (CNS) depression. May cause drowsiness or
dizziness. May cause respiratory irritation.
Can cause central nervous system (CNS) depression.
Causes serious eye irritation.
Over-exposure signs/symptoms
Adverse symptoms may include the following:
respiratory tract irritation
coughing
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
Adverse symptoms may include the following:
irritation
redness
Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential acute health effects
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Date of issue/Date of revision

Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
sulfur oxides
halogenated compounds
metal oxide/oxides
Combustible liquid. In a fire or if heated, a pressure increase will occur and the
container may burst, with the risk of a subsequent explosion. The vapor/gas is heavier
than air and will spread along the ground. Vapors may accumulate in low or confined
areas or travel a considerable distance to a source of ignition and flash back. Runoff to
sewer may create fire or explosion hazard.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
Use dry chemical,
CO₂,
water spray (fog) or foam.
Suitable extinguishing
media
Unsuitable extinguishing
media
Special protective actions
for fire-fighters
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.
No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Methods and materials for containment and cleaning up
For non-emergency
personnel
If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For nonemergency personnel".
Date of issue/Date of revision

Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
Store in accordance with local regulations. Store in a segregated and approved area.
Store in original container protected from direct sunlight in a dry, cool and well-ventilated
area, away from incompatible materials (see Section 10) and food and drink. Store
locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep
container tightly closed and sealed until ready for use. Containers that have been
opened must be carefully resealed and kept upright to prevent leakage. Do not store in
unlabeled containers. Use appropriate containment to avoid environmental
contamination.
Put on appropriate personal protective equipment (see Section 8). Do not breathe
vapor or mist. Do not ingest. Avoid contact with eyes, skin and clothing. Use only with
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do
not enter storage areas and confined spaces unless adequately ventilated. Keep in the
original container or an approved alternative made from a compatible material, kept
tightly closed when not in use. Store and use away from heat, sparks, open flame or
any other ignition source. Use explosion-proof electrical (ventilating, lighting and
material handling) equipment. Use only non-sparking tools. Empty containers retain
product residue and can be hazardous. Do not reuse container.
Precautions for safe handling
Heavy Naphthenic Petroleum Oil
ACGIH TLV (United States, 3/2015).
TWA: 5 mg/m³ 8 hours. Form: Inhalable
fraction
NIOSH REL (United States, 10/2013).
TWA: 5 mg/m³ 10 hours. Form: Mist
STEL: 10 mg/m³ 15 minutes. Form: Mist
OSHA PEL (United States, 2/2013).
TWA: 5 mg/m³ 8 hours.
ACGIH TLV (United States, 3/2015).
Absorbed through skin.
TWA: 200 mg/m³, (as total hydrocarbon
vapor) 8 hours.
Barium Dinonyl Naphthalene Sulfonate
Tetrafluoroethene Polymer
Section 8. Exposure controls/personal protection
Occupational exposure limits (OSHA United States)
Heavy Naphthenic Petroleum Oil
CA Alberta Provincial (Canada, 4/2009).
8 hrs OEL: 5 mg/m³ 8 hours. Form: Mist
15 min OEL: 10 mg/m³ 15 minutes. Form:
Mist
CA Quebec Provincial (Canada, 1/2014).
TWAEV: 5 mg/m³ 8 hours. Form: mist
STEV: 10 mg/m³ 15 minutes. Form: mist
Occupational exposure limits (Canada)
Date of issue/Date of revision

Section 8. Exposure controls/personal protection
Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product.
Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Individual protection measures
Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Environmental exposure
controls
Section 9. Physical and chemical properties
0.071 kPa (0.533 mm Hg) [at 20°C]
Closed cup: 83°C (181.4°F) [Pensky-Martens Closed Cup]
Flammability (solid, gas)
Lower and upper explosive
(flammable) limits
Date of issue/Date of revision

Section 9. Physical and chemical properties
Auto-ignition temperature
Kinematic (room temperature): <0.205 cm2/s (<20.5 cSt)
Kinematic (40°C (104°F)): <0.205 cm2/s (<20.5 cSt)
Partition coefficient: noctanol/water
::Decomposition temperature
Section 10. Stability and reactivity
Hazardous decomposition
products
Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not
allow vapor to accumulate in low or confined areas.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
Reactive or incompatible with the following materials:
oxidizing materials
Possibility of hazardous
reactions
Under normal conditions of storage and use, hazardous reactions will not occur.
No specific test data related to reactivity available for this product or its ingredients.
Section 11. Toxicological information
Heavy Naphthenic Petroleum
Oil
Barium Dinonyl Naphthalene
Sulfonate
Heavy Naphthenic Petroleum
Oil
Barium Dinonyl Naphthalene
Sulfonate
Information on toxicological effects
Date of issue/Date of revision

Section 11. Toxicological information
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
Respiratory tract
irritation and
Narcotic effects
Target organs
Classification
Tetrafluoroethene Polymer
Information on the likely
routes of exposure
Can cause central nervous system (CNS) depression. May cause drowsiness or
dizziness. May cause respiratory irritation.
Can cause central nervous system (CNS) depression.
Causes serious eye irritation.
Symptoms related to the physical, chemical and toxicological characteristics
Adverse symptoms may include the following:
respiratory tract irritation
coughing
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential acute health effects
Date of issue/Date of revision

May cause damage to organs through prolonged or repeated exposure.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
Adverse symptoms may include the following:
irritation
redness
::Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Numerical measures of toxicity
Inhalation (dusts and mists)
Potential immediate
effects
Potential delayed effects
Potential immediate
effects
Potential delayed effects
Section 12. Ecological information
Bioaccumulative potential
No known significant effects or critical hazards.
Acute LC50 2200 µg/l Fresh water
Fish - Lepomis macrochirus
Persistence and degradability
Soil/water partition
coefficient (KOC)
Date of issue/Date of revision

Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Vapor from product residues may create a highly flammable or explosive atmosphere
inside the container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
Section 14. Transport information
Emergency
schedules (EmS)
Not Applicable
Transport
hazard class(es)
Special precautions for user
Transport in bulk according
to Annex II of MARPOL and
the IBC Code
Multi-modal shipping descriptions are provided for informational purposes and do not
consider container sizes. The presence of a shipping description for a particular
mode of transport (sea, air, etc.), does not indicate that the product is packaged
suitably for that mode of transport. All packaging must be reviewed for suitability
prior to shipment, and compliance with the applicable regulations is the sole
responsibility of the person offering the product for transport. People loading and
unloading dangerous goods must be trained on all of the risks deriving from the
substances and on all actions in case of emergency situations.
Date of issue/Date of revision

Section 15. Regulatory information
SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet.
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other
reproductive harm.
Section 16. Other information
Date of issue/Date of
revision
ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
Hazardous Material Information System (U.S.A.)
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910.
1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS®
program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may
be purchased exclusively from J. J. Keller (800) 327-6868.
The customer is responsible for determining the PPE code for this material.
Procedure used to derive the classification
FLAMMABLE LIQUIDS - Category 4
SKIN CORROSION/IRRITATION - Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE
EXPOSURE) (Respiratory tract irritation) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE
EXPOSURE) (Narcotic effects) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED
EXPOSURE) - Category 2
Date of issue/Date of revision

Section 16. Other information
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult
resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and
any hazards associated with the product. This information is provided in good faith and believed to be accurate
as of the effective date herein. However, no warranty, express or implied, is given. The information presented
here applies only to the product as shipped. The addition of any material can change the composition, hazards
and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed
by Sherwin-Williams, including but not limited to the incorporation of non Sherwin-Williams products or the use
or addition of products in proportions not specified by Sherwin-Williams. Regulatory requirements are subject
to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to
ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use
of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to
determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the
product for any purpose other than the purpose shown in the applicable section of this SDS without first
referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for
information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from
any other source.
Date of issue/Date of revision