SWAN and its representatives maintain a fully trained staff of technical specialists
around the world. For any technical question, contact your nearest
SWAN representative, or the manufacturer:
SWAN ANALYTISCHE INSTRUMENTE AG
Studbachstrasse 13
8340 Hinwil
Switzerland
This document describes the main steps for instrument setup, operation and maintenance.
1.Safety Instructions
GeneralThe instructions included in this section explain the potential risks
Targ et
audience
OM LocationThe AMI Operator’s Manual shall be kept in proximity of the instru-
Qualification,
Training
associated with instrument operation and provide important safety
practices designed to minimize these risks.
If you carefully follow the information contained in this section, you
can protect yourself from hazards and create a safer work environment.
More safety instructions are given throughout this manual, at the
respective locations where observation is most important.
Strictly follow all safety instructions in this publication.
Operator: Qualified person who uses the equipment for its intended
purpose.
Instrument operation requires thorough knowledge of applications,
instrument functions and software program as well as all applicable
safety rules and regulations.
ment.
To be qualified for instrument installation and operation, you must:
read and understand the instructions in this manual as well as
the Material Safety Data Sheets.
know the relevant safety rules and regulations.
4A-96.250.831 / 070319
AMI Silitrace Ultra
Safety Instructions
1.1.Warning Notices
The symbols used for safety-related notices have the following significance:
DANGER
Your life or physical wellbeing are in serious danger if such
warnings are ignored.
Follow the prevention instructions carefully.
WARNING
Severe injuries or damage to the equipment can occur if such
warnings are ignored.
Follow the prevention instructions carefully.
CAUTION
Damage to the equipment, minor injury, malfunctions or incorrect process can be the consequence if such warnings are ignored.
Follow the prevention instructions carefully.
Mandatory
Signs
A-96.250.831 / 0703195
The importance of the mandatory signs in this manual.
Safety goggles
Safety gloves
AMI Silitrace Ultra
Safety Instructions
Warning SignsThe importance of the warning signs in this manual.
Electrical shock hazard
Corrosive
Harmful to health
Flammable
Warning general
Attention general
1.2.General Safety Regulations
Legal
Requirements
Spare Parts
and
Disposables
ModificationsModifications and instrument upgrades shall only be carried out by
The user is responsible for proper system operation. All precautions must be followed to ensure safe operation of the instrument.
Use only official SWAN spare parts and disposables. If other parts
are used during the normal warranty period, the manufacturer’s
warranty is voided.
an authorized Service Technician. SWAN will not accept responsibility for any claim resulting from unauthorized modification or alteration.
6A-96.250.831 / 070319
AMI Silitrace Ultra
Safety Instructions
WARNING
Risk of Electrical Shock
If proper operation is no longer possible, the instrument must be
disconnected from all power lines, and measures must be taken
to prevent inadvertent operation.
To prevent from electrical shock, always make sure that the
ground wire is connected.
Service shall be performed by authorized personnel only.
Whenever electronic service is required, disconnect instru-
ment power and power of devices connected to.
– relay 1,
– relay 2,
– alarm relay
WARNING
For safe instrument installation and operation you must read
and understand the instructions in this manual.
WARNING
Only SWAN trained and authorized personnel shall perform the
tasks described in this document.
Download
MSDS
A-96.250.831 / 0703197
The current Safety Data Sheets (SDS) for the above listed Reagents are available for downloading at www.swan.ch.
AMI Silitrace Ultra
Product Description
2.Product Description
2.1.Description of the System
Application
Range
Measuring
Principle
Photometrical
Detection of
Silica
The AMI Silitrace Ultra is a complete monitoring system for the automatic, continuous measurement of trace amounts of silica in ultra
pure water.
Dissolved silica in water is concentrated with the use of a RO (reversed osmosis) membrane followed by a photometrical detection
of silica.
The determination of silica is done by the photometric analysis of
molybdate blue at 815 nm.
Silica and ortho-phosphates react at low pH with ammonium molybdate to the yellow colored molybdosilic acid respectively molybdophosphoric acid. The molybdophosphoric acid is destroyed with
oxalic acid before the molybdosilic acid is reduced with iron-(II)-ammonium-sulfate to the heteropolyblue complex.
Especially the reaction speed of the first reaction step to the molybdosilic acid is relatively slow. It is the most time consuming part of
the whole reaction. As the reaction speed increases with increasing
temperature, it is time saving to heat up the sample. The AMI Silitrace therefore uses a thermostatic reaction chamber with a constant temperature of 45 °C.
At 45 °C the complete reaction only needs 150 s (2.5 min). Because the reaction time plays an important rule in the color development, the pump speed is adjusted constantly. Due to the
automatic heating and reaction time regulation a very high precision is achieved.
8A-96.250.831 / 070319
AMI Silitrace Ultra
A
B
ACDEF
GH
G
Product Description
Concentrator
function
principle
A
Feed water
B
Spiral-wound RO module
C
RO membrane
D
Feed spacer
The Carrcentrator acts as a mesh that holds back large molecules
such as silica and allows smaller molecules (water, Na, etc.) to
pass through. The membrane is rolled to obtain as many layers as
possible. Most of the water (permeate) flows through the membrane and only a small part forms the concentrate. The permeate
and the concentrate leave the module via two separate outlets.
The separation of permeate and concentrate needs a high flow
rate. As a minimum 100 l/h at 2 bar must be provided to press the
water through the membrane.
The aim of this measurement is to detect the silica in the concentrate and calculate it back to the feed water. Three points must be
taken into account:
Concentration factor: Distribution ratio between the total flow
and the concentrate flow.
Separation efficiency: Constant factor of 90%.
Background: Silica reading of the permeate. This reading is
the sum of the silica
– which is in the reagents and
– which passes the membrane.
The background is measured daily, the efficiency is fixed and the
concentration factor is changed constantly by the flows.
E
RO membrane
F
Product spacer
G
Permeate
H
Concentrate
A-96.250.831 / 0703199
AMI Silitrace Ultra
Feed water concentration = Efficiency •
reading Concentrate – reading Permeate (Blanc)
Concentration factor
Concentration factor = Efficiency •
Total flow
Concertrate flow
Reading Permeate = – Log
V
Perm
V
Zero
Product Description
The silica reading on the display is calculated as follows:
Where
Reading Concentrate = – Log
FluidicThe sample enters at the sample inlet [S] and flows through the
concentrator [Q]. The sample is split in a permeate and a concentrate outlet which are led to the flow cell high flow [J] (permeate)
and the flow cell low flow [I] (concentrate). The flow rate is measured with the flow meters attached to the flow cells [I] and [J].
The concentrate is connected to the 6-way valve [H] position 1, the
permeate to position 6. Excess sample overflows into the sample
outlet.
The peristaltic pump [O] sucks the concentrate from the 6-way
valve and pumps it into the reaction chamber [C]. The reaction
chamber is wrapped around a heating device. It has 4 inlets to allow dosing of the necessary reagents.
In the reaction chamber the sample is heated up to 45 °C, eliminating temperature deviations of the sample. In a first step Ammoniummolybdate [K] and sulfuric acid [L] are added, to form the
yellowish molybsilic acid and molybdophosphoric acid.
Afterwards the oxalic acid [M] is added to mask the molybdophosphoric complex. At last the reducing agent ammonium ferrous (II)
sulfate [N] is added. The color of the sample turns to blue. As silica
is only present in trace amounts, the blue color can not be seen.
Afterwards the colored sample flows into the thermostatic cuvette
[D] until it is filled completely. Now the intensity of the color is measured at 815 nm. The color development is proportional to the silica
concentration in the sample.
As the level of the sample in the cuvette increases, the sample
overflows into the siphon tube [F] and eventually the cuvette is
drained spontaneously through the siphon tube. The sample is led
via the aeration and drain tube [R] into the sample outlet.
Dosing, mixing and filling of the photometer are determined by the
rotating speed of the peristaltic pump [O]. This speed is adjusted
automatically and guarantees the correct timing of the measurement.
V
Conc
V
Zero
10A-96.250.831 / 070319
AMI Silitrace Ultra
Product Description
R
Q
P
1A0322 3 4
1
05
A
B
C
12
05
1B
1A
3 402
543
7
6
2
1
02
0114
11
1B
2
03
03
2
3
3
4
4
04
H
04
12
12
E
11
11
F
04
04
G
D
1
2
O
K
U
T
S
A
Standard bottle
B
Photometer module
C
Reaction chamber
D
Cuvette
E
Cuvette de-aeration
F
Sample outlet (siphon tube)
G
Inlet from reaction chamber
H
6-way valve
I
Flow cell low flow
J
Flow cell high flow
K
Reagent 1
L
M
N
01
4
3
I
J
L
Reagent 2
M
Reagent 3
N
Reagent 4
O
Peristaltic pump
P
Zero calibration valve
Q
Concentrator
R
Aeration and drain tube
S
Sample inlet
T
Permeate
U
Concentrate
A-96.250.831 / 07031911
AMI Silitrace Ultra
Product Description
Signal
Outputs
RelaysTwo potential-free contacts programmable as limit switches for
Alarm RelayOne potential free contact.
InputOne input for potential-free contact to freeze the measuring value
Communica-
tion Interface
(optional)
Safety
Features
Two signal outputs programmable for measured values (freely scalable, linear, bilinear, log) or as continuous control output (control
parameters programmable).
Current loop:0/4–20 mA
Maximal burden:510 Ohm
Third signal output available as an option. The third signal output
can be operated as a current source or as a current sink (selectable
via switch).
measuring values, controllers or timer for system cleaning with automatic hold function. Both contacts can be used as normally open
or normally closed.
Maximum load: 1 A/250 VAC
Alternatively:
Open during normal operation, closed on error and loss of
power.
Closed during normal operation, open on error and loss of
power.
Summary alarm indication for programmable alarm values and instrument faults.
or to interrupt control in automated installations (hold function or re-
mote-off).
USB Interface for logger download
Third signal output (can be used in parallel to the USB interface)
RS485 with Fieldbus protocol Modbus or Profibus DP
HART interface
No data loss after power failure. All data is saved in non-volatile
memory.
Over voltage protection of in- and outputs.
Galvanic separation of measuring inputs and signal outputs.
12A-96.250.831 / 070319
AMI Silitrace Ultra
Product Description
2.2.Instrument Specification
Power SupplyVoltage:
Power consumption:
Transmitter
specifications
Sample
requirements
On-siteThe analyzer site must permit connections to:
requirementsSample inlet:
Silica
measurement
Electronics housing
Ambient temperature:
Limit range of operation:
Storage and transport:
Humidity:
Display:
100–240 VAC (± 10%)
50/60 Hz (± 5%)
DC version not available
max. 50 VA
Aluminium with a protection degree of
IP 66 / NEMA 4X
-10 to +50 °C
-25 to +65 °C
-30 to +85 °C
10–90% rel., non condensing
backlit LCD, 75 x 45 mm
100 l/h
5 to 50 °C
2 to 20 bar
pressure free
3
/4“ NPT
Flexible Tube 15x20 mm
5 to 50 °C
0.005 ppb to 25 ppb
±0.005 ppb or ±5%, whichever is greater
3 min
A-96.250.831 / 07031913
AMI Silitrace Ultra
Product Description
DimensionsPanel:
Panel dimensions:
Screws:
Weight:
1200 mm / 47¼”
1120 mm / 44”
stainless steel
400x850x150 mm
8 mm
30.0 kg
640 mm / 25.20”
606 mm / 23.86”
400 mm / 15¾”
ExitEnter
AMI SILITRACE
Ozone Monitor
Trace SiO
Process Analyzer
2
”
/
4 x dia. 10 mm /
824 mm / 32.4”
850 mm / 33½”
2L
2L
2L
2L
14A-96.250.831 / 070319
AMI Silitrace Ultra
Product Description
2.3.Instrument Overview
T
S
R
Q
P
O
N
M
A
Panel
B
Standard bottle
C
Solenoid valve
D
Photometer module
E
6-way valve
F
Flow regulating valve
G
Flow cell low flow
H
Flow meter
I
Flow cell high flow
J
Flow meter
A
B
C
D
E
F
G
H
I
J
K
L
K
Sample inlet low flow
L
Sample inlet high flow
M
Sample outlet
N
Reagent 4
O
Reagent 3
P
Reagent 2
Q
Reagent 1
R
Peristaltic pump
S
Transmitter
T
Concentrator
A-96.250.831 / 07031915
AMI Silitrace Ultra
Installation
3.Installation
3.1.Installation Checklist
CheckInstrument’s specification must conform to the National Electri-
cal Code, all state and local codes, and all plant codes and standards for electrical equipment.
On site requirements
Installation
Electrical
Wiring
Start-upProceed according to Start-up Procedure, p. 32.
100–240 VAC (± 10%), 50/60 Hz (± 5%) power outlet with
ground connection and 50 VA.
Sample line with sufficient sample flow and pressure (see
Instrument Specification, p. 13).
Assemble the Concentrator, p. 17
Mounting of Instrument Panel, p. 20
Connect Sample and Waste, p. 21
NOTICE: Do not switch on the Instrument until all electrical
connections are made.
Connect all external devices like limit switches, current loops
and pumps.
Electrical Connections, p. 22
Connect power cord, see Power Supply, p. 25.
16A-96.250.831 / 070319
AMI Silitrace Ultra
Installation
3.2.Assemble the Concentrator
The concentrator is delivered in the following parts:
ABCEFGHID
A
Concentrator housing
B
Concentrator membrane
C
Tube set for high and
low flow
D
2 O-rings
E
2 covers
1 Insert the concentrator membrane [B] into the concentrator
housing [A].
Consider the flow direction indicated on the membrane label.
The flow direction is from bottom to top.
2 Mark the sample outlet on the concentrator housing.
A-96.250.831 / 07031917
F
4 cover fixing plates with
4 fixing screws
G
Blind plug
H
Serto fitting for sample inlet
I
2 Hollow profiles with pipe
clamps and fixing screws
AMI Silitrace Ultra
E
D
A
F
Installation
3 Put the O-ring [D] into the groove of the cover [E].
4 Put the cover onto the concentrator housing [A].
A
Concentrator housing
D
O-Ring
E
Cover
5 Put the cover fixing plates [F] into the grove of the concentrator
housing.
6 Fix it with the screws, tighten it well.
7 With the second cover, repeat steps 2 to 4 on the other side.
18A-96.250.831 / 070319
AMI Silitrace Ultra
C
C
1
C
2
H
G
Installation
NOTICE: When installing the sample outlet tubes consider the
flow direction. Install the tube set on the side you marked as
sample outlet.
8 Screw the serto fitting [C
thread of the cover.
9 Screw the serto fitting [C
edge of the cover.
10 Tighten the serto fittings well.
11
At the bottom side close the center thread with the blind plug [G].
12 At the bottom side screw the serto fitting [H] into the thread at
the edge of the cover.
C
Tube set for high and
low flow
C
Serto fitting high flow
1
C
Serto fitting low flow
2
], high flow outlet, into the center
1
], low flow outlet, into the thread at the
2
GHBlind plug
Serto fitting sample
inlet
A-96.250.831 / 07031919
AMI Silitrace Ultra
ABC
Installation
3.3.Mounting of Instrument Panel
The first part of this chapter describes the preparing and placing of
the instrument for use.
The instrument must only be installed by trained personnel.
Mount the instrument in vertical position.
For ease of operation mount it so that the display is at eye
level.
For the installation a kit containing the following installation
material is available:
– 4 Screws 8x60 mm
– 4 Dowels
– 4 Washers 8.4/24 mm
Mounting re-
quirements
Mount the
hollow profiles
The instrument is only intended for indoor installation.
For dimensions see Dimensions, p. 14.
Mount the hollow profiles [A] with the pipe clamps [B] facing to the
left side to a wall or a suitable support.
Install the instrument panel to the hollow profiles using the fixing
screws [C].
20A-96.250.831 / 070319
AMI Silitrace Ultra
A
B
C
D
E
F
GJHI
Installation
3.4.Connect Sample and Waste
A
Sample inlet low flow
B
Flow cell low flow
C
Sample inlet
WastePush the 1/2” tube [F] over the hose nozzle [E] and place it into a
A-96.250.831 / 07031921
Sample inlet high flow
D
Flow cell high flow
E
Hose nozzle
Use plastic tubes (FEP, PA, or PE) to connect the sample.
1 Slide the knurled nuts [H] and the compression ferrules [I] over
the plastic tubes [G].
2 Push the plastic tubes into the serto elbow unions [J] at the cor-
responding sample inlets.
3 Tighten the knurled nuts well.
pressure free drain of sufficient capacity.
F
1/2” tube
G
Plastic tubes
H
Knurled nuts
I
Compression ferrules
J
Serto elbow unions
AMI Silitrace Ultra
Installation
3.5.Electrical Connections
WARNING
Risk of electrical shock.
Do not perform any work on electrical components if the transmitter is switched on. Failure to follow safety instructions could
result in serious injury or death.
Always turn off AC power before manipulating electric parts.
Grounding requirements: Only operate the instrument from a
power outlet which has a ground connection.
Make sure the power specification of the instrument corre-
sponds to the power on site.
Cable
thicknesses
In order to comply with IP66, use the following cable thicknesses
ABC
A
PG 11 cable gland: cable Ø
B
PG 7 cable gland: cable Ø
C
PG 9 cable gland: cable Ø
NOTICE: Protect unused cable glands
Wire For Power and Relays: Use max. 1.5 mm
stranded wire with end sleeves.
For Signal Outputs and Input: Use 0.25 mm
stranded wire with end sleeves.
outer
3–6.5 mm
outer
4–8 mm
outer
5–10 mm
2
/ AWG 14
2
/ AWG 23
22A-96.250.831 / 070319
AMI Silitrace Ultra
Installation
WARNING
External Voltage.
External supplied devices connected to relay 1 or 2 or to the
alarm relay can cause electrical shocks
Make sure that the devices connected to the following con-
tacts are disconnected from the power before resuming installation.
– relay 1
– relay 2
– alarm relay
WARNING
To prevent from electrical shock, do not connect the instrument
to the power unless the ground wire (PE) is connected.
Do not connect unless specifically instructed to do so.
WARNING
The mains of the AMI Transmitter must be secured by a main
switch and appropriate fuse or circuit breaker.
A-96.250.831 / 07031923
AMI Silitrace Ultra
Installation
3.5.1Connection Diagram
CAUTION
Use only the terminals shown in this diagram, and only for the
mentioned purpose. Use of any other terminals will cause short
circuits with possible corresponding consequences to material
and personnel.
24A-96.250.831 / 070319
AMI Silitrace Ultra
A
B
C
D
Installation
3.5.2Power Supply
WARNING
Risk of electrical shock
Do not perform any work on electrical components if the transmitter is switched on. Failure to follow safety instructions could
result in serious injury or death.
Always turn off AC power before manipulating electric parts.
Installation and maintenance of electrical parts must be per-
formed by professionals.
A
Power supply connector
B
Neutral conductor, Terminal 2
C
Phase conductor, Terminal 1
D
Protective earth PE
NOTICE: The protective earth wire (Ground) has to be
connected to the grounding terminal.
Installation
requirements
A-96.250.831 / 07031925
The installation must meet the following requirements.
Fuse 1.6 AT
Mains cable to comply with standards IEC 60227 or IEC
60245; flammable rating FV1
Mains equipped with an external switch or circuit-breaker
– near the instrument
– easily accessible to the operator
– marked as interrupter for AMI Silitrace Ultra
AMI Silitrace Ultra
10
12
11
0V
1)
10
12
11
0V
Installation
3.6.Relay Contacts
3.6.1Input
NOTICE: Use only potential-free (dry) contacts.
The total resistance (sum of cable resistance and resistance of
the relay contact) must be less than 50 Ω.
Terminals 30/31
For programming see Program Overview, p. 73.
3.6.2Alarm Relay
NOTICE: Max. load 1 A / 250 VAC
Alarm output for system errors.
Error codes see Troubleshooting, p. 57.
NOTICE: With certain alarms and certain settings of the AMI
transmitter the alarm relay does not switch. The error, however,
is shown on the display.
Ter min alsDescriptionRelay connection
1)
NC
Normally
Closed
10/11Active (opened) during normal
operation.
Inactive (closed) on error and
loss of power.
NO
Normally
Open
12/11Active (closed) during normal
operation.
Inactive (opened) on error and
loss of power.
1) usual use
26A-96.250.831 / 070319
AMI Silitrace Ultra
6
0V
7
6
0V
7
A
B
Installation
3.6.3Relay 1 and 2
NOTICE: Max. load 1 A/250 VAC
Relay 1 and 2 can be configured as normally open or as normally
closed. Standard for both relays is normally open. To configure a
Relay as normally closed, set the jumper in the upper position.
NOTICE: Some error codes and the instrument status may
influence the status of the relays described below.
Relay
config.Terminals
Normally
Open
Normally
Closed
6/ 7: Relay 1
8/ 9: Relay 2
6/ 7: Relay 1
8/ 9: Relay 2
Jumper
pos.DescriptionRelay configuration
Inactive (opened) during
normal operation and loss
of power.
Active (closed) when a programmed function is
executed.
Inactive (closed) during
normal operation and loss
of power.
Active (opened) when a
programmed function is
executed.
ABJumper set as normally open (standard setting)
Jumper set as normally closed
For more information see Program List and Explanations, p. 79.
A-96.250.831 / 07031927
AMI Silitrace Ultra
A
BC
DE
Installation
CAUTION
Risk of damage of the relays in the AMI Transmitter due to
heavy inductive load.
Heavy inductive or directly controlled loads (solenoid valves,
dosing pumps) may destroy the relay contacts.
To switch inductive loads > 0.1 A use an AMI relay box avail-
able as an option or suitable external power relays.
Inductive loadSmall inductive loads (max 0.1A) as for example the coil of a power
Resistive loadResistive loads (max. 1A) and control signals for PLC, impulse
ActuatorsActuators, like motor valves, are using both relays: One relay con-
relay can be switched directly. To avoid noise voltage in the
AMI Transmitter it is mandatory to connect a snubber circuit in parallel to the load.
A snubber circuit is not necessary if an AMI relaybox is used.
A
AC or DC power supply
B
AMI Transmitter
C
External power relay
D
Snubber
E
Power relay coil
pumps and so on can be connected without further measures
A
AB
C
tact is used for opening, the other for closing the valve, i.e. with the
2 relay contacts available, only one motor valve can be controlled.
Motors with loads bigger than 0.1A must be controlled via external
power relays or an AMI relay box.
A
BC
AMI Transmitter
B
PLC or controlled pulse pump
C
Logic
A
AC or DC power supply
B
AMI Transmitter
C
Actuator
M
28A-96.250.831 / 070319
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