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SAFETY DATA SHEET
Revision Number 0
Issuing Date January 5, 2015
Revision Date New
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
Product identifier
Product Name Clorox Commercial Solutions® Tilex®Soap Scum Remover & Disinfectant
Other means of identification
EPA Registration Number
Recommended use of the chemical and restrictions on use
Recommended Use
Uses advised against
Details of the supplier of the safety data sheet
Supplier Address
Clorox Professional Products Company
1221 Broadway
Oakland, CA 94612
Phone: 1-510-271-7000
Emergency telephone number
Emergency Phone Numbers
5813-40-67619
Disinfecting bathroom spray cleaner
No information available
For Medical Emergencies, call: 1-800-446-1014
For Transportation Emergencies, call Chemtrec: 1-800-424-9300
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2. HAZARDS IDENTIFICATION
Classification
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200).
Serious eye damage/eye irritation Category 2A
GHS label elements, including precautionary statements
Signal word
Hazard statements
Causes serious eye irritation
Emergency Overview
Warning
Appearance Clear, colorless
Physical State Liquid
Odor Citrus, green, solvent
Precautionary Statements - Prevention
Wash hands and any exposed skin thoroughly after handling.
Wear eye protection/face protection such as safety glasses.
Precautionary Statements - Response
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
If eye irritation persists: Get medical advice/attention.
Precautionary Statements - Storage
None
Precautionary Statements - Disposal
None
Hazards not otherwise classified (HNOC)
Not Applicable
Unknown Toxicity
2.155% of the mixture consists of ingredient(s) of unknown toxicity
Other information
No information available.
Interactions with Other Chemicals
Do not use or mix with bleach-containing products. To do so may release small amounts of formaldehy de gas.
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3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS-No Weight % Trade Secret
Diethylene glycol monobutyl ether 112-34-5 1 - 5 *
Tetrapotassium ethylenediamine tetraacetate (EDTA) 5964-35-2 1 - 5 *
n-Alkyl (68% C12, 32% C14) di methyl ethylbenzyl
ammonium chloride
n-Alkyl (5% C12, 60% C14, 30% C16, 5% C18)
dimethyl benzyl ammonium chlori de
* The exact percentage (concentration) of composition has been withheld as a trade secr et
85409-23-0 0.1 - 0.2 *
53516-76-0 0.1 - 0.2 *
4. FIRST AID MEASURES
First aid measures
General Advice
Eye Contact
Skin Contact
Inhalation
Ingestion
Protection of First-aiders
Most important symptoms and effects, both acute and delayed
Most Important Symptoms/Effects
Indication of any immediate medical attention and special treatment need ed
Notes to Physician
Show this safety data sheet to the doctor in attendance.
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove
contact lenses, if present and easy to do. Continue rinsing. Keep eye wide open while rinsing.
Do not rub affected area. Get medical attention immediately if irritation persists.
Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes.
If irritation develops, call a doctor.
Move to fresh air. If breathing is affected, call a doctor.
Call a poison control center or doctor immediately. Have person sip a glassful of water if able to
swallow. DO NOT induce vomiting unless told to do so by a poison co ntrol center or doctor.
void contact with skin, eyes or clothing. Use personal protective equipment as required.
Wear personal protective clothing (see section 8).
Stinging and irritation of eyes.
Treat symptomatically.
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5. FIRE-FIGHTING MEASURES
Suitable Extinguishing Media
Use extinguishing measures that are appropriate to local circumstances and the surroundi ng environment.
Unsuitable Extinguishing Media
CAUTION: Use of water spray when fighting fire may be inefficient.
Specific Hazards Arising from the Chemical
No information available
Explosion Data
Sensitivity to Mechanical Impact
Sensitivity to Static Discharge
None
None
Protective Equipment and Precautions for Firefigh t ers
s in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective
gear.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal Precautions
Other Information
Environmental precautions
Environmental Precautions
Methods and material for containment and cleaning up
Methods for Containment
Methods for Cleaning Up
void contact with eyes. Use personal protective equipment as required.
Refer to protective measures listed in Sections 7 and 8.
See Section 12 for additional ecological Information.
Prevent further leakage or spillage if safe to do so.
bsorb and containerize. Wash residual down to sanitary sewer. Contact the sanitary
treatment facility in advance to assure ability to process washed-down material.
7. HANDLING AND STORAGE
Precautions for safe handling
Handling
Conditions for safe storage, including any incompatibilities
Storage
Incompatible Products
Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin,
eyes and clothing. Do not eat, drink or smoke when using this product.
Keep containers tightly closed in a dry, cool and well-ventilated place.
Products containing bleach.
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8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Exposure Guidelines
Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH
Diethylene glycol monobutyl ether
CGIH TLV: American Conference of Governmental Industrial Hygienists - Threshold Limit Value. OSHA PEL: Occupational Safety and Health
dministration - Permissible Exposure Limits. NI OSH IDLH: Immediately Dangerous to Life or Health.
112-34-5
Appropriate engineering controls
Engineering Measures
Individual protection measures, such as personal protective equipment
Eye/Face Protection
Skin and Body Protection
Respiratory Protection
Hygiene Measures
10 ppm TWA
Inhalable fraction and vapor
- -
Showers
Eyewash stations
Ventilation systems
If splashes are likely to occur, wear safety glasses with side-shields. None required for
consumer use.
Wear rubber or neoprene gloves if there is the potential for repeated or prolonged ski n contact.
If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory
protection should be worn. Positive-pressure supplied air respirators may be required for high
airborne contaminant concentrations. Respiratory protection must be provided in accordance
with current local regulations.
Remove and wash contaminated clothing before re-use. Avoid contact with skin, eyes and
clothing. Do not eat, drink or smoke when using this product.
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9. PHYSICAL AND CHEMICAL PROPERTIES
Physical and Chemical Properties
Physical State
Appearance
Color
Property
pH
Melting/freezing point
Boiling point / boiling range
Flash Point
Evaporation rate
Flammability (solid, gas)
Flammability Limits in Air
Upper flammability limit
Lower flammability limit
apor pressure
apor density
Specific Gravity
Water Solubility
Solubility in other solvents
Partition coefficient: n-octanol/water
Autoignition temperature
Decomposition temperature
Kinematic viscosity
Dynamic viscosity
Explosive Properties
Oxidizing Properties
Liquid
Clear
Colorless
alues
11 - 12.5
No data available
No data available
Not flammable
No data available
No data available
No data available
No data available
No data available
No data available
~1.0
Soluble in water
No data available
No data available
No data available
No data available
No data available
No data available
Not explosive
No data available
Odor
Odor Threshold
Remarks/ Method
None known
None known
None known
None known
None known
None known
None known
None known
None known
None known
None known
None known
None known
None known
None known
None known
None known
None known
Citrus, green, solvent
No information available
Other Information
Softening Point
OC Content (%)
Particle Size
Particle Size Distribution
No data available
No data available
No data available
No data available
10. STABILITY AND REACTIVITY
Reactivity
Do not use or mix with bleach-containing products. To do so may release small amounts of formaldehyde gas.
Chemical stability
Stable under recommended storage conditions.
Possibility of Hazardous Reactions
None under normal processing.
Conditions to avoid
None known based on information supplied.
Incompatible materials
Products containing bleach.
Hazardous Decomposition Products
None known based on information supplied.
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11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Product Information
Inhalation
Eye Contact
Skin Contact
Ingestion
Component Information
Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation
Diethylene glycol monobutyl ether
112-34-5
Information on toxicological effects
Symptoms
Delayed and immediate effects as well as chroni c effects from short and long-term exposure
Sensitization
Mutagenic Effects
Carcinogenicity
Reproductive Toxicity
STOT - single exposure
STOT - repeated exposure
Chronic Toxicity
Target Organ Effects
Aspiration Hazard
Numerical measures of toxicity Product Information
The following values are calculated based on chapter 3.1 of the GHS document
Not applicable
Exposure to vapor or mist may irritate respiratory tract.
May cause eye irritation.
Prolonged contact may cause irritation.
Ingestion may cause irritation to mucous membranes and gastrointestinal irritation, nausea,
vomiting, and diarrhea.
3384 mg/kg (Rat) 2700 mg/kg (Rabbit) -
May cause redness and tearing of the eyes.
No information available.
No information available.
Contains no ingredient listed as a carcinogen.
No information available
No information available.
No information available.
Carcinogenic potential is unknown
Respiratory system, eyes, skin, gastrointestinal tract (GI).
No information available.
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12. ECOLOGICAL INFORMATION
Ecotoxicity
Harmful to aquatic life
Persistence and Degradability
No information available.
Bioaccumulation
No information available.
Other Adverse Effects
No information available.
13. DISPOSAL CONSIDERATIONS
Disposal methods
Dispose of in accordance with all applicable federal, state, and local regulations.
Contaminated Packaging
Do not reuse empty containers. Dispose of in accordance with all applicable federal, state, and local regulations.
14. TRANSPORT INFORMATION
DOT
TDG
ICAO
IATA
IMDG/IMO
Not regulated
Not regulated
Not regulated
Not regulated
Not regulated
15. REGULATORY INFORMATION
Chemical Inventories
TSCA
DSL/NDSL
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
U.S. Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains the following
chemical which is subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372.
Chemical Name CAS-No Weight %
Diethylene glycol monobutyl ether (Glycol ethers category) 112-34-5 1 - 5 1.0
ll components of this product are either on the TSCA 8(b) Inventory or otherwise exempt from
listing.
ll components are on the DSL or NDSL.
SARA 313 - Threshold
Values %
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SARA 311/312 Hazard Categories
Acute Health Hazard
Chronic Health Hazard
Fire Hazard
Sudden Release of Pressure Hazard
Reactive Hazard
Clean Water Act
This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR
122.42).
CERCLA
This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or th e Superfund Amendments and Reauthorization
ct (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this
material.
EPA Statement
This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements
under federal pesticide law. These requirements differ from the classific ation criteria and hazard information required for safety data
sheets and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label:
WARNING: Causes substantial but temporary eye injury. Harmful if absorbed through skin. Avoid breathing spray mist. Do
not get in eyes, on skin or on clothing. Wear safety glasses or goggles. Wash thoroughly with soap and water after handling.
Remove contaminated clothing and wash before reuse.
U.S. State Regulations
California Proposition 65
This product does not contain any Proposition 65 chemicals.
U.S. State Right-to-Know Regulations
Chemical Name New Jersey Massachusetts Pennsylvania Rhode Island Illinois
Diethylene glycol monobutyl ether (Glycol ethers category)
112-34-5
International Regulations
Canada
WHMIS Hazard Class
D2B Toxic materials
Yes
No
No
No
No
X X
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16. OTHER INFORMATION
NFPA
HMIS
Health Hazard 2 Flammability 0
Health Hazard 2 Flammability 0
Prepared By
Revision Date
Revision Note
Reference
General Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of
its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates
only to the specific material designated and may not be v alid for such material used in combination with any other materials o
in any process, unless specified in the text
Product Stewardship
23 British American Blvd.
Latham, NY 12110
1-800-572-6501
New
New
1103604/51589001.003
End of Safety Data Sheet
Instability 0
Physical Hazard 0 Personal Protection B
Physical and Chemical Hazards -
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