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SAFETY DATA SHEET
g
BOARDWALK VANDALISM MARK REMOVER 20N16 BWK351A
ersion 1.1 Revision Date 07/14/2016 Print Date 03/21/2017
SECTION 1. PRODUCT AND COMPANY IDENTIFICATION
Material name : Boardwalk Vandalism Mark Remover BWK351A
Material number : 1041285 / A00178
Manufacturer or supplier's details
Company : Boardwalk / Essendant Co.
Address : One Parkway North
Deerfield, IL 60015
Telephone : 844-828-5617
Emergency telephone numbers
For SDS Information : 844-828-5617
For a Medical Emergency :
For a Transportation
Emer
Recommended use of the chemical and restrictions on use
Recommended use : Specialty Cleaner and Remover
ency
: Chemtel: 1(800)255-3924
SECTION 2. HAZARDS IDENTIFICATION
Emergency Overview
Appearance Aerosol containing a liquefied gas
Colour colourless
Odour aromatic
GHS Classification
Flammable aerosols : Category 1
Gases under pressure : Liquefied gas
Skin irritation : Category 2
Eye irritati on : Category 2A
Reproductive toxicity : Category 2
Specific target organ toxicity single exposure
Specific target organ toxicity repeated exposure
(Inhalation)
GHS label elements
Hazard pictograms :
Signal word : Danger
Hazard statements : H222 E xtremely flammable aerosol.
: Category 3 (Central nervous system)
: Category 2
H280 Contains gas under pressure; may explode if heated.
H315 Causes skin irritation.
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H319 Causes serious eye irritation.
H336 May cause drowsiness or d izziness.
H361 Suspected of damaging fertility or the unborn child.
H373 May cause damage to organs t hr o ugh prolonged or
repeated exposure if inhaled.
Precautionary statements :
Prevention:
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read
and understood.
P210 Keep away from heat/sparks/open flames/hot surfaces.
No smoking.
P211 Do not spray on an open flame or other ignition source.
P251 Pressurized contai ner: Do not pierce or burn, even after
use.
P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.
P264 Wash skin thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear eye protection/ face protection.
P280 Wear protective gloves.
P281 Use personal protective equipment as required.
Response:
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P304 + P340 + P312 IF INHALED: Remove victim to fresh air
and keep at rest in a position comfortable for breathing. Call a
POISON CENTER or doctor/ physician if you feel unwell.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water
for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing.
P308 + P313 IF exposed or concerned: Get medical advice/
attention.
P332 + P313 If skin irritation occurs: Get medical advice/
attention.
P337 + P313 If eye irritation persists: Get medical advice/
attention.
P362 Take off contaminated clothing and wash before reuse.
Storage:
P403 + P233 Store in a well-ventilated place. Keep container
tightly closed.
P405 Store locked up.
P410 + P412 Protect from sunlight. Do not expose to
temperatures exceeding 50 °C/ 122 °F.
Disposal:
Dispose of contents/container in accordance with local
regulation.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance / Mixture : Mixture
Hazardous components
Chemical name CAS-No. Concentration [%]
acetone 67-64-1 >= 50 - < 70
toluene 108-88-3 >= 10 - < 20
propane 74-98-6 >= 5 - < 10
2-butoxyethanol 111-76-2 >= 5 - < 10
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SAFETY DATA SHEET
BOARDWALK VANDALISM MARK REMOVER 20N16 BWK351A
ersion 1.1 Revision Date 07/14/2016 Print Date 03/21/2017
butanone 78-93-3 >= 5 - < 10
butane 106-97-8 >= 5 - < 10
The exact percentages of disclosed substances are withheld as trade secrets.
SECTION 4. FIRST AID MEASURES
General advice : Move out of dangerous area.
Show this safety data sheet to the doctor in attendance.
Do not leave the victim unattended.
If inhaled : Remove person to fresh air. If signs/symptoms continue, get
medical attention.
In case of skin contact : In case of contact, immediately flush eyes or skin with plenty
of water for at least 15 minutes while removing contaminated
clothing and shoes.
Wash clothing before reuse.
Call a physician if irritation develops or persists.
In case of eye contact : In case of contact, immediately flush eyes with plenty of water
for at least 15 minutes.
Remove contact lenses.
Keep eye wide open while rinsing.
If eye irritation persists, consult a specialist.
If swallowed : DO NOT induce vomiting unless directed to do so by a
physician or poison control center.
Never give anything by mouth to an unconscious person.
If symptoms persist, call a physician.
SECTION 5. FIREFIGHTING MEASURES
Suitable extinguishing media : Carbon dioxide (CO2)
Foam
Dry chemical
Water
Unsuitable extinguishing
media
Hazardous co mbustion
products
Specific extinguishing
methods
Further information : Use a water spray to cool fully closed containers.
Special pr otective equipment
for firefighters
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions,
protective equipment and
: High volume water jet
: Carbon dioxide (CO2)
Carbon monoxide
Smoke
: Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.
Standard procedure for chemical fires.
: Wear self-contained breathing apparatus for firefighting if
necessary.
: Use personal protective equipment.
Ensure adequate ventilation.
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BOARDWALK VANDALISM MARK REMOVER 20N16 BWK351A
ersion 1.1 Revision Date 07/14/2016 Print Date 03/21/2017
emergency procedures Remove all sources of ignition.
Evacuate personnel to safe areas.
Beware of v apours accumu lating to for m explosive
concentrations. Vapours can accumulate in low areas.
Environmental precautions : Prevent product from entering drains.
Prevent further leakage or spillage if safe to do so.
If the produc t contaminates rivers and lakes or drains inform
respective authorities.
Methods and materials for
containment and cleaning up
SECTION 7. HANDLING AND STORAGE
Advice on safe handling : Avoid exposure - obtain special instructions before use.
Conditions for safe storage : BEWARE: Aerosol is pressurized. Keep away from direct sun
Materials to avoid : Strong oxidizing agents
: Soak up with inert absorbent material (e.g. sand, silica gel,
acid binder, universal binder, sawdust).
Sweep up or vacuum up spillage and collect in suitable
container for disposal.
Avoid contact with skin and eyes.
For personal protection see section 8.
Smoking, eating and drinking should be prohibited in the
application area.
Take precautionary measures against static discharges.
Provide sufficient air exchange and/or exhaust in work rooms.
Dispose of rinse water in accordance with local and national
regulations.
Do not breathe vapours or spray mist.
Always replace cap after use.
exposure and temperatures over 50 °C. Do not open by force
or throw into fire even after use. Do not spray on flames or
red-hot objects.
No smoking.
Observe label precautions .
Keep in a cool, well-ventilated place.
Electrical installations / working materials must comply with
the technological safety standards.
Do not store near acids.
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters
Components CAS-No. Value type
(Form of
exposure)
acetone 67-64-1 TWA 500 ppm ACGIH
STEL 750 ppm ACGIH
TWA 250 ppm
TWA 1,000 ppm OSHA Z-1
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Control
parameters /
Permissible
concentration
590 mg/m3
Basis
NIOSH REL
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2,400 mg/m3
TWA 750 ppm
1,800 mg/m3
STEL 1,000 ppm
2,400 mg/m3
toluene 108-88-3 TWA 20 ppm ACGIH
TWA 100 ppm
375 mg/m3
ST 150 ppm
560 mg/m3
TWA 200 ppm OSHA Z-2
CEIL 300 ppm OSHA Z-2
Peak 500 ppm OSHA Z-2
TWA 100 ppm
375 mg/m3
STEL 150 ppm
560 mg/m3
propane 74-98-6 TWA 1,000 ppm ACGIH
TWA 1,000 ppm
1,800 mg/m3
TWA 1,000 ppm
1,800 mg/m3
TWA 1,000 ppm
1,800 mg/m3
2-butoxyethanol 111-76-2 TWA 20 ppm ACGIH
TWA 5 ppm
24 mg/m3
TWA 50 ppm
240 mg/m3
TWA 25 ppm
120 mg/m3
butanone 78-93-3 TWA 200 ppm ACGIH
STEL 300 ppm ACGIH
TWA 200 ppm
590 mg/m3
ST 300 ppm
885 mg/m3
TWA 200 ppm
590 mg/m3
TWA 200 ppm
590 mg/m3
STEL 300 ppm
885 mg/m3
butane 106-97-8 TWA 800 ppm
1,900 mg/m3
TWA 800 ppm
1,900 mg/m3
OSHA P0
OSHA P0
NIOSH REL
NIOSH REL
OSHA P0
OSHA P0
NIOSH REL
OSHA Z-1
OSHA P0
NIOSH REL
OSHA Z-1
OSHA P0
NIOSH REL
NIOSH REL
OSHA Z-1
OSHA P0
OSHA P0
NIOSH REL
OSHA P0
Biological occupational exposure limits
Component CAS-No. Control
parameters
2-PROPANONE 67-64-1 Acetone Urine End of
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Biological
specimen
Sampling
time
shift (As
soon as
possible
after
exposure
ceases)
Permissible
concentration
50 mg/l ACGIH BEI
Basis
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METHYLBENZENE 108-88-3 Toluene In blood Prior to
last shift
of
workwee
METHYLBENZENE Toluene Urine End of
shift (As
soon as
possible
after
exposure
ceases)
METHYLBENZENE o-Cresol Urine End of
shift (As
soon as
possible
after
exposure
ceases)
Remarks: Creatinine
2-BUTOXYETHANOL 111-76-2 Butoxyacetic
acid (BAA)
Remarks: Creatinine
2-BUTANONE 78-93-3 methyl ethyl
ketone
Engineering measure s
Personal protective equipment
Respiratory p rot e c tion : In case of insuffici ent ventilation, we ar s ui table respirat or y
Hand protection
Remarks : The suitability for a specific workplace should be discussed
Eye protection : Safety glasses
Skin and body protection : Impervious clothing
: effective ventilation in all processing areas
equipment.
Use respiratory protection unless adequate local exhaust
ventilation is provided or exposure assessment demonstrates
that exposures are within recommended exposure guidelines.
with the producers of the protective gloves.
Ensure that eyewash stations and safety showers are close to
the workstation location.
Choose body protection according to the amount and
concentration of the dangerous substance at the work place.
Urine End of
shift (As
soon as
possible
after
exposure
ceases)
Urine End of
shift (As
soon as
possible
after
exposure
ceases)
0.02 mg/l ACGIH BEI
k
0.03 mg/l ACGIH BEI
0.3 mg/g ACGIH BEI
200 mg/g ACGIH BEI
2 mg/l ACGIH BEI
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SAFETY DATA SHEET
BOARDWALK VANDALISM MARK REMOVER 20N16 BWK351A
ersion 1.1 Revision Date 07/14/2016 Print Date 03/21/2017
Hygiene measures : When using do not eat or drink.
When using do not s m o k e.
Wash hands before breaks and at the end of workday.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance : Aerosol containing a liquefied gas
Colour : colourless
Odour : aromatic
Odour Threshold : No data available
pH : No data available
Melting point/freezing point : No data available
Boiling point : No data available
Flash point :
Not applicable
Evaporation rate : No data available
Flammability (solid, gas) : Extremely flammable aerosol.
Upper explosion limit : No data available
Lower explosion limit : No data available
Vapour pressure : No data available
Relative vapour density : No data available
Density : 0.810 g/cm3
Solubility(ies)
Water solubility : partly soluble
Partition coefficient: n-
octanol/water
Auto-ignit i on te mperature : not determined
Thermal decomposition : No data available
Heat of combustion : 35.04 kJ/g
: No data available
SECTION 10. STABILITY AND REACTIVITY
Reactivity : Stable
Chemical st ab i l ity : Stable unde r no rm a l conditions.
Possibility of hazardous
reactions
Conditions to avoid : Heat, flames and sparks.
: Vapours may form explosive mixture with air.
No decomposition if stored and applied as directed.
Extremes of temperature and direct sunlight.
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SAFETY DATA SHEET
A
BOARDWALK VANDALISM MARK REMOVER 20N16 BWK351A
ersion 1.1 Revision Date 07/14/2016 Print Date 03/21/2017
Incompatible materials : Acids
Oxidizing agents
Hazardous decomposition
products
SECTION 11. TOXICOLOGICAL INFORMATION
Potential Health Effects
Carcinogenicity:
IARC
ACGIH
2-butoxyethanol 111-76-2
OSH
NTP
Acute toxicity
Product:
Acute oral toxicity :
Acute inhalation toxicity :
Acute dermal toxicity :
Components:
acetone:
Acute oral toxicity :
Acute inhalation toxicity :
Acute dermal toxicity :
: Carbon monoxide
Carbon dioxide (CO2)
No component of this product present at levels greater than or
equal to 0.1% is identified as probable, possible or confirmed
human carcinogen by IARC.
Confirmed animal carcinogen with unknown relevance to
humans
No component of this product present at levels greater than or
equal to 0.1% is identified as a carcinogen or potential
carcinogen by OSHA.
No component of this product present at levels greater than or
equal to 0.1% is identified as a known or anticipated carcinogen
by NTP.
Acute toxicity estimate : 4,978 mg/kg
Method: Calculation method
Acute toxicity estimate : > 10 mg/l
Exposure time: 4 h
Test atmosphere: dust/mist
Method: Calculation method
Acute toxicity estimate : > 5,000 mg/kg
Method: Calculation method
LD50 Rat: 5,800 mg/kg
LC50 Rat: 132 mg/l
Exposure time: 3 h
LC50 Rat: 50.1 mg/l
LD50 Guinea pig: > 7,426 mg/kg
LD50 Rabbit: > 7,426 mg/kg
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propane:
Acute inhalation toxicity :
butanone:
Acute oral toxicity :
Acute inhalation toxicity :
Acute dermal toxicity :
butane:
Acute inhalation toxicity :
Skin corrosion/irritation
Product:
Remarks: May cause skin irritation in susceptible persons.
Serious eye damage/eye irritation
Product:
Remarks: Eye irritation
Respiratory or skin sensitisation
No data available
Germ cell mutagenicity
No data available
Carcinogenicity
No data available
LC50 Mouse: 1,237 mg/l
Exposure time: 2 h
LC50 Rat: 658 mg/l
Exposure time: 4 h
LC50 Rat: 1,355 mg/l
LD50 Oral Rat: 2, 737 mg / k g
LC50 Mouse: 32,000 mg/l
Exposure time: 4 h
LC50 : 38,000 mg/l
LD50 Dermal Rabbit: 6,480 mg/kg
LC50 Mouse: 1,237 mg/l
Exposure time: 2 h
LC50 Rat: 1,355 mg/l
Reproductive toxicity
No data available
acetone:
toluene:
propane:
2-butoxyethanol:
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ersion 1.1 Revision Date 07/14/2016 Print Date 03/21/2017
butanone:
butane:
STOT - single exposure
No data available
STOT - repeated exposure
No data available
Aspiration toxicity
No data available
Further information
Product:
Remarks: Symptoms of overexposure may be headache, dizziness, tiredness, nausea
and vomiting., Concentrations substantially above the TLV value may cause narcotic
effects., Solvents may degrease the skin.
Components:
toluene:
Remarks: No data available
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
No data available
Persistence and degradability
No data available
Bioaccumulative potential
Product:
Partition coefficient: n-
: Remarks: No data available
octanol/water
Components:
toluene :
Partition coefficient: n-
: Pow: 2.73
octanol/water
butanone :
Partition coefficient: n-
: log Pow: 0.29
octanol/water
butane :
Partition coefficient: n-
: Pow: 2.89
octanol/water
Mobility in soil
No data available
Other adverse effects
No data available
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SAFETY DATA SHEET
BOARDWALK VANDALISM MARK REMOVER 20N16 BWK351A
ersion 1.1 Revision Date 07/14/2016 Print Date 03/21/2017
Product:
Regulation 40 CFR Protection of Environment; Part 82 Protection of
Stratospheric Ozone - CAA Section 602 Class I
Substances
Remarks This product neither contains, nor was manufactured
with a Class I or Class II ODS as defined by the U.S.
Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A
+ B).
Additional ecological
: No data available
information
Components:
toluene :
Additional ecological
: No data available
information
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods
Waste from residues : Do not dispose of waste into sewer.
Do not contaminate ponds, waterways or ditches with
chemical or used container.
Dispose of in accordance with local regulations.
Contaminated packaging : Empty remaining contents.
Dispose of as unused product.
Do not re-use empty containers.
Do not burn, or use a cutting torch on, the empty drum.
SECTION 14. TRANSPORT INFORMATION
Transportation Regulation: 49 CFR (USA):
ORM-D, CONSUMER COMMODITY
Transportation Regulation: IMDG (Vessel):
UN1950, AEROSOLS, 2.1, - Limited quantity
Transportation Regulation: IATA (Cargo Air):
UN1950, Aerosols, flammable, 2.1, - Limited quantity
Transportation Regulation: IATA (Passenger Air):
UN1950, Aerosols, flammable, 2.1, - Limited quantity
Transportation Regulation: TDG (Canada):
UN1950, AEROSOLS, 2.1, - Limited quantity
The product as delivered to the customer conforms to packaging requirements for shipment by road
under US Department of Transportation (DOT) regulations. Additional transportation classifications
noted above are for reference only, and not a certification or warranty of the suitability of the packaging
for shipment under these alternative transport regulations.
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SECTION 15. REGULATORY INFORMATION
EPCRA - Emergency Planning and Community Right-to-Know Act
CERCLA Reportable Quantity
Components CAS-No. Component RQ
(lbs)
toluene 108-88-3 1000 *
*: Calculated RQ exceeds reasonably attainable upper limit.
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.
SARA 311/312 Hazards
SARA 302
SARA 313
California Prop 65
toluene 108-88-3
The components of this product are reported in the following inventories:
TSCA
DSL
For information on the country notification status for other regions please contact the
manufacturer’s regulatory group.
Inventory Acronym and Validity Area Legend:
TSCA (USA), DSL (Canada), NDSL (Canada)
On TSCA Inventory
All components of this product are on the Canadian DSL
: Sudden Release of Pressure Hazard
Acute Healt h Hazard
Chronic Health Hazard
Fire Hazard
: No chemicals in this material are subject to the reporting
requirements of SARA Title III, Section 302.
: The following components are subject to reporting levels
established by SARA Title III, Section 313:
toluene 108-88-3 17 %
WARNING: This product contains a chemical known to the
State of California to cause birth defects or other reproductive
harm.
Calculated product RQ
(lbs)
SECTION 16. OTHER INFORMATION
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SAFETY DATA SHEET
BOARDWALK VANDALISM MARK REMOVER 20N16 BWK351A
ersion 1.1 Revision Date 07/14/2016 Print Date 03/21/2017
Further information
NFPA: HMIS III:
Health
OSHA GHS Label Information:
Hazard pictograms :
Flammability
3
Special hazard.
4
Instability
0
HEALTH
FLAMMABILITY
PHYSICAL HAZARD
3*
4
2
0 = not significant, 1 =Slight,
2 = Moderate, 3 = High
4 = Extreme, * = Chronic
Signal word :
Hazard statements : Extremely flammable aerosol. Contains gas under pressure; may explode if heated.
Precautionary statements :
Danger:
Causes skin irritation. Causes serious eye irritation. May cause drowsiness or
dizziness. Suspected of damaging fertility or the unborn child. May cause damage to
organs through prolonged or repeated exposure if inhaled.
Prevention: Obtain special instructions before use. Do not handle until all safety
precautions have been read and understood. Keep away from heat/sparks/open
flames/hot surfaces. No smoking. Do not spray on an open flame or other ignition
source. Pressurized container: Do not pierce or burn, even after use. Do not breathe
dust/ fume/ gas/ mist/ vapours/ spray. Wash skin thoroughly after handling. Use only
outdoors or in a well-ventilated area. Wear eye protection/ face protection. Wear
protective gloves. Use personal protective equipment as required.
Response: IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove
victim to fresh air and keep at rest in a position comfortable for breathing. Call a
POISON CENTER or doctor/ physician if you feel unwell. IF IN EYES: Rinse cautiously
with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. IF exposed or concerned: Get medical advice/ attention. If skin
irritation occurs: Get medical advice/ attention. If eye irritation persists: Get medical
advice/ attention. Take off contaminated clothing and wash before reuse.
Storage: Store in a well-ventilated place. Keep container tightly closed. Store locked
up. Protect from sunlight. Do not expose to temperatures exceeding 50 °C/ 122 °F.
Disposal: Dispose of contents/container in accordance with local regulation.
Version: 1.1
Revision Date: 07/14/2016
Print Date: 03/21/2017
We believe the statements, technical information and recommendations contained herein are
reliable, but they are given without warranty or guarantee of any kind. The information in this
document applies to this specific material as supplied. It may not be valid for this material if it
is used in combination with any other materials. Users should make their own investigations
to determine the suitability and applicability of the information for their particular purposes.
This SDS has been prepared by the Compliance Services organization supporting this
manufacturer, supplier or distributor.
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