Relevant identified uses of the substance or mixture and uses advised against
Industrial uses: Uses of substances as such or in preparations at industrial sites
Consumer uses: Private households (= general public = consumers)
Professional uses: Public domain (administration, education, entertainment, services, craftsmen)
Supplier's details :
Emergency telephone number
(with hours of operation)
For information regarding the use of this product by a consumer, please refer directly to the product label. This
industrial MSDS is provided for workplace employees, per US OSHA regulations. It contains recommendations
for handling of this product in an occupa tional, or workplace, setting.
Any first aid or warnings that are applicable to consumer use are stated directly on the product label, in
accordance with all applicable government regulations.
Section 2. Hazards identification
OSHA/HCS status :
Classification of the substance or
mixture
GHS label elements
Hazard pictograms :
This material is considered hazardous by the OSHA Hazard
Communication Standard (29 CFR 1910.1200).
FLAMMABLE AEROSOLS - Category 1
:
GASES UNDER PRESSURE - Compressed gas
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2B
Signal word :
Hazard statements :
Danger
Extremely flammable aerosol.
Contains gas under pressure; may explode if heated.
Causes eye irritation.
Pressurized container: may burst if heated.
Precautionary statements
General :
Prevention :
Keep out of reach of children.
Keep away from heat, sparks, open flames and hot surfaces. - No
smoking. Pressurized container: Do not pierce or burn, even after
use. Avoid breathing gas. Do not spray on an open flame or other
ignition source.
Response :
IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
If eye irritation persists: Get medical attention.
Storage :
Protect from sunlight. Do not expose to temperatures exceeding 50
°C/122 °F. Store in a well-ventilated place.
Disposal :
Supplemental label elements :
Hazards not otherwise classified :
Dispose of used up container in accordance with local regulations.
None known.
None known.
Version:
1.3
Date of issue/Date of revision:
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Date of previous issue:
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Section 3. Composition/information on ingredients
Substance/mixture :
CAS number/other identifiers
Ingredient name % CAS number
Alcohol 50 - 75
Mixture
64-17-5
Page:3/17
Hydrofluorocarbon 152a 25 - 50
75-37-6
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
There are no additional ingredients present which, within the current knowledge of the supplier and in
the concentrations applicable, are classified as hazardous to health or the environment and hence require
reporting in this section.
Occupational exposure limits, if available, are listed in Section 8.
Section 4. First-aid measures
Description of necessary first aid measures
Eye contact :
Inhalation :
Skin contact :
Ingestion :
Version:
1.3
Date of issue/Date of revision:
Immediately flush eyes with plenty of water, occasionally lifting the
upper and lower eyelids. Check for and remove any contact lenses.
Continue to rinse for at least 10 minutes. If irritation persists, get
medical attention.
Remove victim to fresh air and keep at rest in a position comfortable
for breathing. If not breathing, if breathi ng is irreg ul a r or if
respiratory arrest occurs, provide artificial respiration or oxygen by
trained personnel. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Get medical attention if adverse
health effects persist or are severe. If unconscious, place in recovery
position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband.
In case of inhalation of decomposition products in a fire, symptoms
may be delayed. The exposed person may need to be kept under
medical surveillance for 48 hours.
Flush contaminated skin with plenty of water. Remove contaminated
clothing and shoes. Get medical attention if symptoms occur. Wash
clothing before reuse. Clean shoes thoroughly before reuse.
Wash out mouth with water. Remove dentures if any. Remove
victim to fresh air and keep at rest in a position comfortable for
breathing. If material has been swallowed and the exposed person is
conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not
induce vomiting unless directed to do so by medical personnel. If
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vomiting occurs, the head should be kept low so that vomit does not
enter the lungs. Get medical attention if adverse health effects persist
or are severe. Never give anything by mouth to an unconscious
person. If unconscious, place in recovery position and get medical
attention immediately. Maintain an open airway. Loosen tight
clothing such as a collar, tie, belt or waistband.
Most important symptoms/effects, acute and delayed
Potential acute health effects
Eye contact :
Inhalation :
Causes eye irritation.
Exposure to decomposition products may cause a health hazard.
Serious effects may be delayed following exposure.
Skin contact :
Ingestion :
No known significant effects or critical hazards.
May be irritating to mouth, throat and stomach.
Over-exposure signs/symptoms
Eye contact :
Adverse symptoms may include the following:
irritation
watering
redness
Inhalation :
Adverse symptoms may include the following:
respiratory tract irritation
coughing
Skin contact :
Ingestion :
No specific data.
No specific data.
Indication of immediate medical attention and special treatment needed, if necessary
Notes to physician :
In case of inhalation of decomposition products in a fire, symptoms
may be delayed. The exposed person may need to be kept under
medical surveillance for 48 hours.
Specific treatments :
No specific treatment.
Protection of first-aiders :
No action shall be taken involving any personal risk or withou t
suitable training. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation.
See toxicological information (Section 11)
Page:4/17
Section 5. Fire-fighting measures
Extinguishing media
Suitable extinguishing media :
Unsuitable extinguishing media :
NFPA 30B Classification :
Version:
1.3
Date of issue/Date of revision:
Use an extinguishing agent suitable for the surrounding fire.
None known.
Aerosol Level 1
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Specific hazards arising from the
chemical
Hazardous thermal
decomposition products
Special protective actions for firefighters
Special protective equipment for
fire-fighters
Extremely flammable aerosol. In a fire or if heated, a pressure
:
increase will occur and the container may burst, with the risk of a
subsequent explosion. Gas may accumulate in low or confined areas
or travel a considerable distance to a source of ignition and flash
back, causing fire or explosion. Bursting aerosol containers may be
propelled from a fire at high speed. Runoff to sewer may create fire
or explosion hazard.
Decomposition products may include the following materials:
:
carbonyl halides
Promptly isolate the scene by removing all persons from the vicinity
:
of the incident if there is a fire. No action shall be taken involving
any personal risk or without suitable training. Move containers from
fire area if this can be done without risk. Use water spray to keep
fire-exposed containers cool.
Fire-fighters should wear appropriate protective equipment and self-
:
contained breathing apparatus (SCBA) with a full face-piece
operated in positive pressure mode.
Page:5/17
Section 6. Accidental release measures
Personal precautions, protective equipment and emergency proce dures
For non-emergency personnel :
For emergency responders :
Environmental precautions :
Methods and materials for containment and cleaning up
Small spill :
Version:
1.3
Date of issue/Date of revision:
No action shall be taken involving any personal risk or withou t
suitable training. Evacuate surrounding areas. Keep unnecessary and
unprotected personnel from entering. In the case of aerosols being
ruptured, care should be taken due to the rapid escape of the
pressurised contents and propellant. If a large number of containers
are ruptured, treat as a bulk material spillage according to the
instructions in the clean-up section. Do not touch or walk through
spilt material. Shut off all ignition sources. No flares, smoking or
flames in hazard area. Avoid breathing vapour or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment.
If specialised clothing is required to deal with the spillage, take note
of any information in Section 8 on suitable and unsuitable materials.
See also the information in "For non-emergency personnel".
Avoid dispersal of spilt material and runoff and contact with soil,
waterways, drains and sewers. Inform the relevant authorities if the
product has caused environmental pollution (sewers, waterways, soil
or air).
Stop leak if without risk. Move containers from spill area. Use
spark-proof tools and explosion-proof equipment. Dilute with water
and mop up if water-soluble. Alternatively, or if water-insoluble,
absorb with an inert dry material and place in an appropriate waste
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disposal container. Dispose of via a licensed waste disposal
contractor.
Large spill :
Stop leak if without risk. Move containers from spill area. Use
spark-proof tools and explosion-proof equipment. Approach the
release from upwind. Prevent entry into sewers, water courses,
basements or confined areas. Wash spillages into an effluent
treatment plant or proceed as follows. Contain and collect spillage
with non-combustible, absorbent material e.g. sand, earth,
vermiculite or diatomaceous earth and place in container for disposal
according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material
may pose the same hazard as the spilt product. Note: see Section 1
for emergency contact information and Section 13 for waste
disposal.
Section 7. Handling and storage
Precautions for safe handling
Protective measures :
Advice on general occupational
hygiene
Conditions for safe storage,
including any incompatibilities
Put on appropriate personal protective equipment (see Section 8).
Pressurised container: protect from sunlight and do not expose to
temperature exceeding 50°C/120°F. Do not pierce or burn, even
after use. Do not ingest. Avoid contact with eyes, skin and clot hi n g.
Avoid breathing gas. Avoid breathing va po u r or m i st . Use only wi t h
adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Store and use away from heat, sparks, open flame or any
other ignition source. Use explosion-proof electrical (ventilating,
lighting and material handling) equipment. Use only non-sparking
tools. Empty containers retain product residue and can be hazardous.
Eating, drinking and smoking should be proh i bi te d in areas where
:
this material is handled, stored and processed. Workers should wash
hands and face before eating, drinking and smoking. Remove
contaminated clothing and protective equipment before entering
eating areas. See also Section 8 for additional information on
hygiene measures.
Store in accordance with local regulations. Store away from direct
:
sunlight in a dry, cool and well-ventilated area, away from
incompatible materials (see Section 10) and food and drink. Protect
from sunlight. Eliminate all ignition sources. Use appropriate
containment to avoid environmental contamination.
Page:6/17
Section 8. Exposure controls/personal protection
Control parameters
Occupational exposure limits
Version:
1.3
Date of issue/Date of revision:
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Ingredient nameExposure limits
Alcohol
OSHA PEL 1989 1989-03-01 TWA
1,900 mg/m3
1,000 ppm
Form:
OSHA PEL 1993-06-30 TWA
1,900 mg/m3
1,000 ppm
Form:
NIOSH REL 1994-06-01 TWA
1,900 mg/m3
1,000 ppm
Form:
ACGIH TLV 2008-11-24 STEL
1,000 ppm
Hydrofluorocarbon 152a
AIHA WEEL 1999-01-01 TWA
1,000 ppm
Page:7/17
Appropriate engineering controls :
Use only with adequate ventilation. If user operations generate dust,
fumes, gas, vapour or mist, use process enclosures, local exhaust
ventilation or other engineering controls to keep worker exposure to
airborne contaminants below any recommended or statutory limits.
The engineering controls also need to keep gas, vapour o r d ust
concentrations below any lower explosive limits. Use explosionproof ventilation equipment.
Environmental exposure controls :
Emissions from ventilation or work process equipment should be
checked to ensure they comply with the requirements of
environmental protection legislation. In some cases, fume scrubbers,
filters or engineering modifications to the process equipment will be
necessary to reduce emissions to acceptable levels.
Individual protection measures
Hygiene measures :
Wash hands, forearms and face thoroughly after handling chemical
products, before eating, smoking and using the lavatory and at the
end of the working period. Appropriate techni q ues sh ould be used to
remove potentially contaminated clothing. Wash contaminated
clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Eye/face protection :
Safety eyewear complying with an approved standard should be
used when a risk assessment indicates this is necessary to avoid
exposure to liquid splashes, mists, gases or dusts. If contact is
possible, the following protection should be wo rn , unless the
assessment indicates a higher degree of protection: chemical splash
goggles.
Skin protection
Version:
1.3
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TRESemmé Hairspray (Aerosol) – All
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Hand protection :
Chemical-resistant, impervious gloves complying with an approved
standard should be worn at all times when handling chemical
products if a risk assessment indicates this is necessary. Considering
the parameters specified by the glove manufacturer, check during
use that the gloves are still retaining their protective properties. It
should be noted that the time to breakthrough for any glove material
may be different for different glove manufacturers. In the case of
mixtures, consisting of several substances, the protection time of the
gloves cannot be accurately estimated.
Body protection :
Personal protective equipment for the body should be selected based
on the task being performed and the risks involved and sh ould be
approved by a specialist before handling this product., When there is
a risk of ignition from static electricity, wear anti-static protective
clothing., For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
Other skin protection :
Appropriate footwear and any additional skin protection measures
should be selected based on the task being performed and the risks
involved and should be approved by a specialist before handling this
product.
Respiratory protection :
Use a properly fitted, air-purifying or air-fed respirator complying
with an approved standard if a risk assessment indicates this is
necessary. Respirator selection must be based on known or
anticipated exposure levels, the hazards of the product and the safe
working limits of the selected respirator.
Page:8/17
Section 9. Physical and chemical properties
Appearance
Physical state :
Colour :
Odour :
Odour threshold :
pH :
Melting point :
Boiling point :
Flash point :
Evaporation rate :
Flammability (solid, gas) :
Lower and upper explosive
(flammable) limits
Vapour density :
Relative density :
Solubility :
Solubility in water :
Partition coefficient: noctanol/water
Version:
1.3
Date of issue/Date of revision:
liquid [aerosol]
colourless
perfumed
Not available.
Not available.
Not applicable
Not available.
Not available.
Not available.
Not available.
Lower: Not available.
:
Upper: Not available.
Not available.
Not available.
Not available.
Not available.
Not available.
:
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Auto-ignition temperature :
Decomposition temperature :
Viscosity :
Not available.
Not available.
Dynamic: Not available.
Kinematic: Not available.
Aerosol product
Type of aerosol :
Can pressure :
Spray
<= 140 psi.
Heat of combustion :
< 20 J/kg
Ignition distance :
<61 cm
Enclosed space ignition - Time
Not available.
:
equivalent
Enclosed space ignition -
Not available.
:
Deflagration density
Flame height :
Flame duration :
Not available.
Not available.
Page:9/17
Section 10. Stability and reactivity
Reactivity :
No specific test data related to reactivity available for this product or
its ingredients.
Chemical stability :
Possibility of hazardous reactions :
The product is stable.
Under normal conditions of storage and use, hazardous reactions
will not occur.
Conditions to avoid :
Incompatible materials :
Hazardous decomposition
products
Avoid all possible sources of ignition (spark or flame).
No specific data.
Under normal conditions of storage and use, hazardous
:
decomposition products should not be produced. Under normal
conditions of storage and use, hazardous decomposition products
should not be produced.
Section 11. Toxicological information
Information on toxicological effects
Acute toxicity
Conclusion/Summary :
Irritation/Corrosion
Conclusion/Summary Skin :
Eyes :
Respiratory :
Version:
1.3
Date of issue/Date of revision:
Very low toxicity to humans or animals.
The mixture is not an irritant for the skin.
Causes eye irritation.
Based on available data, the classification criteria are not met.
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Sensitisation
Conclusion/Summary
Skin :
Respiratory :
Based on available data, the classification criteria are not met.
Based on available data, the classification criteria are not met.
Mutagenicity
Conclusion/Summary :
Not applicable.
Carcinogenicity
Conclusion/Summary :
Not classified or listed by IARC, NTP, OSHA, EU and ACGIH.
Reproductive toxicity
Conclusion/Summary :
Not applicable.
Teratogenicity
Conclusion/Summary :
Not applicable.
Specific target organ toxicity (single exposure)
Not available.
Specific target organ toxicity (repeated exposure)
Not available.
Aspiration hazard
Not available.
Information on the likely routes
Not available.
:
of exposure
Potential acute health effects
Eye contact :
Inhalation :
Causes eye irritation.
Exposure to decomposition products may cause a health hazard.
Serious effects may be delayed following exposure.
Skin contact :
Ingestion :
No known significant effects or critical hazards.
May be irritating to mouth, throat and stomach.
Symptoms related to the physical, chemical and toxicological characteristics
Eye contact :
Adverse symptoms may include the following:
irritation
watering
redness
Page:10/17
Version:
1.3
Date of issue/Date of revision:
11.10.2016
Date of previous issue:
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TRESemmé Hairspray (Aerosol) – All
Variants
Inhalation :
Adverse symptoms may include the following:
respiratory tract irritation
coughing
Skin contact :
Ingestion :
No specific data.
No specific data.
Delayed and immediate effects and also chronic effects from short and long term exposure
No known significant effects or critical hazards.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
Numerical measures of toxicity
Acute toxicity estimates
Route ATE value
OralNot Applicable
Page:11/17
Section 12. Ecological information
Toxicity
Conclusion/Summary :
Persistence and degradability
Conclusion/Summary :
Version:
1.3
Date of issue/Date of revision:
No known significant effects or critical hazards.
No known significant effects or critical hazards.
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Conclusion/Summary :
No known significant effects or critical hazards.
Mobility in soil
Soil/water partition coefficient
Not available.
:
(KOC)
Other adverse effects :
No known significant effects or critical hazards.
Section 13. Disposal considerations
Disposal methods :
RCRA classification :
United States - RCRA Acute hazardous waste "P" List: Not listed
United States - RCRA Toxic hazardous waste "U" List: Not listed
The generation of waste should be avoided or minimised wherever
possible. Disposal of this product, s olut i o ns and any by - pr o duct s
should at all times comply with the requirements of environmental
protection and waste disposal legislation and any regio nal local
authority requirements. Dispose of surplus and non-recyclable
products via a licensed waste disposal contractor. Waste should not
be disposed of untreated to the sewer unless fully compliant with the
requirements of all authorities with jurisdiction. Waste packaging
should be recycled. Incineration or landfill should only be
considered when recycling is not feasible. This material and its
container must be disposed of in a safe way. Empty containers or
liners may retain some product residues. Do not puncture or
incinerate container.
D001 (Ignitable)
Page:12/17
Section 14. Transport information
FOR SHIPMENT IN
CONSUMER
PACKAGING
PROPER SHIPPING
NAME:
HAZARD CLASS:
Transport within user’s premises: always transport in closed
containers that are upright and secure. Ensure that persons
transporting the product have been trained in the event of an
accident or spillage.’
Transport in bulk according to Annex II of MARPOL 73/ 78 and the IBC Code
Not available.
Section 15. Regulatory information
U.S. Federal regulations :
United States - TSCA 8(d) - Health a nd safety studies: Not listed
United States - TSCA 8(a) - Preliminary assessment report
(PAIR): Not listed
United States - TSCA 8(a) - Chemical Data Reporting (CDR):
Not determined
United States - TSCA 8(a) - Dioxin/Furan precursor: Not listed
United States - TSCA 8(a) - Chemical risk rules: Not listed
United States - TSCA 6 - Proposed risk management: Not listed
United States - TSCA 6 - Final risk management: Not listed
United States - TSCA 5(e) - Substances consent order: Not listed
United States - TSCA 5(a)2 - Proposed significant new use rules:
Not listed
United States - TSCA 5(a)2 - Final significant new use rules:
Not listed
United States - TSCA 4(f) - Priority risk review: Not listed
United States - TSCA 4(a) - Proposed test rules: Not listed
United States - TSCA 4(a) - ITC Priority list: Not listed
United States - TSCA 4(a) - Final Test Rules: Not listed
United States - TSCA 12(b) - Chemical export notification:
None of the components are listed.
United States - TSCA 8(c) - Significant adverse reaction (SAR):
Not listed
United States - EPA Clean water act (CWA) section 307 Priority pollutants: Not listed
United States - EPA Clean water act (CWA) section 311 Hazardous substances: Not listed
United States - EPA Clean air act (CAA) section 112 Accidental release prevention - Flammable substances: Listed
United States - EPA Clean air act (CAA) section 112 Accidental release prevention - Toxic substances: Not listed
United States - Department of commerce - Precursor chemical:
Page:13/17
Limited Quantity,
Flammable Gas
ERG #126
Proper Shipping Name
& UN # must be shown
on the package.
Version:
1.3
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Date of previous issue:
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Not listed
Clean Air Act Section 112(b)
:
Not listed
Hazardous Air Pollutants (HAPs)
Clean Air Act Section 602 Class I
:
Not listed
Substances
Clean Air Act Section 602 Class
:
Not listed
II Substances
DEA List I Chemicals (Precursor
:
Not listed
Chemicals)
DEA List II Chemicals (Essential
:
Not listed
Chemicals)
SARA 302/304
:
Composition/information on ingredients
Name%EHSSAR A 302/304
Alcohol 50 - 75
Yes. SARA 304 RQ: 100 lb/lbs
Page:14/17
Hydrofluorocarbon 152a 25 - 50
Yes. SARA 304 RQ: 100 lb/lbs
SARA 304 RQ:
184.1 lbs
SARA 311/312
Classification:
Fire hazard
Sudden release of pressure
Immediate (acute) health hazard
Composition/information on ingredients
Name%Classification
Alcohol 50 - 75
SARA 313
None of the components are listed.
State regulations
Massachusetts :
New York :
The following components are listed:
Alcohol
None of the components are listed.
F, CH
Version:
1.3
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New Jersey :
The following components are listed:
Alcohol
Pennsylvania :
The following components are listed:
Alcohol
US California 22CCR Appendix X Substances
Alcohol
Page:15/17
California Prop. 65:
Not available.
United States inventory (TSCA
:
Exempted
8b)
Canada inventory :
Not determined.
International regulations
International lists :
Philippines inventory (PICCS): Not determined.
New Zealand Inventory of Chemicals (NZIoC): Not determined.
Korea inventory: Not determined.
China inventory (IECSC): Not determined.
Japan inventory: Not determined.
Malaysia Inventory (EHS Register): Not determined.
Taiwan inventory (CSNN): Not determined.
Australia inventory (AICS): Not determined.
Chemical Weapons Convention
List Schedule I Chemicals
Chemical Weapons Convention
List Schedule II Chemicals
Chemical Weapons Convention
List Schedule III Chemicals
EPCRA = Emergency Planning and Community Right‑To‑Know Act
EST = Eastern Standard Time
F = Fire
HAPS = Hazardous Air Pollutants
HCS = Hazard Communication Standard
HMIS = Hazardous Materials Information System
HVOC = High Volatile Organic Compound
GHS = Globally Harmonized System of Classification and Labelling of
Chemicals
IARC = International Agency for the Research of Cancer
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
ICAO = International Civil Aviation Organization
IMDG = International Maritime Dangerous Goods
IMO = International Maritime Organization
ITC = Interagency Testing Committee (TSCA)
KOC = Organic Carbon/Water Partition Constant
LogPow = logarithm of the octanol/water partition coefficient
LVOC = Low Volatile Organic Compound
MARPOL 73/78 = International Convention for the Prevention of Pollution
From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine
pollution)
MPPCF = Million Particles Per Cubic Foot
N/A = Not Applicable
NFPA = National Fire Protection Association
NOEC = No Observable Effect Concentration
NTP = National Toxicology Program
OSHA = Occupation Safety & Health Administration
PEL = Permissible Exposure Limit
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RCRA = Resource Conservation & Recovery Act
RQ = Reportable Quantity
RTK = Right-To-Know
SARA = Superfund Amendments & Reauthorization Act
STEL = Short-Term Exposure Limit
TBD = To Be Determined
TCC = Tagliabue Closed Cup
TCLP = Toxicity Characteristic Leaching Procedure
TDG = Transport of Dangerous Goods
TLV = Threshold Limit Value
TSCA = Toxic Substances Control Act
TWA = Time Weighted Average
UN = United Nations
References :
Evaluation method used for mixture classification: Calculation
method.
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the abovenamed supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or
completeness of the information contained herein. Final determination of suitability of any material is the
sole responsibility of the user. All materials may present unknown hazards and should be used with
caution. Although certain hazards are described herein, we cannot guarantee that these are the only
hazards that exist.
Version:
1.3
Date of issue/Date of revision:
11.10.2016
Date of previous issue:
05.18.2016
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