Page 1/12
Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 07.11.2013 Revision: 07.11.2013
1 Identification of the substance/mixture and of the company/undertaking
·
1.1 Product identifier
·
Trade name: SUPCO 88
·
Article number:
·
1.2 Relevant identified uses of the substance or mixture and uses advised against
No further relevant information available.
·
Application of the substance / the mixture
·
1.3 Details of the supplier of the Safety Data Sheet
·
Manufacturer/Supplier:
Highside Chemicals, Inc.
11114 Reichold Road
Gulfport, MS 39503 USA
Phone: (228) 896-9220
·
1.4 Emergency telephone number:
ChemTel Inc.
(800)255-3924, +1 (813)248-0585
supco88
Oil additive.
2 Hazards identification
·
2.1 Classification of the substance or mixture
·
Classification according to Regulation (EC) No 1272/2008
GHS02 flame
Flam. Liq. 3 H226 Flammable liquid and vapour.
GHS08 health hazard
Carc. 1B H350 May cause cancer.
Asp. Tox. 1 H304 May be fatal if swallowed and enters airways.
GHS07
Acute Tox. 4 H332 Harmful if inhaled.
·
Classification according to Directive 67/548/EEC or Directive 1999/45/EC
Xn; Harmful
R65: Harmful: may cause lung damage if swallowed.
R10: Flammable.
·
Information concerning particular hazards for human and environment:
The product has to be labelled due to the calculation procedure of the "General Classification guideline for
preparations of the EU" in the latest valid version.
(Contd. on page 2)
37.1.11
Page 2/12
Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 07.11.2013 Revision: 07.11.2013
Trade name: SUPCO 88
(Contd. of page 1)
·
Classification system:
The classification is according to the latest editions of the EU-lists, and extended by company and
literature data.
The classification is in accordance with the latest editions of international substances lists, and is
supplemented by information from technical literature and by information provided by the company.
·
2.2 Label elements
·
Labelling according to Regulation (EC) No 1272/2008
The product is classified and labelled according to the CLP regulation.
·
Hazard pictograms
GHS02 GHS07 GHS08
·
Signal word
·
Hazard-determining components of labelling:
Distillates (petroleum), hydrotreated heavy naphthenic
Kerosine (petroleum), hydrodesulfurized
dibenzyl disulphide
·
Hazard statements
H226 Flammable liquid and vapour.
H332 Harmful if inhaled.
H350 May cause cancer.
H304 May be fatal if swallowed and enters airways.
·
Precautionary statements
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P281 Use personal protective equipment as required.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P370+P378 In case of fire: Use foam, powder, or carbon dioxide for extinction.
P331 Do NOT induce vomiting.
P403+P235 Store in a well-ventilated place. Keep cool.
P501 Dispose of contents/container in accordance with local/regional/national/inter national
·
Additional information:
Restricted to professional users.
·
Hazard description:
·
WHMIS-symbols:
B3 - Combustible liquid
Danger
regulations.
·
NFPA ratings (scale 0 - 4)
Health = 0
020
37.1.11
Fire = 2
Reactivity = 0
(Contd. on page 3)
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 07.11.2013 Revision: 07.11.2013
Trade name: SUPCO 88
(Contd. of page 2)
·
HMIS-ratings (scale 0 - 4)
HEALTH
FIRE
REACTIVITY
*0
Health = *0
2
Fire = 2
0
Reactivity = 0
* - Indicates a long term health hazard from repeated or prolonged exposures.
·
HMIS Long Term Health Hazard Substances
None of the ingredients is listed.
·
2.3 Other hazards
·
Results of PBT and vPvB assessment
·
PBT:
Not applicable.
·
vPvB:
Not applicable.
3 Composition/information on ingredients
·
3.2 Mixtures
·
Description:
·
Dangerous components:
CAS: 64742-81-0
EINECS: 265-184-9
Index number: 649-423-00-8
CAS: 150-60-7
EINECS: 205-764-0
·
Additional information:
Mixture of substances listed below with nonhazardous additions.
Kerosine (petroleum), hydrodesulfurized
Xn R65
Flam. Liq. 3, H226
Asp. Tox. 1, H304
dibenzyl disulphide
Xn R20; Xi R37
Acute Tox. 4, H332; STOT SE 3, H335
For the wording of the listed risk phrases refer to section 16.
25-50%
<10%
4 First aid measures
·
4.1 Description of first aid measures
·
General information:
Immediately remove any clothing soiled by the product.
Take affected persons out into the fresh air.
·
After inhalation:
Supply fresh air; consult doctor in case of complaints.
Provide oxygen treatment if affected person has difficulty breathing.
In case of irregular breathing or respiratory arrest provide artificial respiration.
In case of unconsciousness place patient stably in side position for transportation.
·
After skin contact:
Immediately wash with water and soap and rinse thoroughly.
If skin irritation continues, consult a doctor.
·
After eye contact:
Remove contact lenses if worn.
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
37.1.11
(Contd. on page 4)
Page 4/12
Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 07.11.2013 Revision: 07.11.2013
Trade name: SUPCO 88
(Contd. of page 3)
·
After swallowing:
Rinse out mouth and then drink plenty of water.
Do not induce vomiting; call for medical help immediately.
A person vomiting while laying on their back should be turned onto their side.
·
4.2 Most important symptoms and effects, both acute and delayed
Cramp
Acne
Nausea
Unconsciousness
Dizziness
Breathing difficulty
Coughing
·
Hazards
Danger of pulmonary oedema.
Danger of impaired breathing.
·
4.3 Indication of any immediate medical attention and special treatment needed
If swallowed or in case of vomiting, danger of entering the lungs.
Medical supervision for at least 48 hours.
If necessary oxygen respiration treatment.
Later observation for pneumonia and pulmonary oedema.
5 Firefighting measures
·
5.1 Extinguishing media
·
Suitable extinguishing agents:
Water haze or fog
Foam
Fire-extinguishing powder
Carbon dioxide
·
For safety reasons unsuitable extinguishing agents:
Water with full jet
Water spray
·
5.2 Special hazards arising from the substance or mixture
Formation of toxic gases is possible during heating or in case of fire.
·
5.3 Advice for firefighters
·
Protective equipment:
Wear self-contained respiratory protective device.
Wear fully protective suit.
·
Additional information
Eliminate all ignition sources if safe to do so.
Use large quantities of foam as it is partially destroyed by the product.
Cool endangered receptacles with water fog or haze.
6 Accidental release measures
·
6.1 Personal precautions, protective equipment and emergency procedures
Use respiratory protective device against the effects of fumes/dust/aerosol.
(Contd. on page 5)
37.1.11
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 07.11.2013 Revision: 07.11.2013
Trade name: SUPCO 88
(Contd. of page 4)
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Keep away from ignition sources.
Protect from heat.
Particular danger of slipping on leaked/spilled product.
·
6.2 Environmental precautions:
Prevent from spreading (e.g. by damming-in or oil barriers).
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water.
·
6.3 Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Remove from the water surface (e.g. skim or suck off).
Dispose contaminated material as waste according to item 13.
Do not flush with water or aqueous cleansing agents
·
6.4 Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
7 Handling and storage
·
7.1 Precautions for safe handling
Prevent formation of aerosols.
Avoid the formation of oil haze.
Use only in well ventilated areas.
·
Information about fire - and explosion protection:
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
Protect from heat.
When heated the product forms flammable fumes.
Flammable gas-air mixtures may form in empty receptacles.
·
7.2 Conditions for safe storage, including any incompatibilities
·
Storage:
·
Requirements to be met by storerooms and receptacles:
Provide ventilation for receptacles.
Avoid storage near extreme heat, ignition sources or open flame.
Use only receptacles specifically permitted for this substance/product.
·
Information about storage in one common storage facility:
Store away from foodstuffs.
Store away from oxidizing agents.
·
Further information about storage conditions:
·
7.3 Specific end use(s)
No further relevant information available.
Store in cool, dry conditions in well sealed receptacles.
8 Exposure controls/personal protection
·
Additional information about design of technical facilities:
37.1.11
No further data; see item 7.
(Contd. on page 6)
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 07.11.2013 Revision: 07.11.2013
Trade name: SUPCO 88
(Contd. of page 5)
·
8.1 Control parameters
·
Ingredients with limit values that require monitoring at the workplace:
64742-81-0 Kerosine (petroleum), hydrodesulfurized
REL (USA) Long-term value: 100 mg/m³
Kerosene only
TLV (USA) Long-term value: 200 mg/m³
as total hydrocarbon vapor; Skin; P
EV (Canada) Long-term value: 200(G) mg/m³
as total hydrocarbon vapour, Skin
·
DNELs
·
PNECs
·
Additional information:
·
8.2 Exposure controls
·
Personal protective equipment:
·
General protective and hygienic measures:
The usual precautionary measures are to be adhered to when handling chemicals.
Keep away from foodstuffs, beverages and feed.
Wash hands before breaks and at the end of work.
Do not inhale gases / fumes / aerosols.
Avoid contact with the eyes and skin.
·
Respiratory protection:
Use suitable respiratory protective device in case of insufficient ventilation.
Use suitable respiratory protective device when aerosol or mist is formed.
For spills, respiratory protection may be advisable.
NIOSH approved organic vapor respirator equipped with a dust/mist prefilter should be used.
·
Protection of hands:
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove m aterial on consideration of the penetration times, rates of diffusion and the
degradation.
·
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of
quality and varies from manufacturer to manufacturer. As the product is a preparation of several
substances, the resistance of the glove material can not be calculated in advance and has therefore to be
checked prior to the application.
·
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to
be observed.
·
For the permanent contact gloves made of the following materials are suitable:
Butyl rubber, BR
Nitrile rubber, NBR
Neoprene gloves
·
Eye protection:
No further relevant information available.
No further relevant information available.
The lists valid during the making were used as basis.
Safety glasses
(Contd. on page 7)
37.1.11
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 07.11.2013 Revision: 07.11.2013
Trade name: SUPCO 88
(Contd. of page 6)
·
Body protection:
·
Limitation and supervision of exposure into the environment
No further relevant information available.
·
Risk management measures
See Section 7 for additional information.
No further relevant information available.
9 Physical and chemical properties
·
9.1 Information on basic physical and chemical properties
·
General Information
·
Appearance:
Form:
Colour:
·
Odour:
·
Odour threshold:
·
pH-value:
·
Change in condition
Melting point/Melting range:
Boiling point/Boiling range:
·
Flash point:
·
Flammability (solid, gaseous):
·
Ignition temperature:
·
Decomposition temperature:
·
Self-igniting:
·
Danger of explosion:
·
Explosion limits:
Lower:
Upper:
·
Vapour pressure at 20 °C:
·
Density at 20 °C:
·
Relative density
·
Vapour density at 20 °C
·
Evaporation rate at 20 °C
·
Solubility in / Miscibility with
water:
·
Partition coefficient (n-octanol/water):
Oil resistant protective clothing
Liquid
Light brown
Petroleum-like
Not determined.
Not determined.
Undetermined.
304 °F / 151 °C
130 °F / 54 °C
Not applicable.
410 °F / 210 °C
Not determined.
Product is not self-igniting.
Product is not explosive. However, formation of explosive air/
vapour mixtures are possible.
0,7 Vol %
5,0 Vol %
0,1 mmHg
0,851 g/cm³
Not determined.
>1 (AIR = 1)
<1 (Butyl acetate = 1)
Not miscible or difficult to mix.
Not determined.
(Contd. on page 8)
37.1.11
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 07.11.2013 Revision: 07.11.2013
Trade name: SUPCO 88
(Contd. of page 7)
·
Viscosity:
Dynamic at 40 °C:
Kinematic:
·
9.2 Other information
10 Stability and reactivity
·
10.1 Reactivity
·
10.2 Chemical stability
·
Thermal decomposition / conditions to be avoided:
No decomposition if used and stored according to specifications.
·
10.3 Possibility of hazardous reactions
Flammable.
Used empty containers may contain product gases which form explosive mixtures with air.
Can form explosive mixtures in air if heated above flash point and/or when sprayed or atomised.
Toxic fumes may be released if heated above the decomposition point.
Can react violently with oxygen rich (oxidizing) material. Danger of Explosion.
·
10.4 Conditions to avoid
Keep ignition sources away - Do not smoke.
Store away from oxidizing agents.
·
10.5 Incompatible materials:
·
10.6 Hazardous decomposition products:
Hydrocarbons
Carbon monoxide and carbon dioxide
No further relevant information available.
2,0 mPas
Not determined.
No further relevant information available.
11 Toxicological information
·
11.1 Information on toxicological effects
·
Acute toxicity:
·
LD/LC50 values relevant for classification:
64742-52-5 Distillates (petroleum), hydrotreated heavy naphthenic
Oral LD50 >5000 mg/kg (rat)
Dermal LD50 >5000 mg/kg (rabbit)
Inhalative LC50/4h 5 mg/l (rat)
·
Primary irritant effect:
·
on the skin:
·
on the eye:
·
Sensitization:
·
Additional toxicological information:
The product shows the following dangers according to the calculation m ethod of the General EU
Classification Guidelines for Preparations as issued in the latest version:
Inhalation of concentrated vapours as well as oral intake will lead to anaesthesia-like conditions and
headache, dizziness, etc.
Slight irritant effect on skin and mucous membranes.
Slight irritant effect on eyes.
No sensitizing effects known.
(Contd. on page 9)
37.1.11
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 07.11.2013 Revision: 07.11.2013
Trade name: SUPCO 88
(Contd. of page 8)
Carcinogenic.
·
Repeated dose toxicity:
·
CMR effects (carcinogenity, mutagenicity and toxicity for reproduction):
Carc. 1B
12 Ecological information
·
12.1 Toxicity
·
Aquatic toxicity:
·
12.2 Persistence and degradability
·
12.3 Bioaccumulative potential
·
12.4 Mobility in soil
·
Ecotoxical effects:
·
Remark:
·
Additional ecological information:
·
General notes:
Due to mechanical actions of the product (e.g. agglutinations) damages may occur.
Water hazard class 3 (German Regulation) (Self-assessment): extremely hazardous for water
Do not allow product to reach ground water, water course or sewage system, even in small quantities.
Danger to drinking water if even extremely small quantities leak into the ground.
Harmful to aquatic organisms
Due to available data on eliminability/decomposition and bioaccum ulation potential prolonged term
damage of the environment can not be excluded.
Avoid transfer into the environment.
·
12.5 Results of PBT and vPvB assessment
·
PBT:
Not applicable.
·
vPvB:
·
12.6 Other adverse effects
Not applicable.
The material is harmful to the environment.
May cause damage to organs through prolonged or repeated exposure .
The product is partially biodegradable. Significant residuals remain.
No further relevant information available.
No further relevant information available.
No further relevant information available.
13 Disposal considerations
·
13.1 Waste treatment methods
·
Recommendation
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
Product is recyclable as a waste oil. Deliver unused and/or contaminated product to waste oil collectors.
After prior treatment product has to be disposed of in an incinerator for hazardous waste adhering to the
regulations pertaining to the disposal of particularly hazardous waste.
·
Uncleaned packaging:
·
Recommendation:
Disposal must be made according to official regulations.
14 Transport information
·
14.1 UN-Number
·
DOT
37.1.11
N/A
Classified as combustible under US DOT regulations.
Labeling required for single packages≥119 US gal /
(Contd. on page 10)
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 07.11.2013 Revision: 07.11.2013
Trade name: SUPCO 88
(Contd. of page 9)
·
·
ADR, IMDG, IATA
·
14.2 UN proper shipping name
·
DOT
·
ADR
·
IMDG, IATA
·
14.3 Transport hazard class(es)
·
DOT
·
Class
·
ADR
450 L to include Combustible symbol and Proper
Shipping Name.
UN1268
N/A
FLAMMABLE LIQUID, N.O.S. (Kerosine (petroleum),
hydrodesulfurized)
1268 PETROLEUM PRODUCTS, N.O.S.
PETROLEUM PRODUCTS, N.O.S.
N/A
·
Class
·
Label
·
IMDG, IATA
·
Class
·
Label
·
14.4 Packing group
·
DOT
·
ADR, IMDG, IATA
·
14.5 Environmental hazards:
·
Marine pollutant:
·
14.6 Special precautions for user
·
Danger code (Kemler):
·
EMS Number:
·
14.7 Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code
·
Transport/Additional information:
·
ADR
·
Limited quantities (LQ)
·
Transport category
3 (F1) Flammable liquids.
3
3 Flammable liquids.
3
N/A
III
No
Warning: Flammable liquids.
30
F-E,S-E
Not applicable.
5L
3
(Contd. on page 11)
37.1.11
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 07.11.2013 Revision: 07.11.2013
Trade name: SUPCO 88
(Contd. of page 10)
·
Tunnel restriction code
·
UN "Model Regulation":
15 Regulatory information
·
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
·
United States (USA)
·
SARA
·
Section 355 (extremely hazardous substances):
None of the ingredients is listed.
·
Section 313 (Specific toxic chemical listings):
None of the ingredients is listed.
·
TSCA (Toxic Substances Control Act):
All ingredients are listed.
·
Proposition 65 (California):
·
Chemicals known to cause cancer:
Listed under a chemical family; not directly listed by CAS : 64742-94-5.
64742-94-5 Solvent naphtha (petroleum), heavy arom.
91-20-3 naphthalene
·
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
·
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
·
Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
·
Carcinogenic Categories
·
EPA (Environmental Protection Agency)
None of the ingredients is listed.
·
IARC (International Agency for Research on Cancer)
None of the ingredients is listed.
·
TLV (Threshold Limit Value established by ACGIH)
64742-81-0 Kerosine (petroleum), hydrodesulfurized A3
·
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
·
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
D/E
UN1993, F LAMMABL E LIQ UID, N.O.S. (Kerosine
(petroleum), hydrodesulfurized), 3, III
(Contd. on page 12)
37.1.11
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 07.11.2013 Revision: 07.11.2013
Trade name: SUPCO 88
(Contd. of page 11)
·
Canada
·
Canadian Domestic Substances List (DSL)
All ingredients are listed.
·
Canadian Ingredient Disclosure list (limit 0.1%)
None of the ingredients is listed.
·
Canadian Ingredient Disclosure list (limit 1%)
150-60-7 dibenzyl disulphide
·
15.2 Chemical safety assessment:
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
·
Relevant phrases
H226 Flammable liquid and vapour.
H304 May be fatal if swallowed and enters airways.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
R20 Harmful by inhalation.
R37 Irritating to respiratory system.
R65 Harmful: may cause lung damage if swallowed.
·
Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the
International Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
WHMIS: Workplace Hazardous Materials Information System (Canada)
DNEL: Derived No-Effect Level (REACH)
PNEC: Predicted No-Effect Concentration (REACH)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
·
Sources
SDS Prepared by:
ChemTel Inc.
1305 North Florida Avenue
Tampa, Florida USA 33602-2902
Toll Free North America 1-888-255-3924 Intl. +01 813-248-0573
Website: www.chemtelinc.com
A Chemical Safety Assessment has not been carried out.
37.1.11
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