Todol Products B1612373 User Manual

SAFETY DATA SHEET

1.1 Product Identifier

Product Name:

Pur Fill NF12

SDS ID Number

NF12

REACH Registration:

No data available

1.2 Relevant identified uses of the substance or mixture and uses advised against

General Use

One Component Polyurethane Foam Sealant HC

Uses advised against

1.3 Details of the supplier and of the safety data sheet

Manufacturer

TODOL Products

25 Washington Avenue

Natick, MA 01760

1-800-252-3818

1.4 Emergency telephone numbers

In the U.S.A

CHEMTREC (24 hours) 1-800-424-9300

International Emergency

CHEMTREC (24 hours) 1-703-527-3887

Product definition:

Mixture

Classification:

Flammable Aerosol- Category 1

Gases Under Pressure- Compressed Gas

Acute Toxicity Inhalation- Category 4

Skin Irritation- Category 2

Serious Eye Irritation- Category 2A

Respiratory Sensitizing- Category 1

Skin Sensitization – Category 1

Specific Target Organ Toxicity SE 3

Specific Target Organ Toxicity RE 2

2.2 Label elements

Hazard Symbols:
Signal Word:

DANGER

Hazard Statements:

H222- Extremely flammable aerosol

H280- Contains gas under pressure; may explode if heated

H315- Causes Skin Irritation

H317- May cause an allergic skin reaction

H319- Causes Serious Eye Irritation

H332- Harmful if inhaled

H334- May cause allergy or asthma symptoms or breathing difficulties if inhaled

H335- May cause respiratory irritation

H373- May cause damage to organs through prolonged or repeated exposure

Prevention:

P102- Keep Out of Reach of Children

P202- Do not handle until all safety precautions have been read and understood

P210- Keep away from heat/sparks/open flames/hot surfaces-No Smoking

P211- Do not spray on an open flame or other ignition source

P251- Pressurized Container: Do not pierce or burn, even after use

P261- Avoid breathing vapors or fumes

P262- Do not get in eyes, on skin, or on clothing

P264- Wash hands and other skin areas exposed to material thoroughly after handling

P271- Use only outdoors or in a well-ventilated area

P280- Wear protective gloves, protective clothing and eye protection

P285- In case of inadequate ventilation wear respiratory protection

Response:

P302+P352+P333+P313 IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get
medical attention

SECTION 1- PRODUCT AND COMPANY IDENTIFICATION

SECTION 2- HAZARDS IDENTIFICATION

2.1 Classification of substance or mixture

LP PU FOAM SEALANT HC ISSUE DATE: March 2005 LAST REV: January 2015 PAGE 2 OF 8

P304+P341 IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position
comfortable for breathing

P305+P351+P338- IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P314- Get medical advice if you feel unwell
P342+P311- If experiencing respiratory symptoms: Call a POISON CENTER or doctor

P381- Eliminate all ignition sources if safe to do so

Storage:

P403+P405- Store in a well-ventilated place. Store locked up.

P410- Protect from sunlight

P412- Do not expose to temperatures exceeding 50◦C/122◦F.

Disposal:

P501 Dispose of contents/container in accordance with applicable local/regional/national/international
regulations.

% by

Weight

Ingredient

CAS No.

EC Number

Annex Number

EC Classification

60-100

Urethane Pre-Polymer Blend (Non­Hazardous Polyol Blend)

Proprietary

5-10

4,4’ Diphenylmethane diisocyanate
(MDI)

101-68-8

202-966-0

615-005-00-9

Car. Cat 3, R40; Xn R20,

R48/20; Xi R36/37/37,

R42/43

5-10

Polymethylene polyphenyl isocyanate
(PMDI)

9016-87-9

500-079-6

3-7

Isobutane

75-28-5

200-857-2

601-004-00-0

F+, R12

3-7

Dimethyl ether

115-10-6

204-065-8

603-019-00-8

F+, R12

1-5

Propane

74-98-6

200-827-9

601-003-00-5

F+, R12

4.1 Description of first aid measures

Eye:

Immediately flush eyes with large amounts of water for at least 15 minutes, holding the eyes open with fingers and
occasionally lifting the upper and lower lids. Use lukewarm water if possible. If present and easy to do so, remove contact
lenses, If irritation persists, get medical attention.

Skin:

Inhalation:

In case of contact, immediately flush skin with plenty of soap and water. Foam will stick to skin, gently wipe product from skin
with a damp cloth and wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash clothing before
reuse. Call a physician if irritation persists.
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Obtain medical
attention.

Ingestion:

If swallowed, do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an
unconscious person. Get medical advice/attention.

4.2 Most important symptoms and effects, both acute and delayed

Eye:

May cause eye irritation.

Skin:
Inhalation

May cause skin irritation. Symptoms may include redness, edema, drying, defatting and cracking of the skin. May cause an
allergic reaction.
May be harmful if inhaled. May cause respiratory irritation. May cause allergy or asthma symptoms or breathing difficulties if
inhaled.

Ingestion:

May be harmful if swallowed. May cause gastrointestinal irritation: stomach distress, nausea, or vomiting.

4.3 Notes to the physician

Symptoms may not appear immediately. If case of an accident or if you feel unwell, seek medical advice immediately (show label or SDS if
possible).

SECTION 3- COMPOSITION/INFORMATION ON INGREDIENTS

There are not additional ingredients present which, within the current knowledge of the supplier and in the concentration applicable, are classified as
hazardous to the health or environment and hence require reporting in this section.

SECTION 4- FIRST AID MEASURES

LP PU FOAM SEALANT HC ISSUE DATE: March 2005 LAST REV: January 2015 PAGE 3 OF 8

5.1 Extinguishing media

Suitable methods of extinction: Use dry chemical, carbon dioxide, foam, Halon 1211 and water spray or fog.

Unsuitable methods of extinction: Do not use water jets and high pressure water as these may spread the fire

5.2 Special hazards arising from the substance or mixture

Contains flammable propellant. Eliminate all ignition sources. Closed containers may explode due to buildup of pressure when exposed to
extreme heat. Aerosol cans exposed to fire or high temperature can rupture and rocket. Cured foam will burn in the presence of heat,
oxygen and an ignition source.

5.3 Advice to firefighters

Products of combustion: May include and are not limited to: oxides of carbon, oxides of nitrogen, hydrogen fluoride, and traces of

hydrogen cyanide.

Keep upwind of fire. Wear full fire-fighting turn-out gear (full Bunker gear) and respiratory protection (SCBA). Use water spray to keep fire­exposed containers cool. Containers may explode if heated.

6.1 Personal precautions, protective equipment and emergency procedures

Use personal protective equipment recommended in Section 8. Isolate the hazard area and deny entry to unnecessary and
unprotected personnel. Eliminate sources of ignition.

6.2 Environmental precautions

Do not allow to enter sewers, drains, or waterways

6.3 Methods and materials for containment and cleaning up

Method for containment: Uncured product is very sticky; carefully remove the bulk of the foam by scraping it up and then immediately

remove the residue with a rag and solvent such as mineral spirits, acetone (nail polish remover), paint thinner, etc. Once the product is
cured it can only be removed mechanically by scraping, buffing, etc. Use appropriate PPE.

Methods for cleaning up: Scoop up material and place in a disposal container. Dispose of as plastic waste in accordance with all
applicable guidelines and regulations. Vapors can accumulate in low areas. Provide ventilation

6.4 Reference to other sections

For indications about waste treatment, see Section 13

7.1 Precautions for safe handling

Keep away from sources of ignition- No smoking. Do not spray on an open flame or other ignition source. Pressurized container: do not
pierce or burn, even after use. Container may explode if heated. Avoid contact with skin and eyes. Do not breathe
dust/fume/gas/mist/vapors/spray. Do not swallow. Use only in a well-ventilated area or outdoors. Avoid welding or other “hot work” in the
vicinity of exposed cured foam. When using do not eat, drink or smoke. (See section 8)

General hygiene advice: Launder contaminated clothing before reuse. Wash hands before eating, drinking or smoking.

7.2 Conditions for safe storage including any incompatibilities

Store in a dry place. Ideal use temperature is 65F to 80F (18C to 27C). Do not expose aerosol cans to open flame or temperatures
above 122F (50C). Excessive heat can cause premature aging of components resulting in a shorter shelf life. Storage below 55F
(12.7C) may affect foam quality if chemicals are not warmed to room temperature before using. Protect containers from physical abuse.
Keep containers upright. Keep away from children.

CAS No.

Ingredient

OSHA-PEL TWA

ACGIH-TLV

NIOSH

101-68-8

4,4’ Diphenylmethane

diisocyanate

0.02 PPM; 0.2 mg/m3
Ceiling

0.005 ppm; 0.051 mg/ m3 (8
hours) TWA

0.005 ppm; 0.050 mg/m3 TWA

0.02 ppm; 0.2 mg/m3 CEIL

75-28-5

Isobutane 1,000 ppm TWA

800 ppm; 1,900 mg/m3 TWA

115-10-6

Dimethyl ether

74-98-6

Propane

1,000 ppm; 1,800 mg/m

3

TWA

1,000 ppm1,000 ppm; 1,800

mg/m3 TWA

1,000 ppm; 1,800 mg/m3 TWA

8.2 Exposure Controls:

Engineering measures: Use ventilation adequate to keep exposures below recommended exposure limits.

Eye/face Protection: Wear protective safety glasses with side shields or goggles.

SECTION 5- FIRE FIGHTING MEASURES

SECTION 6- ACCIDENTAL RELEASE MEASURES

SECTION 7- HANDLING AND STORAGE

SECTION 8- EXPOSURE CONTROLS/ PERSONAL PROTECTION

8.1 Control Parameters