Superior Abrasives 11133 User Manual

SAFETY DATA SHEET (SDS)
Coated Abrasives
Revision Date: 1/2/2019 Version: 1
Product Identifier
Date of Print: 1/17/2019
Page: 1 of 14
1. Product and Company Identification
Trade Name:
Relevant identified uses of the substance or mixture and uses adivsed against:
General Use:
Grinding and sanding of different kinds of materials. For industrial purposes only.
Details of the supplier of the Safety Data Sheet
Company Name:
Superior Abrasives, LLC 1620 Fieldstone Way Vandalia, Ohio 45377 USA www.superiorabrasives.com email: SDS@superiorabrasives.com Telephone: 1-800-235-9123
Local Tel: 937-278-9123 Fax: 937-278-7581
Emergency overview
Appearance:
Odor:
Classification:
Hazard symbols:
Signal word:
Hazard statements:
2. Hazards Identification
Form: solid Color: varying colors No data availabe Eye Irritation 2A; Carcinogenicity 1A; Toxic to Reproduction (Lactation): Specific Target Organ Toxicity (repeated exposure) 1; Aquatic Toxicity - chronic 3
Danger
Causes serious eye irritation. May cause cancer. May cause harm to breast-fed children. Causes damage to organs through prolonged or repeated exposure. Harmful to aquatic life with long lasting effects.
SAFETY DATA SHEET (SDS)
Coated Abrasives
Revision Date: 1/2/2019 Version: 1
Precautionary statements: Obtain special instructions before use.
Do not breathe dust/fume/gas/mist/vapors/spray. Avoid contact during pregnancy/while nursing. Wash hands and face thoroughly after handling. Do not eat, drink or smoke when using this product. Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or concerned: Get medical adivice/attention. If eye irritation persists: Get medical advise/attention. Store locked up. Dispose of contents/container to hazardous or special waste collection point.
additional information: The hazard identification is based on a formalistic procedure as the hazard statements of
the ingredients are summarized under section 3. This does not correspond to the hazardousness of the product itself. A greater hazard, in most cases, is the exposure to the dust/fumes from the material or paint/coatings being ground. Most of the dust generated during grinding is from the base material being ground and the potential hazard from this exposure must be evaluated. This dust may present a fire or dust explosion hazard and may present a serious health hazard.
Date of Print: 1/17/2019
Page: 2 of 14
Regulatory status
This matrial is considered hazardous by the U.S. OSHA Hazard Communication Standard (29 CFR 1910.1200) and SIMDUT in Canada.
Hazards not otherwise cassified
Processing, e.g. by cutting, sawing or grinding, can produce particles and dust. Inhalation of dust may cause irritation of the respiratory system. Dust may irritate eyes.
See section 11: Toxicological information
Chemical Characterisation:
Relevant ingredients:
CAS No.
CAS 1344-28-1 Aluminium oxide < 70% Not applicable CAS - Vulcanized fiber < 70% Not applicable CAS 409-21-2 Silicon carbide < 60% Not applicable CAS - Cotton cloth < 60% Not applicable CAS - Polyester cloth < 55% Not applicable CAS - Paper < 50% Not applicable CAS 65997-17-3 Fibre glass weaves < 45% Not applicable CAS - Polyamide compound < 45% Not applicable CAS - Synthetic resin, polymerized < 40% Not applicable CAS - Cotton-Polyester cloth < 40% Not applicable CAS 1314-23-4 Zirconium dioxide < 30% Not applicable CAS - Adhesive, cured < 30% Not applicable CAS 471-34-1 Calcium carbonate < 25% Not applicable CAS 60304-36-1 Aluminum potassium fluoride < 25%
Components in synthetic resin, completely embedded.
3. Composition / Information on Ingredients
Designation Content Classification
Acute Toxicity 4 (inhalative). Eye Irritation 2A. Toxic to Reproduction (Lactation). Specific Target Organ Toxicity (Repeated Exposure) 1. Aquatic Toxicity - Chronic 3.
CAS 14075-53-7 Potassium tetrafluoroborate < 20% Not applicable
SAFETY DATA SHEET (SDS)
Coated Abrasives
Revision Date: 1/2/2019 Version: 1
Date of Print: 1/17/2019
Page: 3 of 14
CAS 13775-53-6 < 20%
CAS - Velcro fabric < 20% Not applicable CAS 25038-36-2 EPDM < 15% Not applicable CAS 1332-58-7 Kaolin < 15% Not applicable CAS - Rubber, vulcanized < 10% Not applicable CAS 13463-67-7 Titanium dioxide < 5% Carcinogenicity 2 CAS 1309-37-1 Diiron trioxide < 5% Not applicable CAS - Adhesive tape < 5% Not applicable CAS 1345-25-1 Iron (II) oxide < 1% Not applicable CAS 7631-86-9 Silicon dioxide < 1% Not applicable CAS 1309-48-4 Magnesium oxide <0.5% Not applicable CAS 1305-78-8 Calcium oxide <0.5%
CAS 14808-60-7 Quartz (SiO2) <0.5% Carcinogenicity 1A CAS 1333-86-4 Carbon black <0.5% Not applicable CAS 12055-23-1 Hafnium dioxide <0.4% Not applicable CAS 50-00-0 Formaldehyde <0.1% Acute Toxicity 3 (oral)
Trisodium hexafluoroaluminate (cryolite)
Acute Toxicity 4 (inhalative). Toxic to Reproduction (Lactation). Specific Target Organ Toxicity (Repeated Exposure) 1. Aquatic Toxicity - Chronic 2.
Skin Irritation 2. Eye Damage 1. Specific Target Organ Toxicity (Single Exposure) 3.
Acute Toxicity 3 (dermal) Acute Toxicity 3 (inhalative) Skin Corrosion 1B. Sensitization-skin 1. Germ cell mutagenicity 2 Carcinogenicity 1B
Additional information: The ingredients are embedded in the product.
The components listed above do not represent/include the chemical composition of the Hub.
4. First Aid Measures
Incaseofinhalation: Provide fresh air. If you feel unwell , seek medical adivce.
Followingskincontact: Remove residue with soap and water. In case of skin reactions, consult a physician.
Aftereyecontact: Immediately flush eyes with plenty of flowing water for 10 to 15 minutes holding eyelids apart.
Remove contact lenses, if present and easy to do. Continue rinsing. In case of eye irritation consult an ophthalmologist.
Afterswallowing: Rinse mouth with water. Give water to drink in small sips. If you feel unwell, seek medical advice.
Mostimportantsymptomsandeffects,bothacuteanddelayed
Causes serious eye irritation. Causes damage to organs through prolonged or repeated exposure.
Informationtophysician Treat Symptomatically.
SAFETY DATA SHEET (SDS)
Coated Abrasives
Revision Date: 1/2/2019 Version: 1
Flash point/Flash point range:
Auto-ignition Temperature:
Suitable extinguishing media:
Specific hazards arising from the chemical:
Protective equipment and precautions for firefighters:
Wear a self-contained breathing apparatus and chemical protective clothing.
Additional information
Do not allow fire water to penetrate into surface or ground water.
Personal precautions:
Avoid exposure. Avoid generation of dust. Do not inhale substance. In case of heating: Development of gas/vapor possible. Provide adequate ventilation. Wear appropriate protective equipment Avoid contact with the substance. Keep unprotected people away.
Environmental precautions:
Do not allow to penetrate into soil, waterbodies or drains. In case of release, notify competent authorities.
Methods for clean up:
Take up mechanically, placing in appropriate containers for disposal
No data availabe No data availabe Product is non-combustible. Extinguishing material should therefore be selected according to surroundings.
Can be released in case of fire: Hydrogen fluoride, boron compounds, carbon monoxide, and carbon dioxide (CO2).
Date of Print: 1/17/2019
Page: 4 of 14
5. Fire Fighting Measures
6. Accidental Release Measures
Handling
Advice on safe handlling:
Provide adequate ventilation, and local exhaust as needed. Avoid generation of dust. In case of heating: Development of gas/vapor possible. Do not inhale substance. Wear appropriate protective equipment. Avoid contact with the substance. Obtain special instructions before use. Work place should be equipped with a shower and an eye rinsing apparatus.
Storage
Requirements for storerooms and containers:
Keep container tightly closed and dry. Keep in cool, well-ventilated place.
Hints on joint storage:
Do not store together with oxidizing agents or acids. Do not store together wih food.
7. Handling and Storage
SAFETY DATA SHEET (SDS)
e
g
g
)
g
)
g
)
)
g
g
)
g
g
)
g
g
g
)
g
)
g
)
g
)
g
)
g
)
g
g
g
g
Coated Abrasives
Revision Date: 1/2/2019 Version: 1
8. Exposure Control / Personal Protection
Exposure guidelines
Occupational exposure limit values:
CAS NO.
1334-28-1 Aluminium oxide Canada, Alberta: OEL 8 hour
409-21-2 Silicon carbide Canada, Alberta: OEL 8 hour
Designation Typ
Canada. Quebec: VEMP USA: OSHA: TWA USA: OSHA: TWA
Canada, Alberta: OEL 8 hour
Canada, Alberta: OEL 8 hour
Canada BC: OEL TWA Canada BC: OEL TWA
Canada BC; OEL TWA
Canada Ontario; OEL TWA Canada Ontario; OEL TWA
Canada, Ontario: OEL TWA
Canada, Quebec: VEMP
USA: ACGIH: TWA USA: ACGIH: TWA USA: ACGIH: TWA USA: NIOSH: TWA USA: NIOSH: TWA USA: OSHA: TWA
USA: OSHA: TWA
Date of Print: 1/17/2019
Limit Value
10 m 10 m 15 m 5m
0.1 fibers/cm 10m
3
/m /m3 (inhalable fraction /m3 (inhalable fraction
/m3 (respirable fraction
3
(fibers, inhalable fraction
3
/m
(contains no fibers, inhalable fraction)
3
3 m
/m
(contains no fibers, respirable fraction)
0.1 fibers/cm 10 m
3
(fibers,inhalable fraction
3
/m
(Contains no fibers, inhalable fraction)
3
3m
/m
(Contains no fibers, respirable fraction)
0.1 fibers/cm 10 m
3
(fibers, inhalable fraction
3
/m
(Contains no fibers, inhalable fraction)
3
3m
/m
(Contains no fibers, respirable fraction)
/m
3
10 m (Contains no fibers, inhalable fraction)
0.1 fibers/cm 10m 3 m 10 m 5 m 15 m
5 mg/m
3
(fibers, inhalable fraction
/m3 (inhalable fraction
/m3 (respirable fration
/m3 (inhalable fraction
/m3 (respirable fraction
/m3 (inhalable fraction
3
(respirable fraction)
Page: 5 of 14
65997.17-3 Fiber glass weaves Canada, Alberta: OEL 8 hour
Canada, Alberta: OEL 8 hour
Canada, BC: OEL TWA
Canada, BC: OEL TWA
Canada, Ontario: OEL TWA
Canada, Ontario: OEL TWA
Canada, Quebec: VEMP
1 fibers/cm
3
Glass Fibers, continuous filament
3
5 m
/m Glass Fibers, continuous filament, Glass wool, inhalable fraction
1 fibers/cm
3
Synthetic Vitreous Fibers-Continous filament glass fibers
3
5 m
/m Synthetic Vitreous Fibers-Continous filament glass fibers; inhalable fraction
1 fibers/cm
3
Synthetic Vitreous Fibers-Continous filament glass fibers
3
5 m
/m Synthetic Vitreous Fibers (Man Made Mineral Fibers), Continuous filament glass fibers
/m
3
10 m Continuous filament glass fibers Pt note 1
SAFETY DATA SHEET (SDS)
g
g
g
g
g
g
g
(
g
g
)
g
)
g
)
g
)
g
)
g
g
g
g
)
g
)
g
)
g
)
g
)
g
)
g
)
g
)
g
)
g
)
g
)
g
)
g
)
g
)
g
)
g
)
g
)
Coated Abrasives
Revision Date: 1/2/2019 Version: 1
Date of Print: 1/17/2019
Page: 6 of 14
USA: ACGIH: TWA
USA: ACGIH: TWA
USA: NIOSH: TWA
USA: NIOSH: TWA
1314-23-4 Zirconium dioxide Canada, Alberta: OEL 15 min
Canada, Alberta: OEL 8 hour Canada, BC OEL STEL Canada, BC OEL TWA Canada Quebec: VECD
Canada Quebec: VEMP
USA: ACGIH: STEL USA: ACGIH: TWA USA: NIOSH: STEL USA: NIOSH: TWA USA: OSHA: TWA
1 fibers/cm
3
Synthetic vitreous fibers, Continuous filament glass fibers
3
5 m
/m Synthetic vitreous fibers, Continuous filament glass fibers; inhalable fracton
3 fibers/cm
3
Fibers less than or equal to 3,5 um in diameter and greater than or equal to 10 um in length
3
5 m
/m Fiber glas, Fiberglass, Glass fibers, Glass wool, total dust
3
/m
10 m
3
/m
5 m 10 m 5 m 10 m
3
/m
3
/m
3
/m
Zirconium and compounds,
calculated as Zr)
/m3 (Zirconium and compounds,
5 m calculated as Zr)
/m3 (calculated as Zr
10 m
/m3 (calculated as Zr
5 m
/m3 (calculated as Zr
10 m
/m3 (calculated as Zr
5 m
/m3 (calculated as Zr
5 m
471-34-1 Calcium carbonate Canada, Alberta: OEL 8 hour
Canada, BC OEL STEL
Canada, BC: OEL TWA
Canada Quebec: VEMP USA: NIOSH: TWA USA: NIOSH: TWA USA: OSHA: TWA USA: OSHA: TWA
60304-36-1 Aluminum potassium Canada, Alberta: OEL 8 hour
fluoride Canada, BC: OEL TWA
Canada Quebec: VEMP USA: ACGIH: TWA USA: NIOSH: TWA USA: OSHA: TWA
14075-53-7 Potassium Canada, Alberta: OEL 8 hour
tetrafluoroborate Canada, BC: OEL TWA
Canada Quebec: VEMP USA: ACGIH: TWA USA: NIOSH: TWA USA: OSHA: TWA
10 m 20 m
/m
3
3
/m
(Calcium carbonate incl. Limestone, Marble)
/m
3
10 m (Calcium carbonate incl. Limestone, Marble)
10 m
/m3 (inhalable fraction /m3 (inhalable fraction
10 m
/m3 (respirable fraction
5 m
/m3 (inhalable fraction
15 m
/m3 (respirable fraction
5 m
/m3 (calculated as F
2.5 m
/m3 (calculated as F
2.5 m
/m3 (calculated as F
2.5 m
/m3 (Fluorides, calculated as F
2.5 m
/m3 (calculated as F
2.5 m
/m3 (calculated as F
2.5 m
/m3 (calculated as F
2.5 m
/m3 (calculated as F
2.5 m
/m3 (calculated as F
2.5 m
/m3 (Fluorides, calculated as F
2.5 m
/m3 (calculated as F
2.5 m
/m3 (calculated as F
2.5 m
SAFETY DATA SHEET (SDS)
g
)
g
)
g
)
g
)
g
)
g
)
g
g
g
g
g
)
g
)
g
)
g
)
g
g
g
)
g
)
g
g
g
)
g
g
(
)
g
g
)
g
g
)
g
g
)
g
g
)
g
)
g
g
g
g
g
g
g
)
g
Coated Abrasives
Revision Date: 1/2/2019 Version: 1
Date of Print: 1/17/2019
Page: 7 of 14
13775-53-6 Trisodium Canada, Alberta: OEL 8 hour
hexafluoroaluminate Canada, BC: OEL TWA (cryolite) Canada Quebec: VEMP
USA: ACGIH: TWA USA: NIOSH: TWA USA: OSHA: TWA
1332-58-7 Kaolin Canada, Alberta: OEL 8 hour
Canada, BC: OEL TWA Canada Quebec: VEMP USA: ACGIH: TWA
USA: NIOSH: TWA USA: NIOSH: TWA USA: OSHA: TWA USA: OSHA: TWA
13463-67-7 Titanium dioxide Canada, Alberta: OEL 8 hour
Canada, BC: OEL TWA Canada, BC: OEL TWA Canada, Quebec: VEMP USA: ACGIH: TWA USA: OSHA:TWA
/m3 (calculated as F
2.5 m
/m3 (calculated as F
2.5 m
/m3 (calculated as F
2.5 m
/m3 (Fluorides, calculated as F
2.5 m
/m3 (calculated as F
2.5 m
/m3 (calculated as F
2.5 m
3
/m
2 m
3
/m
2 m
3
/m
5 m
3
/m
2 m respirable fraction (particulate matter containing no asbestos and <1% crystalline silica)
10 m
/m3 (inhalable fraction
/m3 (respirable fraction
5 m
/m3 (inhalable fraction
15 m
/m3 (respirable fraction
5 m
3
/m
10 m 10 m 3 m 10 m 10 m 15 m
3
/m
/m3 (respirable fraction
/m3 (inhalable fraction
3
/m
3
/m
1309-37-1 Diiron trioxide Canada, Alberta: OEL 8 hours
Canada, BC OEL STEL Canada, BC: OEL TWA Canada, BC: OEL TWA Canada, BC: OEL TWA Canada, BC: OEL TWA Canada, Quebec; VEMP Canada, Quebec; VEMP USA: ACGIH; TWA USA: OSHA: TWA
USA: OSHA: TWA USA: OSHA: TWA
7631-86-9 Silicon dioxide USA: NIOSH: TWA
USA: OSHA:TWA 20 mppcf USA: OSHA:TWA
1309-48-4 Magnesium oxide Canada, Alberta: OEL 8 hours
Canada, BC OEL STEL Canada, BC: OEL TWA Canada, Quebec; VEMP USA: ACGIH; TWA USA: OSHA: TWA
/m3 (respirable fraction
5 m
/m3 Smoke; calculated as Fe
10 m 10 m 3 m 5 m 5m 10 m 5 m 5 m 10 m
3
/m
oxide, red /m3 (oxide, red) respirable fraction /m3 (oxide dust
/m3 Smoke; calculated as Fe
/m3 (red
3
/m /m3 (respirable fraction
3
/m
(Iron oxide, fume; calculated as Fe)
15 m
/m3 (inhalable fraction, red
/m3 (red, respirable fraction
5 m
3
/m
6 m
80 m
/m3 total dust
3
/m
10 m
/m3 respirable fraction, Smoke and Dusts
10 m
/m3 respirable fraction, Smoke and Dusts
3 m 10 m 10 m 15 m
3
/m /m3 (inhalable fraction
3
/m
SAFETY DATA SHEET (SDS)
g
g
g
g
g
g
g
g
g
)
g
(
)
g
)
g
)
g
g
)
g
g
g
g
)
g
g
g
g
g
g
Coated Abrasives
Revision Date: 1/2/2019 Version: 1
Date of Print: 1/17/2019
Page: 8 of 14
1305-78-8 Calcium oxide Canada, Alberta: OEL 8 hours
Canada, BC OEL TWA Canada, Quebec; VEMP USA: ACGIH; TWA USA: NIOSH: TWA USA: OSHA: TWA
14808-60-7 Quartz (SiO2) Canada Alberta: OEL 8 hour
Canada, BC:OEL TWA Canada, Ontario: OEL TWA Canada, Quebec: VEMP USA: ACGIH:TWA USA: NIOSH: TWA USA: OSHA: TWA
USA:OSHA : TWA 250 mppcf/%SiO2+5 (fine dust) USA OSHA: TWA
1333-86-4 Carbon Black Canada Alberta: OEL 8 hour
Canada, BC:OEL TWA Canada, Quebec: VEMP USA: ACGIH:TWA USA: NIOSH: TWA
USA: NIOSH: TWA USA: OSHA: TWA
3
/m
2 m
3
/m
2 m
3
/m
2 m
3
/m
2 m
3
/m
2 m
3
/m
5 m
3
0.025 m
0.025 m
0.1 m
0.1 m
0.025 m
0.05 m 10 m
/m
3
/m
/m3 (respirable fraction
3
/m
respirable fraction
/m3 (respirable fraction
/m3 (respirable fraction
/m3 /% SiO2+2
(respirable fraction)
30 m
/m3/% SiO2+2 (inhalable fraction
3
/m
3.5 m
3
/m
3 m
3.5 m 3 m
0.1 m
3
/m
/m3 (inhalable fraction
PAHs/m
3
Carbon black in presence of polycyclic aromatic hydrocarbons (PAHs)
/m /m
3
3
3.5 m
3.5 m
50-00-0 Formaldehyde Canada, Alberta: OEL 8 hour
Canada, Alberta: OEL Ceiling Canada, BC: OEL Ceiling 1 ppm Canada, BC: OEL TWA 0.3 ppm Canada, Ontario: OEL Ceiling 1.5 ppm Canada, Ontario: OEL STEL 1 ppm Canada, Quebec: Plafond NIOSH: Ceiling 0.1 ppm USA: ACGIH: STEL 0.3 ppm (DSEN,RSEN,A1) USA: ACGIH: TWA 0.1 ppm (DSEN,RSEN,A1) USA: NIOSH:TWA 0.016 ppm USA: OSHA: STEL 2 ppm USA: OSHA: TWA 0.75 ppm
0.9 m
1.3 m
3 m
/m3, 0.75ppm /m3, 1 ppm
/m3, 2 ppm
SAFETY DATA SHEET (SDS)
e
Coated Abrasives
Revision Date: 1/2/2019 Version: 1
Biological limit values:
CAS NO.
Designation Typ
Limit Value Parameter Sampling
60304-36-1 Aluminum potassium fluoride USA: ACGIH-BEI, 3 mg/L Fluorides end of exposure or
blood end of shift USA: ACGIH-BEI, 2 mg/L Fluorides prior toshift urine
14075-53-7 Potassium tetrafluoroborate USA: ACGIH-BEI, 3 mg/L Fluorides end of exposure or
blood end of shift USA: ACGIH-BEI, 2 mg/L Fluorides prior toshift urine
13775-53-6 Trisodium hexafluoroaluminate USA: ACGIH-BEI, 3 mg/L Fluorides end of exposure or
blood end of shift USA: ACGIH-BEI, 2 mg/L Fluorides prior toshift urine
Engineering controls
Provide good ventilation and/or an exhaust system in the work area. Technical measures and the application of suitable work processes have priority over personal protection equipment. In case of development of vapors or dust: The use of a local exhaust ventilation is recommended.
Also see information in section 7, storage
Date of Print: 1/17/2019
Page: 9 of 14
Personal protection equipment (PPE)
Eye/face protection:
skin protection:
Respiratory protection:
General hygiene considerations:
Tighltly sealed goggles according to OSHA Standard-29 CFR: 1910.133 or ANSI Z87.1-2010. Wear suitable protective clothing and shoes. Respiratory protection must be worn whenever the TLV (WEL) levels have been exceeded. Use appropriate respiratory protection.: The filter class must be suitable for the maximum contaminant concentration (gas/vapour/aerosol/particulates) that may arise when handling the product. If the concentration is exceeded, self-contained breathing apparatus must be used.
Do not inhale substance. Avoid contact with skin and eyes. When using do not eat, drink or smoke. Change contaminated clothing. Wash hands before breaks and after work. Work place should be equipped with a shower and an eye rinsing apparatus. Obtain special instructions before use.
9. Physical and Chemical Properties
Information on basic physical and chemcial properties
Appearance:
Odor:
Odor threshold:
pH value:
Melting point/freezing point:
Initial boiling point and boiling range:
Flash point/flash point range:
Evaporation rate:
Flammability:
Explosion limits:
Vapor pressure:
Vapor density:
Density:
Solubility:
Partition coefficient: n-octanol/water:
Form: Solid Color: varying colors No data available No data available No data available No data available No data available No data available No data available No data available No data available No data available No data available No data available No data available No data available
SAFETY DATA SHEET (SDS)
Coated Abrasives
Revision Date: 1/2/2019 Version: 1
Date of Print: 1/17/2019
Page: 10 of 14
auto-ignition temperature:
Thermal decomposition:
Additional information:
Reactivity:
Chemical Stability:
Possibility of hazardous reactions:
Conditions to avoid:
Incompatible materials:
Hazardous decomposition products:
Thermal decomposition:
Toxicological tests
Toxicological effects:
No data available No data available No data available
10. Stability and Reactivity
No data available Stable under recommended storage conditions. No hazardous reaction when handled and stored according to provisions. No data available Oxidizing agents, acids. Hydrogen fluoride, boron compounds, carbon monoxide and carbon dioxide (CO2). No data available
11. Toxicological Information
The statements are derived from the properties of the single components. No Toxicological data is available for the product as such. Acute toxicity (oral): Based on available data, the classification criteria are not met. Acute toxicity (dermal): Lack of data. Acute toxicity (inhalative): Based on available data, the classification criteria are not met. Skin corrosion/irritation: Lack of data. Serious eye damage/irritation: Eye irritation 2A = Causes serious eye irritation. Sensitisation to the respiratory tract: Lack of data. Skin sensitisation: Lack of data. Germ cell mutagenicity/Genotoxicity: Lack of data Carcinogenicity: Carcinogenicity 1A = May cause cancer. Reproductive toxicity: Lack of data Effects on or via lactation: Toxic to reproduction (lactation) = May cause harm to breast-fed children. Specific target organ toxicity (single exposure): Lack of data. Specific target organ toxicity (repeated exposure): 1 = Causes damage to organs through prolonged or repeated exposure. Aspiration hazard: Lack of data.
Other information:
Information about Aluminum potassium fluoride. LD50, Rat, oral: >2000 mg/kg LC50, Rat, inhalative: > 3.4 mg/L/h LD50, Rabbit, dermal: >2000 mg/kg
Information about Trisodium hexafluoroaluminate (cryolite): LD50, Rat, oral: >5000 mg/kg LC50, Rat, inhalative: > 4.47 mg/L/h LD50, Rabbit, dermal: >2100 mg/kg
Chronic toxicity carcinogenic effects:
Information about Titanium dioxide: IARC Rating: Group 2B OSHA Carcinogen: not listed NTP Rating: not listed
Information about Diiron trioxide: IARC Rating: Group 3 OSHA Carcinogen: not listed NTP Rating: not listed
Information about Silicon dioxide:
SAFETY DATA SHEET (SDS)
y
Coated Abrasives
Revision Date: 1/2/2019 Version: 1
IARC Rating: Group 3 OSHA Carcinogen: not listed NTP Rating: not listed
Information about Quartz (SiO2): IARC Rating: Group 1 OSHA Carcinogen: not listed NTP Rating: listed
Ecotoxicit
Date of Print: 1/17/2019
Page: 11 of 14
12. Ecological Information
Aquatic toxicity:
Harmful to aquatic life with long lasting effects. Information about Trisodium hexafluoroaluminate (cryolite); Algae toxicity: EC50 Pseudokirchneriella subcapitata (green algae): 8.8 mg/L/72h (OECD 201) Daphnia toxicity: EC50 Daphnia magna (Big water flea): 156 mg/L/48h (OECD 202) Fish toxicity: LC50 Brachydanio rerio (zebra-fish): 99 mg/L/96h (OECD 203)
Mobility in soil
No data available
Persistence and degradability
Further detailas:
No data available
Additional ecological information
General information:
Do not allow to enter into ground-water, surface water or drains.
Product
Recommendation:
Dispose of waste according to applicable legislation.
Contaminated packaging
Recommendation:
Dispose of waste according to applicable legislation. Packing can be recycled or disposed of.
USA: Department of Transportation (DOT)
Proper shipping name:
Not restricted
13. Disposal Considerations
14. Transport Information
Canada: Transportation of Dangerous Goods (TDG)
Shipping name:
Not restricted
Sea transport (IMDG)
Proper shipping name:
Marine pollutant:
Not restricted No
Air transport (IATA)
Proper shipping name:
Not restricted
Further information
No dangerous goods in sense of these transport regulations.
SAFETY DATA SHEET (SDS)
Coated Abrasives
Revision Date: 1/2/2019 Version: 1
15. Regulatory Information
National regulations - Canada
No data available
National regulations - U.S. Federal Regulations
Product:
Alluminum oxide: Other Environmental Laws:
Silicon carbide: NIOSH Recommendations:
Kaolin: NIOSH Recommendations:
Titanium dioxide: Carcinogen Status:
Diiron trioxide: Carcinogen Status:
Silicon dioxide: Carcinogen Status:
Magnesium oxide: NIOSH Recommendations:
Calcium oxide: NIOSH Recommendations:
Quartz (SiO2): Carcinogen Status:
Carbon black: Carcinogen Status:
This product is an aticle as defined by TSCA regulations, and is exempt from TSCA inventory listing requirements.
SARA Title III Section 313, Toxic Release: Conc. 1.0% / Threshold Standard NIOSH Recommendations: Occupational Health Guideline: 0021
Occupational Health Guideline: 0555
Occupational Health Guideline: 0364
IARC Rating: Group 2B OSHA Carcinogen: not listed NTP Rating: not listed NIOSH Recommendations: Occupational Health Guideline: 0617
IARC Rating: Group 3 OSHA Carcinogen: not listed NTP Rating: not listed NIOSH Recommendations: Occupational Health Guideline: 0344
IARC Rating: Group 3 OSHA Carcinogen: not listed NTP Rating: not listed NIOSH Recommendations: Occupational Health Guideline: 0552
Occupational Health Guideline: 0374
Occupational Health Guideline: 0093
IARC Rating: Group 1 OSHA Carcinogen: not listed NTP Rating: not listed NIOSH Recommendations: Occupational Health Guideline: 0553
IARC Rating: Group 2B OSHA Carcinogen: not listed NTP Rating: not listed NIOSH Recommendations: Occupational Health Guideline: 0102
Date of Print: 1/17/2019
Page: 12 of 14
SAFETY DATA SHEET (SDS)
Coated Abrasives
Revision Date: 1/2/2019 Version: 1
Formaldehyde: Carcinogen Status:
IARC Rating: Group 1 OSHA Carcinogen: not listed NTP Rating: listed Clean Air Act: Accidental Release Prevention: Threshold 15000 lbs. / Basis for llisting = b Hazardous Air Pollutants: Code XOV SOCMI Chemical: yes Clean Water Act: Hazardous Substances: RQ 100 lbs. Other Environmental Laws: CERCLA: RQ 100 lbs. RCRA Hazardous Wastes: Code U122 SARA Title III Section 302, EHS: TPQ 500 lbs. / RQ 100 lbs. SARA Title III Section 313, Toxic Release: Conc. 0.1% / Threshold Standard NIOSH Recommendations: Current Intelligence Bulletin: 81-111, 86-122 Occupational Health Guideline: 0293* OSHA Process Safety Management: Threshold 1000 lbs.
National regulations - U.S. State Regulations
Aluminum Oxide: Delaware Air Quality Management List:
DRQ: 100 - RQ State: State requirement differs from Federal Massachusetts Haz. Substance codes: F9 Minnesota Haz. Substance: Codes: A - Ratings: 10.16 - Status: Title III. TRI. New Jersey RTK Hazardous Substance: DOT: - - Sub No.: 2891 - TPQ: Pennsylvania Haz. Substance code: E Washington Air Contaminant: TWA: 10 mg
Zirconium dioxide: Massachusetts Haz. Substance codes: 2 Titanium dioxide: California Proposition 65: cancer
Rhode Island HSL: listed
Diiron trioxide: Idaho Air Pollutant List:
Title 585 -- AAC: 0.25 -- EL: 0.333 -- WEL: 5 Title 586 ­Massachusetts Haz. Substance codes: 2 Pennsylvania Haz. Substance code: ­Washington Air Contaminant: TWA: 5 mg
Quartz (SiO2): California Proposition 65: cancer
Rhode Island HSL: listed
Carbon black: California Proposition 65: cancer
Rhode Island HSL: listed
Date of Print: 1/17/2019
Page: 13 of 14
SAFETY DATA SHEET (SDS)
Coated Abrasives
Revision Date: 1/2/2019 Version: 1
Formaldehyde: California Proposition 65: cancer
Delaware Air Quality Management List: DRQ: 100 - RQ State: Federal Regulations Apply Idaho Air Pollutant List: Title 585: AAC: - EL: - OEL: - Title 586: AAAC: 7.7E-02 - EL: 5/1E-04 - OEF: 1.3E-05 Maine: HAP - 1000 Massachusetts Haz. Substance codes: 1,2,3,4,5,6,7 *E*C* F6 Minnesota Haz. Substance: Codes: ANORT - Rating: 10.91 - Status: Air Pollutant. Carcinogen. Title III. TRI. New Jersey Extraordinarily Hazardous Substance: EPA Threshold: - NJ Threshold: 175 - NJ Group: II - NJ Table: I Part A - NJ Basis: Not on list New Jersey RTK Hazardous Substance: DOT: 1198 - Sub No.: 0946 - TPQ: - EHS: Yes New York List of Hazardous Substances: RQ-Air: 100 - RQ-Land 1 - Note: No Note Associated with this chemical. Pennsylvania Haz. Substance code: ES Washington Air Contaminant: TWA: 75 ppm -- mg - STEL: 2 ppm -- mg - Ceiling - ppm -- mg - Skin: ­West Virginia Toxic Air Pollutant List (Pounds per Year): 1,000 California Proposition 65: cancer Rhode Island HSL: listed
Date of Print: 1/17/2019
Page: 14 of 14
16. Other Information
Hazard rating systems:
NFPA Hazard Rating:
Health: 1 (Slight)
0
1
Reason of Change: None Date of Revision: None
The above information describes exclusively the safety requirements of the product and is based on our present-day knowledge. The information is intended to give you advice about the safe handling of the product named in this safety data sheet, for storage, processing, transport and disposal. The information cannot be transferred to other products.
0
Fire: 0 (Minimal) Reactivity: 0 (Minimal) HMIS Version III Rating: Health: 1 (Slight) - Chronic effects Flammability: 0 (Minimal) Physical Hazard: 0 (Minimal) Personal Protection: X = Consult your supervisor
1
X
Loading...