Tri-Flow TF230101 User Manual

TRI-FLOW® Synthetic Oil
Not available. Aerosol.
(216) 566-2917
SAFETY DATA SHEET
Other means of identification
Product type
Emergency telephone number of the company
Section 1. Identification
:
: :
:
Manufacturer
:
Tri-Flow Industrial Group Cleveland, OH 44115
Relevant identified uses of the substance or mixture and uses advised against
Not applicable.
TF23010
TF23010
Product code
:
Product Information Telephone Number
:
Not available.
Regulatory Information Telephone Number
:
(216) 566-2902
Transportation Emergency Telephone Number
:
(800) 424-9300
Section 2. Hazards identification
FLAMMABLE AEROSOLS - Category 1 GASES UNDER PRESSURE - Compressed gas SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) ­Category 3 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2
Classification of the substance or mixture
:
Signal word
:
Danger
Hazard pictograms
:
Precautionary statements
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 99.8%
OSHA/HCS status
:
This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).
Extremely flammable aerosol. Contains gas under pressure; may explode if heated. May cause respiratory irritation. May cause drowsiness or dizziness. May cause damage to organs through prolonged or repeated exposure.
:
Hazard statements
Date of issue/Date of revision
:
6/28/2016
Date of previous issue
:
6/4/2016
Version
:
2.01
1/12
Section 2. Hazards identification
Prevention
:
Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Do not spray on an open flame or other ignition source. Use only outdoors or in a well-ventilated area. Do not breathe dust or mist. Pressurized container: Do not pierce or burn, even after use.
Response
:
Get medical attention if you feel unwell. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or physician if you feel unwell.
Storage
:
Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F. Store in a well-ventilated place.
Disposal
Dispose of contents and container in accordance with all local, regional, national and international regulations.
Hazards not otherwise classified
:
None known.
Please refer to the SDS for additional information. Keep out of reach of children. Keep upright in a cool, dry place. Do not discard empty can in trash compactor.
Supplemental label elements
DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which can cause permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. FOR INDUSTRIAL USE ONLY.
:
Section 3. Composition/information on ingredients
Aliphatic Solvent
68.41
64742-47-8
Propane
8
74-98-6
Ingredient name
CAS number
% by weight
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health and hence require reporting in this section.
Other means of identification
:
Not available.
Substance/mixture
CAS number/other identifiers
:
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention following exposure or if feeling unwell.
Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Continue to rinse for at least 10 minutes. Get medical attention following exposure or if feeling unwell. Wash clothing before reuse. Clean shoes thoroughly before reuse.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
:
:
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Description of necessary first aid measures
Date of issue/Date of revision
:
6/28/2016
Date of previous issue
:
6/4/2016
Version
:
2.01
2/12
Section 4. First aid measures
Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention. If necessary, call a poison center or physician. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Ingestion
:
Protection of first-aiders
:
No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Notes to physician
:
Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.
Specific treatments
:
No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation
:
Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. May cause respiratory irritation.
Can cause central nervous system (CNS) depression.
:
Ingestion
Skin contact
:
No known significant effects or critical hazards.
No known significant effects or critical hazards.
:
Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation
Adverse symptoms may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness
No specific data.
No specific data.
:
:
:
Eye contact
:
Adverse symptoms may include the following: irritation redness
Potential acute health effects
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Section 5. Fire-fighting measures
Use an extinguishing agent suitable for the surrounding fire.
Extinguishing media
None known.
Suitable extinguishing media
:
Unsuitable extinguishing media
:
Date of issue/Date of revision
:
6/28/2016
Date of previous issue
:
6/4/2016
Version
:
2.01
3/12
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.
Hazardous thermal decomposition products
Specific hazards arising from the chemical
Decomposition products may include the following materials: carbon dioxide carbon monoxide
Extremely flammable aerosol. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Gas may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back, causing fire or explosion. Bursting aerosol containers may be propelled from a fire at high speed. Runoff to sewer may create fire or explosion hazard.
Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective equipment for fire-fighters
:
: :
Special protective actions for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.
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:
No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. In the case of aerosols being ruptured, care should be taken due to the rapid escape of the pressurized contents and propellant. If a large number of containers are ruptured, treat as a bulk material spillage according to the instructions in the clean-up section. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).
Large spill
:
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.
Small spill
:
Methods and materials for containment and cleaning up
For non-emergency personnel
For emergency responders
:
If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non­emergency personnel".
Date of issue/Date of revision
:
6/28/2016
Date of previous issue
:
6/4/2016
Version
:
2.01
4/12
Section 7. Handling and storage
Advice on general occupational hygiene
Conditions for safe storage, including any incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.
Store in accordance with local regulations. Store away from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Protect from sunlight. Store locked up. Eliminate all ignition sources. Use appropriate containment to avoid environmental contamination.
: :
Protective measures
Put on appropriate personal protective equipment (see Section 8). Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do not pierce or burn, even after use. Do not breathe vapor or mist. Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing gas. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Empty containers retain product residue and can be hazardous.
:
Precautions for safe handling
Aliphatic Solvent
ACGIH TLV (United States, 3/2015). Absorbed through skin.
TWA: 200 mg/m³, (as total hydrocarbon vapor) 8 hours.
Propane
NIOSH REL (United States, 10/2013).
TWA: 1000 ppm 10 hours. TWA: 1800 mg/m³ 10 hours.
OSHA PEL (United States, 2/2013).
TWA: 1000 ppm 8 hours. TWA: 1800 mg/m³ 8 hours.
Section 8. Exposure controls/personal protection
Ingredient name
Exposure limits
Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
Appropriate engineering controls
:
Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.
Control parameters
Individual protection measures
Occupational exposure limits (OSHA United States)
None.
Ingredient name
Exposure limits
Occupational exposure limits (Canada)
Environmental exposure controls
:
Date of issue/Date of revision
:
6/28/2016
Date of previous issue
:
6/4/2016
Version
:
2.01
5/12
Section 8. Exposure controls/personal protection
Hand protection
Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use.
Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side­shields.
Eye/face protection Respiratory protection
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:
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Body protection
Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti­static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves.
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Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
Hygiene measures
:
Skin protection
Other skin protection
:
Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
Section 9. Physical and chemical properties
Physical state
Melting point
Vapor pressure
Relative density
Vapor density
Solubility
Liquid.
Not available.
0.76
1.55 [Air = 1]
13.5 kPa (101.325 mm Hg) [at 20°C]
Not available.
Not available.
Odor
pH
Not available.
Color
Evaporation rate
0.192 (butyl acetate = 1)
Auto-ignition temperature
Flash point
Not available.
Closed cup: -29°C (-20.2°F) [Pensky-Martens Closed Cup]
Not available. Not available.
Not available.
Odor threshold
Partition coefficient: n­octanol/water
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Appearance
Boiling point
:
Not available.
Flammability (solid, gas)
:
Not available.
Lower and upper explosive (flammable) limits
:
Lower: 0.7% Upper: 9.5%
Decomposition temperature
:
Not available.
Date of issue/Date of revision
:
6/28/2016
Date of previous issue
:
6/4/2016
Version
:
2.01
6/12
Section 9. Physical and chemical properties
Viscosity
Kinematic (room temperature): <0.205 cm2/s (<20.5 cSt) Kinematic (40°C (104°F)): <0.205 cm2/s (<20.5 cSt)
:
Type of aerosol
:
Spray
Heat of combustion
:
0.00003176 kJ/g
Aerosol product
Molecular weight
:
Not applicable.
Section 10. Stability and reactivity
Hazardous decomposition products
Conditions to avoid
Avoid all possible sources of ignition (spark or flame).
Under normal conditions of storage and use, hazardous decomposition products should not be produced.
The product is stable.
Chemical stability
No specific data.
:
:
:
Incompatible materials
:
Possibility of hazardous reactions
:
Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity
:
No specific test data related to reactivity available for this product or its ingredients.
Section 11. Toxicological information
Acute toxicity
Not available.
Carcinogenicity
Not available.
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Irritation/Corrosion
Not available.
Sensitization
Not available.
Specific target organ toxicity (single exposure)
Information on toxicological effects
Date of issue/Date of revision
:
6/28/2016
Date of previous issue
:
6/4/2016
Version
:
2.01
7/12
Section 11. Toxicological information
Specific target organ toxicity (repeated exposure)
Aliphatic Solvent
Category 3
Not applicable.
Respiratory tract irritation and Narcotic effects
Propane
Category 3
Not applicable.
Respiratory tract irritation and Narcotic effects
Name
Category
Name
Category
Aliphatic Solvent
Category 2
Not determined
Not determined
Propane
Category 2
Not determined
Not determined
Aspiration hazard
Name
Result
Propane
ASPIRATION HAZARD - Category 1
Route of exposure
Target organs
Route of exposure
Target organs
Information on the likely routes of exposure
Inhalation
:
Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. May cause respiratory irritation.
Can cause central nervous system (CNS) depression.
:
Ingestion
Skin contact
:
No known significant effects or critical hazards.
No known significant effects or critical hazards.
:
Eye contact
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation
Adverse symptoms may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness
No specific data.
No specific data.
:
:
:
Eye contact
:
Adverse symptoms may include the following: irritation redness
Delayed and immediate effects and also chronic effects from short and long term exposure
:
Not available.
Potential acute health effects
Potential immediate effects
:
Not available.
Short term exposure
Potential delayed effects
:
Not available.
Potential immediate effects
:
Not available.
Long term exposure
Date of issue/Date of revision
:
6/28/2016
Date of previous issue
:
6/4/2016
Version
:
2.01
8/12
Not available.
May cause damage to organs through prolonged or repeated exposure.
General
:
No known significant effects or critical hazards.
Carcinogenicity
:
No known significant effects or critical hazards.
Mutagenicity
:
No known significant effects or critical hazards.
Teratogenicity
:
Developmental effects
:
No known significant effects or critical hazards.
Fertility effects
:
No known significant effects or critical hazards.
Potential chronic health effects
Numerical measures of toxicity
Not available.
Acute toxicity estimates
Potential delayed effects
:
Not available.
Section 12. Ecological information
Bioaccumulative potential
Other adverse effects
:
No known significant effects or critical hazards.
Not available.
Toxicity
Aliphatic Solvent
Acute LC50 2200 µg/l Fresh water
Fish - Lepomis macrochirus
4 days
Product/ingredient name
Species
Result
Exposure
Persistence and degradability
Soil/water partition coefficient (KOC)
:
Not available.
Mobility in soil
Not available.
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Do not puncture or incinerate container.
:
Disposal methods
Date of issue/Date of revision
:
6/28/2016
Date of previous issue
:
6/4/2016
Version
:
2.01
9/12
Section 14. Transport information
AEROSOLS
2.1
-
AEROSOLS
2.1
-
UN1950
UN1950
-
Emergency schedules (EmS)
LIMITED QUANTITY, F-D, S-U
DOT
Classification
IMDG
UN number
UN proper shipping name
Transport hazard class(es)
Packing group
Additional information
Environmental hazards
Special precautions for user
Transport in bulk according to Annex II of MARPOL and the IBC Code
No.
No. Not available.
:
Proper shipping name
:
Ship type
:
Not available.
Pollution category
:
Not available.
Not available.
:
TDG
Classification
UN1950
AEROSOLS
2.1
-
No.
Product classified as per the following sections of the Transportation of Dangerous Goods Regulations: 2. 13-2.17 (Class 2).
Mexico
Classification
UN1950
AEROSOLS
2.1
-
No.
-
Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (sea, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. People loading and unloading dangerous goods must be trained on all of the risks deriving from the substances and on all actions in case of emergency situations.
IATA
UN1950
AEROSOLS, flammable
2.1
-
No.
-
Section 15. Regulatory information
SARA 313
SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet.
Not applicable.
California Prop. 65
Date of issue/Date of revision
:
6/28/2016
Date of previous issue
:
6/4/2016
Version
:
2.01
10/12
Section 16. Other information
6/28/2016
History
Date of printing
Date of issue/Date of revision
Version
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. This information is provided in good faith and believed to be accurate as of the effective date herein. However, no warranty, express or implied, is given. The information presented here applies only to the product as shipped. The addition of any material can change the composition, hazards and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed by Sherwin-Williams, including but not limited to the incorporation of non Sherwin-Williams products or the use or addition of products in proportions not specified by Sherwin-Williams. Regulatory requirements are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the product for any purpose other than the purpose shown in the applicable section of this SDS without first
Notice to reader
Date of previous issue
:::
:
Key to abbreviations
:
ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations
6/28/2016
6/4/2016
2.01
Hazardous Material Information System (U.S.A.)
2
4
0
Health
Flammability
Physical hazards
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868.
The customer is responsible for determining the PPE code for this material.
Procedure used to derive the classification
Classification
Justification
FLAMMABLE AEROSOLS - Category 1
On basis of test data
GASES UNDER PRESSURE - Compressed gas
Calculation method
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3
Calculation method
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3
Calculation method
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2
Calculation method
Date of issue/Date of revision
:
6/28/2016
Date of previous issue
:
6/4/2016
Version
:
2.01
11/12
Section 16. Other information
referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from any other source.
Date of issue/Date of revision
:
6/28/2016
Date of previous issue
:
6/4/2016
Version
:
2.01
12/12
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