Tri-Flow TF0023008 User Manual

TRI-FLOW® RAPID CLEAN™ Dry Degreaser

Not available.
Aerosol.

[phone]

SAFETY DATA SHEET

Product name

Other means of
identification

Product type

Emergency telephone
number of the company

Section 1. Identification

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:
:

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Manufacturer

:

Tri-Flow Industrial Group
Cleveland, OH 44115

Relevant identified uses of the substance or mixture and uses advised against

Not applicable.

TF0023008

TF0023008

Product code

:

Product Information
Telephone Number

:

Not available.

Regulatory Information
Telephone Number

:

[phone]

Transportation Emergency
Telephone Number

:

[phone]

Section 2. Hazards identification

FLAMMABLE AEROSOLS - Category 1
GASES UNDER PRESSURE - Compressed gas
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A
TOXIC TO REPRODUCTION (Unborn child) - Category 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) ­Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2

Classification of the
substance or mixture

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Signal word

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Danger

Hazard pictograms

:

Precautionary statements

GHS label elements

Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 11.8%

OSHA/HCS status

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This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).

Extremely flammable aerosol.
Contains gas under pressure; may explode if heated.
Causes serious eye irritation.
Suspected of damaging the unborn child.
May cause respiratory irritation.
May cause drowsiness or dizziness.
May cause damage to organs through prolonged or repeated exposure.

:

Hazard statements

Date of issue/Date of revision

:

6/28/2016

Date of previous issue

:

6/4/2016

Version

:

2.01

1/14

Section 2. Hazards identification

Prevention

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Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Wear protective gloves. Wear eye or face protection.
Wear protective clothing. Keep away from heat, hot surfaces, sparks, open flames and
other ignition sources. No smoking. Do not spray on an open flame or other ignition
source. Use only outdoors or in a well-ventilated area. Do not breathe dust or mist.
Wash hands thoroughly after handling. Pressurized container: Do not pierce or burn,
even after use.

Response

:

Get medical attention if you feel unwell. IF exposed or concerned: Get medical
attention. IF INHALED: Remove person to fresh air and keep comfortable for breathing.
Call a POISON CENTER or physician if you feel unwell. IF IN EYES: Rinse cautiously
with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. If eye irritation persists: Get medical attention.

Storage

:

Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50
°C/122 °F. Store in a well-ventilated place.

Disposal

Dispose of contents and container in accordance with all local, regional, national and
international regulations.

Hazards not otherwise
classified

:

None known.

Please refer to the SDS for additional information. Keep out of reach of children. Keep
upright in a cool, dry place. Do not discard empty can in trash compactor.

Supplemental label
elements

DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which
can cause permanent brain and nervous system damage. Intentional misuse by
deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING:
This product contains chemicals known to the State of California to cause cancer and
birth defects or other reproductive harm. FOR INDUSTRIAL USE ONLY.

:

Section 3. Composition/information on ingredients

Acetone

82

67-64-1

Toluene

3.5

108-88-3

Light Aliphatic Hydrocarbon Solvent

2.14

64742-49-0

Light Aliphatic Hydrocarbon Solvent

2.14

68410-97-9

Lt. Aliphatic Hydrocarbon Solvent

1.7

64742-89-8

Ingredient name

CAS number

% by weight

There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health and hence require reporting in this section.

Other means of
identification

:

Not available.

Substance/mixture

CAS number/other identifiers

:

Occupational exposure limits, if available, are listed in Section 8.

Mixture

Any concentration shown as a range is to protect confidentiality or is due to batch variation.

Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.

Section 4. First aid measures

Eye contact

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Description of necessary first aid measures

Date of issue/Date of revision

:

6/28/2016

Date of previous issue

:

6/4/2016

Version

:

2.01

2/14

Section 4. First aid measures

Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and
keep at rest in a position comfortable for breathing. If material has been swallowed and
the exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention. If necessary,
call a poison center or physician. Never give anything by mouth to an unconscious
person. If unconscious, place in recovery position and get medical attention
immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt
or waistband.

Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing
before reuse. Clean shoes thoroughly before reuse.

Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it
is suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Get medical attention. If necessary, call a poison center or physician. If unconscious,
place in recovery position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Skin contact

Inhalation

Ingestion

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:

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Most important symptoms/effects, acute and delayed

Inhalation

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Can cause central nervous system (CNS) depression. May cause drowsiness or
dizziness. May cause respiratory irritation.

Can cause central nervous system (CNS) depression.

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Ingestion

Skin contact

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No known significant effects or critical hazards.

Causes serious eye irritation.

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Eye contact

Over-exposure signs/symptoms

Skin contact

Ingestion

Inhalation

Adverse symptoms may include the following:
respiratory tract irritation
coughing
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
reduced fetal weight
increase in fetal deaths
skeletal malformations

Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations

Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations

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Eye contact

:

Adverse symptoms may include the following:
pain or irritation
watering
redness

Potential acute health effects

Indication of immediate medical attention and special treatment needed, if necessary

Date of issue/Date of revision

:

6/28/2016

Date of previous issue

:

6/4/2016

Version

:

2.01

3/14

Section 4. First aid measures

Protection of first-aiders

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No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation.

Notes to physician

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Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.

Specific treatments

:

No specific treatment.

See toxicological information (Section 11)

Section 5. Fire-fighting measures

Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.

Hazardous thermal
decomposition products

Specific hazards arising
from the chemical

Decomposition products may include the following materials:
carbon dioxide
carbon monoxide

Extremely flammable aerosol. In a fire or if heated, a pressure increase will occur and
the container may burst, with the risk of a subsequent explosion. Gas may accumulate
in low or confined areas or travel a considerable distance to a source of ignition and
flash back, causing fire or explosion. Bursting aerosol containers may be propelled from
a fire at high speed. Runoff to sewer may create fire or explosion hazard.

Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Special protective
equipment for fire-fighters

Use an extinguishing agent suitable for the surrounding fire.

Extinguishing media

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:
:

None known.

Suitable extinguishing
media

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Unsuitable extinguishing
media

:

Special protective actions
for fire-fighters

:

Section 6. Accidental release measures

Environmental precautions

Personal precautions, protective equipment and emergency procedures

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:

No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. In the case of aerosols being ruptured, care should be taken due to the rapid
escape of the pressurized contents and propellant. If a large number of containers are
ruptured, treat as a bulk material spillage according to the instructions in the clean-up
section. Do not touch or walk through spilled material. Shut off all ignition sources. No
flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).

Methods and materials for containment and cleaning up

For non-emergency
personnel

For emergency responders

:

If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non­emergency personnel".

Date of issue/Date of revision

:

6/28/2016

Date of previous issue

:

6/4/2016

Version

:

2.01

4/14

Section 6. Accidental release measures

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.

Large spill

:

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.

Small spill

:

Section 7. Handling and storage

Advice on general
occupational hygiene

Conditions for safe storage,
including any
incompatibilities

Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.

Store in accordance with local regulations. Store away from direct sunlight in a dry, cool
and well-ventilated area, away from incompatible materials (see Section 10) and food
and drink. Protect from sunlight. Store locked up. Eliminate all ignition sources. Use
appropriate containment to avoid environmental contamination.

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:

Protective measures

Put on appropriate personal protective equipment (see Section 8). Pressurized
container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do
not pierce or burn, even after use. Avoid exposure - obtain special instructions before
use. Avoid exposure during pregnancy. Do not handle until all safety precautions have
been read and understood. Do not get in eyes or on skin or clothing. Do not breathe
vapor or mist. Do not ingest. Avoid breathing gas. Use only with adequate ventilation.
Wear appropriate respirator when ventilation is inadequate. Store and use away from
heat, sparks, open flame or any other ignition source. Use explosion-proof electrical
(ventilating, lighting and material handling) equipment. Use only non-sparking tools.
Empty containers retain product residue and can be hazardous.

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Precautions for safe handling

Acetone

ACGIH TLV (United States, 3/2015).

TWA: 250 ppm 8 hours.
STEL: 500 ppm 15 minutes.

NIOSH REL (United States, 10/2013).

TWA: 250 ppm 10 hours.
TWA: 590 mg/m³ 10 hours.

OSHA PEL (United States, 2/2013).

TWA: 1000 ppm 8 hours.
TWA: 2400 mg/m³ 8 hours.

Toluene

OSHA PEL Z2 (United States, 2/2013).

TWA: 200 ppm 8 hours.
CEIL: 300 ppm
AMP: 500 ppm 10 minutes.

NIOSH REL (United States, 10/2013).

TWA: 100 ppm 10 hours.

Section 8. Exposure controls/personal protection

Ingredient name

Exposure limits

Control parameters

Occupational exposure limits (OSHA United States)

Date of issue/Date of revision

:

6/28/2016

Date of previous issue

:

6/4/2016

Version

:

2.01

5/14