SAFETY DATA SHEET
PA1016 TM CHERRY HOT GEL 12/CS
Version 1.0
Revision Date 06/05/2015
Print Date 06/05/2015
Material name
:
PA1016 TM CHERRY HOT GEL 12/CS
Material number
:
000000000001043747
Company
:
Zep Inc.
Address
:
1310 Seaboard Industrial Blvd., NW
Atlanta, GA 30318
Telephone
:
404-352-1680
Emergency telephone numbers
For SDS Information
:
Compliance Services 1-877-428-9937
For a Medical Emergency
:
877-541-2016 Toll Free - All Calls Recorded
For a Transportation
Emergency
:
CHEMTREC: 800-424-9300 - All Calls Recorded.
In the District of Columbia 202-483-7616
Appearance
gel
Colour
clear
Odour
characteristic
Skin irritation
:
Category 2
Serious eye damage
:
Category 1
Respiratory sensitisation
:
Category 1
Skin sensitisation
:
Category 1
Hazard pictograms
:
Signal word
:
Danger
Hazard statements
:
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H334 May cause allergy or asthma symptoms or breathing
difficulties if inhaled.
Precautionary statements
:
Prevention:
P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
P264 Wash skin thoroughly after handling.
P272 Contaminated work clothing should not be allowed out of
the workplace.
SECTION 1. PRODUCT AND COMPANY IDENTIFICATION
Manufacturer or supplier's details
SECTION 2. HAZARDS IDENTIFICATION
Emergency Overview
GHS Classification
GHS Label element
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SAFETY DATA SHEET
PA1016 TM CHERRY HOT GEL 12/CS
Version 1.0
Revision Date 06/05/2015
Print Date 06/05/2015
P280 Wear eye protection/ face protection.
P280 Wear protective gloves.
P285 In case of inadequate ventilation wear respiratory
protection.
Response:
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P304 + P341 IF INHALED: If breathing is difficult, remove
victim to fresh air and keep at rest in a position comfortable for
breathing.
P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with
water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. Immediately call a POISON
CENTER or doctor/ physician.
P333 + P313 If skin irritation or rash occurs: Get medical
advice/ attention.
P342 + P311 If experiencing respiratory symptoms: Call a
POISON CENTER or doctor/ physician.
P362 Take off contaminated clothing and wash before reuse.
Storage:
P403 Store in a well-ventilated place.
Disposal:
P501 Dispose of contents/container in accordance with local
regulation.
IARC
No component of this product present at levels greater than or
equal to 0.1% is identified as probable, possible or confirmed
human carcinogen by IARC.
ACGIH
Confirmed animal carcinogen with unknown relevance to
humans
2-butoxyethanol
111-76-2
OSHA
No component of this product present at levels greater than or
equal to 0.1% is identified as a carcinogen or potential
carcinogen by OSHA.
NTP
No component of this product present at levels greater than or
equal to 0.1% is identified as a known or anticipated carcinogen
by NTP.
Substance / Mixture
:
Mixture
Chemical Name
CAS-No.
Concentration [%]
2-butoxyethanol
111-76-2
>= 5 - < 10
coumarin
91-64-5
>= 5 - < 10
eugenol
97-53-0
>= 5 - < 10
benzaldehyde
100-52-7
>= 5 - < 10
geraniol
106-24-1
>= 5 - < 10
benzyl acetate
140-11-4
>= 5 - < 10
Potential Health Effects
Carcinogenicity:
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous components
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SAFETY DATA SHEET
PA1016 TM CHERRY HOT GEL 12/CS
Version 1.0
Revision Date 06/05/2015
Print Date 06/05/2015
General advice
:
Move out of dangerous area.
Show this safety data sheet to the doctor in attendance.
Do not leave the victim unattended.
If inhaled
:
If unconscious place in recovery position and seek medical
advice.
If symptoms persist, call a physician.
In case of skin contact
:
If skin irritation persists, call a physician.
Wash off immediately with plenty of water for at least 15
minutes.
If on clothes, remove clothes.
In case of eye contact
:
Rinse immediately with plenty of water for at least 15 minutes.
Remove contact lenses.
Protect unharmed eye.
Keep eye wide open while rinsing.
If eye irritation persists, consult a specialist.
If swallowed
:
Keep respiratory tract clear.
Never give anything by mouth to an unconscious person.
If symptoms persist, call a physician.
Take victim immediately to hospital.
DO NOT induce vomiting unless directed to do so by a
physician or poison control center.
Suitable extinguishing media
:
Water spray jet
Carbon dioxide (CO2)
Alcohol-resistant foam
Dry chemical
Unsuitable extinguishing
media
:
High volume water jet
Specific hazards during
firefighting
:
Do not allow run-off from fire fighting to enter drains or water
courses.
Hazardous combustion
products
:
Carbon dioxide (CO2)
Carbon monoxide
Smoke
Specific extinguishing
methods
:
Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.
Further information
:
Collect contaminated fire extinguishing water separately. This
must not be discharged into drains.
Fire residues and contaminated fire extinguishing water must
be disposed of in accordance with local regulations.
Special protective equipment
for firefighters
:
Wear self-contained breathing apparatus for firefighting if
necessary.
SECTION 4. FIRST AID MEASURES
SECTION 5. FIREFIGHTING MEASURES
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SAFETY DATA SHEET
PA1016 TM CHERRY HOT GEL 12/CS
Version 1.0
Revision Date 06/05/2015
Print Date 06/05/2015
Personal precautions,
protective equipment and
emergency procedures
:
Use personal protective equipment.
Avoid dust formation.
Avoid breathing dust.
Ensure adequate ventilation.
Environmental precautions
:
Prevent product from entering drains.
Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains inform
respective authorities.
Methods and materials for
containment and cleaning up
:
Sweep up and shovel.
Keep in suitable, closed containers for disposal.
Advice on safe handling
:
Avoid formation of respirable particles.
Do not breathe vapours/dust.
Avoid exposure - obtain special instructions before use.
Avoid contact with skin and eyes.
For personal protection see section 8.
Smoking, eating and drinking should be prohibited in the
application area.
Provide sufficient air exchange and/or exhaust in work rooms.
Dispose of rinse water in accordance with local and national
regulations.
Persons susceptible to skin sensitisation problems or asthma,
allergies, chronic or recurrent respiratory disease should not
be employed in any process in which this mixture is being
used.
Conditions for safe storage
:
Keep container tightly closed in a dry and well-ventilated
place.
Containers which are opened must be carefully resealed and
kept upright to prevent leakage.
Electrical installations / working materials must comply with
the technological safety standards.
Materials to avoid
:
Oxidizing agents
Store and keep away from bases and alkalies.
Components
CAS-No.
Value type
(Form of
exposure)
Control
parameters /
Permissible
concentration
Basis
2-butoxyethanol
111-76-2
TWA
20 ppm
ACGIH
TWA
5 ppm
NIOSH REL
SECTION 6. ACCIDENTAL RELEASE MEASURES
SECTION 7. HANDLING AND STORAGE
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters
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SAFETY DATA SHEET
PA1016 TM CHERRY HOT GEL 12/CS
Version 1.0
Revision Date 06/05/2015
Print Date 06/05/2015
24 mg/m3
TWA
50 ppm
240 mg/m3
OSHA Z-1
TWA
25 ppm
120 mg/m3
OSHA P0
benzaldehyde
100-52-7
TWA
2 ppm
US WEEL
STEL
4 ppm
US WEEL
benzyl acetate
140-11-4
TWA
10 ppm
ACGIH
Component
CAS-No.
Control
parameters
Biological
specimen
Sampling
time
Permissible
concentration
Basis
2-BUTOXYETHANOL
111-76-2
Butoxyacetic
acid (BAA)
Urine
End of
shift (As
soon as
possible
after
exposure
ceases)
200 mg/g
ACGIH BEI
Remarks:
Creatinine
Respiratory protection
:
Use respiratory protection unless adequate local exhaust
ventilation is provided or exposure assessment demonstrates
that exposures are within recommended exposure guidelines.
Remarks
:
The suitability for a specific workplace should be discussed
with the producers of the protective gloves.
Eye protection
:
Ensure that eyewash stations and safety showers are close to
the workstation location.
Safety glasses
Skin and body protection
:
impervious clothing
Choose body protection according to the amount and
concentration of the dangerous substance at the work place.
Hygiene measures
:
When using do not eat or drink.
When using do not smoke.
Wash hands before breaks and at the end of workday.
Appearance
:
gel
Colour
:
clear
Odour
:
characteristic
Odour Threshold
:
no data available
pH : no data available
Melting point/freezing point
:
> 32.22 °C
Biological occupational exposure limits
Personal protective equipment
Hand protection
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
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SAFETY DATA SHEET
PA1016 TM CHERRY HOT GEL 12/CS
Version 1.0
Revision Date 06/05/2015
Print Date 06/05/2015
Boiling point
:
no data available
Flash point
:
60 °C
Evaporation rate
:
no data available
Upper explosion limit
:
not determined
Lower explosion limit
:
not determined
Vapour pressure
:
not determined
Relative vapour density
:
no data available
Density
:
no data available
Water solubility
:
partly soluble
Solubility in other solvents
:
not determined
Partition coefficient: noctanol/water
:
no data available
Auto-ignition temperature
:
not determined
Thermal decomposition
:
no data available
Viscosity, kinematic
:
no data available
Reactivity
:
Stable
Chemical stability
:
Stable under normal conditions.
Possibility of hazardous
reactions
:
No decomposition if stored and applied as directed.
Conditions to avoid
:
no data available
Heat, flames and sparks.
Incompatible materials
:
Strong acids
Bases
Oxidizing agents
Hazardous decomposition
products
:
Carbon monoxide
Organic Substances
Acute oral toxicity
:
Acute toxicity estimate : 2,698 mg/kg
Solubility(ies)
Viscosity
SECTION 10. STABILITY AND REACTIVITY
SECTION 11. TOXICOLOGICAL INFORMATION
Acute toxicity
Product:
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SAFETY DATA SHEET
PA1016 TM CHERRY HOT GEL 12/CS
Version 1.0
Revision Date 06/05/2015
Print Date 06/05/2015
Method: Calculation method
Acute inhalation toxicity
:
Acute toxicity estimate : > 10 mg/l
Exposure time: 4 h
Test atmosphere: dust/mist
Method: Calculation method
Acute dermal toxicity
:
Acute toxicity estimate : > 5,000 mg/kg
Method: Calculation method
Acute oral toxicity
:
LD50 Oral rat: 293 mg/kg
Remarks: Extremely corrosive and destructive to tissue.
Remarks: May cause irreversible eye damage.
Remarks: Causes sensitisation.
Components:
coumarin:
Skin corrosion/irritation
Product:
Serious eye damage/eye irritation
Product:
Respiratory or skin sensitisation
Product:
Germ cell mutagenicity
no data available
Carcinogenicity
no data available
Reproductive toxicity
no data available
2-butoxyethanol:
coumarin:
eugenol:
benzaldehyde:
geraniol:
benzyl acetate:
STOT - single exposure
no data available
STOT - repeated exposure
no data available
Aspiration toxicity
no data available
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SAFETY DATA SHEET
PA1016 TM CHERRY HOT GEL 12/CS
Version 1.0
Revision Date 06/05/2015
Print Date 06/05/2015
Remarks: no data available
Partition coefficient: noctanol/water
:
Remarks: no data available
Partition coefficient: noctanol/water
:
Pow: 1.48
Partition coefficient: noctanol/water
:
Pow: 2.6
Partition coefficient: noctanol/water
:
Pow: 1.96
Regulation
40 CFR Protection of Environment; Part 82 Protection of
Stratospheric Ozone - CAA Section 602 Class I
Substances
Remarks
This product neither contains, nor was manufactured
with a Class I or Class II ODS as defined by the U.S.
Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A
+ B).
Additional ecological
information
:
An environmental hazard cannot be excluded in the
event of unprofessional handling or disposal., Harmful to
aquatic life with long lasting effects.
Further information
Product:
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
no data available
Persistence and degradability
no data available
Bioaccumulative potential
Product:
Components:
benzaldehyde :
geraniol :
benzyl acetate :
Mobility in soil
no data available
Other adverse effects
no data available
Product:
SECTION 13. DISPOSAL CONSIDERATIONS
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SAFETY DATA SHEET
PA1016 TM CHERRY HOT GEL 12/CS
Version 1.0
Revision Date 06/05/2015
Print Date 06/05/2015
Waste from residues
:
Dispose of in accordance with local regulations.
Do not contaminate ponds, waterways or ditches with
chemical or used container.
The product should not be allowed to enter drains, water
courses or the soil.
Contaminated packaging
:
Empty remaining contents.
Dispose of as unused product.
Do not re-use empty containers.
Transportation Regulation: 49 CFR (USA):
NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS MATERIAL
Transportation Regulation: IMDG (Vessel):
NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS MATERIAL
Transportation Regulation: IATA (Cargo Air):
NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS MATERIAL
Transportation Regulation: IATA (Passenger Air):
NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS MATERIAL
Transportation Regulation: TDG (Canada):
NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS MATERIAL
SARA 311/312 Hazards
:
Acute Health Hazard
SARA 302
:
SARA 302: No chemicals in this material are subject to the
reporting requirements of SARA Title III, Section 302.
SARA 313
:
SARA 313: This material does not contain any chemical
components with known CAS numbers that exceed the
threshold (De Minimis) reporting levels established by SARA
Title III, Section 313.
Disposal methods
SECTION 14. TRANSPORT INFORMATION
SECTION 15. REGULATORY INFORMATION
EPCRA - Emergency Planning and Community Right-to-Know Act
CERCLA Reportable Quantity
This material does not contain any components with a CERCLA RQ.
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.
9 / 11
SAFETY DATA SHEET
PA1016 TM CHERRY HOT GEL 12/CS
Version 1.0
Revision Date 06/05/2015
Print Date 06/05/2015
California Prop 65
This product does not contain any chemicals known to State of
California to cause cancer, birth defects, or any other
reproductive harm.
TSCA
On TSCA Inventory
DSL
This product contains one or several components that are not on the
Canadian DSL nor NDSL.
AICS
Not in compliance with the inventory
NZIoC
Not in compliance with the inventory
PICCS
Not in compliance with the inventory
IECSC
Not in compliance with the inventory
NFPA:
HMIS III:
Hazard pictograms
:
Signal word
:
Danger:
Hazard statements
:
Causes skin irritation. May cause an allergic skin reaction. Causes serious eye
damage. May cause allergy or asthma symptoms or breathing difficulties if inhaled.
Precautionary statements
:
Prevention: Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. Wash skin
thoroughly after handling. Contaminated work clothing should not be allowed out of the
workplace. Wear eye protection/ face protection. Wear protective gloves. In case of
inadequate ventilation wear respiratory protection.
Response: IF ON SKIN: Wash with plenty of soap and water. IF INHALED: If breathing
is difficult, remove victim to fresh air and keep at rest in a position comfortable for
breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON
Flammability
Health
Instability
3
1
0
Special hazard.
FLAMMABILITY
PHYSICAL HAZARD
HEALTH
1
0
3*
0 = not significant, 1 =Slight,
2 = Moderate, 3 = High
4 = Extreme, * = Chronic
The components of this product are reported in the following inventories:
Inventory Acronym and Validity Area Legend:
AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL
(Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TSCA (USA)
SECTION 16. OTHER INFORMATION
Further information
OSHA GHS Label Information:
10 / 11
SAFETY DATA SHEET
PA1016 TM CHERRY HOT GEL 12/CS
Version 1.0
Revision Date 06/05/2015
Print Date 06/05/2015
CENTER or doctor/ physician. If skin irritation or rash occurs: Get medical advice/
attention. If experiencing respiratory symptoms: Call a POISON CENTER or doctor/
physician. Take off contaminated clothing and wash before reuse.
Storage: Store in a well-ventilated place.
Disposal: Dispose of contents/container in accordance with local regulation.
Version:
1.0
Revision Date:
06/05/2015
Print Date:
06/05/2015
We believe the statements, technical information and recommendations contained herein are
reliable, but they are given without warranty or guarantee of any kind. The information in this
document applies to this specific material as supplied. It may not be valid for this material if it
is used in combination with any other materials. Users should make their own investigations
to determine the suitability and applicability of the information for their particular purposes.
This SDS has been prepared by the Compliance Services organization supporting this
manufacturer, supplier or distributor.
Zep Inc. markets products under well recognized and established brand names such as Zep®,
Zep Commercial®,Zep Professional®, Enforcer®, National Chemical™, Selig™, Misty®, Next
Dimension™, Petro®, i-Chem®, TimeMist®, TimeWick™, MicrobeMax®, Country Vet®,
Konk®, Original Bike Spirits®, Blue Coral®, Black Magic®, Rain-X®, Niagara National™, FC
Forward Chemicals®,Rexodan®, Mykal™, and a number of private labeled brands.
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