SAFETY DATA SHEET
A07710CN TM CINNAMON 9000 L1 12N7.5 4/CS
Version 2.1
Revision Date 12/22/2016
Print Date 02/15/2017
Material name
:
A07710CN TM CINNAMON 9000 L1 12N7.5 4/CS
Material number
:
000000000001042639
Company
:
Zep Inc.
Address
:
1310 Seaboard Industrial Blvd., NW
Atlanta, GA 30318
Telephone
:
404-352-1680
Emergency telephone numbers
For SDS Information
:
Compliance Services 1-877-428-9937
For a Medical Emergency
:
877-541-2016 Toll Free - All Calls Recorded
For a Transportation
Emergency
:
CHEMTREC: 800-424-9300 - All Calls Recorded.
In the District of Columbia 202-483-7616
Recommended use
:
Air Care
Appearance
Aerosol containing a liquefied gas
Colour
clear, colourless, light yellow
Odour
characteristic
Flammable aerosols
:
Category 2
Gases under pressure
:
Liquefied gas
Eye irritation
:
Category 2A
Specific target organ toxicity single exposure
:
Category 3 (Central nervous system)
Hazard pictograms
:
Signal word
:
Warning
Hazard statements
:
H223 Flammable aerosol.
H280 Contains gas under pressure; may explode if heated.
H319 Causes serious eye irritation.
H336 May cause drowsiness or dizziness.
Precautionary statements
:
Prevention:
P210 Keep away from heat/sparks/open flames/hot surfaces.
SECTION 1. PRODUCT AND COMPANY IDENTIFICATION
Manufacturer or supplier's details
Recommended use of the chemical and restrictions on use
SECTION 2. HAZARDS IDENTIFICATION
Emergency Overview
GHS Classification
GHS label elements
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SAFETY DATA SHEET
A07710CN TM CINNAMON 9000 L1 12N7.5 4/CS
Version 2.1
Revision Date 12/22/2016
Print Date 02/15/2017
No smoking.
P211 Do not spray on an open flame or other ignition source.
P251 Pressurized container: Do not pierce or burn, even after
use.
P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
P264 Wash skin thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear eye protection/ face protection.
Response:
P304 + P340 + P312 IF INHALED: Remove victim to fresh air
and keep at rest in a position comfortable for breathing. Call a
POISON CENTER or doctor/ physician if you feel unwell.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water
for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing.
P337 + P313 If eye irritation persists: Get medical advice/
attention.
Storage:
P405 Store locked up.
P410 + P412 Protect from sunlight. Do not expose to
temperatures exceeding 50 °C/ 122 °F.
P403 + P235 Store in a well-ventilated place. Keep cool.
Disposal:
Dispose of contents/container in accordance with local
regulation.
Substance / Mixture
:
Mixture
Chemical name
CAS-No.
Concentration [%]
1,1-difluoroethane
75-37-6
>= 50 - < 70
propan-2-ol
67-63-0
>= 20 - < 30
alkanes, C12-14-iso-
68551-19-9
>= 5 - < 10
General advice
:
Show this safety data sheet to the doctor in attendance.
If inhaled
:
Remove to fresh air.
Call a physician or poison control centre immediately.
In case of skin contact
:
Wash off immediately with plenty of water for at least 15
minutes.
Call a physician if irritation persists.
In case of eye contact
:
In case of contact, immediately flush eyes with plenty of water
for at least 15 minutes.
If easy to do, remove contact lens, if worn.
Seek medical advice.
If swallowed
:
Never give anything by mouth to an unconscious person.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous components
The exact percentages of disclosed substances are withheld as trade secrets.
SECTION 4. FIRST AID MEASURES
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SAFETY DATA SHEET
A07710CN TM CINNAMON 9000 L1 12N7.5 4/CS
Version 2.1
Revision Date 12/22/2016
Print Date 02/15/2017
DO NOT induce vomiting unless directed to do so by a
physician or poison control center.
Most important symptoms
and effects, both acute and
delayed
:
Symptoms may include irritation, redness, pain, and rash.
Effects are immediate and delayed.
Symptoms of overexposure may include disorientation;
dizziness; and confusion. May progress to unconsciousness,
paralysis, and convulsions.
Effects are dependent on exposure (dose, concentration,
contact time).
Causes serious eye irritation.
Review section 2 of SDS to see all potential hazards.
Notes to physician
:
Treat symptomatically. Symptoms may be delayed.
Suitable extinguishing media
:
Foam
Carbon dioxide (CO2)
Water
Dry chemical
Specific hazards during
firefighting
:
Do not allow run-off from fire fighting to enter drains or water
courses.
Hazardous combustion
products
:
Carbon dioxide (CO2)
Carbon monoxide
Smoke
Specific extinguishing
methods
:
Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.
Further information
:
For safety reasons in case of fire, cans should be stored
separately in closed containments.
Use a water spray to cool fully closed containers.
Special protective equipment
for firefighters
:
Wear self-contained breathing apparatus for firefighting if
necessary.
Personal precautions,
protective equipment and
emergency procedures
:
Use personal protective equipment.
Remove all sources of ignition.
Evacuate personnel to safe areas.
Beware of vapours accumulating to form explosive
concentrations. Vapours can accumulate in low areas.
Environmental precautions
:
Prevent product from entering drains.
Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains inform
respective authorities.
SECTION 5. FIREFIGHTING MEASURES
SECTION 6. ACCIDENTAL RELEASE MEASURES
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SAFETY DATA SHEET
A07710CN TM CINNAMON 9000 L1 12N7.5 4/CS
Version 2.1
Revision Date 12/22/2016
Print Date 02/15/2017
Methods and materials for
containment and cleaning up
:
Soak up with inert absorbent material (e.g. sand, silica gel,
acid binder, universal binder, sawdust).
Sweep up and shovel into suitable containers for disposal.
Advice on safe handling
:
Do not breathe vapours/dust.
Keep away from fire (No Smoking).
Do not swallow.
Avoid contact with skin and eyes.
Smoking, eating and drinking should be prohibited in the
application area.
Use only with adequate ventilation.
Conditions for safe storage
:
BEWARE: Aerosol is pressurized. Keep away from direct sun
exposure and temperatures over 50 °C. Do not open by force
or throw into fire even after use. Do not spray on flames or
red-hot objects.
No smoking.
Observe label precautions.
Keep in a cool, well-ventilated place.
Electrical installations / working materials must comply with
the technological safety standards.
Materials to avoid
:
Do not freeze.
Store and keep away from, oxidizing agents and acids.
Store and keep away from bases and alkalies.
Storage temperature
:
< 49 °C
Components
CAS-No.
Value type
(Form of
exposure)
Control
parameters /
Permissible
concentration
Basis
1,1-difluoroethane
75-37-6
TWA
1,000 ppm
US WEEL
propan-2-ol
67-63-0
TWA
200 ppm
ACGIH
STEL
400 ppm
ACGIH
TWA
400 ppm
980 mg/m3
NIOSH REL
ST
500 ppm
1,225 mg/m3
NIOSH REL
TWA
400 ppm
980 mg/m3
OSHA Z-1
TWA
400 ppm
980 mg/m3
OSHA P0
STEL
500 ppm
1,225 mg/m3
OSHA P0
PEL
400 ppm
980 mg/m3
CAL PEL
SECTION 7. HANDLING AND STORAGE
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters
4 / 11
SAFETY DATA SHEET
A07710CN TM CINNAMON 9000 L1 12N7.5 4/CS
Version 2.1
Revision Date 12/22/2016
Print Date 02/15/2017
STEL
500 ppm
1,225 mg/m3
CAL PEL
Component
CAS-No.
Control
parameters
Biological
specimen
Sampling
time
Permissible
concentration
Basis
PROPAN-2-OL
67-63-0
Acetone
Urine
End of
shift at
end of
workwee
k
40 mg/l
ACGIH BEI
Engineering measures
:
effective ventilation in all processing areas
Respiratory protection
:
In the case of dust or aerosol formation use respirator with an
approved filter.
Remarks
:
The suitability for a specific workplace should be discussed
with the producers of the protective gloves.
Eye protection
:
Wear face-shield and protective suit for abnormal processing
problems.
Safety glasses
Skin and body protection
:
Impervious clothing
Choose body protection according to the amount and
concentration of the dangerous substance at the work place.
Hygiene measures
:
Handle in accordance with good industrial hygiene and safety
practice.
Appearance
:
Aerosol containing a liquefied gas
Colour
:
clear, colourless, light yellow
Odour
:
characteristic
Odour Threshold
:
No data available
pH : Not applicable
Melting point/freezing point
:
Not applicable
Boiling point
:
No data available
Flash point
:
15.5 °C
Evaporation rate
:
No data available
Upper explosion limit
:
No data available
Lower explosion limit
:
No data available
Biological occupational exposure limits
Personal protective equipment
Hand protection
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
5 / 11
SAFETY DATA SHEET
A07710CN TM CINNAMON 9000 L1 12N7.5 4/CS
Version 2.1
Revision Date 12/22/2016
Print Date 02/15/2017
Vapour pressure
:
No data available
Relative vapour density
:
No data available
Density
:
0.813 g/cm3
Water solubility
:
negligible
Partition coefficient: noctanol/water
:
No data available
Auto-ignition temperature
:
not determined
Thermal decomposition
:
No data available
Viscosity, kinematic
:
No data available
Reactivity
:
Stable
Chemical stability
:
Stable under normal conditions.
Possibility of hazardous
reactions
:
Vapours may form explosive mixture with air.
Conditions to avoid
:
Heat, flames and sparks.
Incompatible materials
:
Oxidizing agents
Acids
Bases
Hazardous decomposition
products
:
Carbon oxides
Aggravated Medical
Condition
:
None known.
Symptoms of Overexposure
:
Symptoms may include irritation, redness, pain, and rash.
Effects are immediate and delayed.
Symptoms of overexposure may include disorientation;
dizziness; and confusion. May progress to unconsciousness,
paralysis, and convulsions.
Effects are dependent on exposure (dose, concentration,
contact time).
Solubility(ies)
Viscosity
SECTION 10. STABILITY AND REACTIVITY
SECTION 11. TOXICOLOGICAL INFORMATION
Potential Health Effects
Carcinogenicity:
6 / 11
SAFETY DATA SHEET
A07710CN TM CINNAMON 9000 L1 12N7.5 4/CS
Version 2.1
Revision Date 12/22/2016
Print Date 02/15/2017
IARC
No component of this product present at levels greater than or
equal to 0.1% is identified as probable, possible or confirmed
human carcinogen by IARC.
ACGIH
No component of this product present at levels greater than or
equal to 0.1% is identified as a carcinogen or potential
carcinogen by ACGIH.
OSHA
No component of this product present at levels greater than or
equal to 0.1% is identified as a carcinogen or potential
carcinogen by OSHA.
NTP
No component of this product present at levels greater than or
equal to 0.1% is identified as a known or anticipated carcinogen
by NTP.
Acute dermal toxicity
:
Acute toxicity estimate : > 5,000 mg/kg
Method: Calculation method
Acute inhalation toxicity
:
LC50 Mouse: 977,000 mg/l
Exposure time: 2 h
Acute oral toxicity
:
LD50 Oral Rat: 4,396 mg/kg
Method: Calculation method
Remarks: May cause skin irritation in susceptible persons.
Remarks: May irritate eyes.
Acute toxicity
Product:
Components:
1,1-difluoroethane:
propan-2-ol:
Skin corrosion/irritation
Product:
Serious eye damage/eye irritation
Product:
Respiratory or skin sensitisation
No data available
Germ cell mutagenicity
No data available
Carcinogenicity
No data available
Reproductive toxicity
No data available
1,1-difluoroethane:
propan-2-ol:
alkanes, C12-14-iso-:
STOT - single exposure
7 / 11
SAFETY DATA SHEET
A07710CN TM CINNAMON 9000 L1 12N7.5 4/CS
Version 2.1
Revision Date 12/22/2016
Print Date 02/15/2017
Remarks: Symptoms of overexposure may be headache, dizziness, tiredness, nausea
and vomiting., Concentrations substantially above the TLV value may cause narcotic
effects., Solvents may degrease the skin.
Partition coefficient: noctanol/water
:
Remarks: No data available
Regulation
40 CFR Protection of Environment; Part 82 Protection of
Stratospheric Ozone - CAA Section 602 Class I
Substances
Remarks
This product neither contains, nor was manufactured
with a Class I or Class II ODS as defined by the U.S.
Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A
+ B).
Additional ecological
information
:
No data available
No data available
STOT - repeated exposure
No data available
Aspiration toxicity
No data available
Further information
Product:
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
No data available
Persistence and degradability
No data available
Bioaccumulative potential
Product:
Mobility in soil
No data available
Other adverse effects
No data available
Product:
SECTION 13. DISPOSAL CONSIDERATIONS
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SAFETY DATA SHEET
A07710CN TM CINNAMON 9000 L1 12N7.5 4/CS
Version 2.1
Revision Date 12/22/2016
Print Date 02/15/2017
Waste from residues
:
Dispose of in accordance with local regulations.
Do not contaminate ponds, waterways or ditches with
chemical or used container.
The product should not be allowed to enter drains, water
courses or the soil.
Contaminated packaging
:
Empty remaining contents.
Dispose of as unused product.
Do not re-use empty containers.
Do not burn, or use a cutting torch on, the empty drum.
Transportation Regulation: 49 CFR (USA):
This material is not classified.
Transportation Regulation: IMDG (Vessel):
This material is not classified.
Transportation Regulation: IATA (Cargo Air):
This material is not classified.
Transportation Regulation: IATA (Passenger Air):
This material is not classified.
Transportation Regulation: TDG (Canada):
This material is not classified.
Components
CAS-No.
Component RQ
(lbs)
Calculated product RQ
(lbs)
cyclohexane
110-82-7
1000
*
SARA 311/312 Hazards
:
Fire Hazard
Sudden Release of Pressure Hazard
Disposal methods
SECTION 14. TRANSPORT INFORMATION
The product as delivered to the customer conforms to packaging requirements for shipment by road
under US Department of Transportation (DOT) regulations. Additional transportation classifications
noted above are for reference only, and not a certification or warranty of the suitability of the packaging
for shipment under these alternative transport regulations.
SECTION 15. REGULATORY INFORMATION
EPCRA - Emergency Planning and Community Right-to-Know Act
CERCLA Reportable Quantity
*: Calculated RQ exceeds reasonably attainable upper limit.
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.
9 / 11
SAFETY DATA SHEET
A07710CN TM CINNAMON 9000 L1 12N7.5 4/CS
Version 2.1
Revision Date 12/22/2016
Print Date 02/15/2017
Acute Health Hazard
SARA 302
:
No chemicals in this material are subject to the reporting
requirements of SARA Title III, Section 302.
SARA 313
:
This material does not contain any chemical components with
known CAS numbers that exceed the threshold (De Minimis)
reporting levels established by SARA Title III, Section 313.
California Prop 65
This product does not contain any chemicals known to State of
California to cause cancer, birth defects, or any other
reproductive harm.
TSCA
On TSCA Inventory
DSL
All components of this product are on the Canadian DSL
NFPA:
HMIS III:
Hazard pictograms
:
Signal word
:
Warning:
Hazard statements
:
Flammable aerosol. Contains gas under pressure; may explode if heated. Causes
serious eye irritation. May cause drowsiness or dizziness.
Precautionary statements
:
Flammability
Health
Instability
1
3
0
Special hazard.
FLAMMABILITY
PHYSICAL HAZARD
HEALTH
3
0
1
0 = not significant, 1 =Slight,
2 = Moderate, 3 = High
4 = Extreme, * = Chronic
The components of this product are reported in the following inventories:
For information on the country notification status for other regions please contact the
manufacturer’s regulatory group.
Inventory Acronym and Validity Area Legend:
TSCA (USA), DSL (Canada), NDSL (Canada)
SECTION 16. OTHER INFORMATION
Further information
OSHA - GHS Label Information:
10 / 11
SAFETY DATA SHEET
A07710CN TM CINNAMON 9000 L1 12N7.5 4/CS
Version 2.1
Revision Date 12/22/2016
Print Date 02/15/2017
Prevention: Keep away from heat/sparks/open flames/hot surfaces. No smoking. Do
not spray on an open flame or other ignition source. Pressurized container: Do not
pierce or burn, even after use. Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
Wash skin thoroughly after handling. Use only outdoors or in a well-ventilated area.
Wear eye protection/ face protection.
Response: IF INHALED: Remove victim to fresh air and keep at rest in a position
comfortable for breathing. Call a POISON CENTER or doctor/ physician if you feel
unwell. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical
advice/ attention.
Storage: Store locked up. Protect from sunlight. Do not expose to temperatures
exceeding 50 °C/ 122 °F. Store in a w ell-ventilated place. Keep cool.
Disposal: Dispose of contents/container in accordance with local regulation.
Version:
2.1
Revision Date:
12/22/2016
Print Date:
02/15/2017
We believe the statements, technical information and recommendations contained herein are
reliable, but they are given without warranty or guarantee of any kind. The information in this
document applies to this specific material as supplied. It may not be valid for this material if it
is used in combination with any other materials. Users should make their own investigations
to determine the suitability and applicability of the information for their particular purposes.
This SDS has been prepared by the Compliance Services organization supporting this
manufacturer, supplier or distributor.
Zep Inc. markets products under well recognized and established brand names such as Zep®,
Zep Commercial®,Zep Professional®, Enforcer®, National Chemical™, Selig™, Misty®, Next
Dimension™, Petro®, i-Chem®, TimeMist®, TimeWick™, MicrobeMax®, Country Vet®,
Konk®, Original Bike Spirits®, Blue Coral®, Black Magic®, Rain-X®, Niagara National™, FC
Forward Chemicals®,Rexodan®, Mykal™, and a number of private labeled brands.
11 / 11
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