COATED ABRASIVES
This safety data sheet pertains to the following products:
Abrasive Caps
Belts
Bore Polisher
Cartridge Rolls - Straight or Tapered
Cones - Chamfering or Center Lap
Cross Pad and Square Pads
Discs - Quick Change, PSA, Flap, Resin Fiber
Flap Wheels - Mounted, Unmounted, Mini, Angle Grinder
Sheets
Shop Rolls
Spiral Bands
Relevant identified uses of the substance or mixture and uses adivsed against:
General Use:
Grinding and sanding of different kinds of materials.
For industrial purposes only.
Details of the supplier of the Safety Data Sheet
Company Name:
Superior Abrasives, LLC
1620 Fieldstone Way
Vandalia, Ohio 45377
USA
www.superiorabrasives.com
email: SDS@superiorabrasives.com
Telephone: 1-800-235-9123
Local Tel: 937-278-9123
Fax: 937-278-7581
Emergency overview
Appearance:
Odor:
Classification:
Hazard symbols:
Signal word:
Hazard statements:
2. Hazards Identification
Form: solid
Color: varying colors
No data availabe
Eye Irritation 2A; Carcinogenicity 1A; Toxic to Reproduction (Lactation):
Specific Target Organ Toxicity (repeated exposure) 1; Aquatic Toxicity - chronic 3
Danger
Causes serious eye irritation.
May cause cancer.
May cause harm to breast-fed children.
Causes damage to organs through prolonged or repeated exposure.
Harmful to aquatic life with long lasting effects.
SAFETY DATA SHEET (SDS)
Coated Abrasives
Revision Date: 1/2/2019
Version: 1
Precautionary statements:Obtain special instructions before use.
Do not breathe dust/fume/gas/mist/vapors/spray.
Avoid contact during pregnancy/while nursing.
Wash hands and face thoroughly after handling.
Do not eat, drink or smoke when using this product.
Avoid release to the environment.
Wear protective gloves/protective clothing/eye protection/face protection.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
IF exposed or concerned: Get medical adivice/attention.
If eye irritation persists: Get medical advise/attention.
Store locked up.
Dispose of contents/container to hazardous or special waste collection point.
additional information:The hazard identification is based on a formalistic procedure as the hazard statements of
the ingredients are summarized under section 3. This does not correspond to the
hazardousness of the product itself. A greater hazard, in most cases, is the exposure to
the dust/fumes from the material or paint/coatings being ground. Most of the dust
generated during grinding is from the base material being ground and the potential
hazard from this exposure must be evaluated. This dust may present a fire or dust
explosion hazard and may present a serious health hazard.
Date of Print: 1/17/2019
Page: 2 of 14
Regulatory status
This matrial is considered hazardous by the U.S. OSHA Hazard Communication
Standard (29 CFR 1910.1200) and SIMDUT in Canada.
Hazards not otherwise cassified
Processing, e.g. by cutting, sawing or grinding, can produce particles and dust.
Inhalation of dust may cause irritation of the respiratory system.
Dust may irritate eyes.
See section 11: Toxicological information
Chemical Characterisation:
Relevant ingredients:
CAS No.
CAS 1344-28-1Aluminium oxide< 70%Not applicable
CAS -Vulcanized fiber< 70%Not applicable
CAS 409-21-2Silicon carbide< 60%Not applicable
CAS -Cotton cloth< 60%Not applicable
CAS -Polyester cloth< 55%Not applicable
CAS -Paper< 50%Not applicable
CAS 65997-17-3Fibre glass weaves< 45%Not applicable
CAS -Polyamide compound< 45%Not applicable
CAS -Synthetic resin, polymerized< 40%Not applicable
CAS -Cotton-Polyester cloth< 40%Not applicable
CAS 1314-23-4Zirconium dioxide< 30%Not applicable
CAS -Adhesive, cured< 30%Not applicable
CAS 471-34-1Calcium carbonate< 25%Not applicable
CAS 60304-36-1Aluminum potassium fluoride< 25%
Components in synthetic resin, completely embedded.
3. Composition / Information on Ingredients
DesignationContent Classification
Acute Toxicity 4 (inhalative). Eye Irritation
2A. Toxic to Reproduction (Lactation).
Specific Target Organ Toxicity (Repeated
Exposure) 1. Aquatic Toxicity - Chronic 3.
CAS 14075-53-7Potassium tetrafluoroborate< 20%Not applicable
SAFETY DATA SHEET (SDS)
Coated Abrasives
Revision Date: 1/2/2019
Version: 1
Date of Print: 1/17/2019
Page: 3 of 14
CAS 13775-53-6< 20%
CAS -Velcro fabric< 20%Not applicable
CAS 25038-36-2EPDM< 15%Not applicable
CAS 1332-58-7Kaolin< 15%Not applicable
CAS -Rubber, vulcanized< 10%Not applicable
CAS 13463-67-7Titanium dioxide< 5%Carcinogenicity 2
CAS 1309-37-1Diiron trioxide< 5%Not applicable
CAS -Adhesive tape< 5%Not applicable
CAS 1345-25-1Iron (II) oxide< 1%Not applicable
CAS 7631-86-9Silicon dioxide< 1%Not applicable
CAS 1309-48-4Magnesium oxide<0.5%Not applicable
CAS 1305-78-8Calcium oxide<0.5%
CAS 14808-60-7Quartz (SiO2)<0.5%Carcinogenicity 1A
CAS 1333-86-4Carbon black<0.5%Not applicable
CAS 12055-23-1Hafnium dioxide<0.4%Not applicable
CAS 50-00-0Formaldehyde<0.1%Acute Toxicity 3 (oral)
Trisodium hexafluoroaluminate
(cryolite)
Acute Toxicity 4 (inhalative). Toxic to
Reproduction (Lactation). Specific Target
Organ Toxicity (Repeated Exposure) 1.
Aquatic Toxicity - Chronic 2.
Skin Irritation 2. Eye Damage 1. Specific
Target Organ Toxicity (Single Exposure) 3.
Causes serious eye irritation. Causes damage to organs through prolonged or repeated exposure.
InformationtophysicianTreat Symptomatically.
SAFETY DATA SHEET (SDS)
Coated Abrasives
Revision Date: 1/2/2019
Version: 1
Flash point/Flash point range:
Auto-ignition Temperature:
Suitable extinguishing media:
Specific hazards arising from the chemical:
Protective equipment and precautions for firefighters:
Wear a self-contained breathing apparatus and chemical protective clothing.
Additional information
Do not allow fire water to penetrate into surface or ground water.
Personal precautions:
Avoid exposure. Avoid generation of dust. Do not inhale substance.
In case of heating: Development of gas/vapor possible.
Provide adequate ventilation. Wear appropriate protective equipment
Avoid contact with the substance. Keep unprotected people away.
Environmental precautions:
Do not allow to penetrate into soil, waterbodies or drains.
In case of release, notify competent authorities.
Methods for clean up:
Take up mechanically, placing in appropriate containers for disposal
No data availabe
No data availabe
Product is non-combustible. Extinguishing material should therefore be selected according to
surroundings.
Can be released in case of fire: Hydrogen fluoride, boron compounds, carbon monoxide,
and carbon dioxide (CO2).
Date of Print: 1/17/2019
Page: 4 of 14
5. Fire Fighting Measures
6. Accidental Release Measures
Handling
Advice on safe handlling:
Provide adequate ventilation, and local exhaust as needed. Avoid generation of dust. In case of heating:
Development of gas/vapor possible. Do not inhale substance. Wear appropriate protective equipment.
Avoid contact with the substance. Obtain special instructions before use. Work place should be equipped
with a shower and an eye rinsing apparatus.
Storage
Requirements for storerooms and containers:
Keep container tightly closed and dry.
Keep in cool, well-ventilated place.
Hints on joint storage:
Do not store together with oxidizing agents or acids.
Do not store together wih food.
Canada, BC OEL STEL
Canada, BC: OEL TWA
Canada, BC: OEL TWA
Canada, BC: OEL TWA
Canada, BC: OEL TWA
Canada, Quebec; VEMP
Canada, Quebec; VEMP
USA: ACGIH; TWA
USA: OSHA: TWA
60304-36-1Aluminum potassium fluorideUSA: ACGIH-BEI,3 mg/LFluoridesend of exposure or
bloodend of shift
USA: ACGIH-BEI,2 mg/LFluoridesprior toshift
urine
14075-53-7Potassium tetrafluoroborateUSA: ACGIH-BEI,3 mg/LFluoridesend of exposure or
bloodend of shift
USA: ACGIH-BEI,2 mg/LFluoridesprior toshift
urine
13775-53-6Trisodium hexafluoroaluminateUSA: ACGIH-BEI,3 mg/LFluoridesend of exposure or
bloodend of shift
USA: ACGIH-BEI,2 mg/LFluoridesprior toshift
urine
Engineering controls
Provide good ventilation and/or an exhaust system in the work area.
Technical measures and the application of suitable work processes have priority over
personal protection equipment.
In case of development of vapors or dust: The use of a local exhaust ventilation is recommended.
Also see information in section 7, storage
Date of Print: 1/17/2019
Page: 9 of 14
Personal protection equipment (PPE)
Eye/face protection:
skin protection:
Respiratory protection:
General hygiene considerations:
Tighltly sealed goggles according to OSHA Standard-29 CFR: 1910.133 or ANSI Z87.1-2010.
Wear suitable protective clothing and shoes.
Respiratory protection must be worn whenever the TLV (WEL) levels have been exceeded.
Use appropriate respiratory protection.:
The filter class must be suitable for the maximum contaminant concentration
(gas/vapour/aerosol/particulates) that may arise when handling the product. If the
concentration is exceeded, self-contained breathing apparatus must be used.
Do not inhale substance.
Avoid contact with skin and eyes.
When using do not eat, drink or smoke. Change contaminated clothing.
Wash hands before breaks and after work.
Work place should be equipped with a shower and an eye rinsing apparatus.
Obtain special instructions before use.
9. Physical and Chemical Properties
Information on basic physical and chemcial properties
Appearance:
Odor:
Odor threshold:
pH value:
Melting point/freezing point:
Initial boiling point and boiling range:
Flash point/flash point range:
Evaporation rate:
Flammability:
Explosion limits:
Vapor pressure:
Vapor density:
Density:
Solubility:
Partition coefficient: n-octanol/water:
Form: Solid
Color: varying colors
No data available
No data available
No data available
No data available
No data available
No data available
No data available
No data available
No data available
No data available
No data available
No data available
No data available
No data available
SAFETY DATA SHEET (SDS)
Coated Abrasives
Revision Date: 1/2/2019
Version: 1
Date of Print: 1/17/2019
Page: 10 of 14
auto-ignition temperature:
Thermal decomposition:
Additional information:
Reactivity:
Chemical Stability:
Possibility of hazardous reactions:
Conditions to avoid:
Incompatible materials:
Hazardous decomposition products:
Thermal decomposition:
Toxicological tests
Toxicological effects:
No data available
No data available
No data available
10. Stability and Reactivity
No data available
Stable under recommended storage conditions.
No hazardous reaction when handled and stored according to provisions.
No data available
Oxidizing agents, acids.
Hydrogen fluoride, boron compounds, carbon monoxide and carbon dioxide (CO2).
No data available
11. Toxicological Information
The statements are derived from the properties of the single components. No Toxicological data is
available for the product as such.
Acute toxicity (oral): Based on available data, the classification criteria are not met.
Acute toxicity (dermal): Lack of data.
Acute toxicity (inhalative): Based on available data, the classification criteria are not met.
Skin corrosion/irritation: Lack of data.
Serious eye damage/irritation: Eye irritation 2A = Causes serious eye irritation.
Sensitisation to the respiratory tract: Lack of data.
Skin sensitisation: Lack of data.
Germ cell mutagenicity/Genotoxicity: Lack of data
Carcinogenicity: Carcinogenicity 1A = May cause cancer.
Reproductive toxicity: Lack of data
Effects on or via lactation: Toxic to reproduction (lactation) = May cause harm to breast-fed children.
Specific target organ toxicity (single exposure): Lack of data.
Specific target organ toxicity (repeated exposure): 1 = Causes damage to organs through prolonged
or repeated exposure.
Aspiration hazard: Lack of data.
Other information:
Information about Aluminum potassium fluoride.
LD50, Rat, oral: >2000 mg/kg
LC50, Rat, inhalative: > 3.4 mg/L/h
LD50, Rabbit, dermal: >2000 mg/kg
Information about Trisodium hexafluoroaluminate (cryolite):
LD50, Rat, oral: >5000 mg/kg
LC50, Rat, inhalative: > 4.47 mg/L/h
LD50, Rabbit, dermal: >2100 mg/kg
Chronic toxicity carcinogenic effects:
Information about Titanium dioxide:
IARC Rating: Group 2B
OSHA Carcinogen: not listed
NTP Rating: not listed
Information about Diiron trioxide:
IARC Rating: Group 3
OSHA Carcinogen: not listed
NTP Rating: not listed
Information about Silicon dioxide:
SAFETY DATA SHEET (SDS)
y
Coated Abrasives
Revision Date: 1/2/2019
Version: 1
IARC Rating: Group 3
OSHA Carcinogen: not listed
NTP Rating: not listed
Information about Quartz (SiO2):
IARC Rating: Group 1
OSHA Carcinogen: not listed
NTP Rating: listed
Ecotoxicit
Date of Print: 1/17/2019
Page: 11 of 14
12. Ecological Information
Aquatic toxicity:
Harmful to aquatic life with long lasting effects.
Information about Trisodium hexafluoroaluminate (cryolite);
Algae toxicity:
EC50 Pseudokirchneriella subcapitata (green algae): 8.8 mg/L/72h (OECD 201)
Daphnia toxicity:
EC50 Daphnia magna (Big water flea): 156 mg/L/48h (OECD 202)
Fish toxicity:
LC50 Brachydanio rerio (zebra-fish): 99 mg/L/96h (OECD 203)
Mobility in soil
No data available
Persistence and degradability
Further detailas:
No data available
Additional ecological information
General information:
Do not allow to enter into ground-water, surface water or drains.
Product
Recommendation:
Dispose of waste according to applicable legislation.
Contaminated packaging
Recommendation:
Dispose of waste according to applicable legislation. Packing can be recycled or disposed of.
USA: Department of Transportation (DOT)
Proper shipping name:
Not restricted
13. Disposal Considerations
14. Transport Information
Canada: Transportation of Dangerous Goods (TDG)
Shipping name:
Not restricted
Sea transport (IMDG)
Proper shipping name:
Marine pollutant:
Not restricted
No
Air transport (IATA)
Proper shipping name:
Not restricted
Further information
No dangerous goods in sense of these transport regulations.
SAFETY DATA SHEET (SDS)
Coated Abrasives
Revision Date: 1/2/2019
Version: 1
15. Regulatory Information
National regulations - Canada
No data available
National regulations - U.S. Federal Regulations
Product:
Alluminum oxide:Other Environmental Laws:
Silicon carbide:NIOSH Recommendations:
Kaolin:NIOSH Recommendations:
Titanium dioxide:Carcinogen Status:
Diiron trioxide:Carcinogen Status:
Silicon dioxide:Carcinogen Status:
Magnesium oxide:NIOSH Recommendations:
Calcium oxide:NIOSH Recommendations:
Quartz (SiO2):Carcinogen Status:
Carbon black:Carcinogen Status:
This product is an aticle as defined by TSCA regulations, and is exempt from TSCA
inventory listing requirements.
SARA Title III Section 313, Toxic Release: Conc. 1.0% / Threshold Standard
NIOSH Recommendations:
Occupational Health Guideline: 0021
Occupational Health Guideline: 0555
Occupational Health Guideline: 0364
IARC Rating: Group 2B
OSHA Carcinogen: not listed
NTP Rating: not listed
NIOSH Recommendations:
Occupational Health Guideline: 0617
IARC Rating: Group 3
OSHA Carcinogen: not listed
NTP Rating: not listed
NIOSH Recommendations:
Occupational Health Guideline: 0344
IARC Rating: Group 3
OSHA Carcinogen: not listed
NTP Rating: not listed
NIOSH Recommendations:
Occupational Health Guideline: 0552
Occupational Health Guideline: 0374
Occupational Health Guideline: 0093
IARC Rating: Group 1
OSHA Carcinogen: not listed
NTP Rating: not listed
NIOSH Recommendations:
Occupational Health Guideline: 0553
IARC Rating: Group 2B
OSHA Carcinogen: not listed
NTP Rating: not listed
NIOSH Recommendations:
Occupational Health Guideline: 0102
Date of Print: 1/17/2019
Page: 12 of 14
SAFETY DATA SHEET (SDS)
Coated Abrasives
Revision Date: 1/2/2019
Version: 1
Formaldehyde:Carcinogen Status:
IARC Rating: Group 1
OSHA Carcinogen: not listed
NTP Rating: listed
Clean Air Act:
Accidental Release Prevention: Threshold 15000 lbs. / Basis for llisting = b
Hazardous Air Pollutants: Code XOV
SOCMI Chemical: yes
Clean Water Act:
Hazardous Substances: RQ 100 lbs.
Other Environmental Laws:
CERCLA: RQ 100 lbs.
RCRA Hazardous Wastes: Code U122
SARA Title III Section 302, EHS: TPQ 500 lbs. / RQ 100 lbs.
SARA Title III Section 313, Toxic Release: Conc. 0.1% / Threshold Standard
NIOSH Recommendations:
Current Intelligence Bulletin: 81-111, 86-122
Occupational Health Guideline: 0293*
OSHA Process Safety Management: Threshold 1000 lbs.
National regulations - U.S. State Regulations
Aluminum Oxide:Delaware Air Quality Management List:
DRQ: 100 - RQ State: State requirement differs from Federal
Massachusetts Haz. Substance codes: F9
Minnesota Haz. Substance:
Codes: A - Ratings: 10.16 - Status: Title III. TRI.
New Jersey RTK Hazardous Substance:
DOT: - - Sub No.: 2891 - TPQ:
Pennsylvania Haz. Substance code: E
Washington Air Contaminant:
TWA: 10 mg
Title 585 -- AAC: 0.25 -- EL: 0.333 -- WEL: 5
Title 586 Massachusetts Haz. Substance codes: 2
Pennsylvania Haz. Substance code: Washington Air Contaminant:
TWA: 5 mg
Quartz (SiO2):California Proposition 65: cancer
Rhode Island HSL: listed
Carbon black:California Proposition 65: cancer
Rhode Island HSL: listed
Date of Print: 1/17/2019
Page: 13 of 14
SAFETY DATA SHEET (SDS)
Coated Abrasives
Revision Date: 1/2/2019
Version: 1
Formaldehyde:California Proposition 65: cancer
Delaware Air Quality Management List:
DRQ: 100 - RQ State: Federal Regulations Apply
Idaho Air Pollutant List:
Title 585: AAC: - EL: - OEL: - Title 586: AAAC: 7.7E-02 - EL: 5/1E-04 - OEF: 1.3E-05
Maine: HAP - 1000
Massachusetts Haz. Substance codes: 1,2,3,4,5,6,7 *E*C* F6
Minnesota Haz. Substance:
Codes: ANORT - Rating: 10.91 - Status: Air Pollutant. Carcinogen. Title III. TRI.
New Jersey Extraordinarily Hazardous Substance:
EPA Threshold: - NJ Threshold: 175 - NJ Group: II - NJ Table: I Part A - NJ Basis: Not on list
New Jersey RTK Hazardous Substance:
DOT: 1198 - Sub No.: 0946 - TPQ: - EHS: Yes
New York List of Hazardous Substances:
RQ-Air: 100 - RQ-Land 1 - Note: No Note Associated with this chemical.
Pennsylvania Haz. Substance code: ES
Washington Air Contaminant:
TWA: 75 ppm -- mg - STEL: 2 ppm -- mg - Ceiling - ppm -- mg - Skin: West Virginia Toxic Air Pollutant List (Pounds per Year): 1,000
California Proposition 65: cancer
Rhode Island HSL: listed
Date of Print: 1/17/2019
Page: 14 of 14
16. Other Information
Hazard rating systems:
NFPA Hazard Rating:
Health: 1 (Slight)
0
1
Reason of Change:None
Date of Revision:None
The above information describes exclusively the safety requirements of the product and is based on our present-day knowledge.
The information is intended to give you advice about the safe handling of the product named in this safety data sheet, for storage,
processing, transport and disposal. The information cannot be transferred to other products.
0
Fire: 0 (Minimal)
Reactivity: 0 (Minimal)
HMIS Version III Rating:
Health: 1 (Slight) - Chronic effects
Flammability: 0 (Minimal)
Physical Hazard: 0 (Minimal)
Personal Protection: X = Consult your supervisor
1
X
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