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SAFETY DATA SHEET
Issuing Date January 5, 2015
Revision Date New
Revision Number 0
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1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
Product identifier
Product Name
Clorox Commercial Solutions® Tilex® Soap Scum Remover & Disinfectant
Other means of identification
EPA Registration Number
5813-40-67619
Recommended use of the chemical and restrictions on use
Recommended Use
Disinfecting bathroom spray cleaner
Uses advised against
No information available
Details of the supplier of the safety data sheet
Supplier Address
The Clorox Company
1221 Broadway
Oakland, CA 94612
USA
Phone: 1-510-271-7000
Emergency telephone number
Emergency Phone Numbers
For Medical Emergencies, call: 1-800-446-1014
For Transportation Emergencies, call Chemtrec: 1-800-424-9300
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2. HAZARDS IDENTIFICATION
Classification
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200).
Serious eye damage/eye irritation
Category 2A
GHS label elements, including precautionary statements
Emergency Overview
Signal word
Warning
Hazard statements
Causes serious eye irritation
Appearance Clear, colorless
Physical State Liquid
Odor Citrus, green, solvent
Precautionary Statements - Prevention
Wash hands and any exposed skin thoroughly after handling.
Wear eye protection/face protection such as safety glasses.
Precautionary Statements - Response
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
If eye irritation persists: Get medical advice/attention.
Precautionary Statements - Storage
None
Precautionary Statements - Disposal
None
Hazards not otherwise classified (HNOC)
Not Applicable
Unknown Toxicity
2.155% of the mixture consists of ingredient(s) of unknown toxicity
Other information
No information available.
Interactions with Other Chemicals
Do not use or mix with bleach-containing products. To do so may release small amounts of formaldehyde gas.
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3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name
CAS-No
Weight %
Trade Secret
Diethylene glycol monobutyl ether
112-34-5
1 - 5
*
Tetrapotassium ethylenediamine tetraacetate (EDTA)
5964-35-2
1 - 5
*
n-Alkyl (68% C12, 32% C14) dimethyl ethylbenzyl
ammonium chloride
85409-23-0
0.1 - 0.2
*
n-Alkyl (5% C12, 60% C14, 30% C16, 5% C18)
dimethyl benzyl ammonium chloride
53516-76-0
0.1 - 0.2
*
* The exact percentage (concentration) of composition has been withheld as a trade secret
4. FIRST AID MEASURES
First aid measures
General Advice
Show this safety data sheet to the doctor in attendance.
Eye Contact
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. Keep eye wide open
while rinsing. Do not rub affected area. Get medical attention immediately if irritation
persists.
Skin Contact
Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20
minutes. If irritation develops, call a doctor.
Inhalation
Move to fresh air. If breathing is affected, call a doctor.
Ingestion
Call a poison control center or doctor immediately. Have person sip a glassful of water if able
to swallow. DO NOT induce vomiting unless told to do so by a poison control center or
doctor.
Protection of First-aiders
Avoid contact with skin, eyes or clothing. Use personal protective equipment as required.
Wear personal protective clothing (see section 8).
Most important symptoms and effects, both acute and delayed
Most Important Symptoms/Effects
Stinging and irritation of eyes.
Indication of any immediate medical attention and special treatment needed
Notes to Physician
Treat symptomatically.
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5. FIRE-FIGHTING MEASURES
Suitable Extinguishing Media
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Unsuitable Extinguishing Media
CAUTION: Use of water spray when fighting fire may be inefficient.
Specific Hazards Arising from the Chemical
No information available
Explosion Data
Sensitivity to Mechanical Impact
None
Sensitivity to Static Discharge
None
Protective Equipment and Precautions for Firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective
gear.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal Precautions
Avoid contact with eyes. Use personal protective equipment as required.
Other Information
Refer to protective measures listed in Sections 7 and 8.
Environmental precautions
Environmental Precautions
See Section 12 for additional ecological Information.
Methods and material for containment and cleaning up
Methods for Containment
Prevent further leakage or spillage if safe to do so.
Methods for Cleaning Up
Absorb and containerize. Wash residual down to sanitary sewer. Contact the sanitary
treatment facility in advance to assure ability to process washed-down material.
7. HANDLING AND STORAGE
Precautions for safe handling
Handling
Handle in accordance with good industrial hygiene and safety practice. Avoid contact with
skin, eyes and clothing. Do not eat, drink or smoke when using this product.
Conditions for safe storage, including any incompatibilities
Storage
Keep containers tightly closed in a dry, cool and well-ventilated place.
Incompatible Products
Products containing bleach.
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8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Exposure Guidelines
Chemical Name
ACGIH TLV
OSHA PEL
NIOSH IDLH
Diethylene glycol monobutyl ether
1310-73-2
10 ppm TWA
Inhalable fraction and vapor
-
-
ACGIH TLV: American Conference of Governmental Industrial Hygienists - Threshold Limit Value. OSHA PEL: Occupational Safety and Health
Administration - Permissible Exposure Limits. NIOSH IDLH: Immediately Dangerous to Life or Health.
Appropriate engineering controls
Engineering Measures
Showers
Eyewash stations
Ventilation systems
Individual protection measures, such as personal protective equipment
Eye/Face Protection
If splashes are likely to occur, wear safety glasses with side-shields. None required for
consumer use.
Skin and Body Protection
Wear rubber or neoprene gloves if there is the potential for repeated or prolonged skin contact.
Respiratory Protection
If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory
protection should be worn. Positive-pressure supplied air respirators may be required for high
airborne contaminant concentrations. Respiratory protection must be provided in accordance
with current local regulations.
Hygiene Measures
Remove and wash contaminated clothing before re-use. Avoid contact with skin, eyes and
clothing. Do not eat, drink or smoke when using this product.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical and Chemical Properties
Physical State
Liquid
Appearance
Clear
Odor
Citrus, green, solvent
Color
Colorless
Odor Threshold
No information available
Property
Values
Remarks/ Method
pH
11 - 12.5
None known
Melting/freezing point
No data available
None known
Boiling point / boiling range
No data available
None known
Flash Point
Not flammable
None known
Evaporation rate
No data available
None known
Flammability (solid, gas)
No data available
None known
Flammability Limits in Air
Upper flammability limit
No data available
None known
Lower flammability limit
No data available
None known
Vapor pressure
No data available
None known
Vapor density
No data available
None known
Specific Gravity
~1.0
None known
Water Solubility
Soluble in water
None known
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9. PHYSICAL AND CHEMICAL PROPERTIES
Solubility in other solvents
No data available
Partition coefficient: n-octanol/water
No data available
None known
None known
Autoignition temperature
No data available
None known
Decomposition temperature
No data available
None known
Kinematic viscosity
No data available
None known
Dynamic viscosity
No data available
None known
Explosive Properties
Not explosive
Oxidizing Properties
No data available
Other Information
Softening Point
No data available
VOC Content (%)
No data available
Particle Size
No data available
Particle Size Distribution
No data available
10. STABILITY AND REACTIVITY
Reactivity
Do not use or mix with bleach-containing products. To do so may release small amounts of formaldehyde gas.
Chemical stability
Stable under recommended storage conditions.
Possibility of Hazardous Reactions
None under normal processing.
Conditions to avoid
None known based on information supplied.
Incompatible materials
Products containing bleach.
Hazardous Decomposition Products
None known based on information supplied.
11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Product Information
Inhalation
Exposure to vapor or mist may irritate respiratory tract.
Eye Contact
May cause eye irritation.
Skin Contact
Prolonged contact may cause irritation.
Ingestion
Ingestion may cause irritation to mucous membranes and gastrointestinal irritation, nausea,
vomiting, and diarrhea.
Component Information
Chemical Name
LD50 Oral
LD50 Dermal
LC50 Inhalation
Diethylene glycol monobutyl ether
112-34-5
3384 mg/kg (Rat)
2700 mg/kg (Rabbit)
-
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Information on toxicological effects
Symptoms
May cause redness and tearing of the eyes.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Sensitization
No information available.
Mutagenic Effects
No information available.
Carcinogenicity
Contains no ingredient listed as a carcinogen.
Reproductive Toxicity
No information available
STOT - single exposure
No information available.
STOT - repeated exposure
No information available.
Chronic Toxicity
Carcinogenic potential is unknown
Target Organ Effects
Respiratory system, eyes, skin, gastrointestinal tract (GI).
Aspiration Hazard
No information available.
Numerical measures of toxicity Product Information
The following values are calculated based on chapter 3.1 of the GHS document
Not applicable
12. ECOLOGICAL INFORMATION
Ecotoxicity
Harmful to aquatic life
Persistence and Degradability
No information available.
Bioaccumulation
No information available.
Other Adverse Effects
No information available.
13. DISPOSAL CONSIDERATIONS
Disposal methods
Dispose of in accordance with all applicable federal, state, and local regulations.
Contaminated Packaging
Do not reuse empty containers. Dispose of in accordance with all applicable federal, state, and local regulations.
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14. TRANSPORT INFORMATION
DOT
Not regulated
TDG
Not regulated
ICAO
Not regulated
IATA
Not regulated
IMDG/IMO
Not regulated
15. REGULATORY INFORMATION
Chemical Inventories
TSCA
All components of this product are either on the TSCA 8(b) Inventory or otherwise exempt from
listing.
DSL/NDSL
All components are on the DSL or NDSL.
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
U.S. Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains the following
chemical which is subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372.
Chemical Name
CAS-No
Weight %
SARA 313 - Threshold
Values %
Diethylene glycol monobutyl ether (Glycol ethers category)
112-34-5
1 - 5
1.0
SARA 311/312 Hazard Categories
Acute Health Hazard
Yes
Chronic Health Hazard
No
Fire Hazard
No
Sudden Release of Pressure Hazard
No
Reactive Hazard
No
Clean Water Act
This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR
122.42).
CERCLA
This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization
Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of
this material.
EPA Statement
This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements
under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data
sheets and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label:
WARNING: Causes substantial but temporary eye injury. Harmful if absorbed through skin. Avoid breathing spray mist.
Do not get in eyes, on skin or on clothing. Wear safety glasses or goggles. Wash thoroughly with soap and water after
handling. Remove contaminated clothing and wash before reuse.
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U.S. State Regulations
California Proposition 65
This product does not contain any Proposition 65 chemicals.
U.S. State Right-to-Know Regulations
Chemical Name
New Jersey
Massachusetts
Pennsylvania
Rhode Island
Illinois
Diethylene glycol monobutyl ether (Glycol ethers category)
112-34-5
X X
International Regulations
Canada
WHMIS Hazard Class
D2B Toxic materials
16. OTHER INFORMATION
NFPA
Health Hazard 2
Flammability 0
Instability 0
Physical and Chemical Hazards -
HMIS
Health Hazard 2
Flammability 0
Physical Hazard 0
Personal Protection B
Prepared By
Product Stewardship
23 British American Blvd.
Latham, NY 12110
1-800-572-6501
Revision Date
New
Revision Note
Reference
New
1067476-B/51589001.003/1103604
General Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date
of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates
only to the specific material designated and may not be valid for such material used in combination with any other materials
or in any process, unless specified in the text
End of Safety Data Sheet
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