Sure Seal CP-PS25 User Manual

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Sure Seal 30 Clear Concrete Sealer Revision Date 4/15/2015
SECTION 1: PRODUCT A
ND COMPANY IDENTIFIC
ATION
SECTION 2: HAZARDS I
DENTIFICATION
Safety Data Sheet
Issue Date 08/16/2002
Product Identifier Product Name Sure Seal Paver Sealer (Oil-Based)
Other means of identification SDS # / Grade CP- 516PSO
UN/ID No. UN 1993
Recommended Use of the Chemical and Restrictions on Use
Relevant identified use(s) - Sealing and protecting concrete and aggregate surfaces.
Details of the Supplier of the Safety Data Sheet
Supplier Perk Products & Chemical Co.
42 Industry Street Nashville, TN 37210
www.Perk-Products.com
Emergency telephone number
Company Phone: (615) 242-6157
Emergency Phone: (800) 424-9300 – CHEMTREC
Classification
Skin Corrosion / Irritation Category 2
Serious Eye Damage / Eye Irritation Category 2
Germ Cell Mutagenicity Category 1B
Carcinogenicity Category 1B
Specific target organ toxicity (single exposure) Category 3
Aspiration Toxicity Category 1
Flammable Liquids Category 3
Signal Word
DANGER
Hazard Statements
Causes Skin Irritation Causes serious eye irritation Carcinogenic May cause respiratory irritation. May cause drowsiness or dizziness May be fatal if swallowed and enters airways Flammable liquid and vapor
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Sure Seal 30 Clear Concrete Sealer Revision Date 4/15/2015
SECTION 3
:
COMPOSITION / INFORM
ATION ON INGREDIENTS
Appearance: Clear, colorless liquid Physical State: Liquid Odor: Moderate aromatic
Precautionary Statements - Prevention
Obtain special instructions before use; do not use until all safety precautions have been read and understood Use personal protective equipment as required Product is combustible Do not ingest Wear eye/face protection Wash skin thoroughly with soap and water Avoid contact with eyes and prolonged contact with skin Vapors harmful, avoid breathing of vapor or mist Use in well ventilated areas Keep away from heat/open flame/other heat sources. –No smoking Keep container closed tightly Ground/bond container and receiving equipment Use explosion-proof equipment Use only non-sparking tools Take precautionary measures against static spark Keep cool
Precautionary Statements - Response
If exposed or concerned: Seek medical advice/attention IF IN EYES: Flush with clan water for at least 10-15 minutes. Call a physician. IF ON SKIN: Wash thoroughly with soap and water. If irritation develops, seek medical attention. IF INDUCED INTERNALLY: Do not induce vomiting. Call a physician or poison control center immediately. IF INHALED: Move to fresh air and avoid breathing fumes. Contact a physician if breathing becomes difficult.
Precautionary Statements – Storage
Store locked up Store in a well-ventilated place. Keep container tightly closed
Precautionary Statements – Disposal
Dispose of contents/container to an approved waste disposal plant
Hazards Not Otherwise Classified (HNOC)
May be harmful in contact with skin
Other Hazards
Toxic to aquatic life with long lasting effects Toxic to aquatic life
Chemical Name CAS No Weight-%
Copolymer of Styrene and 2-Ethylhexylacrylate 25153-46-2 <50
Petroleum naphtha, light aromatic 64742-95-6 <50
1,2,4 Trimethylbenzene 95-63-6 5-25 1,3,5 Trimethylbenzene 108-67-8 0-6
Xylene 1330-20-7 0-2 Cumene 98-82-8 0-2 Styrene 100-42-5 0-1
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Sure Seal 30 Clear Concrete Sealer Revision Date 4/15/2015
SECTION 4
:
FIRST AID MEASURES
SECTION 5: FIRE
-
FIGHTING MEASURES
SECTION 6
:
ACCIDENTAL RELEASE M
EASURES
First Aid Measures
General Advice If exposed or concerned: Get medical advice/attention
Eye Contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. Get medical attention if irritation occurs.
Skin Contact Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes.
Wash contaminated clothing before reuse. Get medical attention if irritation develops or persists.
Inhalation Remove to fresh air. If not breathing, give artificial respiration. Get medical attention immediately.
Ingestion DO NOT induce vomiting because of danger of aspirating liquid into lungs. If spontaneous vomiting occurs,
keep head below hips to prevent aspiration and monitor breathing. Call a physician or poison control center immediately.
Most Important Symptoms and Effects, both Acute and Delayed
Symptoms May cause dermatitis or irritation in some individuals upon prolonged contact. Eyes may have symptoms of
redness, itching, irritation and watering from overexposure. Aspiration hazard: if swallowed can enter lungs and cause damage. May cause irritation to the mucous membranes and upper respiratory tract. Prolonged breathing of vapors may cause nausea, headache, weakness and/or dizziness.
Indication of any Immediate Medical Attention and Special Treatment Needed
Note to Physicians Treat symptomatically
Suitable Extinguishing Media
Water spray (fog). Dry chemical. Alcohol resistant foam. AFFF. Carbon dioxide (CO2)
Unsuitable Extinguishing Media Not determined.
Specific Hazards Arising from the Chemical
Cool surrounding equipment, fire-exposed containers, and structures with water. Vapors may form explosive mistures with air. Vapors may travel to source of ignition and flash back.
Hazardous Combustion Products Carbon monoxide. Carbon dioxide (CO2). Reactive hydrocarbons. Irritating vapors. Sensitivity to Mechanical Impact Sensitive to shock. Sensitivity to Static Discharge Take precautionary measures against static discharge.
Protective Equipment and Precautions for Firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.
Personal Precautions, Protective Equipment and Emergency Procedures
Personal Precautions Use personal protective equipment as required. Remove all sources of ignition.
Environmental Precautions See Section 12 for additional ecological information
Avoid breathing vapors. Ventilate affected area.
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Sure Seal 30 Clear Concrete Sealer Revision Date 4/15/2015
SECTION 7
:
HANDLING AND STORAGE
SECTION 8: EXPOSURE
CONTROL/PERSONAL PRO
TECTION
Methods and Material for Containment and Cleaning Up
Methods for Containment Prevent further leakage or spillage if safe to do so.
Methods for Cleaning Up Absorb spillage with non-combustible, absorbent material. Clean up in
accordance with all applicable regulations.
Precautions for Safe Handling
Advice on Safe Handling Obtain special instructions before use. Do not handle until all safety precautions
have been read and understood. Use personal protection recommended in Section 8. Wash face, hands, and any exposed skin thoroughly after handling. Avoid breathing vapors or mists. Use only with adequate ventilation. Keep away from heat/sparks/open flames/hot surfaces. –No smoking.
Conditions for Safe Storage, Including any Incompatibilities
Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place. Store
locked up.
Packing Materials Do not transfer to unmarked containers.
Incompatible Materials Strong oxidizing agents.
Exposure Guidelines
Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH
1,2,4 Trimethylbenzene 95-63-6
1,3,5 Trimethylbenzene 108-67-8 Xylene 1330-20-7
Cumene 98-82-8
Styrene 100-42-5
Appropriate Engineering Controls
- -
- -
STEL: 150ppm TWA: 100ppm
TWA: 50ppm TWA: 50ppm
STEL: 40ppm TWA: 20ppm
TWA: 100ppm TWA: 435 mg/m³ (vacated) TWA: 100ppm (vacated) TWA: 435 mg/m³ (vacated) STEL: 150ppm (vacated) STEL: 655 mg/m³
TWA: 245 mg/m³ (vacated) TWA: 50ppm (vacated) TWA: 245 mg/m³ (vacated) S* S* TWA: 100ppm
(vacated) TWA: 50ppm (vacated) TWA: 215 mg/m³ (vacated) STEL: 100ppm (vacated) STEL: 425 mg/m³ Ceiling: 200ppm
TWA: 25ppm TWA: 125 mg/m³ TWA: 25ppm TWA: 125 mg/m³
-
IDLH: 900ppm TWA: 50ppm TWA: 245mg/ m³
IDLH: 700ppm TWA: 50ppm TWA: 215mg/m³ STEL: 100ppm STEL: 425mg/m³
Engineering Controls Apply technical measures to comply with the occupational exposure limits.
Individual Protection Measures, such as Personal Protective Equipment
Eye/Face Protection Wear approved safety goggles
Skin and Body Protection Chemical resistant, impermeable gloves. Use protective clothing chemically
Eyewash stations.
resistant to this material.
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Sure Seal 30 Clear Concrete Sealer Revision Date 4/15/2015
SECTION 9: PHYSICAL
AND CHEMICAL PROPERT
IES
SECTION 10
:
STABILITY AND REACTI
VITY
Respiratory Protection Ensure adequate ventilation, especially in confined areas. If applicable, use
process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits.
General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice.
Information on Basic Physical and Chemical Properties
Physical State Liquid Odor Moderate aromatic Appearance Clear, colorless liquid Odor Threshold Not determined Color Clear
Property Values Remarks °Method pH Not Determined Melting Point/Freezing Point Not Determined Boiling Point/Boiling Range 160-174 °C / 320-345 °F Flash Point 37-46 °C / 100-115 °F Tag Closed Cup
Evaporation Rate 0.1 (butyl acetate = 1) @ 25°C
Flammability (Solid, Gas) n/a liquid Upper Flammability Limits Unknown Lower Flammability Limit 1% (approximate) Vapor Pressure <10 mm Hg @ 25°C (77°F) Vapor Density 3.5 (Air=1) Specific Gravity 0.95 (1=Water) @ 15°C Water Solubility Negligible Solubility in Other Solvents Not Determined Partition Coefficient Not Determined Autoignition Temperature 471 °C / 880 °F Decomposition Temperature Not Determined Kinematic Viscosity Not Determined Dynamic Viscosity Not Determined Explosive Properties Not Determined Oxidizing Properties Not Determined
Reactivity
Not reactive under normal conditions.
Chemical Stability
Stable under recommended storage conditions.
Possibility of Hazardous Reactions
None under normal processing.
Conditions to Avoid
Avoid heat, sparks, open flames and other ignition sources.
Incompatible MaterialsStrong Oxidizing Agents.
Hazardous Decomposition Products
Carbon Monoxide.
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Sure Seal 30 Clear Concrete Sealer Revision Date 4/15/2015
SECTION 11
:
TOXICOLOGICAL INFORM
ATION
Information on Likely Routes of Exposure
Product Information
Eye Contact Causes serious eye irritation
Skin Contact Causes skin irritation. May be harmful in contact with skin.
Inhalation Avoid breathing vapors or mists.
Ingestion Do not taste or swallow.
Component Information
Chemical Name Oral LD50 Dermal LD50 Inhalation LC50
Petroleum naptha, light aromatic 64742-95-6 1,2,4 Trimethylbenzene 95-63-6 1,3,5 Trimethylbenzene 108-67-8 Xylene 1330-20-7 Cumene 98-82-8 Styrene 100-42-5
=8400 mg/kg (Rat) >2000 mg/kg (Rabbit) >5.2 mg/L (Rat) 4 h = 3400ppm
(Rat)
=3400 mg/kg (Rat) >3160 mg/kg (Rabbit)
=5000 mg/kg (Rat) -
=4300 mg/kg (Rat) >1700 mg/kg (Rabbit) = 5000ppm (Rat) 4 h = 47635
=1400 mg/kg (Rat) >3160 mg/kg (Rabbit)
=1000 mg/kg (Rat) - =11.8 mg/L (Rat) 4 h
= 18 g/m³ (Rat) 4 h
= 24 g/m³ (Rat) 4 h
Mg/L (Rat) 4 h
=39000 mg/m³ (Rat) 4 h
Information on Physical, Chemical and Toxicological Effects
Symptoms Please see section 4 of this SDS for symptoms
Delayed and Immediate Effects as well as Chronic Effects from Short and Long-term Exposure
Germ Cell Mutagenicity May cause genetic defects.
Carcinogenicity May cause cancer.
Chemical Name ACHIH IARC NTP OSHA
Xylene 1330-20-7 Cumene 98-82-8 Styrene 100-42-5
Legend
IARC (International Agency for Research on Cancer)
Group 2B – Possibly Carcinogenci to Humans Group 3 IARC components are “not classifiable as human carcinogens”
NTP (National Toxicology Program) Reasonably Anticipated – Reasonably Anticipated to be a Human Carcinogen OSHA (Occupational Safety and Health Administration of the US Department of Labor)
X - Present
STOT – Single Exposure May cause respiratory irritation. May cause drowsiness or dizziness.
Group 3
Group 2B X
Group 2B Reasonably Anticipated X
Aspiration Hazard May be fatal if swallowed and enters airways.
Numerical Measures of Toxicity
Not determined
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Sure Seal 30 Clear Concrete Sealer Revision Date 4/15/2015
SECTION 12
:
ECOLOGICAL INFORMATI
ON
Ecotoxicity
Toxic to aquatic organisms. Toxic to aquatic life with long lasting effects.
Chemical Name Algae/aquatic plants Fish Toxicity to
Microorganisms
Petroleum naphtha, light
aromatic
64742-95-6
1,2,4 Trimethylbenzene
95-63-6
1,3,5- Trimethylbenzene
108-67-8 Xylene
1330-20-7
Cumene
98-82-8
Styrene
100-42-5
2.6: 72 h Pseudokirchneriella Subcapitata mg/L EC50
1.4: 72 h Pseudokirchneriella Subcapitata mg/L EC50 0.72: 96 h h Pseudokirchneriella Subcapitata mg/L EC50 0.46
- 4.3: 72 h Pseudokirchneriella subcapitata mg/L EC50 static 0.15 – 3.2: 96 h Pseudokirchneriella subcapitata mg/L EC50 static
9.22: 96 h Oncorhynchus Mykiss mg/L LC50
7.19-8.28: 96 h Pimephales
promelas mg/L LC50
flow-through
3.48: 96 h Pimephales Promelas mg/L LC50
13.4: 96 h Pimephales promelas mg/L LC50
flow-through 2.661 – 4.093: 96 h Oncorhynchus mykiss
mg/L LC50 static 13.5 – 17.3:
96 h Oncorhynchus mykiss mg/L LC50 13.1 – 16.5: 96 h lepomis macrochirus mg/L LC50 flow-through 19:96 h lepomis macrochirus mg/L LC50 7.711-9.591: 96 h
lepomis macrochirus mg/L
LC50 static 23.53 – 29.97: 96
h Pimephales promelas mg/L LC50 static 780: 96 h
cyprinus carpio mg/L LC50
30.26 – 40.75: 96 h Poecilia reticulate mg/L LC50 static
6.04-6.61: 96h h Pimephales promelas mg/L LC50 flow-through 4.8: 96 h
Oncorhynchus mykiss mg/L
LC50 flow-through 2.7: 96 h Oncorhynchus mykiss mg/L LC50 semi-static 5.1: 96 h Poecilia reticulate mg/L LC50 semi-static
3.24-4.99: 96 h Pimephales promelas mg/L LC50 flow-through 19.03-33.53:
96 h Lepomis macrochirus
mg/L LC 50 static 6.75-14.5:
96 h Pimephals promelas
mg/L LC50 static 58.75-
95.32: 96 h Poecilia
Reticulate mg/L LC50 static
EC50 = 0.0084 mg/L 24 h 3.82: 48 h water flea mg/L
EC50 = 0.89 mg/L 5 min EC50 =1.10 mg/L 15 min EC50 =1.48 mg/L 30 min EC50 =172 mg/L 24 h
EC50 = 5.4 mg/L 5 min 3.3 – 7.4: 48 h Daphnia magma
Crustacea
6.14: 48 h Daphnia magma mg/L LC50
6.14: 48 h Daphnia magma
mg/L LC50
50: 24 h Daphnia magma mg/L LC50
EC50 0.6: 48 h Gammarus
Lacustris mg/L LC50
0.6:48 h Daphnia magna
Mg/L EC50 7.9 – 14.1: 48 h
Daphnia magna mg/L EC50
Static
mg/L LC50
Persistence and Degradability
Not determined
Bioaccumulation
Not determined
Mobility
1,2,4 Trimethylbenzene
Xylene
1330-20-7 Cumene 98-82-8
Chemical Name Partition Coefficient
3.63
95-63-6
2.77 – 3.15
3.55
Styrene
100-42-5
2.95
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Sure Seal 30 Clear Concrete Sealer Revision Date 4/15/2015
SECTION 13
:
DISPOSAL CONSIDERATI
ONS
SECTION 14
:
TRANSPORTATION INFOR
MATION
Other Adverse Effects
Not determined
Waste Treatment Methods
Disposal of Waste Do not throw used container in fire. Disposal should be in accordance with local/state/national
regulations.
Contaminated Packaging Do not throw used container in fire. Disposal should be in accordance with local/state/national
regulations.
Chemical Name RCRA RCRA – Basis for Listing RCRA – D Series Wastes RCRA – U Series Wastes
Xylene 1330-20-7
Cumene
98-82-8
This product contains one or more substances that are listed with the State of California as a hazardous waste.
Chemical Name California Hazardous Waste Status
Xylene
1330-20-7
Cumene
98-82-8
Styrene
100-42-5
Included in waste stream: F039
Toxic Ignitable Toxic Ignitable Toxic Ignitable
U239
U055
Note Please see current shipping paper for most up to date shipping information, including exemptions and
special circumstances. This may be non-regulated in non-bulk packages for DOT ground only per 49 CFR 173.150(f)\
DOT
UN/ID No UN1993 Proper Shipping Name Flammable liquid, n.o.s (Light aromatic petroleum naphtha) Hazard Class 3 Packing Group III
IATA
UN/ID No UN1993 Proper Shipping Name Flammable liquid, n.o.s (Light aromatic petroleum naphtha) Hazard Class 3 Packing Group III
IMDG
UN/ID No UN1993 Proper Shipping Name Flammable liquid, n.o.s (Light aromatic petroleum naphtha) Hazard Class 3 Packing Group III
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Sure Seal 30 Clear Concrete Sealer Revision Date 4/15/2015
SECTION 15
:
REGULATORY
INFORMATION
International Inventories
TSCA Listed
Legend:
TSCA – United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELLINCS – European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS – Japan Existing and New Chemical Substances IECSC – China Inventory of Existing Chemical Substances KECL – Korean Existing and Evaluated Chemical Substances PICCS – Philippines Inventory of Chemicals and Chemical Substances
US Federal Regulations
CERCLA
Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ)
1330-20-7
Xylene
Cumene
98-82-8
Styrene
100-42-5
100 lb RQ 100 lb final RQ
RQ 45.4 kg final RQ
5000 lb RQ 5000 lb final RQ
RQ 2270 kg final RQ
1000 lb RQ 1000 lb final RQ
RQ 454 kg final RQ
SARA 311/312 Hazard Categories
Chronic Health Hazard Yes Fire Hazard Yes
SARA 313
Chemical Name CAS No Weight - % SARA 313 – Threshold
Xylene
1330-20-7
Cumene
98-82-8
Styrene
100-42-5
1330-20-7
98-82-8
100-42-5
5-25 1.0
0-2 1.0
0-2 1.0
1,2,4 Trimethylbenzene – 95-63-6 95-63-6 0.1 1.0
CWA (Clean Water Act)
Component CWA – Reportable
CWA – Toxic Pollutants CWA – Priority Pollutants CWA – Hazardous
Quantities
Xylene
1330-20-7
Styrene
100-42-5
100 lb X
1000 lb X
US State Regulations
California Proposition 65
This product contains the following Proposition 65 chemicals.
Values %
Substances
Chemical Name California Proposition 65
Cumene
98-82-8
Carcinogen
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Sure Seal 30 Clear Concrete Sealer Revision Date 4/15/2015
SECTION 16
:
OTHER INFORMATION
U.S. State Right-to-Know Regulations
Chemical Name New Jersey Massachusetts Pennsylvania
Xylene
1330-20-7
Cumene
98-82-8
Styrene
100-42-5
1,2,4 Trimethylbenzene
95-63-6
1,2,5 – Trimethylbenzene
108-67-8
NFPA Health Hazards Flammability Instability Special Hazards
2 2 0 Not determined
HMIS Health Hazards Flammability Instability Personal Protection
2 2 0 Not determined
Issue Date 16-Aug-2002 Last Revision Date 22-April-2015
X
X X X
X
X X
X X X
X
X X
Disclaimer/Statement of Liability:
The information in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. Perk Products Co. makes no warranty expressed or implied concerning this material except that it conforms to the description of this SDS. Neither Perk Products & Chemical Co, Inc., nor the seller shall be held responsible in any manner for personal injury or property damage, or other types of loss resulting from the handling, storage, or use of this product. The buyer assumes all risk.
End of Safety Data Sheet
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