Relevant identified uses of the substance or mixture and uses advised against
Industrial uses: Uses of substances as such or in preparations at industrial sites
Consumer uses: Private households (= general public = consumers)
Professional uses: Public domain (administration, education, entertainment, services, craftsmen)
Supplier's details :
Emergency telephone number
(with hours of operation)
For information regarding the use of this product by a consumer, please refer directly to the product label. This
industrial MSDS is provided for workplace employees, per US OSHA regulations. It contains recommendations
for handling of this product in an occupa tional, or workplace, setting.
Any first aid or warnings that are applicable to consumer use are stated directly on the product label, in
accordance with all applicable government regulations.
Section 2. Hazards identification
OSHA/HCS status :
Classification of the substance or
mixture
GHS label elements
Hazard pictograms :
This material is considered hazardous by the OSHA Hazard
Communication Standard (29 CFR 1910.1200).
FLAMMABLE AEROSOLS - Category 1
:
GASES UNDER PRESSURE - Compressed gas
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2B
Signal word :
Hazard statements :
Danger
Extremely flammable aerosol.
Contains gas under pressure; may explode if heated.
Causes eye irritation.
Pressurized container: may burst if heated.
Precautionary statements
General :
Prevention :
Keep out of reach of children.
Keep away from heat, sparks, open flames and hot surfaces. - No
smoking. Pressurized container: Do not pierce or burn, even after
use. Avoid breathing gas. Do not spray on an open flame or other
ignition source.
Response :
IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
If eye irritation persists: Get medical attention.
Storage :
Protect from sunlight. Do not expose to temperatures exceeding 50
°C/122 °F. Store in a well-ventilated place.
Disposal :
Supplemental label elements :
Hazards not otherwise classified :
Dispose of used up container in accordance with local regulations.
None known.
None known.
Version:
1.3
Date of issue/Date of revision:
11.10.2016
Date of previous issue:
05.18.2016
TRESemmé Hairspray (Aerosol) – All
Variants
Section 3. Composition/information on ingredients
Substance/mixture :
CAS number/other identifiers
Ingredient name % CAS number
Alcohol 50 - 75
Mixture
64-17-5
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Hydrofluorocarbon 152a 25 - 50
75-37-6
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
There are no additional ingredients present which, within the current knowledge of the supplier and in
the concentrations applicable, are classified as hazardous to health or the environment and hence require
reporting in this section.
Occupational exposure limits, if available, are listed in Section 8.
Section 4. First-aid measures
Description of necessary first aid measures
Eye contact :
Inhalation :
Skin contact :
Ingestion :
Version:
1.3
Date of issue/Date of revision:
Immediately flush eyes with plenty of water, occasionally lifting the
upper and lower eyelids. Check for and remove any contact lenses.
Continue to rinse for at least 10 minutes. If irritation persists, get
medical attention.
Remove victim to fresh air and keep at rest in a position comfortable
for breathing. If not breathing, if breathi ng is irreg ul a r or if
respiratory arrest occurs, provide artificial respiration or oxygen by
trained personnel. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Get medical attention if adverse
health effects persist or are severe. If unconscious, place in recovery
position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband.
In case of inhalation of decomposition products in a fire, symptoms
may be delayed. The exposed person may need to be kept under
medical surveillance for 48 hours.
Flush contaminated skin with plenty of water. Remove contaminated
clothing and shoes. Get medical attention if symptoms occur. Wash
clothing before reuse. Clean shoes thoroughly before reuse.
Wash out mouth with water. Remove dentures if any. Remove
victim to fresh air and keep at rest in a position comfortable for
breathing. If material has been swallowed and the exposed person is
conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not
induce vomiting unless directed to do so by medical personnel. If
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TRESemmé Hairspray (Aerosol) – All
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vomiting occurs, the head should be kept low so that vomit does not
enter the lungs. Get medical attention if adverse health effects persist
or are severe. Never give anything by mouth to an unconscious
person. If unconscious, place in recovery position and get medical
attention immediately. Maintain an open airway. Loosen tight
clothing such as a collar, tie, belt or waistband.
Most important symptoms/effects, acute and delayed
Potential acute health effects
Eye contact :
Inhalation :
Causes eye irritation.
Exposure to decomposition products may cause a health hazard.
Serious effects may be delayed following exposure.
Skin contact :
Ingestion :
No known significant effects or critical hazards.
May be irritating to mouth, throat and stomach.
Over-exposure signs/symptoms
Eye contact :
Adverse symptoms may include the following:
irritation
watering
redness
Inhalation :
Adverse symptoms may include the following:
respiratory tract irritation
coughing
Skin contact :
Ingestion :
No specific data.
No specific data.
Indication of immediate medical attention and special treatment needed, if necessary
Notes to physician :
In case of inhalation of decomposition products in a fire, symptoms
may be delayed. The exposed person may need to be kept under
medical surveillance for 48 hours.
Specific treatments :
No specific treatment.
Protection of first-aiders :
No action shall be taken involving any personal risk or withou t
suitable training. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation.
See toxicological information (Section 11)
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Section 5. Fire-fighting measures
Extinguishing media
Suitable extinguishing media :
Unsuitable extinguishing media :
NFPA 30B Classification :
Version:
1.3
Date of issue/Date of revision:
Use an extinguishing agent suitable for the surrounding fire.
None known.
Aerosol Level 1
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Specific hazards arising from the
chemical
Hazardous thermal
decomposition products
Special protective actions for firefighters
Special protective equipment for
fire-fighters
Extremely flammable aerosol. In a fire or if heated, a pressure
:
increase will occur and the container may burst, with the risk of a
subsequent explosion. Gas may accumulate in low or confined areas
or travel a considerable distance to a source of ignition and flash
back, causing fire or explosion. Bursting aerosol containers may be
propelled from a fire at high speed. Runoff to sewer may create fire
or explosion hazard.
Decomposition products may include the following materials:
:
carbonyl halides
Promptly isolate the scene by removing all persons from the vicinity
:
of the incident if there is a fire. No action shall be taken involving
any personal risk or without suitable training. Move containers from
fire area if this can be done without risk. Use water spray to keep
fire-exposed containers cool.
Fire-fighters should wear appropriate protective equipment and self-
:
contained breathing apparatus (SCBA) with a full face-piece
operated in positive pressure mode.
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Section 6. Accidental release measures
Personal precautions, protective equipment and emergency proce dures
For non-emergency personnel :
For emergency responders :
Environmental precautions :
Methods and materials for containment and cleaning up
Small spill :
Version:
1.3
Date of issue/Date of revision:
No action shall be taken involving any personal risk or withou t
suitable training. Evacuate surrounding areas. Keep unnecessary and
unprotected personnel from entering. In the case of aerosols being
ruptured, care should be taken due to the rapid escape of the
pressurised contents and propellant. If a large number of containers
are ruptured, treat as a bulk material spillage according to the
instructions in the clean-up section. Do not touch or walk through
spilt material. Shut off all ignition sources. No flares, smoking or
flames in hazard area. Avoid breathing vapour or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment.
If specialised clothing is required to deal with the spillage, take note
of any information in Section 8 on suitable and unsuitable materials.
See also the information in "For non-emergency personnel".
Avoid dispersal of spilt material and runoff and contact with soil,
waterways, drains and sewers. Inform the relevant authorities if the
product has caused environmental pollution (sewers, waterways, soil
or air).
Stop leak if without risk. Move containers from spill area. Use
spark-proof tools and explosion-proof equipment. Dilute with water
and mop up if water-soluble. Alternatively, or if water-insoluble,
absorb with an inert dry material and place in an appropriate waste
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disposal container. Dispose of via a licensed waste disposal
contractor.
Large spill :
Stop leak if without risk. Move containers from spill area. Use
spark-proof tools and explosion-proof equipment. Approach the
release from upwind. Prevent entry into sewers, water courses,
basements or confined areas. Wash spillages into an effluent
treatment plant or proceed as follows. Contain and collect spillage
with non-combustible, absorbent material e.g. sand, earth,
vermiculite or diatomaceous earth and place in container for disposal
according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material
may pose the same hazard as the spilt product. Note: see Section 1
for emergency contact information and Section 13 for waste
disposal.
Section 7. Handling and storage
Precautions for safe handling
Protective measures :
Advice on general occupational
hygiene
Conditions for safe storage,
including any incompatibilities
Put on appropriate personal protective equipment (see Section 8).
Pressurised container: protect from sunlight and do not expose to
temperature exceeding 50°C/120°F. Do not pierce or burn, even
after use. Do not ingest. Avoid contact with eyes, skin and clot hi n g.
Avoid breathing gas. Avoid breathing va po u r or m i st . Use only wi t h
adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Store and use away from heat, sparks, open flame or any
other ignition source. Use explosion-proof electrical (ventilating,
lighting and material handling) equipment. Use only non-sparking
tools. Empty containers retain product residue and can be hazardous.
Eating, drinking and smoking should be proh i bi te d in areas where
:
this material is handled, stored and processed. Workers should wash
hands and face before eating, drinking and smoking. Remove
contaminated clothing and protective equipment before entering
eating areas. See also Section 8 for additional information on
hygiene measures.
Store in accordance with local regulations. Store away from direct
:
sunlight in a dry, cool and well-ventilated area, away from
incompatible materials (see Section 10) and food and drink. Protect
from sunlight. Eliminate all ignition sources. Use appropriate
containment to avoid environmental contamination.
Page:6/17
Section 8. Exposure controls/personal protection
Control parameters
Occupational exposure limits
Version:
1.3
Date of issue/Date of revision:
11.10.2016
Date of previous issue:
05.18.2016
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