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SAFETY DATA SHEET
Issuing Date January 5, 2015
Revision Date New
Revision Number 0
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1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
Product identifier
Product Name
Clorox Commercial Solutions® Tilex® Disinfects Instant Mold & Mildew Remover
Other means of identification
EPA Registration Number
5813-24-67619
Recommended use of the chemical and restrictions on use
Recommended use
Mold and mildew remover spray
Uses advised against
No information available
Details of the supplier of the safety data sheet
Supplier Address
The Clorox Company
1221 Broadway, Oakland, CA 94612
USA
Phone: 1-510-271-7000
Emergency telephone number
Emergency Phone Numbers
For Medical Emergencies, call: 1-800-446-1014
For Transportation Emergencies, call Chemtrec: 1-800-424-9300
2. HAZARDS IDENTIFICATION
Classification
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200).
Skin corrosion/irritation
Category 3
Serious eye damage/eye irritation
Category 2A
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GHS Label elements, including precautionary statements
Emergency Overview
Signal word
Warning
Hazard Statements
Causes mild skin irritation
Causes serious eye irritation
Appearance Clear, pale yellow
Physical State Liquid
Odor Herbaceous, marine, bleach
Precautionary Statements - Prevention
Wash hands and any exposed skin thoroughly after handling.
Wear eye protection/face protection such as safety glasses.
Precautionary Statements - Response
Eyes
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing. If eye irritation persists: Get medical advice/attention.
Skin
If skin irritation occurs: Get medical advice/attention.
Precautionary Statements - Storage
None
Precautionary Statements - Disposal
None
Hazards not otherwise classified (HNOC)
The following medical conditions may be aggravated by exposure to high concentrations of vapor or mist: heart conditions or
chronic respiratory problems such as asthma, emphysema, or obstructive lung disease.
Unknown Toxicity
0.085% of the mixture consists of ingredient(s) of unknown toxicity
Other information
Toxic to aquatic life with long lasting effects
Very toxic to aquatic life
Interactions with Other Chemicals
Reacts with other household chemicals such as products containing ammonia, toilet bowl cleaners, rust removers, vinegar, or acids to
produce hazardous gases, such as chlorine and other chlorinated compounds.
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3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name
CAS-No
Weight %
Trade Secret
Sodium hypochlorite
7681-52-9
1 - 5
*
Sodium hydroxide
1310-73-2
0.1 - 1
*
* The exact percentage (concentration) of composition has been withheld as a trade secret.
4. FIRST AID MEASURES
First aid measures
General Advice
Show this safety data sheet to the doctor in attendance.
Eye Contact
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. Keep eye wide open
while rinsing. Do not rub affected area. Get medical attention if irritation develops and
persists.
Skin Contact
Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20
minutes. If irritation develops, call a doctor.
Inhalation
Move to fresh air. If breathing is affected, call a doctor.
Ingestion
Call a poison control center or doctor immediately. Have person sip a glassful of water if
able to swallow. DO NOT induce vomiting unless told to do so by a poison control center
or doctor.
Protection of First-aiders
Avoid contact with skin, eyes or clothing. Use personal protective equipment as required.
Wear personal protective clothing (see section 8).
Most important symptoms and effects, both acute and delayed
Most Important Symptoms and
Effects
Stinging and irritation of eyes.
Indication of any immediate medical attention and special treatment needed
Notes to Physician
Treat symptomatically.
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5. FIRE-FIGHTING MEASURES
Suitable Extinguishing Media
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Unsuitable Extinguishing Media
CAUTION: Use of water spray when fighting fire may be inefficient.
Specific Hazards Arising from the Chemical
No information available.
Explosion Data
Sensitivity to Mechanical Impact
None.
Sensitivity to Static Discharge
None.
Protective equipment and precautions for firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal Precautions
Avoid contact with eyes, skin, and clothing. Use personal protective equipment as
required.
Other Information
Refer to protective measures listed in Sections 7 and 8.
Environmental precautions
Environmental Precautions
See Section 12 for ecological Information.
Methods and material for containment and cleaning up
Methods for Containment
Prevent further leakage or spillage if safe to do so.
Methods for Cleaning Up
Absorb and containerize. Wash residual down to sanitary sewer. Contact the sanitary
treatment facility in advance to assure ability to process washed-down material.
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7. HANDLING AND STORAGE
Precautions for safe handling
Handling
Handle in accordance with good industrial hygiene and safety practice. Avoid contact with
skin, eyes or clothing. Do not eat, drink or smoke when using this product.
Conditions for safe storage, including any incompatibilities
Storage
Keep containers tightly closed in a dry, cool and well-ventilated place.
Incompatible Products
Products containing ammonia, toilet bowl cleaners, rust removers, vinegar, or acids.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Exposure Guidelines
Chemical Name
ACGIH TLV
OSHA PEL
NIOSH IDLH
Sodium hydroxide
1310-73-2
Ceiling: 2 mg/m3
TWA: 2 mg/m3
IDLH: 10 mg/m3
Ceiling: 2 mg/m3
ACGIH TLV: American Conference of Governmental Industrial Hygienists - Threshold Limit Value. OSHA PEL: Occupational Safety and Health
Administration - Permissible Exposure Limits. NIOSH IDLH: Immediately Dangerous to Life or Health.
Appropriate engineering controls
Engineering Measures
Showers
Eyewash stations
Ventilation systems
Individual protection measures, such as personal protective equipment
Eye/Face Protection
If splashes are likely to occur: Wear safety glasses with side shields (or goggles). None
required for consumer use.
Skin and Body Protection
Wear protective gloves and protective clothing.
Respiratory Protection
If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved
respiratory protection should be worn. Positive-pressure supplied air respirators may be
required for high airborne contaminant concentrations. Respiratory protection must be
provided in accordance with current local regulations.
Hygiene Measures
Remove and wash contaminated clothing before re-use. Avoid contact with skin, eyes or
clothing. Do not eat, drink or smoke when using this product.
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9. PHYSICAL AND CHEMICAL PROPERTIES
Physical and Chemical Properties
Physical State
Liquid
Appearance
Clear
Odor
Herbaceous, marine, bleach
Color
Pale yellow
Odor Threshold
No information available
Property
Values
Remarks/ Method
pH
12.4 - 12.8
None known
Melting/freezing point
No data available
None known
Boiling point / boiling range
No data available
None known
Flash Point
Not flammable
None known
Evaporation rate
No data available
None known
Flammability (solid, gas)
No data available
None known
Flammability Limits in Air
Upper flammability limit
No data available
None known
Lower flammability limit
No data available
None known
Vapor pressure
No data available
None known
Vapor density
No data available
None known
Specific Gravity
~1.04
None known
Water Solubility
Soluble in water
None known
Solubility in other solvents
No data available
None known
Partition coefficient: n-octanol/water
No data available
None known
Autoignition temperature
No data available
None known
Decomposition temperature
No data available
None known
Kinematic viscosity
No data available
None known
Dynamic viscosity
No data available
None known
Explosive Properties
Not explosive
Oxidizing Properties
No data available
Other Information
Softening Point
No data available
VOC Content (%)
No data available
Particle Size
No data available
Particle Size Distribution
No data available
10. STABILITY AND REACTIVITY
Reactivity
Reacts with other household chemicals such as products containing ammonia, toilet bowl cleaners, rust removers, vinegar, or acids to
produce hazardous gases, such as chlorine and other chlorinated compounds.
Chemical stability
Stable under recommended storage conditions.
Possibility of Hazardous Reactions
None under normal processing.
Conditions to avoid
None known based on information supplied.
Incompatible materials
Products containing ammonia, toilet bowl cleaners, rust removers, vinegar, or acids.
Hazardous Decomposition Products
None known based on information supplied.
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11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Product Information
.
Inhalation
Exposure to vapor or mist may irritate respiratory tract.
Eye Contact
May cause eye irritation.
Skin Contact
Prolonged contact may cause irritation.
Ingestion
Ingestion may cause irritation to mucous membranes and gastrointestinal tract, nausea,
vomiting, and diarrhea.
Component Information
Chemical Name
LD50 Oral
LD50 Dermal
LC50 Inhalation
Sodium hypochlorite
7681-52-9
8200 mg/kg (Rat)
>10000 mg/kg (Rabbit)
-
Sodium hydroxide
1310-73-2
-
1350 mg/kg (Rabbit)
-
Information on toxicological effects
Symptoms
May cause redness and tearing of the eyes.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Sensitization
No information available.
Mutagenic Effects
No information available.
Carcinogenicity
The table below indicates whether each agency has listed any ingredient as a carcinogen.
Chemical Name
ACGIH
IARC
NTP
OSHA
Sodium hypochlorite
7681-52-9
-
Group 3 - -
IARC (International Agency for Research on Cancer)
Group 3 - Not Classifiable as to Carcinogenicity in Humans
Reproductive Toxicity
No information available.
STOT - single exposure
No information available.
STOT - repeated exposure
No information available.
Chronic Toxicity
Carcinogenic potential is unknown.
Target Organ Effects
Respiratory system, eyes, skin, gastrointestinal tract (GI).
Aspiration Hazard
No information available.
Numerical measures of toxicity - Product Information
The following values are calculated based on chapter 3.1 of the GHS document
Not applicable
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12. ECOLOGICAL INFORMATION
Ecotoxicity
Very toxic to aquatic life. Toxic to aquatic life with long lasting effects.
Persistence and Degradability
No information available.
Bioaccumulation
No information available.
Other adverse effects
No information available.
13. DISPOSAL CONSIDERATIONS
Disposal methods
Dispose of in accordance with all applicable federal, state, and local regulations.
Contaminated Packaging
Do not reuse empty containers. Dispose of in accordance with all applicable federal, state, and local regulations.
14. TRANSPORT INFORMATION
DOT
NOT REGULATED
TDG
UN-No
UN3082
Proper Shipping Name
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
Hazard Class
9
Packing Group
III
Description
UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (SODIUM
HYPOCHLORITE), 9, III, MARINE POLLUTANT
ICAO
UN-No
UN3082
Proper Shipping Name
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
Hazard Class
9
Packing Group
III
Description
UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (SODIUM
HYPOCHLORITE), 9, III
IATA
UN-No
UN3082
Proper Shipping Name
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
Hazard Class
9
Packing Group
III
Description
UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (SODIUM
HYPOCHLORITE), 9, III
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IMDG/IMO
UN-No
UN3082
Proper Shipping Name
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
Hazard Class
9
Packing Group
III
EmS No.
F-A, S-F
Marine Pollutant
Product is a marine pollutant according to the criteria set by IMDG/IMO
Description
UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (SODIUM
HYPOCHLORITE), 9, III, MARINE POLLUTANT
15. REGULATORY INFORMATION
Chemical Inventories
TSCA
All components of this product are either on the TSCA 8(b) Inventory or otherwise exempt
from listing.
DSL/NDSL
All components are on the DSL or NDSL.
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
U.S. Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any
chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372
SARA 311/312 Hazard Categories
Acute Health Hazard
Yes
Chronic Health Hazard
No
Fire Hazard
No
Sudden Release of Pressure Hazard
No
Reactive Hazard
No
Clean Water Act
This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21
and 40 CFR 122.42)
Chemical Name
CWA - Reportable
Quantities
CWA - Toxic Pollutants
CWA - Priority Pollutants
CWA - Hazardous
Substances
Sodium hypochlorite
7681-52-9
100 lb
X
Sodium hydroxide
1310-73-2
1000 lb
X
CERCLA
This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302)
Chemical Name
Hazardous Substances RQs
Extremely Hazardous Substances
RQs
RQ
Sodium hypochlorite
7681-52-9
100 lb
-
RQ 100 lb final RQ
RQ 45.4 kg final RQ
Sodium hydroxide
1310-73-2
1000 lb
-
RQ 1000 lb final RQ
RQ 454 kg final RQ
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EPA Statement
This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling
requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information
required for safety data sheets and for workplace labels of non-pesticide chemicals. Following is the hazard information as
required on the pesticide label:
WARNING: Causes substantial but temporary eye injury and can irritate skin. For sensitive skin or prolonged use, wear
gloves. Do not get in eyes or on clothing. Vapors may irritate. Use only in well-ventilated areas. Avoid prolonged
breathing of vapors. Not recommended for use by persons with heart conditions or chronic respiratory problems
such as asthma, emphysema or obstructive lung disease. Due to irritating nature, may be harmful if swallowed.
US State Regulations
California Proposition 65
This product does not contain any Proposition 65 chemicals.
U.S. State Right-to-Know Regulations
Chemical Name
New Jersey
Massachusetts
Pennsylvania
Rhode Island
Illinois
Sodium hypochlorite
7681-52-9
X X X
X
Sodium hydroxide
1310-73-2
X X X
X
International Regulations
Canada
WHMIS Hazard Class
D2B - Toxic materials
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16. OTHER INFORMATION
NFPA
Health Hazard 2
Flammability 0
Instability 0
Physical and Chemical Hazards -
HMIS
Health Hazard 2
Flammability 0
Physical Hazard 0
Personal Protection X
Prepared By
Product Stewardship
23 British American Blvd.
Latham, NY 12110
1-800-572-6501
Revision Date
New
Revision Note
Reference
New
1101803/50049006.004
General Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the
date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.
End of Safety Data Sheet
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