SAFETY DATA SHEET
A07712OS TM CITRUS 9000 L1 12N7.5 4/CS
Version 1.0
Revision Date 02/11/2015
Print Date 06/01/2015
Material name
:
A07712OS TM CITRUS 9000 L1 12N7.5 4/CS
Material number
:
000000000001042649
Company
:
Zep Inc.
Address
:
1310 Seaboard Industrial Blvd., NW
Atlanta, GA 30318
Telephone
:
404-352-1680
Emergency telephone numbers
For SDS Information
:
Compliance Services 1-877-428-9937
For a Medical Emergency
:
877-541-2016 Toll Free - All Calls Recorded
For a Transportation
Emergency
:
CHEMTREC: 800-424-9300 - All Calls Recorded.
In the District of Columbia 202-483-7616
Appearance
Aerosol containing a liquefied gas
Colour
colourless
Odour
characteristic
Flammable aerosols
:
Category 2
Gases under pressure
:
Liquefied gas
Eye irritation
:
Category 2A
Specific target organ toxicity single exposure
:
Category 3 (Central nervous system)
Hazard pictograms
:
Signal word
:
Warning
Hazard statements
:
H223 Flammable aerosol.
H280 Contains gas under pressure; may explode if heated.
H319 Causes serious eye irritation.
H336 May cause drowsiness or dizziness.
Precautionary statements
:
Prevention:
P210 Keep away from heat, hot surfaces, sparks, open flames
and other ignition sources. No smoking.
P211 Do not spray on an open flame or other ignition source.
SECTION 1. PRODUCT AND COMPANY IDENTIFICATION
Manufacturer or supplier's details
SECTION 2. HAZARDS IDENTIFICATION
Emergency Overview
GHS Classification
GHS Label element
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SAFETY DATA SHEET
A07712OS TM CITRUS 9000 L1 12N7.5 4/CS
Version 1.0
Revision Date 02/11/2015
Print Date 06/01/2015
P251 Pressurized container: Do not pierce or burn, even after
use.
P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
P264 Wash skin thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear eye protection/ face protection.
Response:
P304 + P340 + P312 IF INHALED: Remove victim to fresh air
and keep at rest in a position comfortable for breathing. Call a
POISON CENTER or doctor/ physician if you feel unwell.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water
for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing.
P337 + P313 If eye irritation persists: Get medical advice/
attention.
Storage:
P403 + P233 Store in a well-ventilated place. Keep container
tightly closed.
P405 Store locked up.
P410 + P412 Protect from sunlight. Do not expose to
temperatures exceeding 50 °C/ 122 °F.
Disposal:
P501 Dispose of contents/container in accordance with local
regulation.
IARC
No component of this product present at levels greater than or
equal to 0.1% is identified as probable, possible or confirmed
human carcinogen by IARC.
ACGIH
No component of this product present at levels greater than or
equal to 0.1% is identified as a carcinogen or potential
carcinogen by ACGIH.
OSHA
No component of this product present at levels greater than or
equal to 0.1% is identified as a carcinogen or potential
carcinogen by OSHA.
NTP
No component of this product present at levels greater than or
equal to 0.1% is identified as a known or anticipated carcinogen
by NTP.
Substance / Mixture
:
Mixture
Chemical Name
CAS-No.
Concentration [%]
1,1-difluoroethane
75-37-6
>= 50 - < 70
propan-2-ol
67-63-0
>= 20 - < 30
alkanes, C12-14-iso-
68551-19-9
>= 10 - < 20
Potential Health Effects
Carcinogenicity:
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous components
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SAFETY DATA SHEET
A07712OS TM CITRUS 9000 L1 12N7.5 4/CS
Version 1.0
Revision Date 02/11/2015
Print Date 06/01/2015
General advice
:
Show this safety data sheet to the doctor in attendance.
If inhaled
:
Remove to fresh air.
Call a physician or poison control centre immediately.
In case of skin contact
:
Wash off immediately with plenty of water for at least 15
minutes.
Call a physician if irritation persists.
In case of eye contact
:
In case of contact, immediately flush eyes with plenty of water
for at least 15 minutes.
If easy to do, remove contact lens, if worn.
Seek medical advice.
If swallowed
:
If swallowed, DO NOT induce vomiting unless directed to do
so by medical personnel.
Never give anything by mouth to an unconscious person.
Suitable extinguishing media
:
Foam
Carbon dioxide (CO2)
Water spray
Hazardous combustion
products
:
Carbon dioxide (CO2)
Carbon monoxide
Smoke
Specific extinguishing
methods
:
Further information
:
For safety reasons in case of fire, cans should be stored
separately in closed containments.
Use a water spray to cool fully closed containers.
Special protective equipment
for firefighters
:
Wear self-contained breathing apparatus for firefighting if
necessary.
Personal precautions,
protective equipment and
emergency procedures
:
Use personal protective equipment.
Remove all sources of ignition.
Evacuate personnel to safe areas.
Beware of vapours accumulating to form explosive
concentrations. Vapours can accumulate in low areas.
Environmental precautions
:
Prevent product from entering drains.
Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains inform
respective authorities.
Methods and materials for
containment and cleaning up
:
Soak up with inert absorbent material (e.g. sand, silica gel,
acid binder, universal binder, sawdust).
SECTION 4. FIRST AID MEASURES
SECTION 5. FIREFIGHTING MEASURES
SECTION 6. ACCIDENTAL RELEASE MEASURES
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SAFETY DATA SHEET
A07712OS TM CITRUS 9000 L1 12N7.5 4/CS
Version 1.0
Revision Date 02/11/2015
Print Date 06/01/2015
Sweep up and shovel into suitable containers for disposal.
Advice on safe handling
:
Do not breathe vapours/dust.
Keep away from fire (No Smoking).
Do not swallow.
Avoid contact with skin and eyes.
Smoking, eating and drinking should be prohibited in the
application area.
Use only with adequate ventilation.
Conditions for safe storage
:
BEWARE: Aerosol is pressurized. Keep away from direct sun
exposure and temperatures over 50 °C. Do not open by force
or throw into fire even after use. Do not spray on flames or
red-hot objects.
No smoking.
Keep container tightly closed in a dry and well-ventilated
place.
Observe label precautions.
Electrical installations / working materials must comply with
the technological safety standards.
Materials to avoid
:
Keep away from oxidising agents and strongly acid or alkaline
materials.
Storage temperature
:
< 49 °C
Components
CAS-No.
Value type
(Form of
exposure)
Control
parameters /
Permissible
concentration
Basis
1,1-difluoroethane
75-37-6
TWA
1,000 ppm
US WEEL
propan-2-ol
67-63-0
TWA
200 ppm
ACGIH
STEL
400 ppm
ACGIH
TWA
400 ppm
980 mg/m3
NIOSH REL
ST
500 ppm
1,225 mg/m3
NIOSH REL
TWA
400 ppm
980 mg/m3
OSHA Z-1
TWA
400 ppm
980 mg/m3
OSHA P0
STEL
500 ppm
1,225 mg/m3
OSHA P0
Component
CAS-No.
Control
parameters
Biological
specimen
Sampling
time
Permissible
concentration
Basis
SECTION 7. HANDLING AND STORAGE
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters
Biological occupational exposure limits
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SAFETY DATA SHEET
A07712OS TM CITRUS 9000 L1 12N7.5 4/CS
Version 1.0
Revision Date 02/11/2015
Print Date 06/01/2015
PROPAN-2-OL
67-63-0
Acetone
Urine
End of
shift at
end of
workwee
k
40 mg/l
ACGIH BEI
Respiratory protection
:
In the case of vapour formation use a respirator with an
approved filter.
In the case of dust or aerosol formation use respirator with an
approved filter.
Remarks
:
The suitability for a specific workplace should be discussed
with the producers of the protective gloves.
Eye protection
:
Eye wash bottle with pure water
Tightly fitting safety goggles
Wear face-shield and protective suit for abnormal processing
problems.
Skin and body protection
:
impervious clothing
Choose body protection according to the amount and
concentration of the dangerous substance at the work place.
Hygiene measures
:
Handle in accordance with good industrial hygiene and safety
practice.
Appearance
:
Aerosol containing a liquefied gas
Colour
:
colourless
Odour
:
characteristic
Odour Threshold
:
no data available
pH : not applicable
Melting point/freezing point
:
no data available
Boiling point
:
no data available
Flash point
:
not applicable
Evaporation rate
:
not determined
Upper explosion limit
:
no data available
Lower explosion limit
:
no data available
Vapour pressure
:
no data available
Relative vapour density
:
no data available
Density
:
no data available
Personal protective equipment
Hand protection
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Solubility(ies)
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SAFETY DATA SHEET
A07712OS TM CITRUS 9000 L1 12N7.5 4/CS
Version 1.0
Revision Date 02/11/2015
Print Date 06/01/2015
Water solubility
:
negligible
Solubility in other solvents
:
not determined
Partition coefficient: noctanol/water
:
no data available
Auto-ignition temperature
:
not determined
Thermal decomposition
:
no data available
Viscosity, kinematic
:
no data available
Reactivity
:
Stable
Chemical stability
:
Stable under normal conditions.
Possibility of hazardous
reactions
:
Vapours may form explosive mixture with air.
No decomposition if stored and applied as directed.
Conditions to avoid
:
Heat, flames and sparks.
Incompatible materials
:
Oxidizing agents
Alkali metals
Acids
Hazardous decomposition
products
:
Carbon oxides
Acute dermal toxicity
:
Acute toxicity estimate : > 5,000 mg/kg
Method: Calculation method
Acute inhalation toxicity
:
LC50 mouse: 977,000 mg/l
Exposure time: 2 h
Remarks: May cause skin irritation in susceptible persons.
Viscosity
SECTION 10. STABILITY AND REACTIVITY
SECTION 11. TOXICOLOGICAL INFORMATION
Acute toxicity
Product:
Components:
1,1-difluoroethane:
Skin corrosion/irritation
Product:
Serious eye damage/eye irritation
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SAFETY DATA SHEET
A07712OS TM CITRUS 9000 L1 12N7.5 4/CS
Version 1.0
Revision Date 02/11/2015
Print Date 06/01/2015
Remarks: May irritate eyes.
Remarks: Symptoms of overexposure may be headache, dizziness, tiredness, nausea
and vomiting., Concentrations substantially above the TLV value may cause narcotic
effects., Solvents may degrease the skin.
Partition coefficient: noctanol/water
:
Remarks: no data available
Product:
Respiratory or skin sensitisation
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
no data available
Reproductive toxicity
no data available
1,1-difluoroethane:
propan-2-ol:
alkanes, C12-14-iso-:
STOT - single exposure
no data available
STOT - repeated exposure
no data available
Aspiration toxicity
no data available
Further information
Product:
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
no data available
Persistence and degradability
no data available
Bioaccumulative potential
Product:
Mobility in soil
no data available
7 / 10
SAFETY DATA SHEET
A07712OS TM CITRUS 9000 L1 12N7.5 4/CS
Version 1.0
Revision Date 02/11/2015
Print Date 06/01/2015
Regulation
40 CFR Protection of Environment; Part 82 Protection of
Stratospheric Ozone - CAA Section 602 Class I
Substances
Remarks
This product neither contains, nor was manufactured
with a Class I or Class II ODS as defined by the U.S.
Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A
+ B).
Additional ecological
information
:
no data available
Waste from residues
:
Dispose of in accordance with local regulations.
Contaminated packaging
:
Empty remaining contents.
Dispose of as unused product.
Do not re-use empty containers.
Do not burn, or use a cutting torch on, the empty drum.
Transportation Regulation: 49 CFR (USA):
This material is not classified.
Transportation Regulation: IMDG (Vessel):
This material is not classified.
Transportation Regulation: IATA (Cargo Air):
This material is not classified.
Transportation Regulation: IATA (Passenger Air):
This material is not classified.
Transportation Regulation: TDG (Canada):
This material is not classified.
Other adverse effects
no data available
Product:
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods
SECTION 14. TRANSPORT INFORMATION
SECTION 15. REGULATORY INFORMATION
EPCRA - Emergency Planning and Community Right-to-Know Act
8 / 10
SAFETY DATA SHEET
A07712OS TM CITRUS 9000 L1 12N7.5 4/CS
Version 1.0
Revision Date 02/11/2015
Print Date 06/01/2015
Components
CAS-No.
Component RQ
(lbs)
Calculated product RQ
(lbs)
cyclohexane
110-82-7
1000
*
SARA 311/312 Hazards
:
Fire Hazard
Sudden Release of Pressure Hazard
Acute Health Hazard
SARA 302
:
SARA 302: No chemicals in this material are subject to the
reporting requirements of SARA Title III, Section 302.
SARA 313
:
SARA 313: This material does not contain any chemical
components with known CAS numbers that exceed the
threshold (De Minimis) reporting levels established by SARA
Title III, Section 313.
California Prop 65
WARNING: This product contains a chemical known to the
State of California to cause birth defects or other reproductive
harm.
methanol
67-56-1
TSCA
On TSCA Inventory
DSL
This product contains the following components that are not on the
Canadian DSL nor NDSL.
AICS
Not in compliance with the inventory
NZIoC
Not in compliance with the inventory
PICCS
Not in compliance with the inventory
IECSC
Not in compliance with the inventory
CERCLA Reportable Quantity
*: Calculated RQ exceeds reasonably attainable upper limit.
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.
The components of this product are reported in the following inventories:
Inventory Acronym and Validity Area Legend:
AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL
(Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TSCA (USA)
SECTION 16. OTHER INFORMATION
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SAFETY DATA SHEET
A07712OS TM CITRUS 9000 L1 12N7.5 4/CS
Version 1.0
Revision Date 02/11/2015
Print Date 06/01/2015
NFPA:
HMIS III:
Hazard pictograms
:
Signal word
:
Warning:
Hazard statements
:
Flammable aerosol. Contains gas under pressure; may explode if heated. Causes
serious eye irritation. May cause drowsiness or dizziness.
Precautionary statements
:
Prevention: Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking. Do not spray on an open flame or other ignition source.
Pressurized container: Do not pierce or burn, even after use. Avoid breathing dust/
fume/ gas/ mist/ vapours/ spray. Wash skin thoroughly after handling. Use only
outdoors or in a well-ventilated area. Wear eye protection/ face protection.
Response: IF INHALED: Remove victim to fresh air and keep at rest in a position
comfortable for breathing. Call a POISON CENTER or doctor/ physician if you feel
unwell. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical
advice/ attention.
Storage: Store in a well-ventilated place. Keep container tightly closed. Store locked
up. Protect from sunlight. Do not expose to temperatures exceeding 50 °C/ 122 °F.
Disposal: Dispose of contents/container in accordance with local regulation.
Flammability
Health
Instability
1
3
0
Special hazard.
FLAMMABILITY
PHYSICAL HAZARD
HEALTH
3
0
1
0 = not significant, 1 =Slight,
2 = Moderate, 3 = High
4 = Extreme, * = Chronic
Further information
OSHA GHS Label Information:
We believe the statements, technical information and recommendations contained herein are
reliable, but they are given without warranty or guarantee of any kind. The information in this
document applies to this specific material as supplied. It may not be valid for this material if it
is used in combination with any other materials. Users should make their own investigations
to determine the suitability and applicability of the information for their particular purposes.
This SDS has been prepared by the Compliance Services organization supporting this
manufacturer, supplier or distributor.
Zep Inc. markets products under well recognized and established brand names such as Zep®,
Zep Commercial®,Zep Professional®, Enforcer®, National Chemical™, Selig™, Misty®, Next
Dimension™, Petro®, i-Chem®, TimeMist®, TimeWick™, MicrobeMax®, Country Vet®,
Konk®, Original Bike Spirits®, Blue Coral®, Black Magic®, Rain-X®, Niagara National™, FC
Forward Chemicals®,Rexodan®, Mykal™, and a number of private labeled brands.
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