TRI-FLOW® Food Grade Anti-Seize with PTFE
Not available.
Solid.
(216) 566-2917
SAFETY DATA SHEET
Product name
Other means of
identification
Product type
Emergency telephone
number of the company
Section 1. Identification
:
:
:
:
Manufacturer
:
Tri-Flow Industrial Group
Cleveland, OH 44115
Relevant identified uses of the substance or mixture and uses advised against
Not applicable.
TF23015
TF23015
Product code
:
Product Information
Telephone Number
:
Not available.
Regulatory Information
Telephone Number
:
(216) 566-2902
Transportation Emergency
Telephone Number
:
(800) 424-9300
Section 2. Hazards identification
CARCINOGENICITY - Category 2
Classification of the
substance or mixture
:
Signal word
:
Warning
Hazard pictograms
:
Precautionary statements
Prevention
:
Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Wear protective gloves. Wear eye or face protection.
Wear protective clothing.
Response
:
IF exposed or concerned: Get medical attention.
Storage
:
Store locked up.
Disposal
Dispose of contents and container in accordance with all local, regional, national and
international regulations.
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 57.2%
OSHA/HCS status
:
This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Suspected of causing cancer.
:
Hazard statements
Please refer to the SDS for additional information. Keep out of reach of children. Do
not transfer contents to other containers for storage.
Supplemental label
elements
WARNING: This product contains chemicals known to the State of California to cause
cancer. FOR INDUSTRIAL USE ONLY.
:
Date of issue/Date of revision
:
6/28/2016
Date of previous issue
:
6/4/2016
Version
:
2.01
1/10
Section 2. Hazards identification
Hazards not otherwise
classified
:
None known.
Section 3. Composition/information on ingredients
Tetrafluoroethene Polymer
3.5
9002-84-0
Titanium Dioxide
1.6
13463-67-7
Ingredient name
CAS number
% by weight
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health and hence require reporting in this section.
Other means of
identification
:
Not available.
Substance/mixture
CAS number/other identifiers
:
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and
keep at rest in a position comfortable for breathing. If material has been swallowed and
the exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention. Never give
anything by mouth to an unconscious person. If unconscious, place in recovery position
and get medical attention immediately. Maintain an open airway. Loosen tight clothing
such as a collar, tie, belt or waistband.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing
before reuse. Clean shoes thoroughly before reuse.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If
not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial
respiration or oxygen by trained personnel. It may be dangerous to the person providing
aid to give mouth-to-mouth resuscitation. Get medical attention. If unconscious, place
in recovery position and get medical attention immediately. Maintain an open airway.
Loosen tight clothing such as a collar, tie, belt or waistband.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion
:
:::
Description of necessary first aid measures
Most important symptoms/effects, acute and delayed
Inhalation
:
No known significant effects or critical hazards.
No known significant effects or critical hazards.
:
Ingestion
Skin contact
:
No known significant effects or critical hazards.
No known significant effects or critical hazards.
:
Eye contact
Over-exposure signs/symptoms
Skin contact
Inhalation
No specific data.
No specific data.
::Eye contact
:
No specific data.
Potential acute health effects
Date of issue/Date of revision
:
6/28/2016
Date of previous issue
:
6/4/2016
Version
:
2.01
2/10
Section 4. First aid measures
Protection of first-aiders
:
No action shall be taken involving any personal risk or without suitable training. It may
be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Notes to physician
:
Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments
:
No specific treatment.
Ingestion
No specific data.
:
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
halogenated compounds
metal oxide/oxides
No specific fire or explosion hazard.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
Use an extinguishing agent suitable for the surrounding fire.
Extinguishing media
:::
None known.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
:
:
No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Provide adequate ventilation.
Wear appropriate respirator when ventilation is inadequate. Put on appropriate
personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Move containers from spill area. Avoid dust generation. Do not dry sweep. Vacuum
dust with equipment fitted with a HEPA filter and place in a closed, labeled waste
container. Dispose of via a licensed waste disposal contractor.
Small spill
:
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders
:
If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For nonemergency personnel".
Date of issue/Date of revision
:
6/28/2016
Date of previous issue
:
6/4/2016
Version
:
2.01
3/10
Section 6. Accidental release measures
Move containers from spill area. Approach release from upwind. Prevent entry into
sewers, water courses, basements or confined areas. Avoid dust generation. Do not
dry sweep. Vacuum dust with equipment fitted with a HEPA filter and place in a closed,
labeled waste container. Dispose of via a licensed waste disposal contractor. Note:
see Section 1 for emergency contact information and Section 13 for waste disposal.
Large spill
:
Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
Store in accordance with local regulations. Store in original container protected from
direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials
(see Section 10) and food and drink. Store locked up. Keep container tightly closed
and sealed until ready for use. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage. Do not store in unlabeled containers.
Use appropriate containment to avoid environmental contamination.
:
:
Protective measures
Put on appropriate personal protective equipment (see Section 8). Avoid exposure obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Do not get in eyes or on skin or clothing. Do not ingest. If
during normal use the material presents a respiratory hazard, use only with adequate
ventilation or wear appropriate respirator. Keep in the original container or an approved
alternative made from a compatible material, kept tightly closed when not in use. Empty
containers retain product residue and can be hazardous. Do not reuse container.
:
Precautions for safe handling
Tetrafluoroethene Polymer
None.
Titanium Dioxide
ACGIH TLV (United States, 3/2015).
TWA: 10 mg/m³ 8 hours.
OSHA PEL (United States, 2/2013).
TWA: 15 mg/m³ 8 hours. Form: Total dust
Section 8. Exposure controls/personal protection
Ingredient name
Exposure limits
Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:
If user operations generate dust, fumes, gas, vapor or mist, use process enclosures,
local exhaust ventilation or other engineering controls to keep worker exposure to
airborne contaminants below any recommended or statutory limits.
Control parameters
Individual protection measures
Occupational exposure limits (OSHA United States)
None.
Ingredient name
Exposure limits
Occupational exposure limits (Canada)
Environmental exposure
controls
:
Date of issue/Date of revision
:
6/28/2016
Date of previous issue
:
6/4/2016
Version
:
2.01
4/10
Section 8. Exposure controls/personal protection
Hand protection
Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: safety glasses with sideshields.
Eye/face protection
Respiratory protection
:
:
:
Body protection
Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product.
:
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures
:
Skin protection
Other skin protection
:
Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Section 9. Physical and chemical properties
Physical state
Melting point
Vapor pressure
Relative density
Vapor density
Solubility
Solid.
Not available.
1.19
Not available.
Not available.
Not available.
Not available.
Odor
pH
Not available.
Color
Evaporation rate
Not available.
Auto-ignition temperature
Flash point
Not available.
Closed cup: 204°C (399.2°F) [Pensky-Martens Closed Cup]
Not available.
Not available.
Not available.
Odor threshold
Partition coefficient: noctanol/water
:::
:
:
:::
:::
:
:
:
Appearance
Boiling point
:
Not available.
Flammability (solid, gas)
:
Not available.
Lower and upper explosive
(flammable) limits
:
Not available.
Decomposition temperature
:
Not available.
Date of issue/Date of revision
:
6/28/2016
Date of previous issue
:
6/4/2016
Version
:
2.01
5/10
Section 9. Physical and chemical properties
Viscosity
Kinematic (room temperature): >0.205 cm2/s (>20.5 cSt)
Kinematic (40°C (104°F)): >0.205 cm2/s (>20.5 cSt)
:
Molecular weight
:
Not applicable.
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid
No specific data.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
The product is stable.
Chemical stability
No specific data.
:
:
:
Incompatible materials
:
Possibility of hazardous
reactions
:
Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity
:
No specific test data related to reactivity available for this product or its ingredients.
Section 11. Toxicological information
Acute toxicity
Not available.
Carcinogenicity
Not available.
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Irritation/Corrosion
Titanium Dioxide
Skin - Mild irritant
Human
-
72 hours 300
Micrograms
Intermittent
-
Product/ingredient name
Result
Score
Exposure
Observation
Sensitization
Not available.
Species
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
Not available.
Information on toxicological effects
Classification
Tetrafluoroethene Polymer
-3-
Titanium Dioxide
-2B-
Product/ingredient name
NTP
IARC
OSHA
Date of issue/Date of revision
:
6/28/2016
Date of previous issue
:
6/4/2016
Version
:
2.01
6/10
Section 11. Toxicological information
Not available.
Aspiration hazard
Not available.
Not available.
Information on the likely
routes of exposure
Inhalation
:
No known significant effects or critical hazards.
No known significant effects or critical hazards.
:
Ingestion
Skin contact
:
No known significant effects or critical hazards.
No known significant effects or critical hazards.
:
Eye contact
No known significant effects or critical hazards.
General
:
Suspected of causing cancer. Risk of cancer depends on duration and level of
exposure.
Carcinogenicity
:
No known significant effects or critical hazards.
Mutagenicity
:
No known significant effects or critical hazards.
Teratogenicity
:
Developmental effects
:
No known significant effects or critical hazards.
Fertility effects
:
No known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation
No specific data.
No specific data.
No specific data.
:::
Eye contact
:
No specific data.
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Numerical measures of toxicity
Oral
67624 mg/kg
Inhalation (dusts and mists)
18.34 mg/l
Route
ATE value
Acute toxicity estimates
:
Not available.
Potential acute health effects
Potential immediate
effects
:
Not available.
Short term exposure
Potential delayed effects
:
Not available.
Potential immediate
effects
:
Not available.
Long term exposure
Potential delayed effects
:
Not available.
Date of issue/Date of revision
:
6/28/2016
Date of previous issue
:
6/4/2016
Version
:
2.01
7/10
Section 12. Ecological information
Bioaccumulative potential
Other adverse effects
:
No known significant effects or critical hazards.
Not available.
Toxicity
Titanium Dioxide
Acute LC50 >1000000 µg/l Marine water
Fish - Fundulus heteroclitus
96 hours
Product/ingredient name
Species
Result
Exposure
Persistence and degradability
Soil/water partition
coefficient (KOC)
:
Not available.
Mobility in soil
Not available.
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers.
:
Disposal methods
Section 14. Transport information
-
-
-
-
-
-
Not regulated.
Not regulated.
-
Emergency
schedules (EmS)
Not Applicable
DOT
Classification
IMDG
UN number
UN proper
shipping name
Transport
hazard class(es)
Packing group
Additional
information
Environmental
hazards
No.
No.
TDG
Classification
Not regulated.
-
-
-
No.
-
Mexico
Classification
Not regulated.
-
-
-
No.
-
IATA
Not regulated.
-
-
-
No.
-
Date of issue/Date of revision
:
6/28/2016
Date of previous issue
:
6/4/2016
Version
:
2.01
8/10
Section 14. Transport information
Special precautions for user
Transport in bulk according
to Annex II of MARPOL and
the IBC Code
Not available.
:
Proper shipping name
:
Ship type
:
Not available.
Pollution category
:
Not available.
Not available.
:
Multi-modal shipping descriptions are provided for informational purposes and do not
consider container sizes. The presence of a shipping description for a particular
mode of transport (sea, air, etc.), does not indicate that the product is packaged
suitably for that mode of transport. All packaging must be reviewed for suitability
prior to shipment, and compliance with the applicable regulations is the sole
responsibility of the person offering the product for transport. People loading and
unloading dangerous goods must be trained on all of the risks deriving from the
substances and on all actions in case of emergency situations.
Section 15. Regulatory information
SARA 313
SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet.
WARNING: This product contains chemicals known to the State of California to cause cancer.
California Prop. 65
Section 16. Other information
6/28/2016
History
Date of printing
Date of issue/Date of
revision
Version
Date of previous issue
:
:::
6/28/2016
6/4/2016
2.01
Hazardous Material Information System (U.S.A.)
1
1
0
*
Health
Flammability
Physical hazards
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910.
1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS®
program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may
be purchased exclusively from J. J. Keller (800) 327-6868.
The customer is responsible for determining the PPE code for this material.
Procedure used to derive the classification
Classification
Justification
CARCINOGENICITY - Category 2
Calculation method
Date of issue/Date of revision
:
6/28/2016
Date of previous issue
:
6/4/2016
Version
:
2.01
9/10
Section 16. Other information
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult
resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and
any hazards associated with the product. This information is provided in good faith and believed to be accurate
as of the effective date herein. However, no warranty, express or implied, is given. The information presented
here applies only to the product as shipped. The addition of any material can change the composition, hazards
and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed
by Sherwin-Williams, including but not limited to the incorporation of non Sherwin-Williams products or the use
or addition of products in proportions not specified by Sherwin-Williams. Regulatory requirements are subject
to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to
ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use
of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to
determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the
product for any purpose other than the purpose shown in the applicable section of this SDS without first
referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for
information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from
any other source.
Notice to reader
Key to abbreviations
:
ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
Date of issue/Date of revision
:
6/28/2016
Date of previous issue
:
6/4/2016
Version
:
2.01
10/10
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