Classification according to Regulation (EU) No 2015/830
·
Classifications lis ted also are applica ble to the OSHA GHS Ha zard Communication Standard
(29CFR1910.1200).
health hazard
Asp. Tox. 1 H304 May be fatal if swallowed and enters airways.
·
Information concerning particular hazards for human and environment:
The product has to be labelled due to the calculation procedure of the "General Classification guideline for
preparations of the EU" in the latest valid version.
·
Classification system:
The classification is according to the latest editions of the EU-lists, and extended by company and
literature data.
The classification is in accordance with the latest editions of international substances lists, and is
supplemented by information from technical literature and by information provided by the company.
(Contd. on page 2)
40.1.3
Page 2
Safety Data Sheet
according to (EU) 2015 / 830 and OSHA GHS
Revision: February 15, 2016
Trade name: Super Lube® Syncopen® Synthetic Penetrant
(Contd. of page 1)
·
2.2 Label elements
·
Labelling according to Regulation (EC) No 1272/2008
The substance is classified and labelled according to the Globally Harmonized System within the United
States (GHS).
The product is classified and labelled according to the CLP regulation.
·
Hazard pictograms
GHS08
·
Signal word
·
Hazard-determining components of labelling:
Distillates (petroleum), hydrotreated light
·
Hazard statements
H304 May be fatal if swallowed and enters airways.
·
Precautionary statements
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor.
P331Do NOT induce vomiting.
P501Dispose of contents/container in accordance with local/regional/national/international
·
Hazard description:
·
WHMIS-symbols:
·
NFPA ratings (scale 0 - 4)
010
Danger
regulations.
Not hazardous under WHMIS.
Health = 0
Fire = 1
Reactivity = 0
Page 2/11
·
HMIS-ratings (scale 0 - 4)
HEALTH
FIRE
REACTIVITY
·
HMIS Long Term Health Hazard Substances
0
Health = 0
1
Fire = 1
0
Reactivity = 0
None of the ingredients are listed.
·
2.3 Other hazards
·
Results of PBT and vPvB assessment
·
PBT:
Not applicable.
·
vPvB:
Not applicable.
SECTION 3: Composition/information on ingredients
·
3.2 Mixtures
·
Description:
Mixture of substances listed below with nonhazardous additions.
(Contd. on page 3)
40.1.3
Page 3
Safety Data Sheet
according to (EU) 2015 / 830 and OSHA GHS
Revision: February 15, 2016
Trade name: Super Lube® Syncopen® Synthetic Penetrant
·
Dangerous components:
CAS: 64742-47-8
EINECS: 265-149-8
Index number: 649-422-00-2
·
ditional information:
Ad
For the listed ingredients, the identity and exact percentages are being withheld as a trade secret.
For the wording of the listed risk phrases refer to section 16.
SECTION 4: First aid measures
·
4.1 Description of first aid measures
·
General information:
Take affected persons out into the fresh air.
Immediately remove any clothing soiled by the product.
·
After inhalation:
Supply fresh air.
Seek immediate medical advice.
Provide oxygen treatment if affected person has difficulty breathing.
In case of unconsciousness place patient stably in side position for transportation.
·
After skin contact:
Immediately wash with water and soap and rinse thoroughly.
If skin irritation is experienced, consult a doctor.
·
After eye contact:
Remove contact lenses if worn.
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
·
After swallowing:
Rinse out mouth and then drink plenty of water.
Do not induce vomiting; call for medical help immediately.
A person vomiting while laying on their back should be turned onto their side.
·
4.2 Most important symptoms and effects, both acute and delayed
Danger of pulmonary oedema.
Danger of pneumonia.
Danger of impaired breathing.
·
4.3 Indication of any immediate medical attention and special treatment needed
If swallowed, gastric irrigation with added, activated carbon.
If swallowed or in case of vomiting, danger of entering the lungs.
Medical supervision for at least 48 hours.
If necessary oxygen respiration treatment.
Distillates (petroleum), hydrotreated light
Asp. Tox. 1, H304
Page 3/11
(Contd. of page 2)
>50%
(Contd. on page 4)
40.1.3
Page 4
Safety Data Sheet
according to (EU) 2015 / 830 and OSHA GHS
Trade name: Super Lube® Syncopen® Synthetic Penetrant
Later observation for pneumonia and pulmonary oedema.
SECTION 5: Firefighting measures
·
5.1 Extinguishing media
·
Suitable extinguishing agents:
Extinguishing powder. Do not use water.
Carbon dioxide
Foam
·
For safety reasons unsuitable extinguishing agents:
·
5.2 Special hazards arising from the substance or mixture
Formation of toxic gases is possible during heating or in case of fire.
6.1 Personal precautions, protective equipment and emergency procedures
Use respiratory protective device against the effects of fumes/dust/aerosol.
Remove persons from danger area.
Particular danger of slipping on leaked/spilled product.
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Keep away from ignition sources.
·
6.2 Environmental precautions:
Do not allow product to reach sewage system or any water course.
Inform respective authorities in case of seepage into water course or sewage system.
·
6.3 Methods and material for containment and cleaning up:
Absorb with non-combustible liquid-binding material (sand, diatomite, acid binders, universal binders).
Pick up mechanically.
Send for recovery or disposal in suitable receptacles.
Dispose contaminated material as waste according to item 13.
·
6.4 Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
SECTION 7: Handling and storage
·
7.1 Precautions for safe handling
Keep away from heat and direct sunlight.
Avoid splashes or spray in enclosed areas.
Prevent formation of aerosols.
(Contd. on page 5)
40.1.3
Page 5
Safety Data Sheet
according to (EU) 2015 / 830 and OSHA GHS
Trade name: Super Lube® Syncopen® Synthetic Penetrant
Use only in well ventilated areas.
·
Information about fire - and explosion protection:
·
7.2 Conditions for safe storage, including any incompatibilities
·
Storage:
·
Requirements to be met by storerooms and receptacles:
Provide ventilation for receptacles.
Avoid storage near extreme heat, ignition sources or open flame.
·
Information about storage in one common storage facility:
Do not store together with oxidising and acidic materials.
Store away from foodstuffs.
·
Further information about storage conditions:
Store in cool, dry conditions in well sealed receptacles.
Keep container tightly sealed.
·
7.3 Specific end use(s)
No further relevant information available.
Protect from heat.
Page 5/11
Revision: February 15, 2016
(Contd. of page 4)
SECTION 8: Exposure controls/personal protection
·
Additional information about design of technical facilities:
·
8.1 Control parameters
·
Ingredients with limit values that require monitoring at the workplace:
64742-47-8 Distillates (petroleum), hydrotreated light
EL (Canada) Long-term value: 200 mg/m³
Skin
·
DNELs
·
PNECs
·
Additional information:
·
8.2 Exposure controls
·
Personal protective equipment:
·
General protective and hygienic measures:
No further relevant information available.
No further relevant information available.
The lists valid during the making were used as basis.
The usual precautionary measures are to be adhered to when handling chemicals.
Keep away from foodstuffs, beverages and feed.
Wash hands before breaks and at the end of work.
Do not inhale gases / fumes / aerosols.
Avoid close or long term contact with the skin.
Avoid contact with the eyes.
·
Respiratory protection:
Not required under normal conditions of use.
Use suitable respiratory protective device in case of insufficient ventilation.
Use suitable respiratory protective device when aerosol or mist is formed.
For spills, respiratory protection may be advisable.
·
Protection of hands:
No further data; see item 7.
Protective gloves
(Contd. on page 6)
40.1.3
Page 6
Safety Data Sheet
according to (EU) 2015 / 830 and OSHA GHS
Revision: February 15, 2016
Trade name: Super Lube® Syncopen® Synthetic Penetrant
(Contd. of page 5)
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the
preparation/ the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation.
·
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of
quality and varies from manufacturer to manufacturer. As the product is a preparation of several
substances, the resistance of the glove material can not be calculated in advance and has therefore to be
checked prior to the application.
·
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to
be observed.
·
For the permanent contact gloves made of the following materials are suitable:
Not determined.
Not determined.
No further relevant information available.
Page 7/11
Revision: February 15, 2016
(Contd. of page 6)
SECTION 10: Stability and reactivity
·
10.1 Reactivity
·
10.2 Chemical stability
·
Thermal decomposition / conditions to be avoided:
No decomposition if used and stored according to specifications.
·
10.3 Possibility of hazardous reactions
Reacts with strong acids.
Reacts with strong oxidising agents.
Can form explosive mixtures in air if heated above flash point and/or when sprayed or atomised.
Used empty containers may contain product gases which form explosive mixtures with air.
Toxic fumes may be released if heated above the decomposition point.
·
10.4 Conditions to avoid
Keep away from heat and direct sunlight.
Store away from oxidising agents.
·
10.5 Incompatible materials:
·
10.6 Hazardous decomposition products:
Carbon monoxide and carbon dioxide
Hydrocarbons
No further relevant information available.
(Contd. on page 8)
40.1.3
Page 8
Safety Data Sheet
according to (EU) 2015 / 830 and OSHA GHS
Revision: February 15, 2016
Trade name: Super Lube® Syncopen® Synthetic Penetrant
(Contd. of page 7)
SECTION 11: Toxicological information
·
11.1 Information on toxicological effects
·
Acute toxicity:
·
LD/LC50 values relevant for classification:
64742-47-8 Distillates (petroleum), hydrotreated light
Oral LD50 > 5000 mg/kg (rat)
·
Primary irritant effect:
·
on the skin:
·
on the eye:
·
Additional toxicological information:
At long or repeated contact with skin it may cause dermatitis due to the degreasing effect of the solvent.
The product shows the following dangers according to the calculation method of the General EU
Classification Guidelines for Preparations as issued in the latest version:
·
Acute effects (acute toxicity, irritation and corrosivity):
May be fatal if swallowed and enters airways.
May be harmful if swallowed.
·
Repeated dose toxicity:
Repeated exposure may cause skin dryness or cracking.
May cause damage to organs through prolonged or repeated exposure.
No irritant effect.
Slight irritant effect on eyes.
Page 8/11
SECTION 12: Ecological information
·
12.1 Toxicity
·
Aquatic toxicity:
·
12.2 Persistence and degradability
·
12.3 Bioaccumulative potential
·
12.4 Mobility in soil
·
Ecotoxical effects:
·
Remark:
Due to mechanical actions of the product (e.g. agglutinations) damages may occur.
The product is oxygen-consuming. The declared action may be partly caused by lack of oxygen.
·
Additional ecological information:
·
General notes:
This statement was deduced from the properties of the single components.
Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage
system.
·
12.5 Results of PBT and vPvB assessment
·
PBT:
Not applicable.
·
vPvB:
·
12.6 Other adverse effects
Not applicable.
No further relevant information available.
No further relevant information available.
No further relevant information available.
No further relevant information available.
No further relevant information available.
(Contd. on page 9)
40.1.3
Page 9
Safety Data Sheet
according to (EU) 2015 / 830 and OSHA GHS
Revision: February 15, 2016
Trade name: Super Lube® Syncopen® Synthetic Penetrant
(Contd. of page 8)
SECTION 13: Disposal considerations
·
13.1 Waste treatment methods
·
Recommendation
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
Contact waste processors for recycling information.
Product is recyclable as a waste oil. Deliver unused and/or contaminated product to waste oil collectors.
Can be burned with household garbage after consulting with the waste disposal facility operator and the
pertinent authorities and adhering to the necessary technical regulations.
·
Uncleaned packaging:
·
Recommendation:
SECTION 14: Transport information
Disposal must be made according to official regulations.
Page 9/11
·
14.1 UN-Number
·
DOT, ADR, ADN, IMDG, IATA
·
14.2 UN proper shipping name
·
DOT, ADR, ADN, IMDG, IATA
·
14.3 Transport hazard class(es)
·
DOT, ADR, ADN, IMDG, IATA
·
Class
·
14.4 Packing group
·
DOT, ADR, IMDG, IATA
·
14.5 Environmental hazards:
·
Marine pollutant:
·
14.6 Special precautions for user
·
14.7 Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code
·
UN "Model Regulation":
Not Regulated
Not Regulated
Not Regulated
Not Regulated
No
Not applicable.
Not applicable.
-
SECTION 15: Regulatory information
·
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
·
United States (USA)
·
SARA
·
Section 355 (extremely hazardous substances):
None of the ingredients are listed.
·
Section 313 (Specific toxic chemical listings):
None of the ingredients are listed.
·
TSCA (Toxic Substances Control Act):
All ingredients are listed.
(Contd. on page 10)
40.1.3
Page 10
Safety Data Sheet
according to (EU) 2015 / 830 and OSHA GHS
Trade name: Super Lube® Syncopen® Synthetic Penetrant
·
Proposition 65 (California):
·
Chemicals known to cause cancer:
None of the ingredients is listed.
·
Chemicals known to cause reproductive toxicity for females:
None of the ingredients are listed.
·
Chemicals known to cause reproductive toxicity for males:
None of the ingredients are listed.
·
Chemicals known to cause developmental toxicity:
None of the ingredients are listed.
·
Carcinogenic Categories
·
EPA (Environmental Protection Agency)
None of the ingredients are listed.
·
IARC (International Agency for Research on Cancer)
None of the ingredients are listed.
·
TLV (Threshold Limit Value established by ACGIH)
None of the ingredients are listed.
·
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients are listed.
·
Canada
·
Canadian Domestic Substances List (DSL)
All ingredients are listed.
·
Canadian Ingredient Disclosure list (limit 0.1%)
None of the ingredients are listed.
·
Canadian Ingredient Disclosure list (limit 1%)
None of the ingredients are listed.
Page 10/11
Revision: February 15, 2016
(Contd. of page 9)
·
Other regulations, limitations and prohibitive regulations
This product has been classified in accordance with hazard criteria of the Controlled Products Regulations
and the SDS contains all the information required by the Controlled Products Regulations.
·
Substances of very high concern (SVHC) according to REACH, Article 57
None of the ingredients are listed.
·
15.2 Chemical safety assessment:
A Chemical Safety Assessment has not been carried out.
SECTION 16: Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
·
Relevant phrases
H304 May be fatal if swallowed and enters airways.
40.1.3
(Contd. on page 11)
Page 11
Page 11/11
Safety Data Sheet
according to (EU) 2015 / 830 and OSHA GHS
Revision: February 15, 2016
Trade name: Super Lube® Syncopen® Synthetic Penetrant
(Contd. of page 10)
·
Abbreviations and acronyms:
ADR: Accord européen sur le transport des m archandises dangereuses par Route (Eu ropean Agreem ent concerning the
International Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
WHMIS: Workplace Hazardous Materials Information System (Canada)
DNEL: Derived No-Effect Level (REACH)
PNEC: Predicted No-Effect Concentration (REACH)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
Asp. Tox. 1: Aspiration hazard, Hazard Category 1
·
Sources
SDS Prepared by:
ChemTel Inc.
1305 North Florida Avenue
Tampa, Florida USA 33602-2902
Toll Free North America 1-888-255-3924 Intl. +01 813-248-0573
Website: www.chemtelinc.com
40.1.3
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