Wash face, hands and any exposed skin thoroughly after handling
Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking
Keep container tightly closed
Ground/bond container and receiving equipment
Use explosion-proof electrical/ ventilating/ lighting/ equipment
Use only non-sparking tools
Take precautionary measures against static discharge
Wear protective gloves/eye protection/face protection
Precautionary Statements - Response
Specific treatment (see supplemental first aid instructions on this label)
Eyes
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
Immediately call a POISON CENTER or doctor
Skin
If skin irritation occurs: Get medical advice/attention
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower
Wash contaminated clothing before reuse
Fire
In case of fire: Use CO2, dry chemical, or foam to extinguish
Precautionary Statements - Storage
Store in a well-ventilated place. Keep cool
Precautionary Statements - Disposal
Dispose of contents/container to an approved waste disposal plant
Other information
Harmful to aquatic life.
Unknown acute toxicity
0 % of the mixture consists of ingredient(s) of unknown acute oral toxicity
1 % of the mixture consists of ingredient(s) of unknown acute dermal toxicity
17.2 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (gas)
17.2 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (vapor)
17.2 % of the mixture consists of ingredient(s) of unknown toxicity
0 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (dust/mist)
3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance
Not applicable.
Mixture
Chemical nameCAS No.Weight-%Hazardous Material
Information Review Act
registry number (HMIRA
registry #)
Third Party Formulation
(TP # 1425329)
Third Party Formulation
(TP # 1425329)
Third Party Formulation
(TP # 1425329)
-50 - 60%--
-10 - 20%--
-0 - 10%--
4. FIRST AID MEASURES
First aid measures
General advice
Inhalation
Eye contact
Skin contact
Ingestion
Immediate medical attention is required. Show this safety data sheet to the doctor in
attendance.
Remove to fresh air. Get medical attention immediately if symptoms occur.
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Keep
eye wide open while rinsing. Do not rub affected area. Get immediate medical
advice/attention. Remove contact lenses, if present and easy to do. Continue rinsing.
Wash off immediately with soap and plenty of water while removing all contaminated
clothes and shoes. Get medical attention if irritation develops and persists.
Clean mouth with water and drink afterwards plenty of water. Never give anything by mouth
to an unconscious person. Do NOT induce vomiting. Call a physician.
Date HMIRA filed and
date exemption granted
(if applicable)
Self-protection of the first aider
Most important symptoms and effects, both acute and delayed
Symptoms
Indication of any immediate medical attention and special treatment needed
Note to physicians
Remove all sources of ignition. Ensure that medical personnel are aware of the material(s)
involved, take precautions to protect themselves and prevent spread of contamination. Use
personal protective equipment as required. See section 8 for more information. Avoid
contact with skin, eyes or clothing.
Sensitivity to Mechanical Impact
Sensitivity to Static Discharge
Special protective equipment for
fire-fighters
Dry chemical. Carbon dioxide (CO2). Water spray. Alcohol resistant foam.
CAUTION: Use of water spray when fighting fire may be inefficient.
Risk of ignition. Keep product and empty container away from heat and sources of ignition.
In the event of fire, cool tanks with water spray. Fire residues and contaminated fire
extinguishing water must be disposed of in accordance with local regulations.
Carbon oxides.
None.
Yes.
Firefighters should wear self-contained breathing apparatus and full firefighting turnout
gear. Use personal protection equipment.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal precautions
Evacuate personnel to safe areas. Use personal protective equipment as required. See
section 8 for more information. Avoid contact with skin, eyes or clothing. Ensure adequate
ventilation. Keep people away from and upwind of spill/leak. ELIMINATE all ignition sources
(no smoking, flares, sparks or flames in immediate area). Pay attention to flashback. Take
precautionary measures against static discharges. All equipment used when handling the
product must be grounded. Do not touch or walk through spilled material.
Other Information
Methods and material for containment and cleaning up
Methods for containment
Methods for cleaning up
Ventilate the area. Refer to protective measures listed in Sections 7 and 8.
Stop leak if you can do it without risk. Do not touch or walk through spilled material. A vapor
suppressing foam may be used to reduce vapors. Dike far ahead of spill to collect runoff
water. Keep out of drains, sewers, ditches and waterways. Absorb with earth, sand or other
non-combustible material and transfer to containers for later disposal.
Take precautionary measures against static discharges. Dam up. Soak up with inert
absorbent material. Pick up and transfer to properly labeled containers.
7. HANDLING AND STORAGE
Precautions for safe handling
Advice on safe handling
Use personal protection equipment. Avoid breathing vapors or mists. Keep away from heat,
hot surfaces, sparks, open flames and other ignition sources. No smoking. Use grounding
and bonding connection when transferring this material to prevent static discharge, fire or
explosion. Use with local exhaust ventilation. Use spark-proof tools and explosion-proof
equipment. Keep in an area equipped with sprinklers. Use according to package label
instructions. Handle in accordance with good industrial hygiene and safety practice. Avoid
contact with skin, eyes or clothing. Do not eat, drink or smoke when using this product.
Take off contaminated clothing and wash before reuse.
Conditions for safe storage, including any incompatibilities
Storage Conditions
Keep containers tightly closed in a dry, cool and well-ventilated place. Keep away from
heat, sparks, flame and other sources of ignition (i.e., pilot lights, electric motors and static
electricity). Keep in properly labeled containers. Do not store near combustible materials.
Keep in an area equipped with sprinklers. Store in accordance with the particular national
regulations. Store in accordance with local regulations. Store locked up. Keep out of the
reach of children.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Exposure Limits
Chemical nameACGIH TLVOSHA PELNIOSH IDLH
Third Party Formulation (TP #
1425329)
Third Party Formulation (TP #
1425329)
Third Party Formulation (TP #
1425329)
Chemical nameAlbertaBritish ColumbiaOntario TWAEVQuebec
Third Party Formulation
TWA: 10 mg/m
(TP # 1425329)
.
TWA: 10 mg/m
3
TWA: 15 mg/m3 total dust
TWA: 5 mg/m3 respirable
fraction
(vacated) TWA: 15 mg/m3 total
dust
(vacated) TWA: 5 mg/m
respirable fraction
STEL = 15 ppm
TWA: 10 ppm
TWA: 10 ppm
TWA: 25 mg/m
(vacated) TWA: 10 ppm
(vacated) TWA: 25 mg/m
STEL: 1000 ppmTWA: 1000 ppm
TWA: 1900 mg/m
(vacated) TWA: 1000 ppm
(vacated) TWA: 1900 mg/m
3
TWA: 10 mg/m
TWA: 3 mg/m
3
3
TWA: 10 mg/m
TWA: 10 mg/m3 total dust
TWA: 5 mg/m3 respirable dust
3
3
3
IDLH: 50 ppm
TWA: 10 ppm
TWA: 25 mg/m
STEL: 15 ppm
STEL: 37 mg/m
3
IDLH: 3300 ppm 10% LEL
TWA: 1000 ppm
3
TWA: 1900 mg/m
3
3
3
3
TWA: 10 mg/m
3
Third Party Formulation
(TP # 1425329)
Third Party Formulation
(TP # 1425329)
Other Exposure Guidelines
TWA: 10 ppm
TWA: 25 mg/m
STEL: 15 ppm
STEL: 37 mg/m
TWA: 1000 ppm
TWA: 1880 mg/m
Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962
3
3
3
TWA: 10 ppm
STEL: 15 ppm
STEL: 1000 ppmSTEL: 1000 ppmTWA: 1000 ppm
TWA: 10 ppm
STEL: 15 ppm
TWA: 10 ppm
TWA: 25 mg/m
STEL: 15 ppm
STEL: 37 mg/m
TWA: 1880 mg/m
3
3
3
(11th Cir., 1992). See section 15 for national exposure control parameters.
Appropriate engineering controls
Engineering controls
Showers
Eyewash stations
Ventilation systems.
Individual protection measures, such as personal protective equipment
Physical and Chemical Properties
Physical state
Appearance
Odor
Color
Odor Threshold
Property
pH
Melting / freezing point
Boiling point / boiling range
Flash Point
Evaporation Rate
Flammability (solid, gas)
Flammability Limit in Air
Upper flammability limit
Lower flammability limit
Vapor pressure
Vapor density
Relative density
Water Solubility
Solubility(ies)
Partition coefficient: n-octanol/water
Autoignition temperature
Decomposition temperature
Kinematic viscosity
Dynamic viscosity
Wear suitable gloves. Impervious gloves.
Wear suitable protective clothing. Long sleeved clothing. Chemical resistant apron.
Antistatic boots.
No protective equipment is needed under normal use conditions. If exposure limits are
exceeded or irritation is experienced, ventilation and evacuation may be required.
Handle in accordance with good industrial hygiene and safety practice. Do not eat, drink or
smoke when using this product. Contaminated work clothing should not be allowed out of
the workplace. Regular cleaning of equipment, work area and clothing is recommended.
Wash hands before breaks and immediately after handling the product. Avoid contact with
skin, eyes or clothing. Wear suitable gloves and eye/face protection.
Liquid
Red
Vinegar-like
No information available
No information available
Values Remarks Method
3
No data availableNone known
223 °C / 434 °F
49 C / 121 F
No data availableNone known
No data available
None known
None known
No data available
No data available
No data availableNone known
No data availableNone known
21
Miscible
No data availableNone known
unknown
No data availableNone known
No data availableNone known
No data availableNone known
No data available
None known
Other Information
Explosive properties
Oxidizing properties
Softening Point
Molecular Weight
VOC Content (%)
Liquid Density
Bulk Density
Particle Size
Particle Size Distribution
No information available
No information available
No information available
No information available
No information available
No information available
No information available
No information available
No information available
Specific test data for the substance or mixture is not available. May cause irritation of
respiratory tract.
Specific test data for the substance or mixture is not available. Causes serious eye
damage. (based on components). Severely irritating to eyes. May cause burns. May cause
irreversible damage to eyes.
Skin contact
Ingestion
Information on toxicological effects
Symptoms
Numerical measures of toxicity
Acute Toxicity
The following values are calculated based on chapter 3.1 of the GHS document .
0 % of the mixture consists of ingredient(s) of unknown acute oral toxicity
1 % of the mixture consists of ingredient(s) of unknown acute dermal toxicity
17.2 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (gas)
17.2 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (vapor)
0 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (dust/mist)
Component Information
Chemical nameOral LD50Dermal LD50Inhalation LC50
Third Party Formulation (TP #= 29700 mg/kg ( Rat )--
Specific test data for the substance or mixture is not available. Causes skin irritation. (based
on components).
Specific test data for the substance or mixture is not available. Ingestion may cause
gastrointestinal irritation, nausea, vomiting and diarrhea.
Redness. Burning. May cause blindness. May cause redness and tearing of the eyes.
19,857.00 mg/kg
6,543.00 mg/kg
70.00 mg/L
17.2 % of the mixture consists of ingredient(s) of unknown toxicity