SAFETY DATA SHEET
PA1015 TM CITRUS HOT GEL 12/CS
Version 1.0
Revision Date 06/06/2015
Print Date 10/14/2015
Material name
:
PA1015 TM CITRUS HOT GEL 12/CS
Material number
:
000000000001043744
Company
:
Zep Inc.
Address
:
1310 Seaboard Industrial Blvd., NW
Atlanta, GA 30318
Telephone
:
404-352-1680
Emergency telephone numbers
For SDS Information
:
Compliance Services 1-877-428-9937
For a Medical Emergency
:
877-541-2016 Toll Free - All Calls Recorded
For a Transportation
Emergency
:
CHEMTREC: 800-424-9300 - All Calls Recorded.
In the District of Columbia 202-483-7616
Appearance
liquid
Colour
colourless
Odour
pleasant
Skin corrosion
:
Category 1B
Serious eye damage
:
Category 1
Hazard pictograms
:
Signal word
:
Danger
Hazard statements
:
H314 Causes severe skin burns and eye damage.
Precautionary statements
:
Prevention:
P264 Wash skin thoroughly after handling.
P280 Wear protective gloves/ protective clothing/ eye
protection/ face protection.
Response:
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT
induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Remove/ Take off
immediately all contaminated clothing. Rinse skin with water/
shower.
P304 + P340 + P310 IF INHALED: Remove victim to fresh air
SECTION 1. PRODUCT AND COMPANY IDENTIFICATION
Manufacturer or supplier's details
SECTION 2. HAZARDS IDENTIFICATION
Emergency Overview
GHS Classification
GHS Label element
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SAFETY DATA SHEET
PA1015 TM CITRUS HOT GEL 12/CS
Version 1.0
Revision Date 06/06/2015
Print Date 10/14/2015
and keep at rest in a position comfortable for breathing.
Immediately call a POISON CENTER or doctor/ physician.
P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with
water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. Immediately call a POISON
CENTER or doctor/ physician.
P363 Wash contaminated clothing before reuse.
Storage:
P405 Store locked up.
Disposal:
P501 Dispose of contents/container in accordance with local
regulation.
IARC
No component of this product present at levels greater than or
equal to 0.1% is identified as probable, possible or confirmed
human carcinogen by IARC.
ACGIH
No component of this product present at levels greater than or
equal to 0.1% is identified as a carcinogen or potential
carcinogen by ACGIH.
OSHA
No component of this product present at levels greater than or
equal to 0.1% is identified as a carcinogen or potential
carcinogen by OSHA.
NTP
No component of this product present at levels greater than or
equal to 0.1% is identified as a known or anticipated carcinogen
by NTP.
Substance / Mixture
:
Mixture
Chemical Name
CAS-No.
Concentration [%]
Alcohols, C12-13, ethoxylated
66455-14-9
>= 10 - < 20
propan-2-ol
67-63-0
>= 5 - < 10
Quaternary ammonium compounds, benzyl-C1218-alkyldimethyl, chlorides
68391-01-5
>= 5 - < 10
ethanol
64-17-5
>= 1 - < 5
General advice
:
Move out of dangerous area.
Show this safety data sheet to the doctor in attendance.
Do not leave the victim unattended.
If inhaled
:
If unconscious place in recovery position and seek medical
advice.
Consult a physician after significant exposure.
In case of skin contact
:
If skin irritation persists, call a physician.
Wash off immediately with plenty of water for at least 15
Potential Health Effects
Carcinogenicity:
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous components
SECTION 4. FIRST AID MEASURES
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SAFETY DATA SHEET
PA1015 TM CITRUS HOT GEL 12/CS
Version 1.0
Revision Date 06/06/2015
Print Date 10/14/2015
minutes.
If on clothes, remove clothes.
In case of eye contact
:
Remove contact lenses.
Protect unharmed eye.
Keep eye wide open while rinsing.
If eye irritation persists, consult a specialist.
Rinse immediately with plenty of water for at least 15 minutes.
If swallowed
:
Keep respiratory tract clear.
Never give anything by mouth to an unconscious person.
If symptoms persist, call a physician.
DO NOT induce vomiting unless directed to do so by a
physician or poison control center.
Take victim immediately to hospital.
Suitable extinguishing media
:
Water spray jet
Alcohol-resistant foam
Carbon dioxide (CO2)
Dry chemical
Unsuitable extinguishing
media
:
High volume water jet
Specific hazards during
firefighting
:
Do not allow run-off from fire fighting to enter drains or water
courses.
Hazardous combustion
products
:
Carbon dioxide (CO2)
Carbon monoxide
Smoke
Nitrogen oxides (NOx)
Specific extinguishing
methods
:
Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.
Further information
:
Collect contaminated fire extinguishing water separately. This
must not be discharged into drains.
Fire residues and contaminated fire extinguishing water must
be disposed of in accordance with local regulations.
Special protective equipment
for firefighters
:
Wear self-contained breathing apparatus for firefighting if
necessary.
Personal precautions,
protective equipment and
emergency procedures
:
Use personal protective equipment.
Ensure adequate ventilation.
Remove all sources of ignition.
Evacuate personnel to safe areas.
Environmental precautions
:
Prevent product from entering drains.
Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains inform
SECTION 5. FIREFIGHTING MEASURES
SECTION 6. ACCIDENTAL RELEASE MEASURES
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SAFETY DATA SHEET
PA1015 TM CITRUS HOT GEL 12/CS
Version 1.0
Revision Date 06/06/2015
Print Date 10/14/2015
respective authorities.
Methods and materials for
containment and cleaning up
:
Soak up with inert absorbent material (e.g. sand, silica gel,
acid binder, universal binder, sawdust).
Sweep up or vacuum up spillage and collect in suitable
container for disposal.
Advice on safe handling
:
Avoid exposure - obtain special instructions before use.
Avoid contact with skin and eyes.
For personal protection see section 8.
Smoking, eating and drinking should be prohibited in the
application area.
Do not breathe vapours or spray mist.
Take precautionary measures against static discharges.
Provide sufficient air exchange and/or exhaust in work rooms.
Dispose of rinse water in accordance with local and national
regulations.
Conditions for safe storage
:
Keep container tightly closed in a dry and well-ventilated
place.
Observe label precautions.
Electrical installations / working materials must comply with
the technological safety standards.
Materials to avoid
:
Oxidizing agents
Components
CAS-No.
Value type
(Form of
exposure)
Control
parameters /
Permissible
concentration
Basis
propan-2-ol
67-63-0
TWA
200 ppm
ACGIH
STEL
400 ppm
ACGIH
TWA
400 ppm
980 mg/m3
NIOSH REL
ST
500 ppm
1,225 mg/m3
NIOSH REL
TWA
400 ppm
980 mg/m3
OSHA Z-1
TWA
400 ppm
980 mg/m3
OSHA P0
STEL
500 ppm
1,225 mg/m3
OSHA P0
ethanol
64-17-5
TWA
1,000 ppm
ACGIH
TWA
1,000 ppm
1,900 mg/m3
NIOSH REL
TWA
1,000 ppm
1,900 mg/m3
OSHA Z-1
SECTION 7. HANDLING AND STORAGE
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters
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SAFETY DATA SHEET
PA1015 TM CITRUS HOT GEL 12/CS
Version 1.0
Revision Date 06/06/2015
Print Date 10/14/2015
TWA
1,000 ppm
1,900 mg/m3
OSHA P0
Component
CAS-No.
Control
parameters
Biological
specimen
Sampling
time
Permissible
concentration
Basis
PROPAN-2-OL
67-63-0
Acetone
Urine
End of
shift at
end of
workwee
k
40 mg/l
ACGIH BEI
Respiratory protection
:
Use respiratory protection unless adequate local exhaust
ventilation is provided or exposure assessment demonstrates
that exposures are within recommended exposure guidelines.
Remarks
:
The suitability for a specific workplace should be discussed
with the producers of the protective gloves.
Eye protection
:
Ensure that eyewash stations and safety showers are close to
the workstation location.
Safety glasses
Skin and body protection
:
impervious clothing
Choose body protection according to the amount and
concentration of the dangerous substance at the work place.
Hygiene measures
:
When using do not eat or drink.
When using do not smoke.
Wash hands before breaks and at the end of workday.
Appearance
:
liquid
Colour
:
colourless
Odour
:
pleasant
Odour Threshold
:
no data available
pH : 6.5
Melting point/freezing point
:
no data available
Boiling point
:
no data available
Flash point
:
does not flash
Evaporation rate
:
no data available
Upper explosion limit
:
no data available
Lower explosion limit
:
no data available
Biological occupational exposure limits
Personal protective equipment
Hand protection
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
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SAFETY DATA SHEET
PA1015 TM CITRUS HOT GEL 12/CS
Version 1.0
Revision Date 06/06/2015
Print Date 10/14/2015
Vapour pressure
:
not determined
Relative vapour density
:
no data available
Density
:
1.02 g/cm3
Water solubility
:
no data available
Partition coefficient: noctanol/water
:
no data available
Auto-ignition temperature
:
not determined
Thermal decomposition
:
no data available
Viscosity, kinematic
:
no data available
Reactivity
:
Stable
Chemical stability
:
Stable under normal conditions.
Possibility of hazardous
reactions
:
No decomposition if stored and applied as directed.
Conditions to avoid
:
Heat, flames and sparks.
Incompatible materials
:
no data available
Hazardous decomposition
products
:
Carbon oxides
Acute oral toxicity
:
Acute toxicity estimate : 4,731 mg/kg
Method: Calculation method
Acute oral toxicity
:
LD50 Oral rat: 4,396 mg/kg
Method: Calculation method
Acute oral toxicity
:
LD50 Oral rat: 7,060 mg/kg
Acute inhalation toxicity
:
LC50 rat: 124.7 mg/l
Exposure time: 4 h
Solubility(ies)
Viscosity
SECTION 10. STABILITY AND REACTIVITY
SECTION 11. TOXICOLOGICAL INFORMATION
Acute toxicity
Product:
Components:
propan-2-ol:
ethanol:
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SAFETY DATA SHEET
PA1015 TM CITRUS HOT GEL 12/CS
Version 1.0
Revision Date 06/06/2015
Print Date 10/14/2015
Remarks: Extremely corrosive and destructive to tissue.
Remarks: May cause irreversible eye damage.
Remarks: no data available
Skin corrosion/irritation
Product:
Serious eye damage/eye irritation
Product:
Respiratory or skin sensitisation
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
no data available
Reproductive toxicity
no data available
Alcohols, C12-13, ethoxylated:
propan-2-ol:
Quaternary ammonium compounds, benzyl-C12-18-alkyldimethyl, chlorides:
ethanol:
STOT - single exposure
no data available
STOT - repeated exposure
no data available
Aspiration toxicity
no data available
Further information
Product:
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
no data available
Persistence and degradability
no data available
Bioaccumulative potential
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SAFETY DATA SHEET
PA1015 TM CITRUS HOT GEL 12/CS
Version 1.0
Revision Date 06/06/2015
Print Date 10/14/2015
Partition coefficient: noctanol/water
:
Remarks: no data available
Regulation
40 CFR Protection of Environment; Part 82 Protection of
Stratospheric Ozone - CAA Section 602 Class I
Substances
Remarks
This product neither contains, nor was manufactured
with a Class I or Class II ODS as defined by the U.S.
Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A
+ B).
Additional ecological
information
:
no data available
Waste from residues
:
Do not dispose of waste into sewer.
Do not contaminate ponds, waterways or ditches with
chemical or used container.
Send to a licensed waste management company.
Contaminated packaging
:
Empty remaining contents.
Dispose of as unused product.
Do not re-use empty containers.
Transportation Regulation: 49 CFR (USA):
NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS MATERIAL
Transportation Regulation: IMDG (Vessel):
NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS MATERIAL
Transportation Regulation: IATA (Cargo Air):
NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS MATERIAL
Transportation Regulation: IATA (Passenger Air):
NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS MATERIAL
Product:
Mobility in soil
no data available
Other adverse effects
no data available
Product:
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods
SECTION 14. TRANSPORT INFORMATION
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SAFETY DATA SHEET
PA1015 TM CITRUS HOT GEL 12/CS
Version 1.0
Revision Date 06/06/2015
Print Date 10/14/2015
Transportation Regulation: TDG (Canada):
NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS MATERIAL
SARA 311/312 Hazards
:
Acute Health Hazard
SARA 302
:
SARA 302: No chemicals in this material are subject to the
reporting requirements of SARA Title III, Section 302.
SARA 313
:
SARA 313: This material does not contain any chemical
components with known CAS numbers that exceed the
threshold (De Minimis) reporting levels established by SARA
Title III, Section 313.
California Prop 65
This product does not contain any chemicals known to State of
California to cause cancer, birth defects, or any other
reproductive harm.
TSCA
On TSCA Inventory
DSL
All components of this product are on the Canadian DSL.
AICS
On the inventory, or in compliance with the inventory
NZIoC
On the inventory, or in compliance with the inventory
PICCS
On the inventory, or in compliance with the inventory
IECSC
On the inventory, or in compliance with the inventory
SECTION 15. REGULATORY INFORMATION
EPCRA - Emergency Planning and Community Right-to-Know Act
CERCLA Reportable Quantity
This material does not contain any components with a CERCLA RQ.
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.
The components of this product are reported in the following inventories:
Inventory Acronym and Validity Area Legend:
AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL
(Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TSCA (USA)
SECTION 16. OTHER INFORMATION
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SAFETY DATA SHEET
PA1015 TM CITRUS HOT GEL 12/CS
Version 1.0
Revision Date 06/06/2015
Print Date 10/14/2015
NFPA:
HMIS III:
Hazard pictograms
:
Signal word
:
Danger:
Hazard statements
:
Causes severe skin burns and eye damage.
Precautionary statements
:
Prevention: Wash skin thoroughly after handling. Wear protective gloves/ protective
clothing/ eye protection/ face protection.
Response: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or
hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/
shower. IF INHALED: Remove victim to fresh air and keep at rest in a position
comfortable for breathing. Immediately call a POISON CENTER or doctor/ physician. IF
IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Immediately call a POISON CENTER or
doctor/ physician. Wash contaminated clothing before reuse.
Storage: Store locked up.
Disposal: Dispose of contents/container in accordance with local regulation.
Version:
1.0
Revision Date:
06/06/2015
Print Date:
10/14/2015
Flammability
Health
Instability
3
0
0
Special hazard.
FLAMMABILITY
PHYSICAL HAZARD
HEALTH
0
0
3
0 = not significant, 1 =Slight,
2 = Moderate, 3 = High
4 = Extreme, * = Chronic
Further information
OSHA GHS Label Information:
We believe the statements, technical information and recommendations contained herein are
reliable, but they are given without warranty or guarantee of any kind. The information in this
document applies to this specific material as supplied. It may not be valid for this material if it
is used in combination with any other materials. Users should make their own investigations
to determine the suitability and applicability of the information for their particular purposes.
This SDS has been prepared by the Compliance Services organization supporting this
manufacturer, supplier or distributor.
Zep Inc. markets products under well recognized and established brand names such as Zep®,
Zep Commercial®,Zep Professional®, Enforcer®, National Chemical™, Selig™, Misty®, Next
Dimension™, Petro®, i-Chem®, TimeMist®, TimeWick™, MicrobeMax®, Country Vet®,
Konk®, Original Bike Spirits®, Blue Coral®, Black Magic®, Rain-X®, Niagara National™, FC
Forward Chemicals®,Rexodan®, Mykal™, and a number of private labeled brands.
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