Superior Abrasives 11133 User Manual

SAFETY DATA SHEET (SDS)
Coated Abrasives
Revision Date: 1/2/2019 Version: 1
Product Identifier
Date of Print: 1/17/2019
Page: 1 of 14
1. Product and Company Identification
Trade Name:
Relevant identified uses of the substance or mixture and uses adivsed against:
General Use:
Grinding and sanding of different kinds of materials. For industrial purposes only.
Details of the supplier of the Safety Data Sheet
Company Name:
Superior Abrasives, LLC 1620 Fieldstone Way Vandalia, Ohio 45377 USA www.superiorabrasives.com email: SDS@superiorabrasives.com Telephone: 1-800-235-9123
Local Tel: 937-278-9123 Fax: 937-278-7581
Emergency overview
Appearance:
Odor:
Classification:
Hazard symbols:
Signal word:
Hazard statements:
2. Hazards Identification
Form: solid Color: varying colors No data availabe Eye Irritation 2A; Carcinogenicity 1A; Toxic to Reproduction (Lactation): Specific Target Organ Toxicity (repeated exposure) 1; Aquatic Toxicity - chronic 3
Danger
Causes serious eye irritation. May cause cancer. May cause harm to breast-fed children. Causes damage to organs through prolonged or repeated exposure. Harmful to aquatic life with long lasting effects.
SAFETY DATA SHEET (SDS)
Coated Abrasives
Revision Date: 1/2/2019 Version: 1
Precautionary statements: Obtain special instructions before use.
Do not breathe dust/fume/gas/mist/vapors/spray. Avoid contact during pregnancy/while nursing. Wash hands and face thoroughly after handling. Do not eat, drink or smoke when using this product. Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or concerned: Get medical adivice/attention. If eye irritation persists: Get medical advise/attention. Store locked up. Dispose of contents/container to hazardous or special waste collection point.
additional information: The hazard identification is based on a formalistic procedure as the hazard statements of
the ingredients are summarized under section 3. This does not correspond to the hazardousness of the product itself. A greater hazard, in most cases, is the exposure to the dust/fumes from the material or paint/coatings being ground. Most of the dust generated during grinding is from the base material being ground and the potential hazard from this exposure must be evaluated. This dust may present a fire or dust explosion hazard and may present a serious health hazard.
Date of Print: 1/17/2019
Page: 2 of 14
Regulatory status
This matrial is considered hazardous by the U.S. OSHA Hazard Communication Standard (29 CFR 1910.1200) and SIMDUT in Canada.
Hazards not otherwise cassified
Processing, e.g. by cutting, sawing or grinding, can produce particles and dust. Inhalation of dust may cause irritation of the respiratory system. Dust may irritate eyes.
See section 11: Toxicological information
Chemical Characterisation:
Relevant ingredients:
CAS No.
CAS 1344-28-1 Aluminium oxide < 70% Not applicable CAS - Vulcanized fiber < 70% Not applicable CAS 409-21-2 Silicon carbide < 60% Not applicable CAS - Cotton cloth < 60% Not applicable CAS - Polyester cloth < 55% Not applicable CAS - Paper < 50% Not applicable CAS 65997-17-3 Fibre glass weaves < 45% Not applicable CAS - Polyamide compound < 45% Not applicable CAS - Synthetic resin, polymerized < 40% Not applicable CAS - Cotton-Polyester cloth < 40% Not applicable CAS 1314-23-4 Zirconium dioxide < 30% Not applicable CAS - Adhesive, cured < 30% Not applicable CAS 471-34-1 Calcium carbonate < 25% Not applicable CAS 60304-36-1 Aluminum potassium fluoride < 25%
Components in synthetic resin, completely embedded.
3. Composition / Information on Ingredients
Designation Content Classification
Acute Toxicity 4 (inhalative). Eye Irritation 2A. Toxic to Reproduction (Lactation). Specific Target Organ Toxicity (Repeated Exposure) 1. Aquatic Toxicity - Chronic 3.
CAS 14075-53-7 Potassium tetrafluoroborate < 20% Not applicable
SAFETY DATA SHEET (SDS)
Coated Abrasives
Revision Date: 1/2/2019 Version: 1
Date of Print: 1/17/2019
Page: 3 of 14
CAS 13775-53-6 < 20%
CAS - Velcro fabric < 20% Not applicable CAS 25038-36-2 EPDM < 15% Not applicable CAS 1332-58-7 Kaolin < 15% Not applicable CAS - Rubber, vulcanized < 10% Not applicable CAS 13463-67-7 Titanium dioxide < 5% Carcinogenicity 2 CAS 1309-37-1 Diiron trioxide < 5% Not applicable CAS - Adhesive tape < 5% Not applicable CAS 1345-25-1 Iron (II) oxide < 1% Not applicable CAS 7631-86-9 Silicon dioxide < 1% Not applicable CAS 1309-48-4 Magnesium oxide <0.5% Not applicable CAS 1305-78-8 Calcium oxide <0.5%
CAS 14808-60-7 Quartz (SiO2) <0.5% Carcinogenicity 1A CAS 1333-86-4 Carbon black <0.5% Not applicable CAS 12055-23-1 Hafnium dioxide <0.4% Not applicable CAS 50-00-0 Formaldehyde <0.1% Acute Toxicity 3 (oral)
Trisodium hexafluoroaluminate (cryolite)
Acute Toxicity 4 (inhalative). Toxic to Reproduction (Lactation). Specific Target Organ Toxicity (Repeated Exposure) 1. Aquatic Toxicity - Chronic 2.
Skin Irritation 2. Eye Damage 1. Specific Target Organ Toxicity (Single Exposure) 3.
Acute Toxicity 3 (dermal) Acute Toxicity 3 (inhalative) Skin Corrosion 1B. Sensitization-skin 1. Germ cell mutagenicity 2 Carcinogenicity 1B
Additional information: The ingredients are embedded in the product.
The components listed above do not represent/include the chemical composition of the Hub.
4. First Aid Measures
Incaseofinhalation: Provide fresh air. If you feel unwell , seek medical adivce.
Followingskincontact: Remove residue with soap and water. In case of skin reactions, consult a physician.
Aftereyecontact: Immediately flush eyes with plenty of flowing water for 10 to 15 minutes holding eyelids apart.
Remove contact lenses, if present and easy to do. Continue rinsing. In case of eye irritation consult an ophthalmologist.
Afterswallowing: Rinse mouth with water. Give water to drink in small sips. If you feel unwell, seek medical advice.
Mostimportantsymptomsandeffects,bothacuteanddelayed
Causes serious eye irritation. Causes damage to organs through prolonged or repeated exposure.
Informationtophysician Treat Symptomatically.
SAFETY DATA SHEET (SDS)
Coated Abrasives
Revision Date: 1/2/2019 Version: 1
Flash point/Flash point range:
Auto-ignition Temperature:
Suitable extinguishing media:
Specific hazards arising from the chemical:
Protective equipment and precautions for firefighters:
Wear a self-contained breathing apparatus and chemical protective clothing.
Additional information
Do not allow fire water to penetrate into surface or ground water.
Personal precautions:
Avoid exposure. Avoid generation of dust. Do not inhale substance. In case of heating: Development of gas/vapor possible. Provide adequate ventilation. Wear appropriate protective equipment Avoid contact with the substance. Keep unprotected people away.
Environmental precautions:
Do not allow to penetrate into soil, waterbodies or drains. In case of release, notify competent authorities.
Methods for clean up:
Take up mechanically, placing in appropriate containers for disposal
No data availabe No data availabe Product is non-combustible. Extinguishing material should therefore be selected according to surroundings.
Can be released in case of fire: Hydrogen fluoride, boron compounds, carbon monoxide, and carbon dioxide (CO2).
Date of Print: 1/17/2019
Page: 4 of 14
5. Fire Fighting Measures
6. Accidental Release Measures
Handling
Advice on safe handlling:
Provide adequate ventilation, and local exhaust as needed. Avoid generation of dust. In case of heating: Development of gas/vapor possible. Do not inhale substance. Wear appropriate protective equipment. Avoid contact with the substance. Obtain special instructions before use. Work place should be equipped with a shower and an eye rinsing apparatus.
Storage
Requirements for storerooms and containers:
Keep container tightly closed and dry. Keep in cool, well-ventilated place.
Hints on joint storage:
Do not store together with oxidizing agents or acids. Do not store together wih food.
7. Handling and Storage
SAFETY DATA SHEET (SDS)
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Coated Abrasives
Revision Date: 1/2/2019 Version: 1
8. Exposure Control / Personal Protection
Exposure guidelines
Occupational exposure limit values:
CAS NO.
1334-28-1 Aluminium oxide Canada, Alberta: OEL 8 hour
409-21-2 Silicon carbide Canada, Alberta: OEL 8 hour
Designation Typ
Canada. Quebec: VEMP USA: OSHA: TWA USA: OSHA: TWA
Canada, Alberta: OEL 8 hour
Canada, Alberta: OEL 8 hour
Canada BC: OEL TWA Canada BC: OEL TWA
Canada BC; OEL TWA
Canada Ontario; OEL TWA Canada Ontario; OEL TWA
Canada, Ontario: OEL TWA
Canada, Quebec: VEMP
USA: ACGIH: TWA USA: ACGIH: TWA USA: ACGIH: TWA USA: NIOSH: TWA USA: NIOSH: TWA USA: OSHA: TWA
USA: OSHA: TWA
Date of Print: 1/17/2019
Limit Value
10 m 10 m 15 m 5m
0.1 fibers/cm 10m
3
/m /m3 (inhalable fraction /m3 (inhalable fraction
/m3 (respirable fraction
3
(fibers, inhalable fraction
3
/m
(contains no fibers, inhalable fraction)
3
3 m
/m
(contains no fibers, respirable fraction)
0.1 fibers/cm 10 m
3
(fibers,inhalable fraction
3
/m
(Contains no fibers, inhalable fraction)
3
3m
/m
(Contains no fibers, respirable fraction)
0.1 fibers/cm 10 m
3
(fibers, inhalable fraction
3
/m
(Contains no fibers, inhalable fraction)
3
3m
/m
(Contains no fibers, respirable fraction)
/m
3
10 m (Contains no fibers, inhalable fraction)
0.1 fibers/cm 10m 3 m 10 m 5 m 15 m
5 mg/m
3
(fibers, inhalable fraction
/m3 (inhalable fraction
/m3 (respirable fration
/m3 (inhalable fraction
/m3 (respirable fraction
/m3 (inhalable fraction
3
(respirable fraction)
Page: 5 of 14
65997.17-3 Fiber glass weaves Canada, Alberta: OEL 8 hour
Canada, Alberta: OEL 8 hour
Canada, BC: OEL TWA
Canada, BC: OEL TWA
Canada, Ontario: OEL TWA
Canada, Ontario: OEL TWA
Canada, Quebec: VEMP
1 fibers/cm
3
Glass Fibers, continuous filament
3
5 m
/m Glass Fibers, continuous filament, Glass wool, inhalable fraction
1 fibers/cm
3
Synthetic Vitreous Fibers-Continous filament glass fibers
3
5 m
/m Synthetic Vitreous Fibers-Continous filament glass fibers; inhalable fraction
1 fibers/cm
3
Synthetic Vitreous Fibers-Continous filament glass fibers
3
5 m
/m Synthetic Vitreous Fibers (Man Made Mineral Fibers), Continuous filament glass fibers
/m
3
10 m Continuous filament glass fibers Pt note 1
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