SAFETY DATA SHEET
A07760 TM COUNTRY GARDEN 30% 12n6.6
Version 1.1
Revision Date 12/29/2016
Print Date 02/15/2017
Material name
:
A07760 TM COUNTRY GARDEN 30% 12n6.6
Material number
:
000000000001042786
Company
:
Zep Inc.
Address
:
1310 Seaboard Industrial Blvd., NW
Atlanta, GA 30318
Telephone
:
404-352-1680
Emergency telephone numbers
For SDS Information
:
Compliance Services 1-877-428-9937
For a Medical Emergency
:
877-541-2016 Toll Free - All Calls Recorded
For a Transportation
Emergency
:
CHEMTREC: 800-424-9300 - All Calls Recorded.
In the District of Columbia 202-483-7616
Recommended use
:
Air Care
Appearance
Aerosol containing a liquefied gas
Colour
colourless
Odour
characteristic
Flammable aerosols
:
Category 1
Gases under pressure
:
Liquefied gas
Eye irritation
:
Category 2A
Skin sensitisation
:
Category 1
Specific target organ toxicity single exposure
:
Category 3 (Central nervous system)
Hazard pictograms
:
Signal word
:
Danger
Hazard statements
:
H222 Extremely flammable aerosol.
H280 Contains gas under pressure; may explode if heated.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H336 May cause drowsiness or dizziness.
SECTION 1. PRODUCT AND COMPANY IDENTIFICATION
Manufacturer or supplier's details
Recommended use of the chemical and restrictions on use
SECTION 2. HAZARDS IDENTIFICATION
Emergency Overview
GHS Classification
GHS label elements
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SAFETY DATA SHEET
A07760 TM COUNTRY GARDEN 30% 12n6.6
Version 1.1
Revision Date 12/29/2016
Print Date 02/15/2017
Precautionary statements
:
Prevention:
P210 Keep away from heat/sparks/open flames/hot surfaces.
No smoking.
P211 Do not spray on an open flame or other ignition source.
P251 Pressurized container: Do not pierce or burn, even after
use.
P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
P264 Wash skin thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of
the workplace.
P280 Wear eye protection/ face protection.
P280 Wear protective gloves.
Response:
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P304 + P340 + P312 IF INHALED: Remove victim to fresh air
and keep at rest in a position comfortable for breathing. Call a
POISON CENTER or doctor/ physician if you feel unwell.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water
for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing.
P333 + P313 If skin irritation or rash occurs: Get medical
advice/ attention.
P337 + P313 If eye irritation persists: Get medical advice/
attention.
P363 Wash contaminated clothing before reuse.
Storage:
P405 Store locked up.
P410 + P412 Protect from sunlight. Do not expose to
temperatures exceeding 50 °C/ 122 °F.
P403 Store in a well-ventilated place.
Disposal:
Dispose of contents/container in accordance with local
regulation.
Substance / Mixture
:
Mixture
Chemical name
CAS-No.
Concentration [%]
acetone
67-64-1
>= 70 - < 90
propane
74-98-6
>= 10 - < 20
alpha-hexylcinnamaldehyde
101-86-0
>= 0.1 - < 1
7-hydroxycitronellal
107-75-5
>= 0.1 - < 1
General advice
:
Move out of dangerous area.
Show this safety data sheet to the doctor in attendance.
Do not leave the victim unattended.
If inhaled
:
Remove to fresh air.
Consult a physician after significant exposure.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous components
SECTION 4. FIRST AID MEASURES
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SAFETY DATA SHEET
A07760 TM COUNTRY GARDEN 30% 12n6.6
Version 1.1
Revision Date 12/29/2016
Print Date 02/15/2017
If unconscious place in recovery position and seek medical
advice.
In case of skin contact
:
Wash off immediately with plenty of water for at least 15
minutes.
If skin irritation persists, call a physician.
If on clothes, remove clothes.
In case of eye contact
:
Rinse immediately with plenty of water for at least 15 minutes.
If eye irritation persists, consult a specialist.
Remove contact lenses.
Protect unharmed eye.
Keep eye wide open while rinsing.
If swallowed
:
Keep respiratory tract clear.
Drink 1 or 2 glasses of water.
Never give anything by mouth to an unconscious person.
If symptoms persist, call a physician.
DO NOT induce vomiting unless directed to do so by a
physician or poison control center.
Take victim immediately to hospital.
Suitable extinguishing media
:
Foam
Carbon dioxide (CO2)
Water spray jet
Dry chemical
Unsuitable extinguishing
media
:
High volume water jet
Specific hazards during
firefighting
:
Do not allow run-off from fire fighting to enter drains or water
courses.
Hazardous combustion
products
:
Carbon dioxide (CO2)
Carbon monoxide
Smoke
Specific extinguishing
methods
:
Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.
Further information
:
Standard procedure for chemical fires.
For safety reasons in case of fire, cans should be stored
separately in closed containments.
Use a water spray to cool fully closed containers.
Collect contaminated fire extinguishing water separately. This
must not be discharged into drains.
Fire residues and contaminated fire extinguishing water must
be disposed of in accordance with local regulations.
Special protective equipment
for firefighters
:
Wear self-contained breathing apparatus for firefighting if
necessary.
SECTION 5. FIREFIGHTING MEASURES
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SAFETY DATA SHEET
A07760 TM COUNTRY GARDEN 30% 12n6.6
Version 1.1
Revision Date 12/29/2016
Print Date 02/15/2017
Personal precautions,
protective equipment and
emergency procedures
:
Use personal protective equipment.
Ensure adequate ventilation.
Remove all sources of ignition.
Evacuate personnel to safe areas.
Beware of vapours accumulating to form explosive
concentrations. Vapours can accumulate in low areas.
Environmental precautions
:
Prevent product from entering drains.
Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains inform
respective authorities.
Methods and materials for
containment and cleaning up
:
Soak up with inert absorbent material (e.g. sand, silica gel,
acid binder, universal binder, sawdust).
Sweep up or vacuum up spillage and collect in suitable
container for disposal.
Advice on safe handling
:
Do not puncture.
Avoid exposure - obtain special instructions before use.
Avoid contact with skin and eyes.
For personal protection see section 8.
Do not breathe vapours or spray mist.
Take precautionary measures against static discharges.
Provide sufficient air exchange and/or exhaust in work rooms.
Dispose of rinse water in accordance with local and national
regulations.
Always replace cap after use.
Conditions for safe storage
:
BEWARE: Aerosol is pressurized. Keep away from direct sun
exposure and temperatures over 50 °C. Do not open by force
or throw into fire even after use. Do not spray on flames or
red-hot objects.
No smoking.
Observe label precautions.
Keep in a dry, cool and well-ventilated place.
Electrical installations / working materials must comply with
the technological safety standards.
Materials to avoid
:
Store and keep away from, oxidizing agents and acids.
Components
CAS-No.
Value type
(Form of
exposure)
Control
parameters /
Permissible
concentration
Basis
acetone
67-64-1
TWA
250 ppm
ACGIH
SECTION 6. ACCIDENTAL RELEASE MEASURES
SECTION 7. HANDLING AND STORAGE
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters
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SAFETY DATA SHEET
A07760 TM COUNTRY GARDEN 30% 12n6.6
Version 1.1
Revision Date 12/29/2016
Print Date 02/15/2017
STEL
500 ppm
ACGIH
TWA
250 ppm
590 mg/m3
NIOSH REL
TWA
1,000 ppm
2,400 mg/m3
OSHA Z-1
TWA
750 ppm
1,800 mg/m3
OSHA P0
STEL
1,000 ppm
2,400 mg/m3
OSHA P0
STEL
750 ppm
1,780 mg/m3
CAL PEL
C
3,000 ppm
CAL PEL
PEL
500 ppm
1,200 mg/m3
CAL PEL
propane
74-98-6
TWA
1,000 ppm
ACGIH
TWA
1,000 ppm
1,800 mg/m3
NIOSH REL
TWA
1,000 ppm
1,800 mg/m3
OSHA Z-1
TWA
1,000 ppm
1,800 mg/m3
OSHA P0
PEL
1,000 ppm
1,800 mg/m3
CAL PEL
Component
CAS-No.
Control
parameters
Biological
specimen
Sampling
time
Permissible
concentration
Basis
2-PROPANONE
67-64-1
Acetone
Urine
End of
shift (As
soon as
possible
after
exposure
ceases)
25 mg/l
ACGIH BEI
Respiratory protection
:
Use respiratory protection unless adequate local exhaust
ventilation is provided or exposure assessment demonstrates
that exposures are within recommended exposure guidelines.
Remarks
:
The suitability for a specific workplace should be discussed
with the producers of the protective gloves.
Eye protection
:
Safety glasses
Ensure that eyewash stations and safety showers are close to
the workstation location.
Skin and body protection
:
Impervious clothing
Choose body protection according to the amount and
concentration of the dangerous substance at the work place.
Hygiene measures
:
When using do not eat or drink.
When using do not smoke.
Wash hands before breaks and at the end of workday.
Biological occupational exposure limits
Personal protective equipment
Hand protection
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SAFETY DATA SHEET
A07760 TM COUNTRY GARDEN 30% 12n6.6
Version 1.1
Revision Date 12/29/2016
Print Date 02/15/2017
Appearance
:
Aerosol containing a liquefied gas
Colour
:
colourless
Odour
:
characteristic
Odour Threshold
:
No data available
pH : Not applicable
Melting point/freezing point
:
No data available
Boiling point
:
No data available
Flash point
:
Not applicable
Evaporation rate
:
No data available
Flammability (solid, gas)
:
Extremely flammable aerosol.
Upper explosion limit
:
No data available
Lower explosion limit
:
No data available
Vapour pressure
:
No data available
Relative vapour density
:
No data available
Density
:
No data available
Water solubility
:
partly soluble
Solubility in other solvents
:
not determined
Partition coefficient: noctanol/water
:
No data available
Auto-ignition temperature
:
not determined
Thermal decomposition
:
No data available
Viscosity, kinematic
:
No data available
Heat of combustion
:
36.78 kJ/g
Reactivity
:
Stable
Chemical stability
:
Stable under normal conditions.
Possibility of hazardous
:
Vapours may form explosive mixture with air.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Solubility(ies)
Viscosity
SECTION 10. STABILITY AND REACTIVITY
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SAFETY DATA SHEET
A07760 TM COUNTRY GARDEN 30% 12n6.6
Version 1.1
Revision Date 12/29/2016
Print Date 02/15/2017
reactions
No decomposition if stored and applied as directed.
Conditions to avoid
:
Heat, flames and sparks.
Extremes of temperature and direct sunlight.
Incompatible materials
:
Acids
Bases
Oxidizing agents
Hazardous decomposition
products
:
Carbon oxides
IARC
No component of this product present at levels greater than or
equal to 0.1% is identified as probable, possible or confirmed
human carcinogen by IARC.
ACGIH
No component of this product present at levels greater than or
equal to 0.1% is identified as a carcinogen or potential
carcinogen by ACGIH.
OSHA
No component of this product present at levels greater than or
equal to 0.1% is identified as a carcinogen or potential
carcinogen by OSHA.
NTP
No component of this product present at levels greater than or
equal to 0.1% is identified as a known or anticipated carcinogen
by NTP.
Acute oral toxicity
:
LD50 Rat: 5,800 mg/kg
Acute inhalation toxicity
:
LC50 Rat: 132 mg/l
Exposure time: 3 h
LC50 Rat: 50.1 mg/l
Acute dermal toxicity
:
LD50 Guinea pig: > 7,426 mg/kg
LD50 Rabbit: > 7,426 mg/kg
Acute inhalation toxicity
:
LC50 Mouse: 1,237 mg/l
Exposure time: 2 h
LC50 Rat: 658 mg/l
Exposure time: 4 h
SECTION 11. TOXICOLOGICAL INFORMATION
Potential Health Effects
Carcinogenicity:
Acute toxicity
Components:
acetone:
propane:
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SAFETY DATA SHEET
A07760 TM COUNTRY GARDEN 30% 12n6.6
Version 1.1
Revision Date 12/29/2016
Print Date 02/15/2017
LC50 Rat: 1,355 mg/l
Remarks: May cause skin irritation in susceptible persons.
Remarks: Eye irritation
Remarks: Causes sensitisation.
Remarks: Symptoms of overexposure may be headache, dizziness, tiredness, nausea
and vomiting., Concentrations substantially above the TLV value may cause narcotic
effects., Solvents may degrease the skin.
Skin corrosion/irritation
Product:
Serious eye damage/eye irritation
Product:
Respiratory or skin sensitisation
Product:
Germ cell mutagenicity
No data available
Carcinogenicity
No data available
Reproductive toxicity
No data available
acetone:
propane:
alpha-hexylcinnamaldehyde:
7-hydroxycitronellal:
STOT - single exposure
No data available
STOT - repeated exposure
No data available
Aspiration toxicity
No data available
Further information
Product:
8 / 12
SAFETY DATA SHEET
A07760 TM COUNTRY GARDEN 30% 12n6.6
Version 1.1
Revision Date 12/29/2016
Print Date 02/15/2017
Partition coefficient: noctanol/water
:
Remarks: No data available
Partition coefficient: noctanol/water
:
log Pow: 4.686
Regulation
40 CFR Protection of Environment; Part 82 Protection of
Stratospheric Ozone - CAA Section 602 Class I
Substances
Remarks
This product neither contains, nor was manufactured
with a Class I or Class II ODS as defined by the U.S.
Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A
+ B).
Additional ecological
information
:
No data available
Waste from residues
:
Dispose of in accordance with local regulations.
Do not contaminate ponds, waterways or ditches with
chemical or used container.
The product should not be allowed to enter drains, water
courses or the soil.
Contaminated packaging
:
Empty remaining contents.
Dispose of as unused product.
Do not re-use empty containers.
Do not burn, or use a cutting torch on, the empty drum.
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
No data available
Persistence and degradability
No data available
Bioaccumulative potential
Product:
Components:
alpha-hexylcinnamaldehyde :
Mobility in soil
No data available
Other adverse effects
No data available
Product:
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods
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SAFETY DATA SHEET
A07760 TM COUNTRY GARDEN 30% 12n6.6
Version 1.1
Revision Date 12/29/2016
Print Date 02/15/2017
Transportation Regulation: 49 CFR (USA):
ORM-D, CONSUMER COMMODITY
Transportation Regulation: IMDG (Vessel):
UN1950, AEROSOLS, 2.1, - Limited quantity
Transportation Regulation: IATA (Cargo Air):
UN1950, Aerosols, flammable, 2.1, - Limited quantity
Transportation Regulation: IATA (Passenger Air):
UN1950, Aerosols, flammable, 2.1, - Limited quantity
Transportation Regulation: TDG (Canada):
UN1950, AEROSOLS, 2.1, - Limited quantity
Components
CAS-No.
Component RQ
(lbs)
Calculated product RQ
(lbs)
acetone
67-64-1
5000
*
SARA 311/312 Hazards
:
Fire Hazard
Sudden Release of Pressure Hazard
Acute Health Hazard
SARA 302
:
No chemicals in this material are subject to the reporting
requirements of SARA Title III, Section 302.
SARA 313
:
This material does not contain any chemical components with
known CAS numbers that exceed the threshold (De Minimis)
reporting levels established by SARA Title III, Section 313.
California Prop 65
This product does not contain any chemicals known to State of
California to cause cancer, birth defects, or any other
SECTION 14. TRANSPORT INFORMATION
The product as delivered to the customer conforms to packaging requirements for shipment by road
under US Department of Transportation (DOT) regulations. Additional transportation classifications
noted above are for reference only, and not a certification or warranty of the suitability of the packaging
for shipment under these alternative transport regulations.
SECTION 15. REGULATORY INFORMATION
EPCRA - Emergency Planning and Community Right-to-Know Act
CERCLA Reportable Quantity
*: Calculated RQ exceeds reasonably attainable upper limit.
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.
10 / 12
SAFETY DATA SHEET
A07760 TM COUNTRY GARDEN 30% 12n6.6
Version 1.1
Revision Date 12/29/2016
Print Date 02/15/2017
reproductive harm.
TSCA
On TSCA Inventory
DSL
All components of this product are on the Canadian DSL
NFPA:
HMIS III:
Hazard pictograms
:
Signal word
:
Danger:
Hazard statements
:
Extremely flammable aerosol. Contains gas under pressure; may explode if heated.
May cause an allergic skin reaction. Causes serious eye irritation. May cause
drowsiness or dizziness.
Precautionary statements
:
Prevention: Keep away from heat/sparks/open flames/hot surfaces. No smoking. Do
not spray on an open flame or other ignition source. Pressurized container: Do not
pierce or burn, even after use. Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
Wash skin thoroughly after handling. Use only outdoors or in a well-ventilated area.
Contaminated w ork clothing should not be allowed out of the workplace. Wear eye
protection/ face protection. Wear protective gloves.
Response: IF ON SKIN: Wash with plenty of soap and w ater. IF INHALED: Remove
victim to fresh air and keep at rest in a position comfortable for breathing. Call a
POISON CENTER or doctor/ physician if you feel unwell. IF IN EYES: Rinse cautiously
with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. If skin irritation or rash occurs: Get medical advice/ attention. If eye
irritation persists: Get medical advice/ attention. Wash contaminated clothing before
reuse.
Storage: Store locked up. Protect from sunlight. Do not expose to temperatures
exceeding 50 °C/ 122 °F. Store in a w ell-ventilated place.
Flammability
Health
Instability
3
4
0
Special hazard.
FLAMMABILITY
PHYSICAL HAZARD
HEALTH
4
2
3
0 = not significant, 1 =Slight,
2 = Moderate, 3 = High
4 = Extreme, * = Chronic
The components of this product are reported in the following inventories:
For information on the country notification status for other regions please contact the
manufacturer’s regulatory group.
Inventory Acronym and Validity Area Legend:
TSCA (USA), DSL (Canada), NDSL (Canada)
SECTION 16. OTHER INFORMATION
Further information
OSHA - GHS Label Information:
11 / 12
SAFETY DATA SHEET
A07760 TM COUNTRY GARDEN 30% 12n6.6
Version 1.1
Revision Date 12/29/2016
Print Date 02/15/2017
Disposal: Dispose of contents/container in accordance with local regulation.
Version:
1.1
Revision Date:
12/29/2016
Print Date:
02/15/2017
We believe the statements, technical information and recommendations contained herein are
reliable, but they are given without warranty or guarantee of any kind. The information in this
document applies to this specific material as supplied. It may not be valid for this material if it
is used in combination with any other materials. Users should make their own investigations
to determine the suitability and applicability of the information for their particular purposes.
This SDS has been prepared by the Compliance Services organization supporting this
manufacturer, supplier or distributor.
Zep Inc. markets products under well recognized and established brand names such as Zep®,
Zep Commercial®,Zep Professional®, Enforcer®, National Chemical™, Selig™, Misty®, Next
Dimension™, Petro®, i-Chem®, TimeMist®, TimeWick™, MicrobeMax®, Country Vet®,
Konk®, Original Bike Spirits®, Blue Coral®, Black Magic®, Rain-X®, Niagara National™, F C
Forward Chemicals®,Rexodan®, Mykal™, and a number of private labeled brands.
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