Todol Products B1612374 User Manual

Safety Data Sheet

according to Regulation (EC) No 1907/2006

Pur Fill NF16, code BF16

1C B2 polyurethane foam

Print date: 03.06.2014 Page 1 of 11

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Pur Fill NF16, code BF16

1C B2 polyurethane foam

1.2. Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture

Adhesives, sealants

1.3. Details of the supplier of the safety data sheet

Company name:

Street:

Telephone:

e-mail:

Contact person:

e-mail:

Internet:

Responsible Department:

1.4. Emergency telephone
number:

HAGO Chemotechnik GmbH & Co. KG

Bodenseestr. 217

D-81243 MünchenPlace:

[phone]

[e-mail]

Claudia Meyer-Pundsack

[e-mail]

www.hago.de

Dept. Development and Application

public emergency number
Giftnotruf Berlin 030-30686-790 (24 h)

Telephone:

-58

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Indications of danger: F+ - Extremely flammable, Xn - Harmful, Xi - Irritant
R phrases:
Extremely flammable.
Irritating to eyes, respiratory system and skin.
Limited evidence of a carcinogenic effect.
May cause sensitisation by inhalation and skin contact.
Harmful: danger of serious damage to health by prolonged exposure through inhalation.

GHS classification

Hazard categories:
Aerosol: Aerosol 1
Skin corrosion/irritation: Skin Irrit. 2
Serious eye damage/eye irritation: Eye Irrit. 2
Respiratory/skin sensitization: Resp. Sens. 1
Respiratory/skin sensitization: Skin Sens. 1
Carcinogenicity: Carc. 2
Specific target organ toxicity - single exposure: STOT SE 3
Specific target organ toxicity - repeated exposure: STOT RE 2
Hazard Statements:
Extremely flammable aerosol.
Pressurised container: May burst if heated.
Causes skin irritation.
May cause an allergic skin reaction.
Causes serious eye irritation.
May cause allergy or asthma symptoms or breathing difficulties if inhaled .
May cause respiratory irritation.
Suspected of causing cancer.
May cause damage to organs through prolonged or repeated exposure.

2.2. Label elements

Revision No: 7,01 Revision date: 03.06.2014 GB - EN

Safety Data Sheet

according to Regulation (EC) No 1907/2006

Pur Fill NF16, code BF16

1C B2 polyurethane foam

Print date: 03.06.2014 Page 2 of 11

Hazardous components which must be listed on the label

Diphenylmethanediisocyanate, isomers and homologues

Signal word:

Pictograms:

Hazard statements

H222 Extremely flammable aerosol.
H229 Pressurised container: May burst if heated.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled .
H335 May cause respiratory irritation.
H351 Suspected of causing cancer.
H373 May cause damage to organs through prolonged or repeated exposure.

Precautionary statements

P410+P412 Protect from sunlight. Do no expose to temperatures exceeding 50 °C/122 °F.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if

present and easy to do. Continue rinsing.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P271 Use only outdoors or in a well-ventilated area.
P260 Do not breathe vapour/aerosol.
P251 Do not pierce or burn, even after use.
P211 Do not spray on an open flame or other ignition source.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No

smoking.
P102 Keep out of reach of children.

Special labelling of certain mixtures

EUH204 Contains isocyanates. May produce an allergic reaction.

2.3. Other hazards

In case of insufficient ventilation and/or through use, explosive/highly flammable mixtures may develop.

Danger

GHS02-GHS07-GHS08

Persons already sensitised to diisocyanates may develop allergic reactions when using this product.
Persons suffering from asthma, eczema or skin problems should avoid contact, including dermal
contact, with this product. This product should not be used under conditions of poor ventilation unless a
protective mask with an appropriate gas filter (i.e. type A1 according to standard EN 14387) is used.

SECTION 3: Composition/information on ingredients

3.2. Mixtures

Revision No: 7,01 Revision date: 03.06.2014 GB - EN

Safety Data Sheet

according to Regulation (EC) No 1907/2006

Pur Fill NF16, code BF16

1C B2 polyurethane foam

Print date: 03.06.2014 Page 3 of 11

Hazardous components

EC No
CAS No

Index No

REACH No

Chemical name
Classification
GHS classification

Quantity

Diphenylmethanediisocyanate, isomers and homologues
Carc. Cat. 3, Xn - Harmful, Xi - Irritant R40-20-48/20-36/37/38-42/439016-87-9

615-005-01-6

01-2119486772-26

603-019-00-8
01-2119472128-37

601-004-00-0

601-003-00-5

Acute Tox. 4, Skin Irrit. 2, Eye Irrit. 2, Resp. Sens. 1, Skin Sens. 1, Carc. 2, STOT SE
3, STOT RE 2; H332 H315 H319 H334 H317 H351 H335 H373

Tris (2-Chloroisopropyl) Phosphate237-158-7
Xn - Harmful R2213674-84-5

Acute Tox. 4; H302

dimethyl ether204-065-8
F+ - Extremely flammable R12115-10-6

Flam. Gas 1; H220

isobutane200-857-2
F+ - Extremely flammable R1275-28-5

Flam. Gas 1; H220

propane200-827-9
F+ - Extremely flammable R1274-98-6

Flam. Gas 1; H220

Full text of R and H phrases: see Section 16.

SECTION 4: First aid measures

4.1. Description of first aid measures

General information

Move victim out of danger zone. In case of accident or unwellness, seek medical advice immediately
(show directions for use or safety data sheet if possible).

After inhalation

Provide fresh air. In case of irregular breathing or respiratory arrest provide artificial respiration.

After contact with skin

After contact with skin, wash immediately with: Water and soap. In case of skin irritation, seek medical
treatment.

After contact with eyes

In case of contact with eyes, rinse immediately with plenty of flowing water for 10 to 15 minutes holding
eyelids apart. Subsequently consult an ophthalmologist.

After ingestion

Do NOT induce vomiting. Call a physician immediately.

4.2. Most important symptoms and effects, both acute and delayed

Allergic reactions. May cause sensitization by inhalation and skin contact.
Danger of sticking eyes and skin due to curing foam.

4.3. Indication of any immediate medical attention and special treatment needed

First Aid, decontamination, treatment of symptoms.

5 - < 20 %

10 - < 25 %

2.5 - < 10 %

2.5 - < 10 %

1 - < 10 %

SECTION 5: Firefighting measures

Revision No: 7,01 Revision date: 03.06.2014 GB - EN

Safety Data Sheet

according to Regulation (EC) No 1907/2006

Pur Fill NF16, code BF16

1C B2 polyurethane foam

Print date: 03.06.2014 Page 4 of 11

5.1. Extinguishing media

Suitable extinguishing media

Carbon dioxide (CO2). Foam. Extinguishing powder.

Unsuitable extinguishing media

High power water jet.

5.2. Special hazards arising from the substance or mixture

In case of fire may be liberated: Carbon monoxide. Carbon dioxide (CO2). Nitrogen oxides (NOx).
Hydrogen chloride (HCl). Hydrocyanic acid (hydrocyanic acid).
Vapours may form explosive mixtures with air.

5.3. Advice for firefighters

In case of fire and/or explosion do not breathe fumes. Wear a self-contained breathing apparatus and
chemical protective clothing.

Additional information

Use water spray jet to protect personnel and to cool endangered containers. Collect contaminated fire
extinguishing water separately. Do not allow entering drains or surface water.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Provide adequate ventilation. Remove all sources of ignition.
Avoid contact with skin, eyes and clothes. Do not breathe vapour/aerosol.

6.2. Environmental precautions

Do not allow to enter into surface water or drains.
Do not allow to enter into soil/subsoil.

6.3. Methods and material for containment and cleaning up

Provide adequate ventilation. Allow stiffening. Take up mechanically.

6.4. Reference to other sections

Treat the recovered material as prescribed in the section on waste disposal .
Handling, Personal protection equipment: See protective measures under point 7 and 8.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Advice on safe handling

Provide adequate ventilation as well as local exhaustion at critical locations. Do not use in enclosed
rooms.

Advice on protection against fire and explosion

Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50 °C. Do
not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material. Keep
away from sources of ignition - No smoking. Keep out of the reach of children. Vapours may form
explosive mixtures with air. Take precautionary measures against static discharge.

7.2. Conditions for safe storage, including any incompatibilities

Requirements for storage rooms and vessels

Keep in a cool, well-ventilated place.

Advice on storage compatibility

Do not store together with: Oxidizing agents.

Further information on storage conditions

Protect from sunlight. Do no expose to temperatures exceeding 50 °C/122 °F.
Recommended storage temperature: 15 - 23 °C. Storage above 23 °C will reduce shelf life
significantly, depending on temperature and duration.

7.3. Specific end use(s)

Revision No: 7,01 Revision date: 03.06.2014 GB - EN