Terro T514 User Manual

Page 1
SAFETY DATA SHEET
(800) 424-9300
Regulatory Licenses
None
Issuing Date No data available Revision Date 28-Dec-2017 Revision Number 2
NGHS / English
_____________________________________________________________________________________________
The supplier identified below generated this SDS using the UL SDS template. UL did not test, certify, or approve the substance described in this SDS, and all information in this SDS was provided by the supplier or was reproduced from publically available regulatory data sources. UL makes no representations or warranties regarding the completeness or accuracy of the information in this SDS and disclaims all liability in connection with the use of this information or the substance described in this SDS. The layout, appearance and format of this SDS is © 2014 UL LLC. All rights reserved.
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Product identifier
Product Name
Other means of identification
Product Code(s)
Recommended use of the chemical and restrictions on use
Recommended Use
Restrictions on use
Details of the supplier of the safety data sheet
Supplier Identification
Address
Telephone
E-mail
Emergency telephone number
Terro Reusable Dual Action Wasp & Fly Trap Plus
T514
Trap and/or Bait Station
No information available
Senoret Chemical Company, Inc.
69 North Locust St. Lititz Pennsylvania 17543 United States
Phone:(800) 800-1819 Fax:(800) 800-1819
aodonnell@woodstream.com
Company Emergency Phone Number
Classification
Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 1 Flammable liquids
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(717) 626-2125
2. HAZARDS IDENTIFICATION
Category 3
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Appearance Red Physical state Liquid Odor Vinegar-like
GHS Label elements, including precautionary statements
Danger
Hazard statements
Causes skin irritation Causes serious eye damage Flammable liquid and vapor
Precautionary Statements - Prevention
Wash face, hands and any exposed skin thoroughly after handling Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking Keep container tightly closed Ground/bond container and receiving equipment Use explosion-proof electrical/ ventilating/ lighting/ equipment Use only non-sparking tools Take precautionary measures against static discharge Wear protective gloves/eye protection/face protection
Precautionary Statements - Response
Specific treatment (see supplemental first aid instructions on this label)
Eyes
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Immediately call a POISON CENTER or doctor
Skin
If skin irritation occurs: Get medical advice/attention IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower Wash contaminated clothing before reuse
Fire
In case of fire: Use CO2, dry chemical, or foam to extinguish
Precautionary Statements - Storage
Store in a well-ventilated place. Keep cool
Precautionary Statements - Disposal
Dispose of contents/container to an approved waste disposal plant
Other information
Harmful to aquatic life.
Unknown acute toxicity
0 % of the mixture consists of ingredient(s) of unknown acute oral toxicity 1 % of the mixture consists of ingredient(s) of unknown acute dermal toxicity
17.2 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (gas)
17.2 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (vapor)
17.2 % of the mixture consists of ingredient(s) of unknown toxicity
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0 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (dust/mist)
3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance
Not applicable.
Mixture
Chemical name CAS No. Weight-% Hazardous Material
Information Review Act
registry number (HMIRA
registry #)
Third Party Formulation
(TP # 1425329)
Third Party Formulation
(TP # 1425329)
Third Party Formulation
(TP # 1425329)
- 50 - 60% - -
- 10 - 20% - -
- 0 - 10% - -
4. FIRST AID MEASURES
First aid measures
General advice
Inhalation
Eye contact
Skin contact
Ingestion
Immediate medical attention is required. Show this safety data sheet to the doctor in attendance. Remove to fresh air. Get medical attention immediately if symptoms occur.
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Keep eye wide open while rinsing. Do not rub affected area. Get immediate medical advice/attention. Remove contact lenses, if present and easy to do. Continue rinsing.
Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Get medical attention if irritation develops and persists.
Clean mouth with water and drink afterwards plenty of water. Never give anything by mouth to an unconscious person. Do NOT induce vomiting. Call a physician.
Date HMIRA filed and
date exemption granted
(if applicable)
Self-protection of the first aider
Most important symptoms and effects, both acute and delayed
Symptoms
Indication of any immediate medical attention and special treatment needed
Note to physicians
Remove all sources of ignition. Ensure that medical personnel are aware of the material(s) involved, take precautions to protect themselves and prevent spread of contamination. Use personal protective equipment as required. See section 8 for more information. Avoid contact with skin, eyes or clothing.
Burning sensation.
Treat symptomatically.
5. FIRE-FIGHTING MEASURES
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Suitable Extinguishing Media
Unsuitable extinguishing media
Specific hazards arising from the chemical
Hazardous Combustion Products
Explosion Data
Sensitivity to Mechanical Impact Sensitivity to Static Discharge
Special protective equipment for fire-fighters
Dry chemical. Carbon dioxide (CO2). Water spray. Alcohol resistant foam.
CAUTION: Use of water spray when fighting fire may be inefficient.
Risk of ignition. Keep product and empty container away from heat and sources of ignition. In the event of fire, cool tanks with water spray. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.
Carbon oxides.
None. Yes.
Firefighters should wear self-contained breathing apparatus and full firefighting turnout gear. Use personal protection equipment.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal precautions
Evacuate personnel to safe areas. Use personal protective equipment as required. See section 8 for more information. Avoid contact with skin, eyes or clothing. Ensure adequate ventilation. Keep people away from and upwind of spill/leak. ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Pay attention to flashback. Take precautionary measures against static discharges. All equipment used when handling the product must be grounded. Do not touch or walk through spilled material.
Other Information
Methods and material for containment and cleaning up
Methods for containment
Methods for cleaning up
Ventilate the area. Refer to protective measures listed in Sections 7 and 8.
Stop leak if you can do it without risk. Do not touch or walk through spilled material. A vapor suppressing foam may be used to reduce vapors. Dike far ahead of spill to collect runoff water. Keep out of drains, sewers, ditches and waterways. Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal.
Take precautionary measures against static discharges. Dam up. Soak up with inert absorbent material. Pick up and transfer to properly labeled containers.
7. HANDLING AND STORAGE
Precautions for safe handling
Advice on safe handling
Use personal protection equipment. Avoid breathing vapors or mists. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use grounding and bonding connection when transferring this material to prevent static discharge, fire or explosion. Use with local exhaust ventilation. Use spark-proof tools and explosion-proof equipment. Keep in an area equipped with sprinklers. Use according to package label instructions. Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes or clothing. Do not eat, drink or smoke when using this product. Take off contaminated clothing and wash before reuse.
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Conditions for safe storage, including any incompatibilities
Storage Conditions
Keep containers tightly closed in a dry, cool and well-ventilated place. Keep away from heat, sparks, flame and other sources of ignition (i.e., pilot lights, electric motors and static electricity). Keep in properly labeled containers. Do not store near combustible materials. Keep in an area equipped with sprinklers. Store in accordance with the particular national regulations. Store in accordance with local regulations. Store locked up. Keep out of the reach of children.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Exposure Limits
Chemical name ACGIH TLV OSHA PEL NIOSH IDLH
Third Party Formulation (TP #
1425329)
Third Party Formulation (TP #
1425329)
Third Party Formulation (TP #
1425329)
Chemical name Alberta British Columbia Ontario TWAEV Quebec
Third Party Formulation
TWA: 10 mg/m
(TP # 1425329)
.
TWA: 10 mg/m
3
TWA: 15 mg/m3 total dust
TWA: 5 mg/m3 respirable
fraction
(vacated) TWA: 15 mg/m3 total
dust
(vacated) TWA: 5 mg/m
respirable fraction
STEL = 15 ppm
TWA: 10 ppm
TWA: 10 ppm
TWA: 25 mg/m
(vacated) TWA: 10 ppm
(vacated) TWA: 25 mg/m
STEL: 1000 ppm TWA: 1000 ppm
TWA: 1900 mg/m
(vacated) TWA: 1000 ppm
(vacated) TWA: 1900 mg/m
3
TWA: 10 mg/m
TWA: 3 mg/m
3
3
TWA: 10 mg/m
TWA: 10 mg/m3 total dust
TWA: 5 mg/m3 respirable dust
3
3
3
IDLH: 50 ppm TWA: 10 ppm
TWA: 25 mg/m
STEL: 15 ppm
STEL: 37 mg/m
3
IDLH: 3300 ppm 10% LEL
TWA: 1000 ppm
3
TWA: 1900 mg/m
3
3
3
3
TWA: 10 mg/m
3
Third Party Formulation
(TP # 1425329)
Third Party Formulation
(TP # 1425329)
Other Exposure Guidelines
TWA: 10 ppm
TWA: 25 mg/m
STEL: 15 ppm STEL: 37 mg/m TWA: 1000 ppm
TWA: 1880 mg/m
Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962
3
3
3
TWA: 10 ppm
STEL: 15 ppm
STEL: 1000 ppm STEL: 1000 ppm TWA: 1000 ppm
TWA: 10 ppm
STEL: 15 ppm
TWA: 10 ppm
TWA: 25 mg/m
STEL: 15 ppm
STEL: 37 mg/m
TWA: 1880 mg/m
3
3
3
(11th Cir., 1992). See section 15 for national exposure control parameters.
Appropriate engineering controls
Engineering controls
Showers Eyewash stations Ventilation systems.
Individual protection measures, such as personal protective equipment
Eye/face protection
Tight sealing safety goggles.
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Hand protection
Skin and body protection
Respiratory protection
General hygiene considerations
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical and Chemical Properties Physical state Appearance Odor Color Odor Threshold
Property pH Melting / freezing point Boiling point / boiling range Flash Point Evaporation Rate Flammability (solid, gas)
Flammability Limit in Air Upper flammability limit Lower flammability limit Vapor pressure
Vapor density Relative density Water Solubility Solubility(ies) Partition coefficient: n-octanol/water Autoignition temperature Decomposition temperature Kinematic viscosity Dynamic viscosity
Wear suitable gloves. Impervious gloves.
Wear suitable protective clothing. Long sleeved clothing. Chemical resistant apron. Antistatic boots.
No protective equipment is needed under normal use conditions. If exposure limits are exceeded or irritation is experienced, ventilation and evacuation may be required.
Handle in accordance with good industrial hygiene and safety practice. Do not eat, drink or smoke when using this product. Contaminated work clothing should not be allowed out of the workplace. Regular cleaning of equipment, work area and clothing is recommended. Wash hands before breaks and immediately after handling the product. Avoid contact with skin, eyes or clothing. Wear suitable gloves and eye/face protection.
Liquid Red Vinegar-like No information available No information available
Values Remarks Method
3 No data available None known 223 °C / 434 °F 49 C / 121 F No data available None known
No data available
None known None known
No data available No data available
No data available None known No data available None known 21 Miscible No data available None known unknown No data available None known No data available None known No data available None known No data available
None known
Other Information Explosive properties Oxidizing properties Softening Point Molecular Weight VOC Content (%) Liquid Density Bulk Density Particle Size Particle Size Distribution
No information available No information available No information available No information available No information available No information available No information available No information available No information available
10. STABILITY AND REACTIVITY
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Reactivity
Chemical stability
Possibility of Hazardous Reactions
Hazardous Polymerization
Conditions to avoid
Incompatible materials
Hazardous Decomposition Products
No information available.
Stable under normal conditions.
None under normal processing.
Hazardous polymerization does not occur.
Heat, flames and sparks.
Strong acids. Strong bases. Strong oxidizing agents.
Carbon oxides.
11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Product Information
Inhalation
Eye contact
Specific test data for the substance or mixture is not available. May cause irritation of respiratory tract.
Specific test data for the substance or mixture is not available. Causes serious eye damage. (based on components). Severely irritating to eyes. May cause burns. May cause irreversible damage to eyes.
Skin contact
Ingestion
Information on toxicological effects
Symptoms
Numerical measures of toxicity
Acute Toxicity
The following values are calculated based on chapter 3.1 of the GHS document .
ATEmix (oral) ATEmix (dermal) ATEmix (inhalation-dust/mist)
Unknown acute toxicity
0 % of the mixture consists of ingredient(s) of unknown acute oral toxicity 1 % of the mixture consists of ingredient(s) of unknown acute dermal toxicity
17.2 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (gas)
17.2 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (vapor) 0 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (dust/mist)
Component Information
Chemical name Oral LD50 Dermal LD50 Inhalation LC50
Third Party Formulation (TP # = 29700 mg/kg ( Rat ) - -
Specific test data for the substance or mixture is not available. Causes skin irritation. (based on components).
Specific test data for the substance or mixture is not available. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea.
Redness. Burning. May cause blindness. May cause redness and tearing of the eyes.
19,857.00 mg/kg 6,543.00 mg/kg
70.00 mg/L
17.2 % of the mixture consists of ingredient(s) of unknown toxicity
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1425329)
Third Party Formulation (TP #
1425329)
Third Party Formulation (TP #
1425329)
Delayed and immediate effects as well as chronic effects from short and long-term exposure
= 3310 mg/kg ( Rat ) = 1060 mg/kg ( Rabbit ) = 11.4 mg/L ( Rat ) 4 h
= 7060 mg/kg ( Rat ) - = 124.7 mg/L ( Rat ) 4 h
Skin corrosion/irritation
Serious eye damage/eye irritation
Respiratory or skin sensitization
Germ cell mutagenicity
Carcinogenicity
The table below indicates whether each agency has listed any ingredient as a carcinogen.
Chemical name ACGIH IARC NTP OSHA
Third Party Formulation
(TP # 1425329)
Legend
ACGIH (American Conference of Governmental Industrial Hygienists)
A3 - Animal Carcinogen
IARC (International Agency for Research on Cancer)
Group 1 - Carcinogenic to Humans
NTP (National Toxicology Program)
Known - Known Carcinogen
OSHA (Occupational Safety and Health Administration of the US Department of Labor)
X - Present
Reproductive toxicity
Classification based on data available for ingredients. Irritating to skin.
Classification based on data available for ingredients. Causes burns. Risk of serious damage to eyes.
No information available.
No information available.
No information available.
A3 Group 1 Known X
No information available.
STOT - single exposure
STOT - repeated exposure
Aspiration hazard
No information available.
No information available.
No information available.
12. ECOLOGICAL INFORMATION
Ecotoxicity
Chemical name Toxicity to Algae Toxicity to Fish Toxicity to
Third Party Formulation
(TP # 1425329)
Third Party Formulation
(TP # 1425329)
_____________________________________________________________________________________________
Harmful to aquatic life.
- 96h LC50: = 79 mg/L (Pimephales promelas)
96h LC50: = 75 mg/L
(Lepomis macrochirus)
- 96h LC50: 12.0 - 16.0
mL/L (Oncorhynchus
mykiss) 96h LC50: > 100
Microorganisms EC50 = 8.8 mg/L 15 min EC50 = 8.8 mg/L 25 min
EC50 = 8.8 mg/L 5 min
EC50 = 34634 mg/L 30
min
EC50 = 35470 mg/L 5
Daphnia Magna (Water
Flea)
48h EC50: = 65 mg/L 24h
EC50: = 47 mg/L
24h EC50: = 10800 mg/L
48h EC50: = 2 mg/L 48h
LC50: 9268 - 14221
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Persistence and Degradability
Bioaccumulation
Chemical name Log Pow Third Party Formulation (TP # 1425329) -0.31 Third Party Formulation (TP # 1425329) -0.32
Mobility
Other adverse effects
Waste treatment methods
Waste from residues/unused products
Contaminated packaging
mg/L (Pimephales
promelas) 96h LC50:
13400 - 15100 mg/L
(Pimephales promelas)
No information available.
No information available.
No information available.
min mg/L
13. DISPOSAL CONSIDERATIONS
Should not be released into the environment. Dispose of in accordance with local regulations. Dispose of waste in accordance with environmental legislation.
Empty containers pose a potential fire and explosion hazard. Do not cut, puncture of weld containers.
US EPA Waste Number
California Waste Codes
This product contains one or more substances that are listed with the State of California as a hazardous waste.
Chemical name California Hazardous Waste Third Party Formulation (TP # 1425329) Toxic
Third Party Formulation (TP # 1425329) Toxic
D001
331
Corrosive
Ignitable
Ignitable
14. TRANSPORT INFORMATION
DOT
Proper Shipping Name Hazard Class Description Emergency Response Guide Number
TDG
UN-No. Proper Shipping Name Hazard Class
CONSUMER COMMODITY ORM-D CONSUMER COMMODITY, ORM-D 127
UN1170 ETHANOL SOLUTION 3
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Packing Group Description
MEX
UN-No. Proper Shipping Name Hazard Class Packing Group Description
ICAO
UN-No. Proper Shipping Name Hazard Class Packing Group Description
IATA
UN-No. Proper Shipping Name Hazard Class Packing Group ERG Code Description
IMDG/IMO
UN-No. Proper Shipping Name Hazard Class Packing Group EmS-No. Description
III UN1170, ETHANOL SOLUTION, 3, III
UN1170 ETHANOL SOLUTION 3 III UN1170, ETHANOL SOLUTION, 3, III
UN1170 ETHANOL SOLUTION 3 III UN1170, ETHANOL SOLUTION, 3, III
UN1170 ETHANOL SOLUTION 3 III 3L UN1170, ETHANOL SOLUTION, 3, III
UN1170 ETHANOL SOLUTION 3 III F-E, S-D UN1170, ETHANOL SOLUTION, 3, III, (49°C C.C.)
RID
UN-No. Proper Shipping Name Hazard Class Packing Group Classification code Description ADR/RID-Labels
ADR
UN-No. Proper Shipping Name Hazard Class Packing Group Classification code Tunnel restriction code Description
ADN
UN-No. Proper Shipping Name Hazard Class Packing Group Classification code Special Provisions Description
UN1170 ETHANOL SOLUTION 3 III F1 UN1170, ETHANOL SOLUTION, 3, III 3
UN1170 ETHANOL SOLUTION 3 III F1 (D/E) UN1170, ETHANOL SOLUTION, 3, III, (D/E)
UN1170 ETHANOL SOLUTION 3 III F1 144, 601 UN1170, ETHANOL SOLUTION, 3, III
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Hazard Labels Limited Quantity Ventilation
3 5 L VE01
15. REGULATORY INFORMATION
Safety, health and environmental regulations/legislation specific for the substance or mixture
International Regulations
Ozone-depleting substances (ODS) Not applicable
Persistent Organic Pollutants Not applicable
Export Notification requirements Not applicable
International Inventories TSCA DSL/NDSL EINECS/ELINCS ENCS KECL PICCS AICS
Legend TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances
Contact supplier for inventory compliance status. Contact supplier for inventory compliance status. Contact supplier for inventory compliance status. Contact supplier for inventory compliance status. Contact supplier for inventory compliance status. Contact supplier for inventory compliance status. Contact supplier for inventory compliance status.
US Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372
SARA 311/312 Hazard Categories
Should this product meet EPCRA 311/312 Tier reporting criteria at 40 CFR 370, refer to Section 2 of this SDS for appropriate classifications. Under the amended regulations at 40 CFR 370, EPCRA 311/312 Tier II reporting for the 2017 calendar year will need to be consistent with updated hazard classifications.
CWA (Clean Water Act)
This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42)
Chemical name CWA - Reportable
Quantities
Third Party Formulation
(TP # 1425329)
CERCLA
This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive
5000 lb X
CWA - Toxic Pollutants CWA - Priority
Pollutants
CWA - Hazardous
Substances
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Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302)
Chemical name Hazardous Substances RQs Extremely Hazardous
Substances RQs
Third Party Formulation (TP #
1425329)
5000 lb RQ 5000 lb final RQ
RQ 2270 kg final RQ
RQ
US State Regulations
California Proposition 65
This product contains the following Proposition 65 chemicals. Ethyl alcohol is only a considered a Proposition 65 developmental hazard when it is ingested as an alcoholic beverage.
Chemical name California Proposition 65
Third Party Formulation (TP # 1425329) - Carcinogen
Developmental
U.S. State Right-to-Know Regulations
.
Chemical name New Jersey MassachusettsPennsylvania Rhode Island Illinois
Third Party Formulation (TP # 1425329) X X
Third Party Formulation (TP # 1425329) X X X X
Third Party Formulation (TP # 1425329) X X X X
16. OTHER INFORMATION
NFPA
HMIS
Prepared By
Revision Date
Revision Note
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text
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Health hazards 3 Flammability 2 Instability 0 Physical and Chemical
Properties -
Health hazards 3 Flammability 2 Physical hazards 0 Personal Protection X
Product Stewardship 23 British American Blvd. Latham, NY 12110 1-800-572-6501
28-Dec-2017
No information available
End of Safety Data Sheet
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SAFETY DATA SHEET
T514
Size
1 each
Senoret Chemical Company
Regulatory Licenses
None
Issuing Date
5/01/2015
_____________________________________________________________________________________________
The supplier identified below generated this SDS using the UL SDS template. UL did not test, certify, or approve the substance described in this SDS, and all information in this SDS was provided by the supplier or was reproduced from publically available regulatory data sources. UL makes no representations or warranties regarding the completeness or accuracy of the information in this SDS and disclaims all liability in connection with the use of this information or the substance described in this SDS. The layout, appearance and format of this SDS is © 2014 UL LLC. All rights reserved.
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1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
Product identifier
Product Name Terro Reusable Dual Action Wasp & Fly Trap Plus I-2500
Other means of identification
Synonyms
Recommended use of the chemical and restrictions on use
Recommended Use
Uses advised against
None
Insecticide - Flying Bug Insecticide - Non-aerosol
No information available
Details of the supplier of the safety data sheet
Supplier Name Supplier Address
Supplier Phone Number
Supplier Email Emergency telephone number
Company Emergency Phone Number
Woodstream Corp. 69 North Locust St. Lititz PA 17543 US Phone:(717) 626-2125 Fax:(717) 626-1912 Contact Phone(717) 626-2125 [email protected]
314 308 2565
2. HAZARDS IDENTIFICATION
Classification
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Skin corrosion/irritation Category 1 Sub-category A Serious eye damage/eye irritation Category 1
GHS Label elements, including precautionary statements
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Emergency Overview
Signal word Danger
Hazard Statements
Causes severe skin burns and eye damage
Appearance Red
Precautionary Statements - Prevention
Do not breathe dust/fume/gas/mist/vapors/spray Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection
Precautionary Statements - Response
Immediately call a POISON CENTER or doctor/physician Specific treatment (see supplemental first aid instructions on this label)
Eyes
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Immediately call a POISON CENTER or doctor/physician
Skin
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower Wash contaminated clothing before reuse
Inhalation
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Immediately call a POISON CENTER or doctor/physician
Ingestion
IF SWALLOWED: Rinse mouth. DO NOT induce vomiting
Precautionary Statements - Storage
Store locked up
Physical State Liquid Odor Vinegar-like
Precautionary Statements - Disposal
Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC)
Not applicable
Unknown Toxicity
0% of the mixture consists of ingredient(s) of unknown toxicity
Other information
No information available
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Interactions with Other Chemicals
No information available.
3. COMPOSITION/INFORMATION ON INGREDIENTS
.
Chemical Name CAS No. Weight-% Trade Secret
Acetic acid 64-19-7
*The exact percentage (concentration) of composition has been withheld as a trade secret
3 - 7
*
4. FIRST AID MEASURES
First aid measures
General Advice
Eye Contact
Skin Contact
Inhalation
Ingestion
Self-protection of the first aider
Immediate medical attention is required. Show this safety data sheet to the doctor in attendance.
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Keep eye wide open while rinsing. Do not rub affected area. Remove contact lenses, if present and easy to do. Continue rinsing. Seek immediate medical attention/advice.
Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Seek immediate medical attention/advice.
Remove to fresh air. If breathing has stopped, give artificial respiration. Get medical attention immediately. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. If breathing is difficult, (trained personnel should) give oxygen. Delayed pulmonary edema may occur. Get medical attention immediately if symptoms occur.
Do NOT induce vomiting. Rinse mouth immediately and drink plenty of water. Never give anything by mouth to an unconscious person. Call a physician or poison control center immediately.
Ensure that medical personnel are aware of the material(s) involved, take precautions to protect themselves and prevent spread of contamination. Avoid contact with skin, eyes or clothing. Avoid direct contact with skin. Use barrier to give mouth-to-mouth resuscitation. Use personal protective equipment as required. Wear personal protective clothing (see section 8).
Most important symptoms and effects, both acute and delayed
Most Important Symptoms and
Burning sensation.
Effects
Indication of any immediate medical attention and special treatment needed
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Notes to Physician
Product is a corrosive material. Use of gastric lavage or emesis is contraindicated. Possible perforation of stomach or esophagus should be investigated. Do not give chemical antidotes. Asphyxia from glottal edema may occur. Marked decrease in blood pressure may occur with moist rales, frothy sputum, and high pulse pressure.
5. FIRE-FIGHTING MEASURES
Suitable Extinguishing Media
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Unsuitable extinguishing media
CAUTION: Use of water spray when fighting fire may be inefficient.
Specific Hazards Arising from the Chemical
The product causes burns of eyes, skin and mucous membranes. Thermal decomposition can lead to release of irritating gases and vapors.
Uniform Fire Code
Hazardous Combustion Products
Carbon oxides.
Explosion Data Sensitivity to Mechanical Impact
Sensitivity to Static Discharge
Corrosive: Acid-Liquid
No.
No.
Protective equipment and precautions for firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal Precautions
Other Information
Environmental Precautions
Environmental Precautions
Methods and material for containment and cleaning up
Methods for Containment
Attention! Corrosive material. Avoid contact with skin, eyes or clothing. Ensure adequate ventilation. Use personal protective equipment as required. Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak.
Refer to protective measures listed in Sections 7 and 8.
Refer to protective measures listed in Sections 7 and 8. Prevent further leakage or spillage if safe to do so. Should not be released into the environment. Do not allow to enter into soil/subsoil. Prevent product from entering drains.
Prevent further leakage or spillage if safe to do so.
Methods for cleaning up
Soak up with inert absorbent material. Pick up and transfer to properly labeled containers.
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STORAGE AND DISPOSAL STORAGE: Store product in original container, in a cool, dry place. DISPOSAL: Place container in trash receptacle or dispose of in a sanitary landfill. Burning is not a legal form of disposal.
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7. HANDLING AND STORAGE
Precautions for safe handling
Handling
Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes or clothing. In case of insufficient ventilation, wear suitable respiratory equipment. Use only with adequate ventilation and in closed systems. Do not eat, drink or smoke when using this product. Take off contaminated clothing and wash before reuse.
Conditions for safe storage, including any incompatibilities
Storage
Keep containers tightly closed in a dry, cool and well-ventilated place. Protect from moisture. Store locked up. Keep out of the reach of children. Store away from other materials.
Incompatible Products
Acids. Bases. Oxidizing agent.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Exposure Guidelines
Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH
Acetic acid
64-19-7
ACGIH TLV: American Conference of Governmental Industrial Hygienists - Threshold Limit Value OSHA PEL: Occupational Safety and Health Administration - Permissible Exposure Limits NIOSH IDLH Immediately Dangerous to Life or Health
STEL = 15 ppm
TWA: 10 ppm
TWA: 10 ppm
TWA: 25 mg/m
(vacated) TWA: 10 ppm
(vacated) TWA: 25 mg/m
3
IDLH: 50 ppm TWA: 10 ppm
3
TWA: 25 mg/m
STEL: 15 ppm
STEL: 37 mg/m
3
3
Other Exposure Guidelines
Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992) See section 15 for national exposure control parameters
Appropriate engineering controls
Engineering Measures
Showers Eyewash stations Ventilation systems
Individual protection measures, such as personal protective equipment
Eye/Face Protection
Skin and Body Protection
Face protection shield.
Wear protective gloves and protective clothing. Long sleeved clothing. Chemical resistant apron. Impervious gloves.
Respiratory Protection
No protective equipment is needed under normal use conditions. If exposure limits are exceeded or irritation is experienced, ventilation and evacuation may be required.
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Hygiene Measures
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical and Chemical Properties
Physical State Appearance Color
Property pH Melting / freezing point Boiling point / boiling range Flash Point Evaporation Rate Flammability (solid, gas) Flammability Limit in Air
Upper flammability limit
Lower flammability limit Vapor pressure Vapor density Specific Gravity Water Solubility Solubility in other solvents Partition coefficient: n-octanol/water Autoignition temperature Decomposition temperature Kinematic viscosity Dynamic viscosity Explosive properties Oxidizing Properties
Handle in accordance with good industrial hygiene and safety practice. Take off contaminated clothing and wash before reuse. Avoid contact with skin, eyes or clothing. Wear suitable gloves and eye/face protection. Do not eat, drink or smoke when using this product. Contaminated work clothing should not be allowed out of the workplace. Regular cleaning of equipment, work area and clothing is recommended. Wash hands before breaks and immediately after handling the product. For environmental protection, remove and wash all contaminated protective equipment before re-use.
Liquid Red No information available
Values Remarks/ Method
3.5 None known No data available None known 100 °C / 212 °F None known No data available None known No data available None known No data available None known
No data available No data available No data available None known No data available None known No data available None known Soluble in water None known No data available None known No data available None known No data available None known No data available None known No data available None known No data available None known No data available No data available
Odor Odor Threshold
Vinegar-like No information available
Other Information
Softening Point VOC Content (%) Particle Size Particle Size Distribution
No data available No data available No data available
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10. STABILITY AND REACTIVITY
Reactivity
No data available.
Chemical stability
Stable under recommended storage conditions.
Possibility of Hazardous Reactions
None under normal processing.
Hazardous Polymerization
Hazardous polymerization does not occur.
Conditions to avoid
Exposure to air or moisture over prolonged periods.
Incompatible materials
Acids. Bases. Oxidizing agent.
Hazardous Decomposition Products
Carbon oxides.
11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Product Information
Inhalation
Eye Contact
Skin Contact
Ingestion
.
Specific test data for the substance or mixture is not available. Corrosive by inhalation. (based on components). Inhalation of corrosive fumes/gases may cause coughing, choking, headache, dizziness, and weakness for several hours. Pulmonary edema may occur with tightness in the chest, shortness of breath, bluish skin, decreased blood pressure, and increased heart rate. Inhaled corrosive substances can lead to a toxic edema of the lungs. Pulmonary edema can be fatal. May cause irritation of respiratory tract.
Specific test data for the substance or mixture is not available. Causes burns. (based on components). Corrosive to the eyes and may cause severe damage including blindness. Causes serious eye damage. May cause irreversible damage to eyes.
Specific test data for the substance or mixture is not available. Corrosive. (based on components). Causes burns.
Specific test data for the substance or mixture is not available. Causes burns. (based on components). Ingestion causes burns of the upper digestive and respiratory tracts. May cause severe burning pain in the mouth and stomach with vomiting and diarrhea of dark blood. Blood pressure may decrease. Brownish or yellowish stains may be seen around the mouth. Swelling of the throat may cause shortness of breath and choking. May cause lung damage if swallowed. May be fatal if swallowed and enters airways. Ingestion may cause irritation to mucous membranes. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea.
Component Information
Chemical Name Oral LD50 Dermal LD50 Inhalation LC50
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Acetic acid 64-19-7
= 3310 mg/kg ( Rat ) = 1060 µL/kg ( Rabbit ) = 11.4 mg/L ( Rat ) 4 h
Information on toxicological effects
Symptoms
Erythema (skin redness). Burning. May cause blindness. Coughing and/ or wheezing.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Sensitization
Mutagenic Effects
Carcinogenicity
Reproductive Toxicity
STOT - single exposure
STOT - repeated exposure
Chronic Toxicity
No information available.
No information available.
Contains no ingredient listed as a carcinogen.
No information available.
No information available.
No information available.
Chronic exposure to corrosive fumes/gases may cause erosion of the teeth followed by jaw necrosis. Bronchial irritation with chronic cough and frequent attacks of pneumonia are common. Gastrointestinal disturbances may also be seen.
Target Organ Effects
Respiratory system. Eyes. Skin. Gastrointestinal tract (GI). Teeth. Blood.
Aspiration Hazard
No information available.
Numerical measures of toxicity Product Information
The following values are calculated based on chapter 3.1 of the GHS document
ATEmix (oral)
66,200.00 mg/kg
ATEmix (dermal)
22,145.52 mg/kg (ATE)
ATEmix (inhalation-dust/mist)
228.00 mg/l
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12. ECOLOGICAL INFORMATION
Ecotoxicity
Harmful to aquatic life.
Chemical Name Toxicity to Algae Toxicity to Fish Toxicity to
Acetic acid
64-19-7
96h LC50: = 79 mg/L
(Pimephales promelas) 96h
LC50: = 75 mg/L (Lepomis
macrochirus)
EC50 = 8.8 mg/L 15 min EC50 = 8.8 mg/L 25 min
EC50 = 8.8 mg/L 5 min
Persistence and Degradability
No information available.
Bioaccumulation
Chemical Name Log Pow
Acetic acid
64-19-7
Other adverse effects
No information available.
13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Disposal methods
This material, as supplied, is not a hazardous waste according to Federal regulations (40 CFR 261). This material could become a hazardous waste if it is mixed with or otherwise comes in contact with a hazardous waste, if chemical additions are made to this material, or if the material is processed or otherwise altered. Consult 40 CFR 261 to determine whether the altered material is a hazardous waste. Consult the appropriate state, regional, or local regulations for additional requirements.
Microorganisms
-0.31
Daphnia Magna (Water
Flea)
48h EC50: = 65 mg/L 24h
EC50: = 47 mg/L
Contaminated Packaging
California Hazardous Waste Codes
Dispose of contents/containers in accordance with local regulations.
232
This product contains one or more substances that are listed with the State of California as a hazardous waste.
Chemical Name
Acetic acid
64-19-7
California Hazardous Waste
Toxic
Corrosive
Ignitable
14. TRANSPORT INFORMATION
DOT
TDG
MEX
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NOT REGULATED
Not regulated
Not regulated
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ICAO
IATA
IMDG/IMO
RID
ADR
ADN
Not regulated
Not regulated
Not regulated
Not regulated
Not regulated
Not regulated
15. REGULATORY INFORMATION
International Inventories
TSCA Complies DSL All components are listed either on the DSL or NDSL.
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
US Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372
SARA 311/312 Hazard Categories
Acute Health Hazard Chronic Health Hazard Fire Hazard Sudden release of pressure hazard Reactive Hazard
Yes No No No No
CWA (Clean Water Act)
This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42)
Chemical Name CWA - Reportable
Acetic acid
64-19-7
Quantities
5000 lb X
CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous
Substances
CERCLA
This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302)
Chemical Name Hazardous Substances RQs Extremely Hazardous Substances
Acetic acid
64-19-7
5000 lb RQ 5000 lb final RQ
RQs
RQ 2270 kg final RQ
RQ
US State Regulations
California Proposition 65
This product does not contain any Proposition 65 chemicals.
U.S. State Right-to-Know Regulations
This product does not contain any substances regulated by state right-to-know regulations.
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This chemical is a pesticide product that is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets and for workplace labels of non-pesticide chemicals. The hazard information required on the pesticide label is reproduced below. The pesticide label also includes other important information, including directions for use.
Product Label Signal Word: Caution Avoid eye contact. Wash from skin with soap and water to avoid irritation.
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International Regulations
Mexico National occupational exposure limits
Component Carcinogen Status Exposure Limits
Acetic acid
64-19-7 ( 3 - 7 )
Mexico - Occupational Exposure Limits - Carcinogens
Canada WHMIS Hazard Class
E - Corrosive material
Mexico: TWA 10 ppm
Mexico: TWA 25 mg/m
Mexico: STEL 15 ppm
Mexico: STEL 37 mg/m
3
3
16. OTHER INFORMATION
NFPA Health Hazards 3 Flammability 0 Instability 0 Physical and
Chemical Hazards -
HMIS Health Hazards 3
Flammability 0
Physical Hazard 0 Personal Protection
X
Prepared By
Product Stewardship 23 British American Blvd. Latham, NY 12110 1-800-572-6501
Issuing Date Revision Date Revision Note
22-Feb-2012 13-Nov-2014 No information available
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text
End of Safety Data Sheet
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