Page 1
Safety Data Sheet
according to (EU) 2015 / 830 and OSHA GHS
Revision: February 9, 2016
SE CTION 1: Identification of the substance/mixture and of the company/
undertaking
·
1.1 Product identifier
·
Trade name: Super Lube® Fire Resistant Hydraulic Fluid
·
Article number:
·
1.2 Relevant identified uses of the substance or mixture and uses advised against
No further relevant information available.
·
Application of the substance / the mixture
·
1.3 Details of the supplier of the Safety Data Sheet
·
Manufacturer/Supplier:
Synco Chemical Corporation
24 DaVinci Dr., P.O. Box 405
Bohemia, NY 11716
Telephone: 631-567-5300
Email: info@super-lube.com
·
1.4 Emergency telephone number:
CHEMTREC
1-800-424-9300 (US/Canada)
+01 703-527-3887 (International)
No other identifiers
Hydraulic fluid
Page 1/12
SECTION 2: Hazards identification
·
2.1 Classification of the substance or mixture
·
Classification according to Regulation (EU) No 2015/830
Classificatio ns listed also are applicable to the OSHA GHS Ha zard Commun ication Standard
(29CFR1910.1200).
health hazard
STOT RE 2 H373 May cause damage to the kidneys through prolonged or repeated exposure. Route of
exposure: Oral.
corrosion
Eye Dam. 1 H318 Causes serious eye damage.
Skin Irrit. 2 H315 Causes skin irritation.
(Contd. on page 2)
40.1.5
Page 2
Safety Data Sheet
according to (EU) 2015 / 830 and OSHA GHS
Revision: February 9, 2016
Trade name: Super Lube® Fire Resistant Hydraulic Fluid
(Contd. of page 1)
·
Information concerning particular hazards for human and environment:
The product has to be labelled due to the calculation procedure of the "General Classification guideline for
preparations of the EU" in the latest valid version.
·
Classification system:
The classification is according to the latest editions of the EU-lists, and extended by company and
literature data.
The classification is in accordance with the latest editions of international substances lists, and is
supplemented by information from technical literature and by information provided by the company.
·
Additional information:
There are no other hazards not otherwise classified that have been identified.
0 percent of the mixture consists of component(s) of unknown toxicity
·
2.2 Label elements
·
Labelling according to Regulation (EC) No 1272/2008
The product is additionally classified and labelled according to the Globally Harmonized System within the
United States (GHS).
The product is classified and labelled according to the CLP regulation.
·
Hazard pictograms
Page 2/12
GHS05 GHS08
·
Signal word
·
Hazard-determining components of labelling:
Danger
ethanediol
2-dimethylaminoethanol
2,2'-oxybisethanol
·
Hazard statements
H315 Causes skin irritation.
H318 Causes serious eye damage.
H373 May cause damage to the kidneys through prolonged or repeated exposure. Route of exposure:
Oral.
·
Precautionary statements
P260 Do not breathe mist/vapours/spray.
P264 Wash thoroughly after handling.
P280 Wear protective gloves / eye protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P362 Take off contaminated clothing and wash before reuse.
P314 Get medical advice/attention if you feel unwell.
P302+P352 IF ON SKIN: Wash with plenty of water.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
(Contd. on page 3)
40.1.5
Page 3
Safety Data Sheet
according to (EU) 2015 / 830 and OSHA GHS
Trade name: Super Lube® Fire Resistant Hydraulic Fluid
·
Hazard description:
·
WHMIS-symbols:
D2A - Very toxic material causing other toxic effects
·
NFPA ratings (scale 0 - 4)
Health = 2
210
·
HMIS-ratings (scale 0 - 4)
Fire = 1
Reactivity = 0
Page 3/12
Revision: February 9, 2016
(Contd. of page 2)
HEALTH
FIRE
REACTIVITY
*2
Health = *2
1
Fire = 1
0
Reactivity = 0
* - Indicates a long term health hazard from repeated or prolonged exposures.
·
HMIS Long Term Health Hazard Substances
None of the ingredients are listed.
·
2.3 Other hazards
·
Results of PBT and vPvB assessment
·
PBT:
Not applicable.
·
vPvB:
Not applicable.
SECTION 3: Composition/information on ingredients
·
3.2 Mixtures
·
Description:
·
Dangerous components:
CAS: 107-21-1
EINECS: 203-473-3
Index number: 603-027-00-1
CAS: 111-46-6
EINECS: 203-872-2
Index number: 603-140-00-6
Mixture of substances listed below with nonhazardous additions.
ethanediol
STOT RE 2, H373
Acute Tox. 4, H302
2,2'-oxybisethanol
STOT RE 2, H373
Acute Tox. 4, H302
25-50%
10-25%
(
Contd. on page 4)
40.1.5
Page 4
Safety Data Sheet
according to (EU) 2015 / 830 and OSHA GHS
Trade name: Super Lube® Fire Resistant Hydraulic Fluid
CAS: 67762-36-1
EINECS: 267-013-3
Fatty acids, C6-C12
Skin Corr. 1C, H314; Eye Dam. 1, H318
Page 4/12
Revision: February 9, 2016
(Contd. of page 3)
2,5%
CAS: 108-01-0
EINECS: 203-542-8
Index number: 603-047-00-0
2-dimethylaminoethanol
Flam. Liq. 3, H226
Skin Corr. 1B, H314
2,5%
Acute Tox. 4, H302; Acute Tox. 4, H312; Acute Tox. 4, H332
·
Additional information:
For the listed ingredients, the identity and exact percentages are being withheld as a trade secret.
For the wording of the listed risk phrases refer to section 16.
SECTION 4: First aid measures
·
4.1 Description of first aid measures
·
General information:
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48
hours after the accident.
·
After inhalation:
·
After skin contact:
Immediately rinse with water.
If skin irritation continues, consult a doctor.
·
After eye contact:
Remove contact lenses if worn.
Rinse opened eye for several minutes under running water. Then consult a doctor.
·
After swallowing:
Rinse out mouth and then drink plenty of water.
Do not induce vomiting; call for medical help immediately.
·
4.2 Most important symptoms and effects, both acute and delayed
Irritant to skin and mucous membranes.
Strong irritant with the danger of severe eye injury.
·
Hazards
Causes serious eye damage.
May cause damage to the kidneys through prolonged or repeated exposure. Route of exposure: Oral.
May be harmful if inhaled.
·
4.3 Indication of any immediate medical attention and special treatment needed
Medical supervision for at least 48 hours.
Supply fresh air; consult doctor in case of complaints.
SECTION 5: Firefighting measures
·
5.1 Extinguishing media
·
Suitable extinguishing agents:
·
For safety reasons unsuitable extinguishing agents:
·
5.2 Special hazards arising from the substance or mixture
40.1.5
Use fire extinguishing methods suitable to surrounding conditions.
None.
No further relevant information available.
(Contd. on page 5)
Page 5
Safety Data Sheet
according to (EU) 2015 / 830 and OSHA GHS
Revision: February 9, 2016
Trade name: Super Lube® Fire Resistant Hydraulic Fluid
·
5.3 Advice for firefighters
·
Protective equipment:
Wear self-contained respiratory protective device.
Wear fully protective suit.
·
Additional information
SECTION 6: Accidental release measures
·
6.1 Personal precautions, protective equipment and emergency procedures
Ensure adequate ventilation
·
6.2 Environmental precautions:
·
6.3 Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Pick up mechanically.
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Send for recovery or disposal in suitable receptacles.
·
6.4 Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
No further relevant information available.
Do not allow to enter sewers/ surface or ground water.
Page 5/12
(Contd. of page 4)
SECTION 7: Handling and storage
·
7.1 Precautions for safe handling
Prevent formation of aerosols.
Use only in well ventilated areas.
·
Information about fire - and explosion protection:
·
7.2 Conditions for safe storage, including any incompatibilities
·
Storage:
·
Requirements to be met by storerooms and receptacles:
·
Information about storage in one common storage facility:
No special measures required.
No special requirements.
Store away from foodstuffs.
Store away from oxidising agents.
Do not store together with alkalis (caustic solutions).
Do not store together with oxidising and acidic materials.
·
Further information about storage conditions:
·
7.3 Specific end use(s)
No further relevant information available.
None.
SECTION 8: Exposure controls/personal protection
·
Additional information about design of technical facilities:
No further data; see item 7.
(Contd. on page 6)
40.1.5
Page 6
Safety Data Sheet
according to (EU) 2015 / 830 and OSHA GHS
Trade name: Super Lube® Fire Resistant Hydraulic Fluid
·
8.1 Control parameters
·
Ingredients with limit values that require monitoring at the workplace:
107-21-1 ethanediol
IOELV (EU) Short-term value: 104 mg/m³, 40 ppm
Long-term value: 52 mg/m³, 20 ppm
Skin
TLV (USA) Long-term value: NIC-10* mg/m³
Ceiling limit: (100) mg/m³
(H);*as inhalable fraction and vapor
EL (Canada) Short-term value: 20** mg/m³
Long-term value: 10** mg/m³
Ceiling limit: 100* mg/m³, 50*** ppm
*Aerosol; **Particulate; ***Vapour
EV (Canada) Ceiling limit: 100 mg/m³
111-46-6 2,2'-oxybisethanol
WEEL (USA) Long-term value: 10 mg/m³
108-01-0 2-dimethylaminoethanol
EV (Canada) Short-term value: 22 mg/m³, 6 ppm
Long-term value: 11 mg/m³, 3 ppm
·
DNELs
·
PNECs
·
Additional information:
·
8.2 Exposure controls
·
Personal protective equipment:
·
General protective and hygienic measures:
The usual precautionary measures are to be adhered to when handling chemicals.
Keep away from foodstuffs, beverages and feed.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
·
Respiratory protection:
Not required under normal conditions of use.
For spills, respiratory protection may be advisable.
·
Protection of hands:
No further relevant information available.
No further relevant information available.
The lists valid during the making were used as basis.
Page 6/12
Revision: February 9, 2016
(Contd. of page 5)
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation.
·
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of
quality and varies from manufacturer to manufacturer. As the product is a prepar ation of several
substances, the resistance of the glove material can not be calculated in advance and has therefore to be
checked prior to the application.
(Contd. on page 7)
40.1.5
Page 7
Safety Data Sheet
according to (EU) 2015 / 830 and OSHA GHS
Revision: February 9, 2016
Trade name: Super Lube® Fire Resistant Hydraulic Fluid
(Contd. of page 6)
·
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to
be observed.
·
Eye protection:
Contact lenses should not be worn.
Safety glasses
·
Body protection:
·
Limitation and supervision of exposure into the environment
No further relevant information available.
SECTION 9: Physical and chemical properties
Protective work clothing
Page 7/12
·
9.1 Information on basic physical and chemical properties
·
General Information
·
Appearance:
Form:
Colour:
·
Odour:
·
Odour threshold:
·
pH-value at 20 °C (68 °F):
·
Change in condition
Melting point/Melting range:
Boiling point/Boiling range:
·
Flash point:
·
Flammability (solid, gaseous):
·
Auto/Self-ignition temperature:
·
Decomposition temperature:
·
Self-igniting:
·
Danger of explosion:
·
Explosion limits:
Lower:
Upper:
·
Vapour pressure:
·
Density at 20 °C (68 °F):
·
Relative density
·
Vapour density
·
Evaporation rate
Liquid
Red
Mild
Not determined.
9,2
Not Determined.
>100 °C (>212 °F)
Not applicable.
Not applicable.
Not determined.
Not determined.
Product is not self-igniting.
Product does not present an explosion hazard.
Not determined.
Not determined.
Not determined.
1 g/cm³ (8,345 lbs/gal)
Not determined.
Not determined.
Not determined.
(Contd. on page 8)
40.1.5
Page 8
Safety Data Sheet
according to (EU) 2015 / 830 and OSHA GHS
Trade name: Super Lube® Fire Resistant Hydraulic Fluid
·
Solubility in / Miscibility with
water:
·
Partition coefficient (n-octanol/water):
·
Viscosity:
Dynamic:
Kinematic:
·
9.2 Other information
SECTION 10: Stability and reactivity
·
10.1 Reactivity
·
10.2 Chemical stability
·
Thermal decomposition / conditions to be avoided:
No decomposition if used and stored according to specifications.
·
10.3 Possibility of hazardous reactions
Reacts with strong alkali.
Reacts with strong acids and oxidising agents.
·
10.4 Conditions to avoid
·
10.5 Incompatible materials:
·
10.6 Hazardous decomposition products:
Carbon monoxide and carbon dioxide
Nitrogen oxides
No further relevant information available.
No further relevant information available.
Fully miscible.
Not determined.
Not determined.
Not determined.
No further relevant information available.
Page 8/12
Revision: February 9, 2016
(Contd. of page 7)
SECTION 11: Toxicological information
·
11.1 Information on toxicological effects
·
Acute toxicity:
·
LD/LC50 values relevant for classification:
107-21-1 ethanediol
Oral LD50 5840 mg/kg (rat)
Dermal LD50 9530 mg/kg (rabbit)
111-46-6 2,2'-oxybisethanol
Oral LD50 12565 mg/kg (rat)
Dermal LD50 11890 mg/kg (rabbit)
·
Primary irritant effect:
·
on the skin:
·
on the eye:
·
Sensitisation:
·
Subacute to chronic toxicity:
May cause damage to the kidneys through prolonged or repeated exposure. Route of exposure: Oral.
·
Additional toxicological information:
The product shows the following dangers according to the calculation m ethod of the General EU
Classification Guidelines for Preparations as issued in the latest version:
Irritant to skin and mucous membranes.
Strong irritant with the danger of severe eye injury.
No sensitising effects known.
(Contd. on page 9)
40.1.5
Page 9
Safety Data Sheet
according to (EU) 2015 / 830 and OSHA GHS
Revision: February 9, 2016
Trade name: Super Lube® Fire Resistant Hydraulic Fluid
(Contd. of page 8)
Harmful
Toxic and/or corrosive effects may be delayed up to 24 hours.
·
Acute effects (acute toxicity, irritation and corrosivity):
Irritating to skin.
Causes serious eye damage.
·
Repeated dose toxicity:
May cause damage to the kidneys through prolonged or repeated exposure. Route of exposure: Oral.
·
CMR effects (carcinogenity, mutagenicity and toxicity for reproduction):
SECTION 12: Ecological information
·
12.1 Toxicity
·
Aquatic toxicity:
·
12.2 Persistence and degradability
·
12.3 Bioaccumulative potential
·
12.4 Mobility in soil
·
Additional ecological information:
·
General notes:
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage
system.
Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water
·
12.5 Results of PBT and vPvB assessment
·
PBT:
Not applicable.
·
vPvB:
·
12.6 Other adverse effects
Not applicable.
No further relevant information available.
No further relevant information available.
No further relevant information available.
No further relevant information available.
No further relevant information available.
See Section 15.
Page 9/12
SECTION 13: Disposal considerations
·
13.1 Waste treatment methods
·
Recommendation
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
The user of this material has the responsibility to dispose of unused material, residues and containers in
compliance with all relevant local, state and federal laws and regulations regarding treatment, storage and
disposal for hazardous and nonhazardous wastes. Residual materials should be treated as hazardous.
·
Uncleaned packaging:
·
Recommendation:
·
Recommended cleansing agents:
Disposal must be made according to official regulations.
Water, if necessary together with cleansing agents.
SECTION 14: Transport information
·
14.1 UN-Number
·
DOT, ADR, ADN, IMDG, IATA
·
14.2 UN proper shipping name
·
DOT, ADR, ADN, IMDG, IATA
Not Regulated
Not Regulated
(Contd. on page 10)
40.1.5
Page 10
Safety Data Sheet
according to (EU) 2015 / 830 and OSHA GHS
Trade name: Super Lube® Fire Resistant Hydraulic Fluid
·
14.3 Transport hazard class(es)
·
DOT, ADR, ADN, IMDG, IATA
·
Class
·
14.4 Packing group
·
DOT, ADR, IMDG, IATA
·
14.5 Environmental hazards:
·
Marine pollutant:
·
14.6 Special precautions for user
·
14.7 Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code
·
UN "Model Regulation":
SECTION 15: Regulatory information
Not Regulated
Not Regulated
No
Not applicable.
Not applicable.
-
Page 10/12
Revision: February 9, 2016
(Contd. of page 9)
·
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
·
United States (USA)
·
SARA
·
Section 355 (extremely hazardous substances):
None of the ingredients are listed.
·
Section 313 (Specific toxic chemical listings):
107-21-1 ethanediol
·
TSCA (Toxic Substances Control Act):
All ingredients are listed.
·
Proposition 65 (California):
·
Chemicals known to cause cancer:
None of the ingredients is listed.
·
Chemicals known to cause reproductive toxicity for females:
None of the ingredients are listed.
·
Chemicals known to cause reproductive toxicity for males:
None of the ingredients are listed.
·
Chemicals known to cause developmental toxicity:
None of the ingredients are listed.
·
Carcinogenic Categories
·
EPA (Environmental Protection Agency)
None of the ingredients are listed.
·
IARC (International Agency for Research on Cancer)
None of the ingredients are listed.
·
TLV (Threshold Limit Value established by ACGIH)
107-21-1 ethanediol A4
(Contd. on page 11)
40.1.5
Page 11
Page 11/12
Safety Data Sheet
according to (EU) 2015 / 830 and OSHA GHS
Revision: February 9, 2016
Trade name: Super Lube® Fire Resistant Hydraulic Fluid
(Contd. of page 10)
·
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients are listed.
·
Canada
·
Canadian Domestic Substances List (DSL)
All ingredients are listed.
·
Canadian Ingredient Disclosure list (limit 0.1%)
None of the ingredients are listed.
·
Canadian Ingredient Disclosure list (limit 1%)
107-21-1 ethanediol
·
Other regulations, limitations and prohibitive regulations
This product has been classified in accordance with hazard criteria of the Controlled Products Regulations
and the SDS contains all the information required by the Controlled Products Regulations.
·
Substances of very high concern (SVHC) according to REACH, Article 57
None of the ingredients are listed.
·
15.2 Chemical safety assessment:
A Chemical Safety Assessment has not been carried out.
SECTION 16: Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
Relevant phrases
·
H226
H302
H312
H314
H318
H332
H373
·
Abbreviations and acronyms:
ADR: Accord européen sur le t ransport des marchandises dangereuses par Route (European Agreement concerning the
International Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
Flammable liquid and vapour.
Harmful if swallowed.
Harmful in contact with skin.
Causes severe skin burns and eye damage.
Causes serious eye damage.
Harmful if inhaled.
May caus e damage to the kidneys through prolonged or repeated exposure. Route of
exposure: Oral.
(Contd. on page 12)
40.1.5
Page 12
Safety Data Sheet
according to (EU) 2015 / 830 and OSHA GHS
Trade name: Super Lube® Fire Resistant Hydraulic Fluid
Page 12/12
Revision: February 9, 2016
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
HMIS: Hazardous Materials Identification System (USA)
WHMIS: Workplace Hazardous Materials Information System (Canada)
DNEL: Derived No-Effect Level (REACH)
PNEC: Predicted No-Effect Concentration (REACH)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
Flam. Liq. 3: Flammable liquids, Hazard Category 3
Acute Tox. 4: Acute toxicity, Hazard Category 4
Skin Corr. 1B: Skin corrosion/irritation, Hazard Category 1B
Skin Corr. 1C: Skin corrosion/irritation, Hazard Category 1C
Skin Irrit. 2: Skin corrosion/irritation, Hazard Category 2
Eye Dam. 1: Serious eye damage/eye irritation, Hazard Category 1
STOT RE 2: Specific target organ toxicity - Repeated exposure, Hazard Category 2
·
Sources
SDS Prepared by:
ChemTel Inc.
1305 North Florida Avenue
Tampa, Florida USA 33602-2902
Toll Free North America 1-888-255-3924 Intl. +01 813-248-0573
Website: www.chemtelinc.com
(Contd. of page 11)
40.1.5
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